CN104594032A - Waterproof anti-grease contamination spray and production process thereof - Google Patents
Waterproof anti-grease contamination spray and production process thereof Download PDFInfo
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- CN104594032A CN104594032A CN201410837713.3A CN201410837713A CN104594032A CN 104594032 A CN104594032 A CN 104594032A CN 201410837713 A CN201410837713 A CN 201410837713A CN 104594032 A CN104594032 A CN 104594032A
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Abstract
The invention discloses a waterproof anti-grease contamination spray. The waterproof anti-grease contamination spray comprises following components in percentage by weight: 2-10% of fluorosilicone surfactant, 5-30% of cosolvent, 10-40% of diluent, 0.1-2% of essence and 20-50% of propellant, wherein the fluorosilicone surfactant is one or two selected from perfluoro methyl acrylate and perfluoro ethyl methyl acrylate or is a mixture of organic resin and long-chain silane compounded according to a mass ratio of 1:(0.2-0.5). The invention also discloses a production process of the waterproof anti-grease contamination spray. The production process comprises the following steps: preparing raw materials, tinning and sealing, filling propellant, installing sprinkler head and cap and the like. The product of the invention has uniform dispersion, even atomization, capability of permeating into small pores, good odour, and functions of waterproofing and waterproof restoring, and is free of discolouration and free of toxicity or harm. The waterproof anti-grease contamination spray is a unique aerosol with components available for DIY. The production of the invention requires no special environment conditions, and is low in cost, rational in process and feasible for scale production.
Description
Technical field
The present invention relates to daily field of fine chemical, particularly the dirty spray of a kind of waterproof and oilproof and production technology thereof.
Background technology
At present, the waterproof and oilproof process of the product surface such as leather, fabric increases coatings at product surface often, and coating process often needs just can obtain finished product by heating technique, and thus its finished product mainly comes from the large-scale production such as industry, factory, and cost is high.There are the three anti-products such as ripe waterproof and oilproof in the market, but its technique for applying is complicated, the equipment and the strict temperature that need specialty control, and general non-chemical plant, as Leather Shoes Factory or leather shop, clothing factory or clothes shop etc. then do not possess the execution conditions of grease-proof and waterproof, can only purchase large batch of waterproof material from Leather Factory, Ran Hua factory in batches, cost is high, cumbersome.
The waterproof technology of aforementioned complexity cannot meet consumers in general in daily life and thirst for DIY at any time and carry out the demand of waterproof and oilproof process, also cannot meet the individual demand such as small lot, multi items that significant market occurs.As in the north, due to long-term rainwater weather, textiles, the leathers such as clothes, footwear, case and bag need to have waterproof feature, when these products such as textiles, leather because the reasons such as Long-Time Service cause water-proof function to lack, need to carry out waterproof reparation, the occasions such as military, field also usually need finished product to have waterproof feature, in these cases, people thirst for more urgently having and a kind ofly to carry with, can realize waterproof and oilproof, spray series products easy to use the short time, waterproof can be solved, problem that grease proofing and function is repaired, offer convenience to life; In addition in some Leather Factories, Shoes Factory, clothing factory; frequent meeting is because water proof equipment is not enough or need promptly to carry out waterproof processing process because of plant issue; more thirst for a kind of waterproof construction easy, equipment cost can be saved, can construct on a large scale, waterproof and the good waterproof product of waterproof repair function, the waterproof processing problem that them can be helped to solve typical products in mass production as soon as possible occur.
In a word, develop and provide one can carry out the process of DIY waterproof and oilproof, the easy construction dirty spray of waterproof and oilproof timely, very urgently.
Summary of the invention
For the deficiencies in the prior art, the object of the invention is to, the dirty spray of the waterproof and oilproof providing a kind of amateur dyeization, Leather Factory also can carry out the process of DIY waterproof and oilproof, this product adopts environmental protection raw material, leather and fabric etc. without waterproof and oilproof function can be processed under normal temperature and pressure conditions, waterproof oil-proof result can be reached, to meet growing individual demand after simple construction.
The present invention for the adopted technical scheme that achieves the above object is:
The dirty spray of a kind of waterproof and oilproof, it is made up of the component of following percetage by weight:
Preferably, described fluoride silicon surfactant is one or both in perfluoroalkyl acrylate, perfluor alkyl ethyl acrylate.
