CN106349463A - Odorless alkyd resin and preparation method thereof - Google Patents
Odorless alkyd resin and preparation method thereof Download PDFInfo
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- CN106349463A CN106349463A CN201610720425.9A CN201610720425A CN106349463A CN 106349463 A CN106349463 A CN 106349463A CN 201610720425 A CN201610720425 A CN 201610720425A CN 106349463 A CN106349463 A CN 106349463A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
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- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention provides an odorless alkyd resin which comprises the following raw materials in parts by weight: 27-32 parts of dibasic acid or acid anhydride, 19-33 parts of alcohol, 11-22 parts of fatty acid, 1-5 parts of benzoic acid, 0.5-3 parts of vegetable oil, 25-50 parts of solvent and 0.03-0.2 part of antioxidant. The alcohol is dibasic alcohol and/or polylol. The alkyd resin provided by the invention has obviously higher dryness, and maintains the advantages of low odor and quick odor dissipation in the coating, paint and other products made from the alkyd resin. The odorless alkyd resin still has longer activation period in a high-temperature construction environment. The combination of the odorless alkyd resin and the matte paint has the advantages of favorable matting property and favorable comprehensive properties of the paint film. In practical application, the odorless alkyd resin can be well cured even at the low temperature of 0 DEG C, is basically odorless 12 hours after being sprayed and almost odorless after 24 hours, and thus, achieves the level of approximate to the water-based odorless paint.
Description
Technical field
The invention belongs to chemical field is and in particular to a kind of net taste alkyd resin and preparation method thereof.
Background technology
At present, after conventional alkyd resin based coatings have house ornamentation spraying application, abnormal smells from the patient is big, the lacking of abnormal smells from the patient residence time length
Point, badly influences the air ambient of interior, is unfavorable for the lifting of quality of life it is suppressed that consumption increases, particularly constrains
The development further of oil paint.
With Chinese national economy sustained and rapid development, environmental conservation is increasingly paid attention to, to net taste alkyd resin and adopt
The use demand of the alkyd resin based coatings being obtained with it increasingly increases.In order to better meet related needs, current this area
Some researchs are carried out with regard to reducing paint film odor, after finding spraying, the abnormal smells from the patient of residual is mainly derived from film forming procedure and can not join
The small-molecule mixture that again can not vapor away in time with curing reaction, therefore reducing the minimizing that it is critical only that of paint film odor, these are little
The ratio of molecular substance.In prior art by do not replaced using vegetable oil using fatty acid method, to subtract
The ratio of few free fatty, is finally reached the relatively low effect of abnormal smells from the patient after construction.However, the plant due to more amount to be used
Oil, is necessary for the step for high temperature alcoholysis, otherwise because vegetable oil is poor with the compatibility of resin, very on operating procedure
The phenomenon of turbid appearance easily occurs and to ultimately result in paint film property poor.And the consequence that alcoholysis brings is exactly under production efficiency
Fall, the color of resin is also deep simultaneously.In addition, through actual contrast, replacing fatty acid not shut out completely with vegetable oil
The abnormal smells from the patient of exhausted film.Therefore, in terms of reducing film abnormal smells from the patient, existing alkyd resin based coatings still suffer from defect in performance,
For example net taste is not sufficiently effective, occurs in that the partially slow problem of coating dryness simultaneously, particularly after temperature is down to zero, generally arrives
The degree that almost cannot solidify, has had a strong impact on the production efficiency of application unit.This defect constrains pushing away of this kind of product
Wide and application, particularly in the temperature such as North China lower ground area.
Content of the invention
For the problems referred to above, the invention provides the alkyd resin that a kind of dryness and net taste effect get a promotion simultaneously, should
Alkyd resin has that abnormal smells from the patient is low after forming paint film, and dissipate fast feature, has preferable dryness, in sub-zero temperature simultaneously
The lower solidification effect of degree is good.
