CN104609736B - A kind of glass anti-dazzle liquid and preparation method thereof and the method for preparing anti-dazzle glas using the anti-dazzle liquid - Google Patents
A kind of glass anti-dazzle liquid and preparation method thereof and the method for preparing anti-dazzle glas using the anti-dazzle liquid Download PDFInfo
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- C03—GLASS; MINERAL OR SLAG WOOL
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Abstract
The invention discloses a kind of glass anti-dazzle liquid and preparation method thereof and the method for preparing anti-dazzle glas using the anti-dazzle liquid, in terms of mass fraction, are mixed with by following raw materials according and are formed：22% ammonium fluoride, 4.1% ammonium sulfate, 1.9% potassium sulfate, 2.8% calcium fluoride, 1.0% zinc chloride, 1.5% prodan, 4.4% barium sulfate, 1.5% corn starch, 0.8% mass concentration be 50% glucose solution and 17% mass concentration be 98% concentrated sulphuric acid, 43% deionized water, wherein, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan and barium sulfate are chemical pure.Good using anti-dazzle glas light transmission obtained in the present invention, thin and thick is uniform, and surface is not easy to leave cut and fingerprint.Meanwhile, it is without waste liquid and waste gas discharge during anti-dazzle glas is prepared, little for the hazardness of operator and environment, with good economic benefit and social benefit.
Description
Technical field
The present invention relates to a kind of preparation of anti-dazzle liquid and using method, and in particular to a kind of glass anti-dazzle liquid and its preparation
Method and the method for preparing anti-dazzle glas using the anti-dazzle liquid.
Background technology
Anti-dazzle glas is exactly original sheet glass surface through special PROCESS FOR TREATMENT so as to had compared with general glass
Relatively low reflectance and higher transmittance, make glass that unrestrained transmitting is produced under intense light conditions, reduce the interference of ambient light, improve
The visibility of display picture and brightness, so as to produce good visual effect.The anti-dazzle glas sold in the market mainly by
Two methods are obtained：One kind is to plate one layer of anti-dazzle thin-membrane on the surface of the glass, and a kind of is direct with the method for chemical attack
The surface of glass is processed.
CN103921487A discloses a kind of method of glare proof glass processing, and the method utilizes low pressure atomizing spray gun by silicon
Resin material is sprayed at glass substrate surface and forms silicones film layer.The silicones film layer is coarse film layer, and Jing acid enters one
Then the glass baseplate is toasted 20 minutes～80 minutes at a temperature of 200 DEG C～400 DEG C, is obtained with anti-dazzle by step process
The glass of function.Although preferable through the glass antiglare effect of plated film, technics comparing is complicated, relatively costly, and, in room
Also easily come off under the conditions of the harsh environments such as outer wind and weather or cut, speckle etc. are left on surface, affect its transparency
And outward appearance.It is Radix Acaciae senegalis, Fluohydric acid., hydrochloric acid, fluohydric acid gas ammonia and Polyethylene Glycol that CN102476912A is described with composition
Glass anti-dazzle liquid, is processed to glass basis by the anti-dazzle liquid, can obtain the glass with antiglare effect.Although technique is simple
It is single, but the Radix Acaciae senegalis powder body valency in raw material is somewhat expensive, it is relatively costly, and as hydrochloric acid is easy to volatilization, corrosive power
By force, the harm for operator during processing is larger, is not easily recycled process.
It is badly in need of now a kind of preparation process is simple, low cost, stable performance are environmentally friendly, little is damaged to operator
Anti-dazzle glas preparation method.
The content of the invention
For the defect for overcoming above-mentioned prior art to exist, it is an object of the invention to provide a kind of glass anti-dazzle liquid and
Its preparation method and the method for preparing anti-dazzle glas using the anti-dazzle liquid, obtained in the present invention, anti-dazzle glas light transmission is good, thin
Thick uniform, surface is not easy to leave cut and fingerprint, can be widely applied to electronic display, glass showcase show window, large-scale advertisement
The fields such as board, photo frame, meanwhile, without waste liquid and waste gas discharge during anti-dazzle glas is prepared, for operator and environment
Hazardness it is little, production cost can further be reduced by the recycling of waste liquid, with good economic benefit and society
Benefit.
