CN104610618A - Oil resistant rubber - Google Patents

Oil resistant rubber Download PDF

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Publication number
CN104610618A
CN104610618A CN201510049059.4A CN201510049059A CN104610618A CN 104610618 A CN104610618 A CN 104610618A CN 201510049059 A CN201510049059 A CN 201510049059A CN 104610618 A CN104610618 A CN 104610618A
Authority
CN
China
Prior art keywords
parts
rubber
butadiene rubber
isoprene
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510049059.4A
Other languages
Chinese (zh)
Inventor
陈永亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd
Original Assignee
LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd filed Critical LIUZHOU ZHONGPEI RUBBER PARTS MANUFACTURING Co Ltd
Priority to CN201510049059.4A priority Critical patent/CN104610618A/en
Publication of CN104610618A publication Critical patent/CN104610618A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses oil resistant rubber, belonging to the technical field of rubber for automobile oil cylinder sealing. The oil resistant rubber is prepared from the following components in parts by weight: 35-46 parts of styrene-isoprene-butadiene rubber, 20-30 parts of isoprene-butadiene rubber, 20-26 parts of polyhexamethylene biguanide hydrochloride, 8-12 parts of zinc oxide, 5-8 parts of dithiodimorpholine, 2-4 parts of stearic acid, 1-5 parts of isobutyltriethoxysilicon, 5-8 parts of ethyl carbamate and 1-5 parts of sodium pyrosulfite. The oil resistant rubber is prepared by mainly compounding two types of conjugated diene rubber and then adopting the following auxiliary components: 26 parts of polyhexamethylene biguanide hydrochloride, zinc oxide, dithiodimorpholine, stearic acid, isobutyltriethoxysilicon, ethyl carbamate and sodium pyrosulfite, so that the oil resistance of the oil resistant rubber can be effectively improved.

Description

Oil resisting rubber
Technical field
The present invention relates to automobile oil cylinder sealing field of rubber technology, particularly relate to a kind of oil resisting rubber.
Background technology
Along with the development of auto manufacturing technology, the performance requriements of people to each parts of automobile is also more and more higher, particularly about the oil resistance requirement of automobile oil cylinder sealing rubber.At present, although existing oil resisting rubber product category is various, but the problem of ubiquity oil-proofness poor performance.
Summary of the invention
The invention provides a kind of oil resisting rubber, this oil resisting rubber oil-proofness is good, can solve the problem that existing oil resisting rubber product also exists oil-proofness poor performance.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is:
It is made up of the component of following weight part:
Styrene isoprene butadiene rubber (SIBR) 35 parts ~ 46 parts, isoprene-butadiene rubber 20 parts ~ 30 parts, hexamethylene 20 parts ~ 26 parts, 8 parts ~ 12 parts, zinc oxide, dimorpholinyl disulfide 5 parts ~ 8 parts, stearic acid 2 parts ~ 4 parts, isobutyl-triethoxysilicane 1 part ~ 5 parts, urethanum 5 parts ~ 8 parts and Sodium Pyrosulfite 1 part ~ 5 parts.
In technique scheme, technical scheme is more specifically: styrene isoprene butadiene rubber (SIBR) 35 parts, isoprene-butadiene rubber 20 parts, hexamethylene 26 parts, 12 parts, zinc oxide, dimorpholinyl disulfide 7 parts, stearic acid 3 parts, isobutyl-triethoxysilicane 1 part, urethanum 8 parts and Sodium Pyrosulfite 3 parts.
Further, styrene isoprene butadiene rubber (SIBR) 46 parts, isoprene-butadiene rubber 30 parts, hexamethylene 26 parts, 8 parts, zinc oxide, dimorpholinyl disulfide 5 parts, stearic acid 4 parts, isobutyl-triethoxysilicane 5 parts, urethanum 6 parts and Sodium Pyrosulfite 5 parts.
Further, styrene isoprene butadiene rubber (SIBR) 40 parts, isoprene-butadiene rubber 25 parts, hexamethylene 22 parts, 10 parts, zinc oxide, dimorpholinyl disulfide 8 parts, stearic acid 2 parts, isobutyl-triethoxysilicane 3 parts, urethanum 5 parts and Sodium Pyrosulfite 1 part.
Owing to adopting technique scheme, the beneficial effect that the present invention obtains is:
The present invention mainly selects two kinds of conjugated diene rubbers composite, then is equipped with hexamethylene 26 parts, zinc oxide, dimorpholinyl disulfide, stearic acid, isobutyl-triethoxysilicane, urethanum and Sodium Pyrosulfite make oil resisting rubber together, can effectively improve its oil resistance.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, and protection scope of the present invention is not only confined to following examples.
Embodiment 1
This oil resisting rubber is made up of following component: styrene isoprene butadiene rubber (SIBR) 3.5kg, isoprene-butadiene rubber 2.0kg, hexamethylene 2.6kg, zinc oxide 1.2kg, dimorpholinyl disulfide 0.7kg, stearic acid 0.3kg, isobutyl-triethoxysilicane 0.1kg, urethanum 0.8kg and Sodium Pyrosulfite 0.3kg.
Compared with the oil resisting rubber product that existing market is sold, the oil resistance of the oil resisting rubber that the present embodiment obtains improves 30%.
Embodiment 2
This oil resisting rubber is made up of following component: styrene isoprene butadiene rubber (SIBR) 4.6kg, isoprene-butadiene rubber 3.0kg, hexamethylene 2.6kg, zinc oxide 0.8kg, dimorpholinyl disulfide 0.5kg, stearic acid 0.4kg, isobutyl-triethoxysilicane 0.5kg, urethanum 0.6kg and Sodium Pyrosulfite 0.5kg.
Compared with the oil resisting rubber product that existing market is sold, the oil resistance of the oil resisting rubber that the present embodiment obtains improves 33.2%.
Embodiment 3
This oil resisting rubber is made up of following component: styrene isoprene butadiene rubber (SIBR) 4.0kg, isoprene-butadiene rubber 2.5kg, hexamethylene 2.2kg, zinc oxide 1.0kg, dimorpholinyl disulfide 0.8kg, stearic acid 0.2kg, isobutyl-triethoxysilicane 0.3kg, urethanum 0.5kg and Sodium Pyrosulfite 0.1kg.
Compared with the oil resisting rubber product that existing market is sold, the oil resistance of the oil resisting rubber that the present embodiment obtains improves 32.1%.

