CN104613241A - High-strength metal composite tube - Google Patents

High-strength metal composite tube Download PDF

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Publication number
CN104613241A
CN104613241A CN201410711342.4A CN201410711342A CN104613241A CN 104613241 A CN104613241 A CN 104613241A CN 201410711342 A CN201410711342 A CN 201410711342A CN 104613241 A CN104613241 A CN 104613241A
Authority
CN
China
Prior art keywords
metal composite
high strength
composite pipe
accounts
reinforced plastics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410711342.4A
Other languages
Chinese (zh)
Inventor
施建东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU DONGTAO METAL COMPOSITE MATERIAL Co Ltd
Original Assignee
CHANGSHU DONGTAO METAL COMPOSITE MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGSHU DONGTAO METAL COMPOSITE MATERIAL Co Ltd filed Critical CHANGSHU DONGTAO METAL COMPOSITE MATERIAL Co Ltd
Priority to CN201410711342.4A priority Critical patent/CN104613241A/en
Publication of CN104613241A publication Critical patent/CN104613241A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/04Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/38Layered products comprising a layer of synthetic resin comprising epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/42Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/10Coatings characterised by the materials used by rubber or plastics

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

The invention discloses a high-strength metal composite tube. The high-strength metal composite tube is composed of coating glass reinforced plastic, base-layer base material and composite-layer quartz sand. The glass reinforced plastic is fiberglass reinforced plastic or epoxy reinforced plastic or phenolic reinforced plastic. The base material comprises unsaturated polyester, epoxy resin and phenolic resin. The quartz sand comprises silicate and silicon dioxide. The glass reinforced plastic accounts for 61%-79 % the total weight of the high-strength metal composite tube, the base material accounts for 2%-14% total weight of the high-strength metal composite tube, and the quartz sand accounts for 18%-26% the total weight of the high-strength metal composite tube. The high-strength metal composite tube has the advantages of being good in corrosion resistance, wear resistance and high in strength.