Technical scheme for realizing above-mentioned purpose is as follows:
The present invention provides a kind of net taste alkyd resin, and its raw material comprises binary acid or anhydride, alcohol, fatty acid, benzoic acid, plant
Thing oil, solvent, antioxidant；
Wherein, count by weight, the amount of each raw material is: binary acid or anhydride 27-32 part, alcohol 19-33 part, fatty acid
11-22 part, benzoic acid 1-5 part, vegetable oil 0.5-3 part, solvent 25-50 part, antioxidant 0.03-0.2 part；
Preferably, count by weight, the amount of each raw material is: binary acid or 27.7 parts of anhydride, 27.7 parts of alcohol, fatty acid
15.3 parts, 3.1 parts of benzoic acid, 1.3 parts of vegetable oil, 30.0 parts of solvent, 0.07 part of antioxidant；
Wherein said alcohol is dihydroxylic alcohols and/or polyhydric alcohol.
Preferably, described binary acid or anhydride be selected from one of phthalic anhydride, adipic acid or M-phthalic acid or
Multiple；Preferably, described binary acid or anhydride are phthalic anhydride.
Preferably, described polyhydric alcohol is trimethylolpropane and/or tetramethylolmethane, preferably trimethylolpropane；
Preferably, described dihydroxylic alcohols are selected from one or more of neopentyl glycol, diethylene glycol, ethylene glycol or hexanediol.
Preferably, described fatty acid is selected from one of synthetic fatty acid, Oleic acid, linoleic acid, cocinic acid or lauric acid
Or it is multiple；Preferably, described synthetic fatty acid is selected from c6-c14Fatty acid and its mixture；Preferably, described fatty acid is the moon
Cinnamic acid.
Preferably, described vegetable oil is selected from one or more of Oleum Glycines, oleum lini, Chinese tallowtree seed oil or Oleum Ricini it is preferable that institute
State vegetable oil and be selected from oleum lini.
Preferably, described solvent is selected from xylene solution and/or butyl acetate；Preferably, described xylene solution is dense
Spend for >=99.5%.
Preferably, described antioxidant is selected from hypophosphorous acid and/or triphenyl phosphite.
The present invention also provides a kind of preparation method of alkyd resin of the present invention, and described preparation method includes walking as follows
Rapid:
(1) binary acid or anhydride, the alcohol of 30-70% (percentage by weight), fatty acid, benzoic acid, 2.8- are taken in proportion
The solvent of 12% (percentage by weight) and antioxidant, heat up, are passed through co2, after backflow 0.5-3h, it is cooled to 120-160 DEG C；
(2) add surplus alcohol and vegetable oil in the reactant obtaining to step (1), heat up, reacting to viscosity is 10-90
Second, after be cooled to 120-160 DEG C, add balance solvent, stir, obtain final product；
Preferably, heat up as being warming up to backflow described in described step (1)；
Preferably, heat up as being warming up to 200-205 DEG C described in described step (2).
Preferably, described preparation method comprises the steps:
(1) binary acid or anhydride, the alcohol of 30-70% (percentage by weight), fatty acid, benzoic acid, 2.8- are taken in proportion
The solvent of 12% (percentage by weight) and antioxidant, are warming up to backflow, are passed through co2, after backflow 0.5-3 hour, it is cooled to 120-
160℃；
(2) add surplus alcohol and vegetable oil in the reactant obtaining to step (1), be warming up to 200-205 DEG C, react to acid
Value≤16mgkoh/g, viscosity be the 10-90 second, after be cooled to 120-160 DEG C, add balance solvent, stir, obtain final product.
The alkyd resin that alkyd resin of the present invention and preparation method of the present invention obtain is preparing coating, paint
In purposes.
The alkyd resin that the present invention provides has been obviously improved the dryness of resin, maintains simultaneously and is prepared by described alkyd resin
The abnormal smells from the patient of the products such as the coating that obtains, paint is low, dissipate fast advantage；Still there is under construction at high temperature environment longer pot-life；
When joining dumb light paint, extinction performance and paint film combination property are good；In actual applications, even also can be good in a low temperature of zero degree
Good solidification, substantially can't smell abnormal smells from the patient after spraying 12h, almost can't smell abnormal smells from the patient, reached the water close to aqueouss net taste coating after 24h
Flat.
Specific embodiment
Referring to specific embodiment, the present invention to be described.It will be appreciated by those skilled in the art that these embodiments are only
For the present invention is described, it limits the scope of the present invention never in any form.
