CN104610805B - The preparation method of the water color ink binder that a kind of inorganic material is compound with waterborne polyurethane resin - Google Patents
The preparation method of the water color ink binder that a kind of inorganic material is compound with waterborne polyurethane resin Download PDFInfo
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- CN104610805B CN104610805B CN201510019416.2A CN201510019416A CN104610805B CN 104610805 B CN104610805 B CN 104610805B CN 201510019416 A CN201510019416 A CN 201510019416A CN 104610805 B CN104610805 B CN 104610805B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/42—Clays
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The present invention designs water color ink field, in order to solve that existing water color ink drying property is the best and existing water color ink quick dry agent or the technical problem of the inadequate environmental protection of drying retardant, the invention provides the preparation method of a kind of inorganic material water color ink binder compound with waterborne polyurethane resin, including galapectite and the thermal activation of meerschaum, acid activation and silane coupler modified, then i.e. obtain, by compound to the modified inorganic material of gained and waterborne polyurethane resin, the water color ink binder that inorganic material is compound with waterborne polyurethane resin.The water color ink binder that the inorganic material prepared by the inventive method is compound with waterborne polyurethane resin, after being re-dubbed water color ink, the rate of drying of water color ink first quick and back slow, is conducive to printing.The water color ink binder asepsis environment-protecting that simultaneously prepared by the present invention, and due to the filling of inorganic material, also enhance heat resistance and the anti-wear performance of water color ink.
Description
Technical field
The present invention relates to water color ink field, particularly relate to the preparation method of a kind of inorganic material water color ink binder compound with waterborne polyurethane resin.
Background technology
Water color ink is the ink made for solvent with water, specific aqueous high molecular resin, pigment, water and cosolvent etc. are prepared from through physical and chemical process combination.Having compared oiliness and machine solvent type ink, water color ink does not results in the volatilization of a large amount of organic solvent, and toxicity is low, and the healthy impact on direct labor is little, and in the today increasingly paying attention to environmental conservation and health of human body, water color ink has huge development prospect.But, owing to the development of water color ink does not has the full-fledged of solvent type ink, Shortcomings in many performances, such as, water color ink is compared with solvent type ink, its drying property is poor, and the drying property of water color ink, depend on that its binder, the binder of general water color ink are waterborne polyurethane resin resin, waterborne polyurethane resin etc. greatly, the water absorption of these resins is relatively strong, is unfavorable for the turnover of moisture.If water color ink is dried too slow, can cause leaflet underdry, ink adheres on dancing roll, and leaflet tarnishes, and also can affect double exposure effect, cause print quality problem；Water color ink is dried too fast, and easily in printing process, ink has not also been done at printable fabric surface penetration, causes ink to be suspended in printable fabric surface, and adhesive force is deteriorated.Therefore water color ink is in printing process when just spreading out printable fabric surface, and rate of drying wants fast, but when being dried to a certain degree, needs to slow down rate of drying, and being beneficial to water color ink has time enough to penetrate in printable fabric.
Printing is made it easier in order to improve the drying property of water color ink, typically can add drying retardant or quick dry agent in water color ink, general drying retardant or quick dry agent be mainly composed of the organic solvents such as ketone, not only environmental protection not, human body is also harmful to, and for the regulation of water color ink drying property, also accelerate rate of drying the most simply or reduce rate of drying, the drying property required in printing process with water color ink is not inconsistent.
Galapectite and meerschaum belong to inorganic mineral material, the crystal of galapectite is hollow tubular form that is straight or that bend, meerschaum has a layer chain structure, therefore galapectite has microcellular structure with surface and the inside of meerschaum, it it is preferable humidity adjusting material, the aperture of micropore is the biggest, is more conducive to the turnover of moisture, and its moisture releasing performance is the best.
