CN104610288B - A kind of phenyl triazole silver complex with potential fluorescent material and preparation method thereof - Google Patents
A kind of phenyl triazole silver complex with potential fluorescent material and preparation method thereof Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 7
- 238000002360 preparation method Methods 0.000 title abstract description 8
- BRRDEYQCJTVYOC-UHFFFAOYSA-N 4-phenyl-2h-triazole;silver Chemical compound [Ag].C1=NNN=C1C1=CC=CC=C1 BRRDEYQCJTVYOC-UHFFFAOYSA-N 0.000 title description 2
- CGRLXLHYYDSTKR-UHFFFAOYSA-N 1-phenyl-1H-1,2,4-triazole Chemical compound N1=CN=CN1C1=CC=CC=C1 CGRLXLHYYDSTKR-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000013078 crystal Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 6
- 229910052709 silver Inorganic materials 0.000 claims abstract 3
- 239000004332 silver Substances 0.000 claims abstract 3
- IZMQEWJIPXXVLK-UHFFFAOYSA-N [Ag].C1(=CC=CC=C1)N1N=CN=C1 Chemical compound [Ag].C1(=CC=CC=C1)N1N=CN=C1 IZMQEWJIPXXVLK-UHFFFAOYSA-N 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 230000005260 alpha ray Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract description 14
- 239000000706 filtrate Substances 0.000 abstract description 6
- 238000003756 stirring Methods 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 238000001914 filtration Methods 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 15
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 8
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 239000005751 Copper oxide Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229910000431 copper oxide Inorganic materials 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 238000002447 crystallographic data Methods 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- MOFINMJRLYEONQ-UHFFFAOYSA-N [N].C=1C=CNC=1 Chemical class [N].C=1C=CNC=1 MOFINMJRLYEONQ-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005564 crystal structure determination Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- GRONZTPUWOOUFQ-UHFFFAOYSA-M sodium;methanol;hydroxide Chemical compound [OH-].[Na+].OC GRONZTPUWOOUFQ-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/10—Silver compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
The invention discloses 1 phenyl 1H 1,2,4 triazole silver complex [Ag (L)2](NO3) (1) structural motif as shown in Figure 1.Also disclose [Ag (L) simultaneously2](NO3) preparation method of (1) (L=1 phenyl 1H 1,2,4 triazole).It is to use " room temperature volatility process ", i.e. AgNO3Filtering after stirring half an hour in water with L, filtrate room temperature obtains being suitable for the colourless rhabdolith of X ray single crystal diffraction after volatilizing one week.The present invention further discloses 1 phenyl 1H 1,2,4 triazole silver complex [Ag (L)2](NO3) (1) (L=1 phenyl 1H 1,2,4 triazole) as the application in terms of potential fluorescent material.
Description
The present invention obtains state natural sciences fund general project (21471113), young top-notch personnel's support plan, sky
Education Commission of Jinshi City general project (20140506), Tianjin Normal University's Middl-age and youth faculty Academic innovations advance planning item
(52XC1401), meter is cultivated by Tianjin State Scientific and Technological Commission general project (11JCYBJC03600) and Tianjin innovation team of institution of higher education
Draw the subsidy of (TD12-5038).
Technical field
The invention belongs to organic and Inorganic synthese technical field, relate to 1-phenyl-1H-1,2,4-triazole silver complexes
[Ag(L)2](NO3) (1) (L=1-phenyl-1H-1,2,4-triazole) preparation method and as potential fluorescent material should
With.
Background technology
1,2,4-triazole and derivant thereof have the coordination feature of pyrazoles and imidazoles concurrently, are that the bridging that coordination ability is stronger is joined
Body, has synthesized and has characterized substantial amounts of monokaryon, multinuclear and multidimensional compound the most.These parts can be former with the nitrogen on 1,2
Son forms N1, N2-bridging pattern with metallic ion coordination, can be by 2,4 for 4 unsubstituted 1,2,4-triazole derivatives
On nitrogen-atoms formed N2, N4-bridging pattern, this N2, N4-bridging pattern is with the N1 of imidazoles in metalloenzyme, N3-bridging pattern
Similar.Specific use for triazole class compounds is also manifested by the design of molecular device, and synthesis has different dimension
Metal complex has been the vital step of device.
The present invention is i.e. to select AgNO3Filtering after stirring half an hour in D water with L, filtrate room temperature obtains after volatilizing one week
It is suitable for the colourless rhabdolith [Ag (L) of X-ray single crystal diffraction2](NO3) (1) (L=1-phenyl-1H-1,2,4-three nitrogen
Azoles).This coordination compound is alternatively arranged as potential fluorescent material aspect and is applied.
Summary of the invention
It is an object of the present invention to provide a kind of 1-phenyl-1H-1,2,4-triazole silver complex [Ag (L)2]
(NO3) (1) (L=1-phenyl-1H-1,2,4-triazole) monocrystalline and preparation method thereof.