Experimental technique in following embodiments, if no special instructions, is conventional method.Used former in following embodiments
Material, reagent material etc., if no special instructions, are commercially available purchase product.
Embodiment 1: the preparation of alkyd resin of the present invention
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
14g Oleic acid, 264g phthalic anhydride, 140g lauric acid, 31g benzoic acid, 93g trimethylolpropane, 14g adipic acid, heat up
Logical co2, stirring, it is cooled to 140-150 DEG C after backflow 1h, add 184g tetramethylolmethane, 14g oleum lini, be warming up to 200 DEG C,
It is incubated between 200-205 DEG C, start viscosimetric to acid number≤16mgkoh/g, to viscosity in the 30-50 second, be cooled to 120-140
DEG C, the concentration of addition 195g is 99.5% xylene solution, 88g butyl acetate latting drown, filtering and discharging after stirring.
Embodiment 2: the preparation of alkyd resin of the present invention
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
14g Oleic acid, 217g phthalic anhydride, 140g lauric acid, 31g benzoic acid, 93g trimethylolpropane, 60g adipic acid, heat up
Logical co2, stirring, it is cooled to 140-150 DEG C after backflow 1h, add 184g tetramethylolmethane, 14g oleum lini, be warming up to 200 DEG C,
It is incubated between 200-205 DEG C, start viscosimetric to acid number≤16mgkoh/g, to viscosity in the 25-40 second, be cooled to 120-140
DEG C, the concentration of addition 195g is 99.5% xylene solution, 88g butyl acetate latting drown, filtering and discharging after stirring.
Embodiment 3: the preparation of alkyd resin of the present invention
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
14g Oleic acid, 264g phthalic anhydride, 130g lauric acid, 31g benzoic acid, 200g trimethylolpropane, 14g adipic acid, heat up
Logical co2, stirring, it is cooled to 140-150 DEG C after backflow 1h, add 100g tetramethylolmethane, 14g oleum lini, be warming up to 200 DEG C,
It is incubated between 200-205 DEG C, start viscosimetric to acid number≤16mgkoh/g, to viscosity in the 25-40 second, be cooled to 120-140
DEG C, the concentration of addition 200g is 99.5% xylene solution, 88g butyl acetate latting drown, filtering and discharging after stirring.
Table 1: alkyd resin performance of the present invention
Abnormal smells from the patient classification in table 1: 1 is tasteless, 2 substantially tasteless, 3 abnormal smells from the patients are faint, 4 abnormal smells from the patients are obvious, 5 abnormal smells from the patients are strong.
As seen from Table 1, net taste alkyd resin of the present invention achieves good net taste effect, and abnormal smells from the patient dissipates soon, same
When dryness and paint film satisfactory mechanical property.
Comparative example 1: the preparation of alkyd resin
The xylene solution of concentration ＞ 60% of 17g, 0.7g hypophosphorous acid, 14g is sequentially added in 1000ml four-hole boiling flask
Oleic acid, 264g phthalic anhydride, 140g lauric acid, 31g benzoic acid, 93g trimethylolpropane, 14g adipic acid, 184g season penta
Tetrol, 14g oleum lini, heat up logical co2, stirring, it is cooled to 150-140 DEG C after backflow 1h, separating esterification water after backflow makes temperature
Rise to 200 DEG C, be incubated between 200-205 DEG C, start viscosimetric to acid number≤16mgkoh/g, to viscosity in 30-50
Second, it is cooled to 120-140 DEG C, add the xylene solution of concentration ＞ 60%, the 88g butyl acetate latting drown of 195g, stir
Filtering and discharging afterwards.
Comparative example 2: the preparation of alkyd resin
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
221g Oleic acid, 264g phthalic anhydride, 31g benzoic acid, 93g trimethylolpropane, 14g adipic acid, 184g tetramethylolmethane,
14g oleum lini, heat up logical co2, stirring, it is cooled to 150-140 DEG C after backflow 1h, separating esterification water after backflow makes temperature rise to
200 DEG C, it is incubated between 200-205 DEG C, starts viscosimetric to acid number≤16mgkoh/g, to viscosity in the 20-35 second, lower the temperature
To 120-140 DEG C, the concentration of addition 220g is 99.5% xylene solution, 88g butyl acetate latting drown, filters after stirring
Discharging.
