CN104630809A - Novel room temperature efficient treatment agent suitable for metal surface, and use method thereof - Google Patents
Novel room temperature efficient treatment agent suitable for metal surface, and use method thereof Download PDFInfo
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- CN104630809A CN104630809A CN201310554108.0A CN201310554108A CN104630809A CN 104630809 A CN104630809 A CN 104630809A CN 201310554108 A CN201310554108 A CN 201310554108A CN 104630809 A CN104630809 A CN 104630809A
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- triethylamine
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention provides a novel room temperature efficient treatment agent suitable for the metal surface, and a use method thereof. The novel room temperature efficient treatment agent comprises amino sulfonic acid, ethylene oxide, butyl acetate, alkyl phenol polyoxyethylene ether and triethylamine, and specifically comprises, by mass, 10-15 parts of amino sulfonic acid, 1-5 parts of ethylene oxide, 3-8 parts of butyl acetate, 3-8 parts of alkyl phenol polyoxyethylene ether, 3-9 parts of triethylamine, and 55-80 parts of water. According to the present invention, when the novel room temperature efficient treatment agent is used to clean a work-piece, only the work-piece to be treated is required to be dipped in the treatment liquid, and is taken out after 30 min, and the treatment liquid has the low skin corrosion, such that the operation can be performed by hands, and convenience and rapidness are provided; the work-piece is taken out from the treatment liquid, the residual treatment liquid on the surface is wiped out, and the work-piece surface still has the original gloss; and in addition, the product of the present invention has characteristics of strong detergency, quickly metal surface dirt removing, no work-piece corrosion, a certain anti-rust function, no toxicity, no irritating odor, and environmental protection.
Description
Technical field
The present invention relates to electrochemical deoiling scale remover field, be specially a kind of new and effective treatment agent of normal temperature and the using method thereof that are applicable to metallic surface.
Background technology
From the eighties in 20th century, people adopt acid degreasing agent at room temperature degreasing.Containing a large amount of pollutent such as nitric acid, hydrofluoric acid, chromic salt in this technique tank liquor, the Sustainable development of human health and environment is caused and has a strong impact on.The grease-removing agent of safe and reliable, the decreasing pollution of development of new, the feature such as simple to operate has become the main direction of studying of present clean-out system.
Summary of the invention
Technical problem solved by the invention is to provide a kind of new and effective treatment agent of normal temperature and the using method thereof that are applicable to metallic surface, to solve the problem in above-mentioned background technology.
Technical problem solved by the invention realizes by the following technical solutions: a kind of new and effective treatment agent of normal temperature and using method thereof being applicable to metallic surface, its composition comprises: thionamic acid, oxyethane, butylacetate, alkylphenol polyoxyethylene, triethylamine, its concrete quality proportioning is: thionamic acid: 10 ~ 15 parts, propylene oxide: 1 ~ 5 part, butylacetate: 3 ~ 8 parts, alkylphenol polyoxyethylene: 3 ~ 8 parts, triethylamine: 3 ~ 9 parts, water: 55 ~ 80 parts.
Its composition quality proportioning of described efficient treatment agent is: thionamic acid: 10 parts, propylene oxide: 4 parts, butylacetate: 4 parts, alkylphenol polyoxyethylene: 5 parts, triethylamine: 7 parts, water: 70 parts.
Described efficient treatment agent preparation method is: in reactor, add water, thionamic acid, propylene oxide, butylacetate, alkylphenol polyoxyethylene, triethylamine successively, normal temperature and pressure, reaction times is 20 ~ 50 minutes, be uniformly mixed simultaneously, occur without caking phenomenon, discharging, draws finished product.
Treatment agent of the present invention has a wide range of applications in industries such as aerospace, electronics, automobile, building, bridge, nuclear industry and weapon industries.
Compared with current public technology, there is following advantage in the present invention: when using the present invention to clean workpiece, only need be immersed in treatment solution by pending, take out after 30 minutes, because treatment solution is very little to the corrodibility of skin, can free-handly operate, convenient and swift.Taken out from treatment solution by workpiece, the treatment solution cleaning surface remains, and workpiece surface still has original gloss.In addition, product strong detergency of the present invention can remove rapidly metallic surface dirt, do not corrode workpiece and have certain antirust function, nontoxic, have no irritating odor, environmental protection.
Embodiment
Object is reached and effect is easy to understand in order to make technique means of the present invention, creation characteristic, workflow, using method, below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
A kind of new and effective treatment agent of normal temperature and using method thereof being applicable to metallic surface, its composition comprises: thionamic acid, oxyethane, butylacetate, alkylphenol polyoxyethylene, triethylamine, its concrete quality proportioning is: thionamic acid: 10 ~ 15 parts, propylene oxide: 1 ~ 5 part, butylacetate: 3 ~ 8 parts, alkylphenol polyoxyethylene: 3 ~ 8 parts, triethylamine: 3 ~ 9 parts, water: 55 ~ 80 parts.
Described efficient treatment agent preparation method is: in reactor, add water, thionamic acid, propylene oxide, butylacetate, alkylphenol polyoxyethylene, triethylamine successively, normal temperature and pressure, reaction times is 20 ~ 50 minutes, be uniformly mixed simultaneously, occur without caking phenomenon, discharging, draws finished product.