Preferably, described fluoride silicon surfactant is organic fluorine and the long chain silane mixture that 1:0.2-0.5 is composite in mass ratio.
Preferably, described chaotropic agent is one or both in kerosene, ethyl acetate, butyl acetate;
Preferably, described diluent be in ethanol, methyl alcohol, isopropyl alcohol or propane, butane, pentane, hexane, heptane one or both or multiple composite.
Preferably, described essence is one or more in lemon, sweet osmanthus, vanilla; Described propellant is one or both in the third butane or dimethyl ether.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluoride silicon surfactant 2-10%; Chaotropic agent 5-30%; Diluent 10-40%; Essence 0.1-2%; Propellant 20-50%;
(2) chaotropic agent is added in retort or blending vat, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
Preferably, in described step (1) fluorine surfactant be perfluoroalkyl acrylate, perfluor alkyl ethyl acrylate one or both or be organic fluorine and the long chain silane composite mixture of 1:0.2-0.5 in mass ratio.
Preferably, in described step (1), chaotropic agent is one or both in kerosene, ethyl acetate, butyl acetate; Described diluent is one or both in ethanol, methyl alcohol, isopropyl alcohol or propane, butane, pentane, hexane, heptane.
Preferably, in described step (1), essence is one or more in lemon, sweet osmanthus, vanilla; Described propellant is one or both in the third butagas, liquefied petroleum gas or dimethyl ether gas.
Compared with prior art, tool has the following advantages in the present invention:
1, fluorine silicon materials preferred oil dissolubility of the present invention, after finished product solvent evaporates ambient temperature curable; Product formula composition is few, and technique is simple, has the good promotion potential of production widely;
2, finished product of the present invention is generally the bottle packaging of 100-300ML, easy to carry;
3, during finished product application, construction is simple, without temperature requirement, without particular surroundings requirement, is widely used in individual DIY, shoe shop or factory, clothes shop or clothes factory, has good market potential;
4, the finished product engineering time is short, and it is dirty that short a few minutes can realize DIY waterproof and oilproof;
5, the present invention is widely used, and is widely used in synthetic fiber, natural fabric and blended fabric thereof as terylene, nylon, cotton, silk, hair, paper, leather etc.
6, finished product of the present invention is uniformly dispersed, is atomized homogeneous, gained spray and is permeable in pore, without whiting, smell is good, nontoxic, and after construction, fabric and leather possess rapidly oil-stain-preventing, water-proof function, keep the breathable moisture permeability of fabric at grease-proof and waterproof simultaneously.
7, this product adopts environmental protection raw material, can process, can reach waterproof oil-proof result, to meet growing individual demand after simply constructing under normal temperature and pressure conditions to without the leather of waterproof and oilproof function and fabric etc.The present invention is easy to use, and technique is simple, product of the present invention through for many years in international and domestic market application, through terminal consumer's feedback, there is extraordinary grease proofing and waterproof effect, obtain good Social and economic benef@.
Above-mentioned is the general introduction of invention technical scheme, and below in conjunction with detailed description of the invention, the present invention will be further described.
Detailed description of the invention:
The dirty spray of the waterproof and oilproof that embodiment 1 the present embodiment provides, it is made up of the component of following percetage by weight:
Preferably, described fluorine surfactant is one or both in perfluoroalkyl acrylate, perfluor alkyl ethyl acrylate.
Preferably, described fluorine surfactant is organic fluorine and the long chain silane mixture that 1:0.2-0.5 is composite in mass ratio.
Preferably, described chaotropic agent be in ester class, ethyl acetate, butyl acetate one or both or multiple;
Preferably, described diluent be in ethanol, methyl alcohol, isopropyl alcohol or propane, butane, pentane, hexane, heptane one or both or multiple.
Preferably, described essence is one or more in lemon, sweet osmanthus, vanilla; Described propellant is one or both in the third butane or dimethyl ether, specifically can select voluntarily as required.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluorine surfactant 2-10%; Chaotropic agent 5-30%; Diluent 10-40%; Essence 0.1-2%; Propellant 20-50%;
(2) chaotropic agent is added in retort or blending vat, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
Preferably, in described step (1) fluorine surfactant be perfluoroalkyl acrylate, perfluor alkyl ethyl acrylate one or both or be organic fluorine and the long chain silane composite mixture of 1:0.2-0.5 in mass ratio.