Summary of the invention
In order to solve that existing water color ink drying property is the best and existing water color ink quick dry agent or the technical problem of the inadequate environmental protection of drying retardant, the invention provides the preparation method of a kind of inorganic material water color ink binder compound with waterborne polyurethane resin, water color ink binder prepared by the method can regulate the water color ink drying property when printing the most stage by stage, and asepsis environment-protecting, improve the printability of water color ink.
The preparation method that the specific scheme is that the compound water color ink binder of a kind of inorganic material and waterborne polyurethane resin of the present invention, is carried out as follows:
A, galapectite powder is crossed 300-600 mesh sieve, then it is obtained thermal activation galapectite at 400-600 DEG C of roasting temperature after 2-4 hour；Then being that 2-5% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation galapectites, 100 parts of mass concentrations, after stirring 2-4 hour at a temperature of 30-40 DEG C, filtration drying obtains acid activation galapectite；
B, sepiolite powder is crossed 300-600 mesh sieve, then it is obtained thermal activation meerschaum at 300-400 DEG C of roasting temperature after 2-4 hour；Then being that 2-5% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation meerschaums, 100 parts of mass concentrations, after stirring 3-5 hour at a temperature of 40-50 DEG C, filtration drying obtains acid activation meerschaum；
C, acid activation galapectite and the acid activation meerschaum of above-mentioned gained are joined in ethanol water, and at a temperature of 60-80 DEG C, carry out ultrasound wave dispersion 0.5-1h, it is subsequently adding silane coupler, continue insulation ultrasound wave dispersion 1-1.5h, afterwards sucking filtration, wash, be dried to obtain modified meerschaum and modified galapectite, above-mentioned acid activation galapectite, acid activation meerschaum, ethanol water, the weight consumption ratio of silane coupler be: 1:1:20-30:3-5；
D, the modified meerschaum of above-mentioned gained and modified galapectite are joined in waterborne polyurethane resin solution, obtaining the water color ink binder that inorganic material is compound with waterborne polyurethane resin after stirring at 30-50 DEG C, the weight consumption ratio of described modified galapectite, modified meerschaum and waterborne polyurethane resin solution is: 1:1:50-100.
Containing partially crystallizable water, absorption water and impurity in galapectite and meerschaum, owing to water of crystallization, absorption water and impurity are present in the micropore in galapectite and meerschaum or interlayer, the turnover of later stage hydrone can be blocked, the most respectively galapectite and meerschaum are carried out thermal activation treatment, water of crystallization in galapectite and meerschaum, absorption water and impurity can be removed, increase micropore size, improve its moisture releasing performance.Respectively galapectite and meerschaum are carried out acid activation process, on the one hand the metal ion in galapectite and meerschaum construction unit can be removed, on the other hand hydrion surface can be combined generation Si-OH with the siliconoxygen bond on surface, and follow-up and resin carries out cross-linking reaction.Galapectite after thermal activation and acid activation and meerschaum are carried out silane coupler modified again so that it is have more preferable dispersibility, and preferably cross-link with waterborne polyurethane resin, it is not easy to agglomeration occurs.In addition, after inorganic material has been filled into resin, after inorganic material has bigger specific surface area, and micropore size increase, moisture releasing efficiency is greatly improved.
The water color ink made after the compound water color ink binder of inorganic material prepared by the inventive method and waterborne polyurethane resin and pigment and other additive compounds, in printing process, when water color ink has just spread out on printable fabric surface, form a tunic, specific surface area becomes suddenly big, due to the specific surface area that inorganic material is bigger, large quantity of moisture is fled from from micropore, water color ink rate of drying is very fast, when being dried to a certain degree, osmotic pressure due to water color ink inside and outside, rate of drying gradually slows down, water color ink is made to have time enough to penetrate in printable fabric, strengthen the adhesive force with printable fabric, and now the content of moisture is less, it is not result in that attribute ink adheres on dancing roll, time leaflet tarnish.
As preferably, the mass concentration of the ethanol water described in step c is 10-20%.
As preferably, described silane coupler is silane resin acceptor kh-550, Silane coupling reagent KH-570 or silane coupler KH-590.