To reach above-mentioned purpose, the present invention is adopted the following technical scheme that：
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：19～26% fluorination
Ammonium, 3.8～4.6% ammonium sulfate, 1.6～2.1% potassium sulfate, 2.6～4% calcium fluoride, 0.5～2% zinc chloride, 1
～2% prodan, 3～6% barium sulfate, 1～3% starch, 0.5～2% glucose solution and 14～18%
Concentrated sulphuric acid, balance of deionized water.
Further, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan and being of barium sulfate
Learn pure.
Further, the mass concentration of glucose solution is 50%, and the mass concentration of concentrated sulphuric acid is 98%.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder grinds respectively and sieves, and is then mixed and stirred for uniform, formation compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged some hours, and it is stirred continuously during ageing, finally obtains anti-
Dizzy liquid.
Further, step 2) in raw material grind respectively after cross 200 mesh sieves.
Further, step 4) in mixed liquid B 16～24h is aged under conditions of 20～25 DEG C.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in ethanol solution, using taking out and dry after ultrasonic Treatment；
2) with colloid by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in anti-dazzle liquid and processes；
4) will be through step 3) cleaning of the original sheet glass deionized water that processes, then drying to obtain anti-dazzle glas.
Further, step 1) in utilize 3～5min of ultrasonic Treatment.
Further, step 3) in anti-dazzle liquid treatment temperature be 18～25 DEG C, process time be 30～120s.
Further, step 1) described in ethanol solution mass concentration be 20～80%, step 2) described in glue
Body is solid gum.
Compared with prior art, the present invention has following beneficial technique effect：
In the present invention, ammonium fluoride used, the purpose of calcium fluoride are in order to introduce fluorion, so as to generate with strong sulfuric acid response
HF is eroded to glass；Barium sulfate used, the effect of starch are, for the viscosity for increasing anti-dazzle liquid, to reduce glass surface fluorine
The dissolubility of silicate, advantageously forms hair side；In the present invention, zinc chloride used, prodan, glucose add as accelerator
Enter in anti-dazzle liquid, be conducive to glass surface to form uniform trickle hair side；Use in the present invention sulphuric acid and fluoride (ammonium fluoride,
Calcium fluoride) replace be easy to volatilize Fluohydric acid. and hydrochloric acid, not only make the performance of anti-dazzle liquid more stable, also reduce because acid volatilization
Infringement to environment and human body, while replacing expensive Radix Acaciae senegalis powder body with starch and glucose, greatly can drop
Low cost, good according to anti-dazzle glas light transmission obtained in the present invention, transmitance is more than 82%, and glossiness is more than 65%, and thin and thick
Uniformly, surface is not easy to leave cut and fingerprint, can be widely applied to electronic display, glass showcase show window, large board,
The fields such as photo frame, with good economic benefit and social benefit.
Specific embodiment
Below embodiments of the present invention are described in further detail：
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：19～26% fluorination
Ammonium, 3.8～4.6% ammonium sulfate, 1.6～2.1% potassium sulfate, 2.6～4% calcium fluoride, 0.5～2% zinc chloride, 1
～2% prodan, 3～6% barium sulfate, 1～3% starch, 0.5～2% mass concentration are that 50% glucose is molten
Liquid and 14～18% mass concentration be 98% concentrated sulphuric acid, balance of deionized water, wherein, ammonium fluoride, ammonium sulfate, sulphuric acid
It is pure that potassium, calcium fluoride, zinc chloride, prodan and barium sulfate are chemistry.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder is ground and 200 mesh standard sieves excessively in mortar respectively, is then mixed and is stirred in being incorporated in blender, forms compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 16～24h under conditions of 20～25 DEG C, during ageing not
Disconnected magnetic stirrer, finally obtains anti-dazzle liquid.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in the ethanol solution that mass concentration is 20～80%, and is cleaned in ultrasonic washing unit
Dry during baking oven is removed and placed in after 3～5min；
2) with solid gum by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in hanging basket, processes using in anti-dazzle liquid, and treatment temperature is 18
～25 DEG C, process time is 30～120s；
4) will be through step 3) the deionized water cleaning in the accumulator tank of the original sheet glass that processes, then put and do in an oven
It is dry to obtain anti-dazzle glas.