Preferably, in described step (1), chaotropic agent is one or both in lipid, ethyl acetate, butyl acetate; Described diluent is one or both in ethanol, methyl alcohol, isopropyl alcohol or propane, butane, pentane, hexane, heptane.
Preferably, in described step (1), essence is one or more in lemon, sweet osmanthus, vanilla; Described propellant is one or both in the third butagas, liquefied petroleum gas or dimethyl ether gas.
Embodiment 2
The dirty spray of the waterproof and oilproof that the present embodiment provides and production technology thereof, substantially the same manner as Example 1, its difference is: the dirty spray of a kind of waterproof and oilproof, and it is made up of the component of following percetage by weight:
Preferably, described fluorine surfactant is perfluoroalkyl acrylate;
Preferably, described chaotropic agent is ethyl acetate;
Preferably, ethanol, the heptane of described diluent to be mass ratio be 1:1.
Preferably, described essence is lemon; Described propellant is the third butagas.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluorine surfactant 2%; Chaotropic agent 21%; Diluent 40%; Essence 2%; Propellant 35%;
(chaotropic agent adds in retort or blending vat by 2, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
Embodiment 3
The dirty spray of the waterproof and oilproof that the present embodiment provides and production technology thereof, substantially identical with embodiment 1,2, its difference is: the dirty spray of a kind of waterproof and oilproof, and it is made up of the component of following percetage by weight:
Preferably, described fluorine surfactant is perfluor alkyl ethyl acrylate.
Preferably, described chaotropic agent is kerosene;
Preferably, ethanol, the n-hexane of described diluent to be mass ratio be 1:1.
Preferably, in described step (1), essence is sweet osmanthus; Described propellant is liquefied petroleum gas.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluorine surfactant 6%; Chaotropic agent 5%; Diluent 37.9%; Essence 1.1%; Propellant 50%;
(chaotropic agent adds in retort or blending vat by 2, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
Embodiment 4
The dirty spray of the waterproof and oilproof that the present embodiment provides and production technology thereof, substantially identical with embodiment 1,2,3, its difference is: the dirty spray of a kind of waterproof and oilproof, and it is made up of the component of following percetage by weight:
Preferably, described fluorine surfactant is organic fluorine and the long chain silane mixture that 1:0.2 is composite in mass ratio.
Preferably, described chaotropic agent is butyl acetate;
Preferably, isopropyl alcohol, the pentane of described diluent to be mass ratio be 1:1.
Preferably, described essence is vanilla; Described propellant is dimethyl ether gas.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluorine surfactant 10%; Chaotropic agent 30%; Diluent 38%; Essence 2%; Propellant 20%;
(2) chaotropic agent is added in retort or blending vat, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
Embodiment 5
The dirty spray of the waterproof and oilproof that the present embodiment provides and production technology thereof, substantially identical with embodiment 1,2,3,4, its difference is: the dirty spray of a kind of waterproof and oilproof, and it is made up of the component of following percetage by weight:
Preferably, described fluorine surfactant is organic fluorine and the long chain silane mixture that 1:0.35 is composite in mass ratio.
Preferably, butyl acetate, the ethyl acetate of described chaotropic agent to be mass ratio be 1:1;
Preferably, described diluent is hexane.
Preferably, described essence is lemon, sweet osmanthus; Described propellant is dimethyl ether.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluorine surfactant 8.9%; Chaotropic agent 17%; Diluent 25%; Essence 0.1%; Propellant 49%;
(2) chaotropic agent is added in retort or blending vat, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
Embodiment 6
The dirty spray of the waterproof and oilproof that the present embodiment provides and production technology thereof, substantially identical with embodiment 1,2,3,4,5, its difference is: the dirty spray of a kind of waterproof and oilproof, and it is made up of the component of following percetage by weight:
Preferably, described fluorine surfactant is organic fluorine and the long chain silane mixture that 1:0.5 is composite in mass ratio.
Preferably, described chaotropic agent is butyl acetate;
Preferably, described diluent is heptane;
Preferably, described essence is vanilla; Described propellant is the third butagas and dimethyl ether mass ratio is 1:1.
A production technology for the dirty spray of above-mentioned waterproof and oilproof, it comprises the steps:
(1) raw material is taken according to setting ratio: fluorine surfactant 10%; Chaotropic agent 30%; Diluent 10%; Essence 2%; Propellant 48%;
(2) chaotropic agent is added in retort or blending vat, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
The present invention is not limited to above-mentioned embodiment, adopts component, the method identical or approximate with the above embodiment of the present invention, and the dirty spray of other waterproof and oilproofs obtained and production technology thereof, all within scope.