As preferably, the solid content of the waterborne polyurethane resin solution described in step d is 30-40wt%.
Being compared with the prior art, the invention has the beneficial effects as follows: the water color ink binder that the machine material prepared by the inventive method is compound with waterborne polyurethane resin, after being re-dubbed water color ink, the rate of drying of water color ink first quick and back slow, is conducive to printing.The water color ink binder asepsis environment-protecting that simultaneously prepared by the present invention.Additionally, due to the filling of inorganic material, also enhance heat resistance and the anti-wear performance of water color ink.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
The preparation method of the water color ink binder that a kind of inorganic material is compound with waterborne polyurethane resin, is carried out as follows:
A, galapectite powder is crossed 500 mesh sieves, then it is obtained thermal activation galapectite at 500 DEG C of roasting temperatures after 3 hours；Then being that 3% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation galapectites, 100 parts of mass concentrations, after stirring 3 hours at a temperature of 35 DEG C, filtration drying obtains acid activation galapectite；
B, sepiolite powder is crossed 500 mesh sieves, then it is obtained thermal activation meerschaum at 350 DEG C of roasting temperatures after 3 hours；Then being that 3% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation meerschaums, 100 parts of mass concentrations, after stirring 4 hours at a temperature of 45 DEG C, filtration drying obtains acid activation meerschaum；
C, acid activation galapectite and the acid activation meerschaum of above-mentioned gained are joined in the ethanol water that mass concentration is 15%, and at a temperature of 70 DEG C, carry out ultrasound wave dispersion 0.75h, it is subsequently adding silane resin acceptor kh-550, continue insulation ultrasound wave dispersion 1.25h, afterwards sucking filtration, wash, be dried to obtain modified meerschaum and modified galapectite, above-mentioned acid activation galapectite, acid activation meerschaum, ethanol water, silane resin acceptor kh-550 weight consumption ratio for 1:1:25:4；
D, the modified meerschaum of above-mentioned gained and modified galapectite are joined in the waterborne polyurethane resin solution that solid content is 35wt%, obtaining the water color ink binder that inorganic material and waterborne polyurethane resin are compound after stirring at 40 DEG C, the weight consumption of described modified galapectite, modified meerschaum and waterborne polyurethane resin solution ratio is for 1:1:75.
Embodiment 2
The preparation method of the water color ink binder that a kind of inorganic material is compound with waterborne polyurethane resin, is carried out as follows:
A, galapectite powder is crossed 300 mesh sieves, then it is obtained thermal activation galapectite at 400 DEG C of roasting temperatures after 4 hours；Then being that 2% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation galapectites, 100 parts of mass concentrations, after stirring 4 hours at a temperature of 30 DEG C, filtration drying obtains acid activation galapectite；
B, sepiolite powder is crossed 300 mesh sieves, then it is obtained thermal activation meerschaum at 300 DEG C of roasting temperatures after 4 hours；Then being that 2% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation meerschaums, 100 parts of mass concentrations, after stirring 5 hours at a temperature of 40 DEG C, filtration drying obtains acid activation meerschaum；
C, acid activation galapectite and the acid activation meerschaum of above-mentioned gained are joined in the ethanol water that mass concentration is 10%, and at a temperature of 60 DEG C, carry out ultrasound wave dispersion 1h, it is subsequently adding Silane coupling reagent KH-570, continue insulation ultrasound wave dispersion 1.5h, afterwards sucking filtration, wash, be dried to obtain modified meerschaum and modified galapectite, above-mentioned acid activation galapectite, acid activation meerschaum, ethanol water, Silane coupling reagent KH-570 weight consumption ratio for 1:1:20:3；
D, the modified meerschaum of above-mentioned gained and modified galapectite are joined in the waterborne polyurethane resin solution that solid content is 40wt%, obtaining the water color ink binder that inorganic material and waterborne polyurethane resin are compound after stirring at 30 DEG C, the weight consumption of described modified galapectite, modified meerschaum and waterborne polyurethane resin solution ratio is for 1:1:50.