Following technical scheme is current inventor provides for this:
1-phenyl-1H-1,2,4-triazole silver complex [Ag (L)2](NO3) (1) (L=1-phenyl-1H-1,2,4-
Triazole) crystal structure as shown in Figure 1.
The present invention further discloses 1-phenyl-1H-1,2,4-triazole silver complex [Ag (L)2](NO3) (1) (L =
1-phenyl-1H-1,2,4-triazoles) monocrystalline, it is characterised in that this mono-crystalline structures uses APEX II CCD single crystal diffractometer, makes
With being incident radiation through graphite monochromatised Mok alpha ray (λ=0.71073), collect diffraction with ω-2 θ scan mode
Point, obtains cell parameter through least square refinement, utilizes SHELXL-97 direct method solution from difference Fourier electron density map
Single crystal data:
The crystallographic data of table 1. coordination compound 1
1-phenyl-1H-1,2,4-triazole silver complex [Ag (L) of the present invention2](NO3) (1) (L=1-phenyl-
1H-1,2,4-triazoles) preparation method of monocrystalline, its feature is using " room temperature volatility process ", i.e. AgNO3Stir in water with L
Filtering after half an hour, filtrate room temperature volatilizees one week to prepare this coordination compound
One preferred example of the present invention:
The preparation of 1-phenyl-1H-1,2,4-triazole (L)
In polar solvent, use " one kettle way ", 1-bromobenzene, 1H-1,2,4-triazoles, potassium carbonate and copper oxide are being added
Reaction preparation under heat condition；Wherein 1-phenyl-1H-1,2,4-triazole: 1H-1,2,4-triazole: potassium carbonate: rubbing of copper oxide
That ratio is 2:5:30:1；
The present invention preferred 1-phenyl-1H-1,2,4-triazole: 1H-1,2,4-triazole: potassium carbonate: copper oxide mole
Ratio is 2:5:30:1；Reaction temperature 100 DEG C, 48 hours response time.In polar solvent, use " one kettle way ", by 1-phenyl-
1H-1,2,4-triazoles, 1H-1,2,4-triazoles, potassium carbonate and copper oxide prepare this organic compound in a heated condition；
Presently preferred embodiment:
L (0.1 mmol) and AgNO3(0.1 mmo) filters after stirring half an hour in 10 mL water, and filtrate is colourless.Often
Temperature volatilization has the colourless bulk crystals of applicable X-ray single crystal diffraction after one week.Productivity: 55%.Elementary analysis (C16H14AgN7O3)
Theoretical value (%): C, 41.76；H, 3.07；N, 21.31.Measured value: C, 41.97；H, 3.09；N, 21.32.
One disclosed by the invention 1-phenyl-1H-1,2,4-triazole silver complex [Ag (L)2](NO3) (1) (L =
1-phenyl-1H-1,2,4-triazole) can be applied as potential fluorescent material aspect.
A kind of 1-phenyl-1H-1,2,4-triazole silver complex [Ag (L) disclosed by the invention2](NO3) (1) (L =
1-phenyl-1H-1,2,4-triazole) monocrystalline have the advantage that and feature be:
(1) operation is simple and easy to do.
(2) reaction yield is high, and the purity of products obtained therefrom is high.
(3) [the Ag (L) prepared by the present invention2](NO3) (1) (L=1-phenyl-1H-1,2,4-triazole) produce into
This is low, and method is easy, is suitable for large-scale production.
Accompanying drawing explanation
The crystal structure figure of Fig. 1: coordination compound 1.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, and embodiment is only explanatory, is in no way intended to it
Limit the scope of the present invention by any way.All of raw material is such as: anthracene nucleus etc. are all to enter from chemical reagents corporation both domestic and external
Row is bought, and through continuation purification but does not directly use.Raw materials used 1-bromobenzene, 1H-1,2,4-triazole, potassium carbonate,
Copper oxides etc. are commercially available.
Embodiment 1
It is separately added into CuO (1 in equipped with 50 mL three neck round bottom flasks of magneton, reflux condenser and thermometer
Mmol), potassium carbonate (30 mmol), 1H-1,2,4-triazoles (5 mmol), 1-phenyl-1H-1,2,4-triazoles (2
Mmol), 20 mL DMF.Start stirring at 80-200oC, reacts 12-120 hour.After reaction terminates, reactant liquor is down to room
Temperature, filters, and filtrate adds 100mL water, separates out a large amount of precipitation, sucking filtration, collects filter cake, yield 78.3%.1-phenyl-1H-1,2,4-
Triazole (L).
Embodiment 2
1-phenyl-1H-1,2,4-triazole (L) (0.1 mmol) and AgNO3(0.1 mmo) stirs in 10 mL water
Filtering after half an hour, filtrate is colourless.Room temperature has the colourless bulk crystals of applicable X-ray single crystal diffraction after volatilizing one week.Productivity:
55%.Elementary analysis (C16H14AgN7O3) theoretical value (%): C, 41.76；H, 3.07；N, 21.31.Measured value: C, 41.97；H,
3.09；N, 21.32.