The recycling of anti-dazzle liquid
1) first, the rinse water in accumulator tank in above-mentioned steps is reclaimed；
2) and then, carried out the preparation again of solution and be aged 16 under conditions of 20～25 DEG C with the rinse water come up is reclaimed
～24 hours；
3) it is last, when the processing speed of anti-dazzle liquid declines, the good anti-dazzle liquid of above-mentioned ageing is added in anti-dazzle liquid, i.e.,
The corrosion rate to glass can be kept.
The present invention is described in further detail with reference to embodiment：
Embodiment 1
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：22% ammonium fluoride,
4.1% ammonium sulfate, 1.9% potassium sulfate, 2.8% calcium fluoride, 1.0% zinc chloride, 1.5% prodan, 4.4%
Barium sulfate, 1.5% corn starch, 0.8% mass concentration are 50% glucose solution and 17% mass concentration is
98% concentrated sulphuric acid, 43% deionized water, wherein, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan
And barium sulfate be chemistry it is pure.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder is ground and 200 mesh standard sieves excessively in mortar respectively, is then mixed and is stirred in being incorporated in blender, forms compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 24h under conditions of 20 DEG C, and magnetic force is constantly used during ageing
Agitator is stirred, and finally obtains anti-dazzle liquid.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in the ethanol solution that mass concentration is 20%, and 5min is cleaned in ultrasonic washing unit
After be removed and placed in drying in baking oven；
2) with solid gum by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in hanging basket, processes using in anti-dazzle liquid, and treatment temperature is 20
DEG C, process time is 50s；
4) will be through step 3) the deionized water cleaning in the accumulator tank of the original sheet glass that processes, then put and do in an oven
It is dry to obtain anti-dazzle glas.
The recycling of anti-dazzle liquid
1) first, the rinse water in accumulator tank in above-mentioned steps is reclaimed；
2) and then, with reclaim the rinse water come up carry out solution preparation again and under conditions of 20 DEG C ageing 24 it is little
When；
3) it is last, when the processing speed of anti-dazzle liquid declines, the good anti-dazzle liquid of above-mentioned ageing is added in anti-dazzle liquid, i.e.,
The corrosion rate to glass can be kept.
Embodiment 2
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：24% ammonium fluoride, 4%
Ammonium sulfate, 1.9% potassium sulfate, 2.8% calcium fluoride, 1.0% zinc chloride, 1.5% prodan, 3.5% sulfur
Sour barium, 2.5% corn starch, 1.8% mass concentration be 50% glucose solution and 17% mass concentration be 98%
Concentrated sulphuric acid, 40% deionized water, wherein, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan and
It is pure that barium sulfate is chemistry.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder is ground and 200 mesh standard sieves excessively in mortar respectively, is then mixed and is stirred in being incorporated in blender, forms compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 20h under conditions of 22 DEG C, and magnetic force is constantly used during ageing
Agitator is stirred, and finally obtains anti-dazzle liquid.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in the ethanol solution that mass concentration is 40%, and 5min is cleaned in ultrasonic washing unit
After be removed and placed in drying in baking oven；
2) with solid gum by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in hanging basket, processes using in anti-dazzle liquid, and treatment temperature is 22
DEG C, process time is 70s；
4) will be through step 3) the deionized water cleaning in the accumulator tank of the original sheet glass that processes, then put and do in an oven
It is dry to obtain anti-dazzle glas.