Description

The metal composite pipe of high strength
Technical field
The present invention relates to a kind of metal composite pipe of high strength.
Background technique
Phenolic plastic are plastics the most ancient in the world, visible everywhere in daily life.In China, first block of glass fibre reinforced plastics is exactly phenolic fiberglass reinforced plastics, and it grows up with military industrial expansion, replaces high-quality hardwood to make rifle in early days with phenolic fiberglass reinforced plastics.Along with the development of semi-conductor industry, develop again phenolic aldehyde lamination printed circuit plate.Due to its high temperature resistant, fire-retardant, resistance to ablation characteristics, guided missile, satellite are used as the materials such as radome, rocket engine cast, jet pipe.Because this kind of phenol aldehyde glass Steel material all needs High Temperature High Pressure shaping, therefore greatly limit the application development in civilian industry.Unsaturated polyester glass steel due to moulding process easy, thus obtain a wide range of applications in the every field of national economy and develop.Present phenolic resin of new generation is provided with the moulding process similar to unsaturated polyester, thus its application is greatly extended, sum up it and have 3 large features: one is high flame retardant, not only require that oxygen index wants high by modern fire requirement, and require that smoke density is low, toxicity is little, Novel phenolic glass fibre reinforced plastics oxygen index can reach more than 80, and smoke density only has 3/1000ths, only about 0.3 of unsaturated polyester; Two is that heatproof is high, and its heat distortion temperature is greater than 250 degree, and under 180 degree, flexural strength conservation rate keeps 85%, vinylite flexural strength conservation rate ability about 30% under 150 degree that current heatproof is the highest; Three is that acid resistance is good, and someone says that phenolic fiberglass reinforced plastics is " acidproof king ", and it is except nitric acid, hydrofluoric acid, 98% sulfuric acid, and 100% glacial acetic acid is all resistance to.Require the occasion of high flame retardant, the cost ratio flame retardant type unsaturated polyester of phenolic resin and furan want considerably cheaper, and therefore Novel phenolic glass fibre reinforced plastics will have extremely wide application prospect.
Summary of the invention
The invention provides a kind of metal composite pipe with the high strength of the good and intensity high advantage of corrosion resistance, wear resistance.
Technological scheme of the present invention is: a kind of metal composite pipe of high strength, the metal composite pipe of described high strength comprises the glass fibre reinforced plastics of coating, the body material of basic unit and the silica sand of cladding combine, described glass fibre reinforced plastics is organic toughened glass, fiber glass epoxy or phenolic fiberglass reinforced plastics, described body material comprises unsaturated polyester, epoxy resin and phenolic resin, described silica sand comprises silicate and silica, described glass fibre reinforced plastics accounts for the 61%-79% of the overall component of metal composite pipe of high strength, described body material accounts for the 2%-14% of the overall component of metal composite pipe of high strength, described silica sand accounts for the 18%-26% of the overall component of metal composite pipe of high strength.
In a preferred embodiment of the present invention, described phenolic fiberglass reinforced plastics comprises phenolic resin and glass fibre.
In a preferred embodiment of the present invention, described glass fibre reinforced plastics accounts for 74% of the overall component of metal composite pipe of high strength, described body material accounts for 2% of the overall component of metal composite pipe of high strength, and described silica sand accounts for 24% of the overall component of metal composite pipe of high strength.
The metal composite pipe of a kind of high strength of the present invention, has corrosion resistance, wear resistance is good and intensity is high advantage.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Wherein, the metal composite pipe of described high strength comprises the glass fibre reinforced plastics of coating, the body material of basic unit and the silica sand of cladding combine, described glass fibre reinforced plastics is organic toughened glass, fiber glass epoxy or phenolic fiberglass reinforced plastics, described body material comprises unsaturated polyester, epoxy resin and phenolic resin, described silica sand comprises silicate and silica, described glass fibre reinforced plastics accounts for the 61%-79% of the overall component of metal composite pipe of high strength, described body material accounts for the 2%-14% of the overall component of metal composite pipe of high strength, described silica sand accounts for the 18%-26% of the overall component of metal composite pipe of high strength, described phenolic fiberglass reinforced plastics comprises phenolic resin and glass fibre.
Further illustrate, described glass fibre reinforced plastics accounts for 74% of the overall component of metal composite pipe of high strength, and described body material accounts for 2% of the overall component of metal composite pipe of high strength, and described silica sand accounts for 24% of the overall component of metal composite pipe of high strength.
Further illustrating, glass fibre reinforced plastics another name glass fiber reinforced plastic, i.e. fibre-reinforced plastics.Fiber difference according to adopting is divided into glass fiber reinforced composite plastics (GFRP), fibre reinforced composite plastic (CFRP), and boron fiber strengthens composite plastic etc.It as reinforcing material, makes a kind of composite material of body material using glass fibre and goods (glass cloth, band, felt, yarn etc.) thereof with synthetic resin.Fibre reinforced composites are made up of reinforcing fiber and matrix.The diameter of fiber (or whisker) is very little, and generally below 10 μm, defect is less less again, and fracture strain is about within 30/1000ths, is brittle material, easy damaged, ruptures and is corroded.Matrix phase is for fiber, and intensity, modulus are all much lower, but can withstand large strain, often has viscoelasticity and elastoplasticity, is toughness material.The plastic base composite material of glass fiber reinforcement.Because its intensity is equivalent to steel, again containing glass ingredient, also there is the such color and luster of glass, body, corrosion-resistant, electrical insulation, the performance such as heat insulation, as glass, the implication of glass fibre reinforced plastics just refers to the reinforced plastic that reinforcing material made by glass fibre, synthetic resin makes Bond, glass fiber reinforced plastic, expands carbon fiber, boron fiber, aramid fibre, alumina fibre and silicon carbide fiber etc. to by glass fibre.
Further illustrating, quartz has higher fire performance, is industrially often divided into by silica sand: common silica sand, purity quartzite, glass sand, tekite sand and silicon powder etc.Common silica sand, i.e. SiO2 >=90-99% Fe2O3≤0.06-0.02%, refractoriness 1750 DEG C, appearance parts large particle, there is Calusena lansium packing on surface.Common silica sand is generally adopt natural quartz ore, and through fragmentation, washing, dries, a kind of water treatment filter material of postsearch screening; This filtrate has: free from admixture, and without angle, school, density is large, and mechanical strength is high, and the feature that dirt-carrying energy line of force life cycle is long is the ideal material of Water Treatment.Particle size range 5-220 order, can produce by user's requirement granularity.Predominant use: metallurgical, black silicon carbide, glass and glassware, enamel, cast steel, water filtration, sodium silicate, chemical industry, the industries such as spray is noisy.The invention provides a kind of metal composite pipe of high strength, there is corrosion resistance, wear resistance is good and intensity is high advantage.
The specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention, and the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims (3)