Embodiment 1
Get in mass ratio: thionamic acid: 15 parts, propylene oxide: 5 parts, butylacetate: 8 parts, alkylphenol polyoxyethylene: 8 parts, triethylamine: 9 parts, water: 55 parts of hybrid reaction 30min both obtained finished product, reaching cleaning performance and foam is less, producing, for cleaning cold-rolling mild steel plate without precipitation.
Embodiment 2
Get in mass ratio: thionamic acid: 12 parts, propylene oxide: 5 parts, butylacetate: 6 parts, alkylphenol polyoxyethylene: 5 parts, triethylamine: 8 parts, water: 64 parts, hybrid reaction 30min both obtained finished product, reaching cleaning performance and foam is less, producing, for cleaning carbon steel part without precipitation.
Embodiment 3
Get in mass ratio: thionamic acid: 7 parts, propylene oxide: 3 parts, butylacetate: 3 parts, alkylphenol polyoxyethylene: 3 parts, triethylamine: 4 parts, water: 80 parts, hybrid reaction 40min both obtained finished product, reaching cleaning performance and foam is less, producing, for cleaning thin aluminum sheet without precipitation.
Embodiment 4
Get in mass ratio: thionamic acid: 10 parts, propylene oxide: 4 parts, butylacetate: 4 parts, alkylphenol polyoxyethylene: 4 parts, triethylamine: 8 parts, water: 70 parts, hybrid reaction 30min both obtained finished product, reaching cleaning performance and foam is less, producing, for cleaning brass part without precipitation.
When using the present invention to clean workpiece, only need pending be immersed in treatment solution, take out after 30 minutes, because treatment solution is very little to the corrodibility of skin, can free-handly operating, convenient and swift.Taken out from treatment solution by workpiece, the treatment solution cleaning surface remains, and workpiece surface still has original gloss.In addition, product strong detergency of the present invention can remove rapidly metallic surface dirt, do not corrode workpiece and have certain antirust function, nontoxic, have no irritating odor, environmental protection.
More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (3)
1. one kind is applicable to the new and effective treatment agent of normal temperature and the using method thereof of metallic surface, its composition comprises: thionamic acid, oxyethane, butylacetate, alkylphenol polyoxyethylene, triethylamine, it is characterized in that: its concrete quality proportioning is: thionamic acid: 10 ~ 15 parts, propylene oxide: 1 ~ 5 part, butylacetate: 3 ~ 8 parts, alkylphenol polyoxyethylene: 3 ~ 8 parts, triethylamine: 3 ~ 9 parts, water: 55 ~ 80 parts.
2. a kind of new and effective treatment agent of normal temperature and using method thereof being applicable to metallic surface according to claim 1, it is characterized in that: described efficient treatment agent preparation method is: in reactor, add water, thionamic acid, propylene oxide, butylacetate, alkylphenol polyoxyethylene, triethylamine successively, normal temperature and pressure, reaction times is 20 ~ 50 minutes, be uniformly mixed simultaneously, occur without caking phenomenon, discharging, draws finished product.
3. a kind of new and effective treatment agent of normal temperature and using method thereof being applicable to metallic surface according to claim 1, it is characterized in that: its composition quality proportioning of described efficient treatment agent is: thionamic acid: 10 parts, propylene oxide: 4 parts, butylacetate: 4 parts, alkylphenol polyoxyethylene: 5 parts, triethylamine: 7 parts, water: 70 parts.
Priority Applications (1)
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CN201310554108.0A CN104630809A (en) | 2013-11-11 | 2013-11-11 | Novel room temperature efficient treatment agent suitable for metal surface, and use method thereof |
Applications Claiming Priority (1)
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CN201310554108.0A CN104630809A (en) | 2013-11-11 | 2013-11-11 | Novel room temperature efficient treatment agent suitable for metal surface, and use method thereof |
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CN104630809A true CN104630809A (en) | 2015-05-20 |
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CN201310554108.0A Pending CN104630809A (en) | 2013-11-11 | 2013-11-11 | Novel room temperature efficient treatment agent suitable for metal surface, and use method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1861774A (en) * | 2006-06-05 | 2006-11-15 | 太仓市宝马环境工程有限公司 | Degreased cleaning agent |
JP2009084390A (en) * | 2007-09-28 | 2009-04-23 | Dai Ichi Kogyo Seiyaku Co Ltd | Metal cleaning agent composition and metal cleaning agent |
CN103046061A (en) * | 2012-12-22 | 2013-04-17 | 黄山金瑞泰科技有限公司 | Cleaning agent for development equipment and use method thereof |
-
2013
- 2013-11-11 CN CN201310554108.0A patent/CN104630809A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1861774A (en) * | 2006-06-05 | 2006-11-15 | 太仓市宝马环境工程有限公司 | Degreased cleaning agent |
JP2009084390A (en) * | 2007-09-28 | 2009-04-23 | Dai Ichi Kogyo Seiyaku Co Ltd | Metal cleaning agent composition and metal cleaning agent |
CN103046061A (en) * | 2012-12-22 | 2013-04-17 | 黄山金瑞泰科技有限公司 | Cleaning agent for development equipment and use method thereof |
Non-Patent Citations (1)
Title |
---|
尤凯尔逊著: "《基本有机合成工艺学》", 31 January 1960 * |
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