The recycling of anti-dazzle liquid
1) first, the rinse water in accumulator tank in above-mentioned steps is reclaimed；
2) and then, with reclaim the rinse water come up carry out solution preparation again and under conditions of 25 DEG C ageing 16 it is little
When；
3) it is last, when the processing speed of anti-dazzle liquid declines, the good anti-dazzle liquid of above-mentioned ageing is added in anti-dazzle liquid, i.e.,
The corrosion rate to glass can be kept.
Embodiment 3
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：25% ammonium fluoride,
4.3% ammonium sulfate, 2% potassium sulfate, 3.4% calcium fluoride, 0.6% zinc chloride, 1.0% prodan, 5.0%
Barium sulfate, 2.0% corn starch, 0.5% mass concentration are 50% glucose solution and 15% mass concentration is
98% concentrated sulphuric acid, 41.2% deionized water, wherein, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, hexafluosilicic acid
It is pure that sodium and barium sulfate are chemistry.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder is ground and 200 mesh standard sieves excessively in mortar respectively, is then mixed and is stirred in being incorporated in blender, forms compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 18h under conditions of 23 DEG C, and magnetic force is constantly used during ageing
Agitator is stirred, and finally obtains anti-dazzle liquid.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in the ethanol solution that mass concentration is 30%, and 3min is cleaned in ultrasonic washing unit
After be removed and placed in drying in baking oven；
2) with solid gum by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in hanging basket, processes using in anti-dazzle liquid, and treatment temperature is 23
DEG C, process time is 100s；
4) will be through step 3) the deionized water cleaning in the accumulator tank of the original sheet glass that processes, then put and do in an oven
It is dry to obtain anti-dazzle glas.
The recycling of anti-dazzle liquid
1) first, the rinse water in accumulator tank in above-mentioned steps is reclaimed；
2) and then, with reclaim the rinse water come up carry out solution preparation again and under conditions of 22 DEG C ageing 18 it is little
When；
3) it is last, when the processing speed of anti-dazzle liquid declines, the good anti-dazzle liquid of above-mentioned ageing is added in anti-dazzle liquid, i.e.,
The corrosion rate to glass can be kept.
Embodiment 4
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：19% ammonium fluoride,
3.8% ammonium sulfate, 1.6% potassium sulfate, 4% calcium fluoride, 2% zinc chloride, 2% prodan, 6% sulphuric acid
Barium, 1% corn starch, 2% mass concentration be 50% glucose solution and 18% mass concentration be 98% dense sulfur
Acid, 40.6% deionized water, wherein, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan and sulphuric acid
It is pure that barium is chemistry.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder is ground and 200 mesh standard sieves excessively in mortar respectively, is then mixed and is stirred in being incorporated in blender, forms compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 24h under conditions of 20 DEG C, and magnetic force is constantly used during ageing
Agitator is stirred, and finally obtains anti-dazzle liquid.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in the ethanol solution that mass concentration is 60%, and 4min is cleaned in ultrasonic washing unit
After be removed and placed in drying in baking oven；
2) with solid gum by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in hanging basket, processes using in anti-dazzle liquid, and treatment temperature is 18
DEG C, process time is 120s；
4) will be through step 3) the deionized water cleaning in the accumulator tank of the original sheet glass that processes, then put and do in an oven
It is dry to obtain anti-dazzle glas.
The recycling of anti-dazzle liquid
1) first, the rinse water in accumulator tank in above-mentioned steps is reclaimed；
2) and then, with reclaim the rinse water come up carry out solution preparation again and under conditions of 20 DEG C ageing 24 it is little
When；
3) it is last, when the processing speed of anti-dazzle liquid declines, the good anti-dazzle liquid of above-mentioned ageing is added in anti-dazzle liquid, i.e.,
The corrosion rate to glass can be kept.
Embodiment 5
A kind of glass anti-dazzle liquid, in terms of mass fraction, is mixed with by following raw materials according and is formed：26% ammonium fluoride,
4.6% ammonium sulfate, 2.1% potassium sulfate, 2.6% calcium fluoride, 0.5% zinc chloride, 1% prodan, 3% sulfur
Sour barium, 3% corn starch, 0.5% mass concentration are 50% glucose solution and 18% mass concentration is 98%
Concentrated sulphuric acid, 38.7% deionized water, wherein, ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan and
It is pure that barium sulfate is chemistry.