Embodiment 3
The preparation method of the water color ink binder that a kind of inorganic material is compound with waterborne polyurethane resin, is carried out as follows:
A, galapectite powder is crossed 600 mesh sieves, then it is obtained thermal activation galapectite at 600 DEG C of roasting temperatures after 2 hours；Then being that 5% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation galapectites, 100 parts of mass concentrations, after stirring 2 hours at a temperature of 40 DEG C, filtration drying obtains acid activation galapectite；
B, sepiolite powder is crossed 600 mesh sieves, then it is obtained thermal activation meerschaum at 400 DEG C of roasting temperatures after 2 hours；Then being that 5% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation meerschaums, 100 parts of mass concentrations, after stirring 3 hours at a temperature of 50 DEG C, filtration drying obtains acid activation meerschaum；
C, acid activation galapectite and the acid activation meerschaum of above-mentioned gained are joined in the ethanol water that mass concentration is 20%, and at a temperature of 80 DEG C, carry out ultrasound wave disperse 0. 5h, it is subsequently adding silane coupler KH-590, continue insulation ultrasound wave dispersion 1.5h, afterwards sucking filtration, wash, be dried to obtain modified meerschaum and modified galapectite, above-mentioned acid activation galapectite, acid activation meerschaum, ethanol water, silane coupler KH-590 weight consumption ratio for 1:1:30:5；
D, the modified meerschaum of above-mentioned gained and modified galapectite are joined in the waterborne polyurethane resin solution that solid content is 30wt%, obtaining the water color ink binder that inorganic material and waterborne polyurethane resin are compound after stirring at 50 DEG C, the weight consumption of described modified galapectite, modified meerschaum and waterborne polyurethane resin solution ratio is for 1:1:100.
Embodiment 4
The preparation method of the water color ink binder that a kind of inorganic material is compound with waterborne polyurethane resin, is carried out as follows:
A, galapectite powder is crossed 400 mesh sieves, then it is obtained thermal activation galapectite at 450 DEG C of roasting temperatures after 2.5 hours；Then being that 4% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation galapectites, 100 parts of mass concentrations, after stirring 2.5 hours at a temperature of 38 DEG C, filtration drying obtains acid activation galapectite；
B, sepiolite powder is crossed 400 mesh sieves, then it is obtained thermal activation meerschaum at 380 DEG C of roasting temperatures after 2.5 hours；Then being that 4% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation meerschaums, 100 parts of mass concentrations, after stirring 3.5 hours at a temperature of 46 DEG C, filtration drying obtains acid activation meerschaum；
C, acid activation galapectite and the acid activation meerschaum of above-mentioned gained are joined in the ethanol water that mass concentration is 17%, and at a temperature of 75 DEG C, carry out ultrasound wave dispersion 0.8h, it is subsequently adding silane resin acceptor kh-550, continue insulation ultrasound wave dispersion 1.3h, afterwards sucking filtration, wash, be dried to obtain modified meerschaum and modified galapectite, above-mentioned acid activation galapectite, acid activation meerschaum, ethanol water, silane resin acceptor kh-550 weight consumption ratio for 1:1:28:4.5；
D, the modified meerschaum of above-mentioned gained and modified galapectite are joined in the waterborne polyurethane resin solution that solid content is 39wt%, obtaining the water color ink binder that inorganic material and waterborne polyurethane resin are compound after stirring at 45 DEG C, the weight consumption of described modified galapectite, modified meerschaum and waterborne polyurethane resin solution ratio is for 1:1:80.
The above, be only presently preferred embodiments of the present invention, not impose any restrictions the present invention, every any simple modification, change and equivalent transformation made above example according to the technology of the present invention essence, all still falls within the protection domain of technical solution of the present invention.