Comparative example 3: the preparation of alkyd resin
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
14g Oleic acid, 264g phthalic anhydride, 86g lauric acid, 64g benzoic acid, 93g trimethylolpropane, 14g adipic acid, heat up logical
co2, stirring, after being cooled to 150-140 DEG C after backflow 1h, add 184g tetramethylolmethane, 14g oleum lini, be warming up to 200 DEG C,
It is incubated between 200-205 DEG C, start viscosimetric to acid number≤16mgkoh/g, to viscosity in the 30-50 second, be cooled to 120-140
DEG C, the concentration of addition 195g is 99.5% xylene solution, 80g butyl acetate latting drown, filtering and discharging after stirring.
Comparative example 4: the preparation of alkyd resin
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
14g Oleic acid, 268g phthalic anhydride, 142g lauric acid, 31g benzoic acid, 94g trimethylolpropane, 14g adipic acid, heat up
Logical co2, stirring, backflow 1h after be cooled to 150-140 DEG C, add 187g tetramethylolmethane, be warming up to 200 DEG C, 200-205 DEG C it
Between be incubated, to acid number≤16mgkoh/g start viscosimetric, to viscosity in the 30-50 second, be cooled to 120-140 DEG C, add 195g
Concentration be 99.5% xylene solution, 89g butyl acetate latting drown, filtering and discharging after stirring.
Comparative example 5: the preparation of alkyd resin
The concentration sequentially adding 17g in 1000ml four-hole boiling flask is 99.5% xylene solution, 0.7g hypophosphorous acid,
14g Oleic acid, 264g phthalic anhydride, 20g lauric acid, 31g benzoic acid, 93g trimethylolpropane, 14g adipic acid, heat up logical
co2, stirring, it is cooled to 150-140 DEG C after backflow 1h, add 184g tetramethylolmethane, 134g oleum lini, be warming up to 200 DEG C,
It is incubated between 200-205 DEG C, start viscosimetric to acid number≤16mgkoh/g, to viscosity in the 10-30 second, be cooled to 120-140
DEG C, the concentration of addition 195g is 99.5% xylene solution, 88g butyl acetate latting drown, filtering and discharging after stirring.
Table 2: the performance comparison of alkyd resin of the present invention and the alkyd resin prepared by comparative example
Abnormal smells from the patient classification in table 2: 1 is tasteless, 2 substantially tasteless, 3 abnormal smells from the patients are faint, 4 abnormal smells from the patients are obvious, 5 abnormal smells from the patients are strong.
As seen from Table 2, when in comparative example 1 concentration be 99.5% xylene solution change into concentration ＞ 60% dimethylbenzene molten
During liquid, the abnormal smells from the patient of obtained alkyd resin dissipates relatively slowly, and after spraying 24h, paint film just reaches the degree of substantially tasteless；Work as contrast
In example 2, the ratio of Oleic acid is improved to after 22.1%, paint film odor clearly, even paint film is still also after spraying 24h
There is faint abnormal smells from the patient；After benzoic ratio being improved to 6.4% in comparative example 3, substantially and the residence time is long for abnormal smells from the patient, spray
After applying 24h, paint film still also has faint odor.After not using vegetable oil in comparative example 4, in addition to dryness is slightly decreased, abnormal smells from the patient
And other performances have no significant change.In comparative example 5, the ratio of vegetable oil is improved to after 13.4 parts, due to vegetable oil and resin
The compatibility is poor, leads to resin turbid appearance, and the performance of paint film each side is all poor, and abnormal smells from the patient also receives large effect.
Alkyd resin of the present invention has been obviously improved the dryness especially low temperature dryness of resin, applying in high temperature environments
Work pot-life longer (gel time), paint film combination property is good, and substantially tasteless after spraying 24h, for preparing net taste coating, paint
There is provided filmogen Deng product.
Claims (11)
1. a kind of net taste alkyd resin, its raw material comprises binary acid or anhydride, alcohol, fatty acid, benzoic acid, vegetable oil, solvent, resists
Oxygen agent；
Wherein, count by weight, the amount of each raw material is: binary acid or anhydride 27-32 part, alcohol 19-33 part, fatty acid 11-22
Part, benzoic acid 1-5 part, vegetable oil 0.5-3 part, solvent 25-50 part, antioxidant 0.03-0.2 part.