Claims (4)

1. an oil resisting rubber, is characterized in that being made up of the component of following weight part:
Styrene isoprene butadiene rubber (SIBR) 35 parts ~ 46 parts, isoprene-butadiene rubber 20 parts ~ 30 parts, hexamethylene 20 parts ~ 26 parts, 8 parts ~ 12 parts, zinc oxide, dimorpholinyl disulfide 5 parts ~ 8 parts, stearic acid 2 parts ~ 4 parts, isobutyl-triethoxysilicane 1 part ~ 5 parts, urethanum 5 parts ~ 8 parts and Sodium Pyrosulfite 1 part ~ 5 parts.
2. oil resisting rubber according to claim 1, it is characterized in that: styrene isoprene butadiene rubber (SIBR) 35 parts, isoprene-butadiene rubber 20 parts, hexamethylene 26 parts, 12 parts, zinc oxide, dimorpholinyl disulfide 7 parts, stearic acid 3 parts, isobutyl-triethoxysilicane 1 part, urethanum 8 parts and Sodium Pyrosulfite 3 parts.
3. oil resisting rubber according to claim 1, it is characterized in that: styrene isoprene butadiene rubber (SIBR) 46 parts, isoprene-butadiene rubber 30 parts, hexamethylene 26 parts, 8 parts, zinc oxide, dimorpholinyl disulfide 5 parts, stearic acid 4 parts, isobutyl-triethoxysilicane 5 parts, urethanum 6 parts and Sodium Pyrosulfite 5 parts.
4. oil resisting rubber according to claim 1, it is characterized in that: styrene isoprene butadiene rubber (SIBR) 40 parts, isoprene-butadiene rubber 25 parts, hexamethylene 22 parts, 10 parts, zinc oxide, dimorpholinyl disulfide 8 parts, stearic acid 2 parts, isobutyl-triethoxysilicane 3 parts, urethanum 5 parts and Sodium Pyrosulfite 1 part.
CN201510049059.4A 2015-01-30 2015-01-30 Oil resistant rubber Pending CN104610618A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510049059.4A CN104610618A (en) 2015-01-30 2015-01-30 Oil resistant rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510049059.4A CN104610618A (en) 2015-01-30 2015-01-30 Oil resistant rubber

Publications (1)

Publication Number Publication Date
CN104610618A true CN104610618A (en) 2015-05-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510049059.4A Pending CN104610618A (en) 2015-01-30 2015-01-30 Oil resistant rubber

Country Status (1)

Country Link
CN (1) CN104610618A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1547601A (en) * 2001-06-28 2004-11-17 �����ּ�����˾ Tyre tread reinforced with silica having a low specific surface area
CN103756035A (en) * 2013-12-27 2014-04-30 北京彤程创展科技有限公司 Rubber composition and preparation method thereof
CN103957736A (en) * 2011-12-23 2014-07-30 米其林集团总公司 Shoe sole comprising a rubber composition based on nitrile-butadiene rubber, an oil and a resin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1547601A (en) * 2001-06-28 2004-11-17 �����ּ�����˾ Tyre tread reinforced with silica having a low specific surface area
CN103957736A (en) * 2011-12-23 2014-07-30 米其林集团总公司 Shoe sole comprising a rubber composition based on nitrile-butadiene rubber, an oil and a resin
CN103756035A (en) * 2013-12-27 2014-04-30 北京彤程创展科技有限公司 Rubber composition and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李永河 主编: "《橡胶硫化技术》", 31 May 2012 *

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Application publication date: 20150513