Claims (9)
1. the dirty spray of waterproof and oilproof, is characterized in that, be made up of the component of following percetage by weight:
2. the dirty spray of waterproof and oilproof according to claim 1, is characterized in that, described fluorine surfactant is one or both in perfluoroalkyl acrylate, perfluor alkyl ethyl acrylate.
3. the dirty spray of waterproof and oilproof according to claim 1, it is characterized in that, described fluorine surfactant is organic fluorine and the long chain silane mixture that 1:0.2-0.5 is composite in mass ratio.
4. the dirty spray of waterproof and oilproof according to claim 1, is characterized in that, described chaotropic agent is that kerosene and ester class are as one or both in ethyl acetate, butyl acetate; Described diluent be in ethanol, methyl alcohol, isopropyl alcohol or propane, butane, pentane, hexane, heptane one or both or multiple composite.
5. the dirty spray of waterproof and oilproof according to claim 1, it is characterized in that, described essence is one or more in lemon, sweet osmanthus, vanilla; Described propellant is one or both in the third butagas, liquefied petroleum gas or dimethyl ether gas.
6. a production technology for the dirty spray of the waterproof and oilproof that one of claim 1-5 is described, is characterized in that, comprise the steps:
(1) raw material is taken according to setting ratio: fluoride silicon surfactant 2-10%; Chaotropic agent 5-30%; Diluent 10-40%; Essence 0.1-2%; Propellant 20-50%;
(2) chaotropic agent is added in retort or blending vat, normal temperature and pressure mix and blend 20-30min, add fluoride silicon surfactant lentamente simultaneously, be uniformly mixed 10min afterwards, add diluent and essence, after in stirring at low speed 10min, gained compound is distributed in inhalator jar, can or aluminium pot, sealing;
(3) fill with propellant in the tank of step (2), shower nozzle and lid are set on tank afterwards.
7. the production technology of the dirty spray of waterproof and oilproof according to claim 6, it is characterized in that, in described step (1) fluorine surfactant be perfluoroalkyl acrylate, perfluor alkyl ethyl acrylate one or both or be organic fluorine and the long chain silane composite mixture of 1:0.2-0.5 in mass ratio.
8. the production technology of the dirty spray of waterproof and oilproof according to claim 6, is characterized in that, in described step (1), chaotropic agent is one or both in kerosene or ethyl acetate, butyl acetate; Described diluent be in ethanol, methyl alcohol, isopropyl alcohol or propane, butane, pentane, hexane, heptane one or both or multiple composite.
9. the production technology of the dirty spray of waterproof and oilproof according to claim 6, is characterized in that, in described step (1), essence is one or more in lemon, sweet osmanthus, vanilla; Described propellant is one or both in the third butagas, liquefied petroleum gas or dimethyl ether gas.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410837713.3A CN104594032A (en) | 2014-12-29 | 2014-12-29 | Waterproof anti-grease contamination spray and production process thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410837713.3A CN104594032A (en) | 2014-12-29 | 2014-12-29 | Waterproof anti-grease contamination spray and production process thereof |
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| CN201410837713.3A Pending CN104594032A (en) | 2014-12-29 | 2014-12-29 | Waterproof anti-grease contamination spray and production process thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106119443A (en) * | 2016-06-15 | 2016-11-16 | 崔晓雪 | The grease proofing antifouling nursing agent of aerosol type surface waterproofing |
| CN109233477A (en) * | 2017-04-27 | 2019-01-18 | 广州赫厉狮森汽车用品有限公司 | A kind of self-cleaning spray of waterproof and oilproof and preparation method thereof |
| CN114908579A (en) * | 2022-05-30 | 2022-08-16 | 南京中敖日化科技有限公司 | Water-proof and oil-resistant aerosol for surface and vamp of clothes and preparation method thereof |
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| CN104018342A (en) * | 2014-06-06 | 2014-09-03 | 佛山市泰克斯乐科技有限公司 | Aerosol can type water and oil repellent product and preparation method thereof |
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| CN1167798A (en) * | 1996-06-06 | 1997-12-17 | 李峰 | Spray leahter care polishing agent |
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Application publication date: 20150506 |