2. it is characterised in that counting by weight, the amount of each raw material is alkyd resin according to claim 1: binary acid
Or 27.7 parts of anhydride, 27.7 parts of alcohol, 15.3 parts of fatty acid, 3.1 parts of benzoic acid, 1.3 parts of vegetable oil, 30.0 parts of solvent, antioxidant
0.07 part；
Wherein said alcohol is dihydroxylic alcohols and/or polyhydric alcohol.
3. alkyd resin according to claim 1 is it is characterised in that described binary acid or anhydride are selected from phthalic acid
One or more of acid anhydride, adipic acid or M-phthalic acid；Preferably, described binary acid or anhydride are phthalic anhydride.
4. alkyd resin according to any one of claim 1 to 3 is it is characterised in that described polyhydric alcohol is trihydroxy methyl
Propane and/or tetramethylolmethane, preferably trimethylolpropane；
Preferably, described dihydroxylic alcohols are selected from one or more of neopentyl glycol, diethylene glycol, ethylene glycol or hexanediol.
5. alkyd resin according to any one of claim 1 to 4 is it is characterised in that described fatty acid is selected from synthetic fat
One or more of fat acid, Oleic acid, linoleic acid, cocinic acid or lauric acid；Preferably, described synthetic fatty acid is selected from c6-
c14Fatty acid and its mixture；Preferably, described fatty acid is lauric acid.
6. alkyd resin according to any one of claim 1 to 5 is it is characterised in that described vegetable oil is selected from Oleum Glycines, Asia
One or more of Oleum Sesami, Chinese tallowtree seed oil or Oleum Ricini are it is preferable that described vegetable oil is selected from oleum lini.
7. alkyd resin according to any one of claim 1 to 6 is it is characterised in that described solvent is molten selected from dimethylbenzene
Liquid and/or butyl acetate；Preferably, the concentration of described xylene solution is >=99.5%.
8. alkyd resin according to any one of claim 1 to 7 is it is characterised in that described antioxidant is selected from hypophosphorous acid
And/or triphenyl phosphite.
9. a kind of preparation method of alkyd resin according to any one of claim 1 to 8, described preparation method include as
Lower step:
(1) binary acid or anhydride, the alcohol of 30-70% (percentage by weight), fatty acid, benzoic acid, 2.8-12% (weight are taken in proportion
Amount percentage ratio) solvent and antioxidant, heat up, be passed through co2, after backflow 0.5-3h, it is cooled to 120-160 DEG C；
(2) add surplus alcohol and vegetable oil in the reactant obtaining to step (1), heat up, reacting to viscosity is the 10-90 second, after
It is cooled to 120-160 DEG C, add balance solvent, stir, obtain final product；
Preferably, heat up as being warming up to backflow described in described step (1)；
Preferably, it is warming up to 200-205 DEG C described in described step (2).
10. preparation method according to claim 9, described preparation method comprises the steps:
(1) binary acid or anhydride, the alcohol of 30-70% (percentage by weight), fatty acid, benzoic acid, 2.8-12% (weight are taken in proportion
Amount percentage ratio) solvent and antioxidant, be warming up to backflow, be passed through co2, after backflow 0.5-3 hour, it is cooled to 120-160 DEG C；
(2) add surplus alcohol and vegetable oil in the reactant obtaining to step (1), be warming up to 200-205 DEG C, react to acid number≤
16mgkoh/g, viscosity be the 10-90 second, after be cooled to 120-160 DEG C, add balance solvent, stir, obtain final product.
Alkyd resin any one of 11. claim 1 to 8 and the preparation method described in claim 9 or 10 obtain
Alkyd resin prepare coating, paint in purposes.