The preparation method of above-mentioned glass anti-dazzle liquid, comprises the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, shallow lake
Powder is ground and 200 mesh standard sieves excessively in mortar respectively, is then mixed and is stirred in being incorporated in blender, forms compound；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, formed
Mixed liquor A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 16h under conditions of 25 DEG C, and magnetic force is constantly used during ageing
Agitator is stirred, and finally obtains anti-dazzle liquid.
A kind of method for preparing anti-dazzle glas using above-mentioned anti-dazzle liquid, comprises the following steps：
1) original sheet glass is put in the ethanol solution that mass concentration is 80%, and 5min is cleaned in ultrasonic washing unit
After be removed and placed in drying in baking oven；
2) with solid gum by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in hanging basket, processes using in anti-dazzle liquid, and treatment temperature is 25
DEG C, process time is 30s；
4) will be through step 3) the deionized water cleaning in the accumulator tank of the original sheet glass that processes, then put and do in an oven
It is dry to obtain anti-dazzle glas.
The recycling of anti-dazzle liquid
1) first, the rinse water in accumulator tank in above-mentioned steps is reclaimed；
2) and then, with reclaim the rinse water come up carry out solution preparation again and under conditions of 25 DEG C ageing 16 it is little
When；
3) it is last, when the processing speed of anti-dazzle liquid declines, the good anti-dazzle liquid of above-mentioned ageing is added in anti-dazzle liquid, i.e.,
The corrosion rate to glass can be kept.
Fine and smooth by anti-dazzle glas surface particles obtained in said method, antiglare effect is good.Use visible light light-splitting luminosity
Measure anti-dazzle glas transmitance be more than 82%；The glossiness that anti-dazzle glas is measured with vancometer is more than 65%.
Replace and be easy to Fluohydric acid. and the hydrochloric acid for volatilizing in the present invention with sulphuric acid and fluoride (ammonium fluoride, calcium fluoride), no
Only make the performance of anti-dazzle liquid more stable, also reduce because of acid infringement of the volatilization to environment and human body, while with starch and Fructus Vitis viniferae
Sugar replaces expensive Radix Acaciae senegalis powder body, can greatly reduces cost.According to anti-dazzle glas printing opacity obtained in the present invention
Property it is good, thin and thick is uniform, and surface is not easy to leave cut and fingerprint, can be widely applied to electronic display, glass showcase show window, big
The fields such as type billboard, photo frame.With good economic benefit and social benefit.
Claims (6)
1. a kind of glass anti-dazzle liquid, it is characterised in that in terms of mass fraction, be mixed with by following raw materials according and formed：19～
26% ammonium fluoride, 3.8～4.6% ammonium sulfate, 1.6～2.1% potassium sulfate, 2.6～4% calcium fluoride, 0.5～2%
Zinc chloride, 1～2% prodan, 3～6% barium sulfate, 1～3% starch, 0.5～2% glucose solution with
And 14～18% concentrated sulphuric acid, balance of deionized water, wherein ammonium fluoride, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, fluorine silicon
Sour sodium and barium sulfate are that chemistry is pure, and the mass concentration of glucose solution is 50%, and the mass concentration of concentrated sulphuric acid is 98%.
2. the preparation method of the glass anti-dazzle liquid described in claim 1, it is characterised in that comprise the following steps：
1) each several part raw material is weighed according to raw material composition；
2) by step 1) ammonium fluoride that weighs, ammonium sulfate, potassium sulfate, calcium fluoride, zinc chloride, prodan, barium sulfate, starch point
200 mesh sieves are not ground and crossed, uniform, formation compound is then mixed and stirred for；
3) by step 2) compound and the step 1 that obtain) deionized water that weighs, glucose solution mix homogeneously, and forms mixing
Liquid A, is then added slowly to concentrated sulphuric acid in mixed liquor A, stirs while adding, and forms mixed liquid B；
4) by step 3) mixed liquid B that obtains is aged 16～24h under conditions of 20～25 DEG C, constantly stirs during ageing
Mix, finally obtain anti-dazzle liquid.