1. the metal composite pipe of a high strength, it is characterized in that: the metal composite pipe of described high strength comprises the glass fibre reinforced plastics of coating, the body material of basic unit and the silica sand of cladding combine, described glass fibre reinforced plastics is organic toughened glass, fiber glass epoxy or phenolic fiberglass reinforced plastics, described body material comprises unsaturated polyester, epoxy resin and phenolic resin, described silica sand comprises silicate and silica, described glass fibre reinforced plastics accounts for the 61%-79% of the overall component of metal composite pipe of high strength, described body material accounts for the 2%-14% of the overall component of metal composite pipe of high strength, described silica sand accounts for the 18%-26% of the overall component of metal composite pipe of high strength.
2. the metal composite pipe of high strength according to claim 1, is characterized in that: described phenolic fiberglass reinforced plastics comprises phenolic resin and glass fibre.
3. the metal composite pipe of high strength according to claim 1, it is characterized in that: described glass fibre reinforced plastics accounts for 74% of the overall component of metal composite pipe of high strength, described body material accounts for 2% of the overall component of metal composite pipe of high strength, and described silica sand accounts for 24% of the overall component of metal composite pipe of high strength.
CN201410711342.4A 2014-12-01 2014-12-01 High-strength metal composite tube Pending CN104613241A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410711342.4A CN104613241A (en) 2014-12-01 2014-12-01 High-strength metal composite tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410711342.4A CN104613241A (en) 2014-12-01 2014-12-01 High-strength metal composite tube

Publications (1)

Publication Number Publication Date
CN104613241A true CN104613241A (en) 2015-05-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418134A (en) * 2017-05-14 2017-12-01 南通德瑞森复合材料有限公司 A kind of high strength glass fibre reinforced grid material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1208144A (en) * 1998-07-24 1999-02-17 侯贤忠 GRP-thin wall stainless steel composite pipe and its making process
EP2233816A2 (en) * 2009-03-27 2010-09-29 Perma-Liner Industries, Inc. Scrim-enforced pipe liner
CN202402823U (en) * 2011-12-23 2012-08-29 浙江新世管道股份有限公司 Novel glass fibre-reinforced plastic sand-filled pipe
CN102797916A (en) * 2012-08-16 2012-11-28 广西盛世鸿霞玻璃钢制品有限公司 Multilayer structure glass fiber reinforced plastic tube
CN103307370A (en) * 2013-07-03 2013-09-18 南通市长海实业有限公司 Novel fiber reinforced plastic pipe

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1208144A (en) * 1998-07-24 1999-02-17 侯贤忠 GRP-thin wall stainless steel composite pipe and its making process
EP2233816A2 (en) * 2009-03-27 2010-09-29 Perma-Liner Industries, Inc. Scrim-enforced pipe liner
CN202402823U (en) * 2011-12-23 2012-08-29 浙江新世管道股份有限公司 Novel glass fibre-reinforced plastic sand-filled pipe
CN102797916A (en) * 2012-08-16 2012-11-28 广西盛世鸿霞玻璃钢制品有限公司 Multilayer structure glass fiber reinforced plastic tube
CN103307370A (en) * 2013-07-03 2013-09-18 南通市长海实业有限公司 Novel fiber reinforced plastic pipe

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418134A (en) * 2017-05-14 2017-12-01 南通德瑞森复合材料有限公司 A kind of high strength glass fibre reinforced grid material

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150513

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