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Cited By (11)
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| CN107151314A (en) * | 2017-06-08 | 2017-09-12 | 华伦纳路新材料有限公司 | A kind of stearic acid modified self-cleaning taste woodcare paint alkyd resin and preparation method thereof |
| CN107434847A (en) * | 2017-09-26 | 2017-12-05 | 广东美涂士建材股份有限公司 | A kind of net taste alkyd resin of high-solid lower-viscosity rapid draing and preparation method and application |
| CN108084422A (en) * | 2017-12-15 | 2018-05-29 | 合众（佛山）化工有限公司 | A kind of antibacterial aqueous alkyd resin of structural type and preparation method thereof |
| CN108624224A (en) * | 2017-03-20 | 2018-10-09 | 洛阳尖端技术研究院 | A kind of anti-adhesive coating material and preparation method thereof |
| CN109575255A (en) * | 2018-11-22 | 2019-04-05 | 三棵树涂料股份有限公司 | A kind of preparation method of ordor removing quick-drying alkide resin |
| CN109749614A (en) * | 2019-01-10 | 2019-05-14 | 广东鸿昌化工有限公司 | A kind of polyurethane ordor removing based white primer and preparation method thereof |
| CN112794995A (en) * | 2020-12-30 | 2021-05-14 | 广东花王涂料有限公司 | Odor-free resin, preparation method and application |
| CN112851920A (en) * | 2020-12-31 | 2021-05-28 | 东胜化学(上海)有限公司 | Alkyd resin and preparation method thereof |
| CN115449063A (en) * | 2022-10-24 | 2022-12-09 | 昆勒聚合物(上海)有限公司 | Low-odor high-hardness high-sealing-performance woodware sealing primer polymer |
| CN116102718A (en) * | 2022-12-12 | 2023-05-12 | 湖北嘉跃涂料有限公司 | Alkyd resin with high solid content and high flash point and odor removal and preparation method thereof |
| CN116355507A (en) * | 2023-03-15 | 2023-06-30 | 广东百川化工有限公司 | High-transparency aconitum kusnezoffii primer with long coating effective period after blending and preparation method thereof |
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| CN107151314A (en) * | 2017-06-08 | 2017-09-12 | 华伦纳路新材料有限公司 | A kind of stearic acid modified self-cleaning taste woodcare paint alkyd resin and preparation method thereof |
| CN107434847B (en) * | 2017-09-26 | 2020-07-10 | 广东美涂士建材股份有限公司 | High-solid-content low-viscosity quick-drying odor-removing alkyd resin and preparation method and application thereof |
| CN107434847A (en) * | 2017-09-26 | 2017-12-05 | 广东美涂士建材股份有限公司 | A kind of net taste alkyd resin of high-solid lower-viscosity rapid draing and preparation method and application |
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| CN109575255A (en) * | 2018-11-22 | 2019-04-05 | 三棵树涂料股份有限公司 | A kind of preparation method of ordor removing quick-drying alkide resin |
| CN109575255B (en) * | 2018-11-22 | 2021-04-13 | 安徽三棵树涂料有限公司 | Preparation method of odorless quick-drying alkyd resin |
| CN109749614A (en) * | 2019-01-10 | 2019-05-14 | 广东鸿昌化工有限公司 | A kind of polyurethane ordor removing based white primer and preparation method thereof |
| CN112794995A (en) * | 2020-12-30 | 2021-05-14 | 广东花王涂料有限公司 | Odor-free resin, preparation method and application |
| CN112851920A (en) * | 2020-12-31 | 2021-05-28 | 东胜化学(上海)有限公司 | Alkyd resin and preparation method thereof |
| CN112851920B (en) * | 2020-12-31 | 2021-12-07 | 东胜化学(上海)有限公司 | Alkyd resin and preparation method thereof |
| CN115449063A (en) * | 2022-10-24 | 2022-12-09 | 昆勒聚合物(上海)有限公司 | Low-odor high-hardness high-sealing-performance woodware sealing primer polymer |
| CN116102718A (en) * | 2022-12-12 | 2023-05-12 | 湖北嘉跃涂料有限公司 | Alkyd resin with high solid content and high flash point and odor removal and preparation method thereof |
| CN116355507A (en) * | 2023-03-15 | 2023-06-30 | 广东百川化工有限公司 | High-transparency aconitum kusnezoffii primer with long coating effective period after blending and preparation method thereof |
| CN116355507B (en) * | 2023-03-15 | 2024-02-09 | 广东百川化工有限公司 | High-transparency aconitum kusnezoffii primer with long coating effective period after blending and preparation method thereof |
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