Claims (4)
1. the preparation method of the water color ink binder that an inorganic material and waterborne polyurethane resin are combined, it is characterised in that carry out as follows:
A, galapectite powder is crossed 300-600 mesh sieve, then it is obtained thermal activation galapectite at 400-600 DEG C of roasting temperature after 2-4 hour；Then being that 2-5% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation galapectites, 100 parts of mass concentrations, after stirring 2-4 hour at a temperature of 30-40 DEG C, filtration drying obtains acid activation galapectite；
B, sepiolite powder is crossed 300-600 mesh sieve, then it is obtained thermal activation meerschaum at 300-400 DEG C of roasting temperature after 2-4 hour；Then being that 2-5% hydrochloric acid solution successively joins in 100 parts of water by 10 parts of described thermal activation meerschaums, 100 parts of mass concentrations, after stirring 3-5 hour at a temperature of 40-50 DEG C, filtration drying obtains acid activation meerschaum；
C, acid activation galapectite and the acid activation meerschaum of above-mentioned gained are joined in ethanol water, and at a temperature of 60-80 DEG C, carry out ultrasound wave dispersion 0.5-1h, it is subsequently adding silane coupler, continue insulation ultrasound wave dispersion 1-1.5h, afterwards sucking filtration, wash, be dried to obtain modified meerschaum and modified galapectite, above-mentioned acid activation galapectite, acid activation meerschaum, ethanol water, the weight consumption ratio of silane coupler be: 1:1:20-30:3-5；
D, the modified meerschaum of above-mentioned gained and modified galapectite are joined in waterborne polyurethane resin solution, obtaining the water color ink binder that inorganic material is compound with waterborne polyurethane resin after stirring at 30-50 DEG C, the weight consumption ratio of described modified galapectite, modified meerschaum and waterborne polyurethane resin solution is: 1:1:50-100.
2. the preparation method of the water color ink binder that inorganic material as claimed in claim 1 is compound with waterborne polyurethane resin, it is characterised in that the mass concentration of the ethanol water described in step c is 10-20%.
3. the preparation method of the water color ink binder that inorganic material as claimed in claim 1 is compound with waterborne polyurethane resin, it is characterised in that described silane coupler is silane resin acceptor kh-550, Silane coupling reagent KH-570 or silane coupler KH-590.
4. the preparation method of the water color ink binder that inorganic material as claimed in claim 3 is compound with waterborne polyurethane resin, it is characterised in that the solid content of the waterborne polyurethane resin solution described in step d is 30-40wt%.
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| CN115851085B (en) * | 2023-03-02 | 2023-05-02 | 广东睿智环保科技股份有限公司 | Polyester resin self-cleaning powder coating and preparation method thereof |
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| JPS6157667A (en) * | 1984-08-29 | 1986-03-24 | Canon Inc | Ink-jet recording method |
| CN101348629A (en) * | 2008-09-17 | 2009-01-21 | 中国建筑材料科学研究总院 | Indoor coating having humidity conditioning function and construction method thereof |
| CN101368014B (en) * | 2008-09-17 | 2010-08-11 | 中国建筑材料科学研究总院 | Inorganic putty powder with function of governing humidness |
| CN102888147A (en) * | 2011-07-19 | 2013-01-23 | 天津天元天昊化工有限公司 | Environment-protection black ink and its preparation method |
| CN102604491A (en) * | 2012-03-09 | 2012-07-25 | 东莞大宝化工制品有限公司 | Inner-wall humidifying emulsion paint |
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Denomination of invention: Preparation method of water-based ink binder composed of inorganic material and water-based polyurethane resin Effective date of registration: 20210630 Granted publication date: 20170104 Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd. Pledgor: CHANGXING AIFEITE PLASTIC TECHNOLOGY Co.,Ltd. Registration number: Y2021330000728 |
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Date of cancellation: 20220307 Granted publication date: 20170104 Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd. Pledgor: CHANGXING AIFEITE PLASTIC TECHNOLOGY CO.,LTD. Registration number: Y2021330000728 |
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