Embodiment 3
Crystal structure determination uses APEX II CCD single crystal diffractometer, uses through graphite monochromatised Mok alpha ray (λ
=0.71073) it is incident radiation, collects point diffraction with ω-2 θ scan mode, obtain structure cell through least square refinement
Parameter, utilizes software to solve crystal structure from difference Fourier electron density map, and through Lorentz lorentz and polarity effect correction.All
H atom synthesized by difference Fourier and determine through preferable position calculation.Detailed axonometry data are shown in Table 1.Structural motif
See Fig. 1.
The crystallographic data of table 1. coordination compound 1
Embodiment 4
The concrete instance that dyestuff or luminous agent use
Method: differentiated pulse volt-ampere (DPV) the curve negotiating Princeton Applied Research Laboratory of dye solution is developed
PARSTAT 2273 electrochemical workstation is measured.The DPV test of solution uses three-electrode system, and glass-carbon electrode is working electrode,
Auxiliary electrode is platinum plate electrode, homemade Ag/AgNO3Electrode is reference electrode；Electrolyte is the acetonitrile of 0.1mol L-1TBAP
Solution.With the Oxidation of Ferrocene reversible point of reduction to as internal standard, obtain the corrected value between test system and standard hydrogen electrode system.
Monochromatic incident illumination photoelectric transformation efficiency (IPCE) describes DSCs photoelectric transformation efficiency under monochromatic light effect, is to turn
Move on to the electron number of external circuit and the ratio of incident illumination subnumber.During measurement, 500 W xenon lamps are used to pass through as light source, incident illumination
The multifunctional assembled grating spectrograph of WDS-5 type obtains the monochromatic light under different wave length λ；Monochromatic light exposure is in the light sun of battery
Pole, is read current value I by Keithley2400 digital sourcemeter.Monochromatic good fortune illumination is micro-by USB4000 plug-and-play
Type light spectral instrument is measured.
Step: in order to have any actual knowledge of dyestuff at TiO2Adsorbance on film, by dye sensitization TiO2Nanometer crystal film (geometric surface
Long-pending about 1 cm2) it is immersed in 10 mL 0.01 mol L-1Sodium hydroxide methanol solution in overnight, treat that dyestuff desorbs completely
The absorbance of rear mensuration solution.Wash one's face and rinse one's mouth according to absorbance and molar absorptivity and can calculate dyestuff on unit are nanometer crystal film
Adsorbance.The adsorbance of this triphen amino-compound is 4.9 × 10-4 mol/cm2。
Result: compared with the methanol solution of dyestuff, dyestuff is at TiO2Absorption spectrum on film the most substantially broadens and red shift.This
Show that dye molecule is at TiO2Define the first and J-aggregation of tail.Say from the operation principle of DSCs, the light that dye aggregation causes
Spectrum width and red shift are highly beneficial for the widening of photoelectric respone scope of dyestuff.But meanwhile, dye aggregation is known from experience
It is substantially reduced its electron injection efficiency, thus causes the degraded performance of DSCs.So, generally add co-adsorption in dye solution
Agent suppresses the gathering of dyestuff.Triphenylamine base dyestuff is in methanol solution and at TiO2The fluorescence of the purple solution on membrane electrode is surveyed
Pilot production is with 2.5 × 10-5The methanol solution of mol/L, maximum emission wavelength is positioned at 589 nm.
After the preferred embodiment described in detail, it is familiar with this skilled worker and is clearly understood that, without departing from above-mentioned
Can carry out various change and amendment under claim and spirit, all technical spirit according to the present invention are to above example institute
Any simple modification, equivalent variations and the modification made, belongs to the scope of technical solution of the present invention.And the present invention is not illustrated
The restriction of example embodiment in book.
Claims (1)
1.1-phenyl-1H-1,2,4-triazole silver complex monocrystalline are as the application in terms of potential fluorescent material, and its feature exists
Use APEX II CCD single crystal diffractometer in this mono-crystalline structures, use through graphite monochromatised Mok alpha ray, λ=0.71073
For incident radiation, collect point diffraction with ω-2 θ scan mode, obtain cell parameter through least square refinement, from difference
Fourier electron density map utilizes SHELXL-97 direct method to solve single crystal data:
The structure of 1-phenyl-1H-1,2,4-triazole silver complex monocrystalline: [Ag (L)2](NO3), L=1-phenyl-1H-1,2,
4-triazole.
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Non-Patent Citations (2)
| Title |
|---|
| Synthesis and Crystal Structures of Coordination Complexes Containing Cu2I2 Units and Their Application in Luminescence and Catalysis;Huaixia Zhao et al;《ChemPlusChem》;20130904;第78卷;1491-1502 * |
| 银（Ⅰ）、金（Ⅰ）和3，5-二烷基-1，2，4-三氮唑配合物的合成与结构化学研究;王英利;《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》;20071015;B014-161 * |
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