3. the method that the anti-dazzle liquid described in a kind of utilization claim 1 prepares anti-dazzle glas, it is characterised in that including following step
Suddenly：
1) original sheet glass is put in ethanol solution, using taking out and dry after ultrasonic Treatment；
2) with colloid by step 1) in the original sheet glass that cleaned be not required to one side to be processed and protect；
3) by through step 2) original sheet glass that processes is put in anti-dazzle liquid and processes；
4) will be through step 3) cleaning of the original sheet glass deionized water that processes, then drying to obtain anti-dazzle glas.
4. method according to claim 3, it is characterised in that step 1) in utilize 3～5min of ultrasonic Treatment.
5. method according to claim 3, it is characterised in that step 3) in the treatment temperature of anti-dazzle liquid be 18～25 DEG C,
Process time is 30～120s.
6. method according to claim 3, it is characterised in that step 1) described in the mass concentration of ethanol solution be 20
～80%, step 2) described in colloid be solid gum.
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| CN201510072253.4A CN104609736B (en) | 2015-02-11 | 2015-02-11 | A kind of glass anti-dazzle liquid and preparation method thereof and the method for preparing anti-dazzle glas using the anti-dazzle liquid |
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|---|---|---|---|
| CN201510072253.4A CN104609736B (en) | 2015-02-11 | 2015-02-11 | A kind of glass anti-dazzle liquid and preparation method thereof and the method for preparing anti-dazzle glas using the anti-dazzle liquid |
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| CN106186713A (en) * | 2016-07-14 | 2016-12-07 | 郑州航空工业管理学院 | A kind of anti-dazzle glas etching solution and the method utilizing this anti-dazzle liquid processing anti-dazzle glas |
| CN106219992A (en) * | 2016-07-14 | 2016-12-14 | 郑州航空工业管理学院 | A kind of chemical etching preparation technology of anti-dazzle glas |
| CN105948521A (en) * | 2016-07-14 | 2016-09-21 | 郑州航空工业管理学院 | Etching treatment liquid for preparing antireflection glass |
| CN108191253B (en) * | 2016-12-22 | 2020-11-20 | 蓝思科技（长沙）有限公司 | Frosting liquid, preparation method and application thereof, and method for preparing anti-dazzle glass |
| CN106800374A (en) * | 2016-12-30 | 2017-06-06 | 天津天翔玻璃制造有限公司 | A kind of glass processing AG anti-dazzle liquids and its application |
| CN108147674A (en) * | 2017-12-29 | 2018-06-12 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of preparation method of glare proof glass |
| CN110734229B (en) * | 2019-11-21 | 2022-04-22 | 陕西科技大学 | Super-hydrophobic anti-reflection frosted glass and preparation method thereof |
| CN112777941A (en) * | 2021-01-13 | 2021-05-11 | 赣州帝晶光电科技有限公司 | Preparation method of AG anti-dazzle glass etching process |
| US20230183570A1 (en) * | 2021-12-15 | 2023-06-15 | Corning Incorporated | Etchants for making textured glass articles |
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| CN101215097B (en) * | 2008-01-03 | 2010-09-15 | 东华大学 | Formulation of anti-dazzle glass product etching liquid and etching technique |
| CN101314522B (en) * | 2008-06-12 | 2010-09-08 | 东华大学 | Method for preparing anti-dazzle glass |
| US8236190B2 (en) * | 2008-06-13 | 2012-08-07 | United Technologies Corporation | Recast removal method |
| CN102432185B (en) * | 2011-09-30 | 2014-09-10 | 郑州恒昊玻璃技术有限公司 | Etching liquid and etching process for anti-dazzle glass product |
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