CN104592861A - Antifouling anticorrosion coating for surfaces of steel structures - Google Patents

Antifouling anticorrosion coating for surfaces of steel structures Download PDF

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Publication number
CN104592861A
CN104592861A CN201510095601.XA CN201510095601A CN104592861A CN 104592861 A CN104592861 A CN 104592861A CN 201510095601 A CN201510095601 A CN 201510095601A CN 104592861 A CN104592861 A CN 104592861A
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steel structure
structure surface
antifouling
anticorrosive coating
parts
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CN201510095601.XA
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CN104592861B (en
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夏学云
宋国新
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Shanghai Min Xuan Steel Structure Work Co Ltd
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Shanghai Min Xuan Steel Structure Work Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1606Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612Non-macromolecular compounds
    • C09D5/1625Non-macromolecular compounds organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses an antifouling anticorrosion coating for surfaces of steel structures. The antifouling anticorrosion coating comprises the following components in part by weight: 10-30 parts of epoxy resin, 10-30 parts of perchlorovinyl resin, 4-8 parts of talc powder, 1-3 parts of titanium dioxide, 0.4-1 part of nano-silica, 4-8 parts of tetrabutyl orthosilicate, 0.5-3 parts of coalescing agent, 0.2-2 parts of antifouling bactericide and 15-35 parts of solvent. The antifouling anticorrosion coating has excellent antifouling anticorrosion effect and especially has antibacterial effect; the formed coatings have excellent impact resistance and are widely applicable to factories, warehouses, residential buildings, hospitals, office buildings, shopping malls, waiting rooms and many other places as well as instruments.

Description

The antifouling anticorrosive coating of steel structure surface
Technical field
The present invention relates to a kind of coating, be specifically related to the antifouling anticorrosive coating of a kind of steel structure surface.
Background technology
Steel structure surface priming paint mainly uses modified polyester resin or epoxy resin, guarantees thus and the adaptation of matrix steel plate, erosion resistance etc.In addition, outside surface investment precoat uses polyester, acrylic coating etc., thus, stain resistance (stain resistance), ornamental (decorativeness), scratch resistance (scratchresistance), shielding etc. is mainly given.On the other hand, this precoated steel plate (precoated steel sheet) application (painting), process number when baking (baking) are many, time for it is also many, therefore from the view point of rationalization, the saving resource of painting operation, the filming of film is expected.
Steel structure surface requires the performance that high rigidity, high working property, stain resistance, chemical resistant properties (chemicalresistance), water tolerance, erosion resistance etc. are more.Wherein, for carrying out application, baking the precoated steel plate of rear enforcement punch process, processibility particularly punch process (pressformability) is very important performance.Here so-called punch process, refers to that the painting membrane damage in the operations such as bending, drawing when being processed into different shape by flat metal plate, cutting is few.In the processing such as bending machining of comparing mitigation, the stretching of film itself, the larger then processibility of the degree of flexibility are better.In the strict punch process as drawing processing (drawing), except stretching, the flexibility of film, can deformation resistant or add the intensity of stress in man-hour and scratch resistance also very important.Therefore, work out one and can form both antifouling protection against corrosions, again there is damage resistant, there is the coating of the film of better shock-resistance simultaneously, be extremely important.
In addition, the antifouling anticorrosive coating of steel structure surface of the prior art, be often referred to for general greasy dirt, soda acid spot etc., can not be effectively antibacterial, when some are higher to hygienic requirements, needing often to carry out artificial disinfection could use, and the antifouling anticorrosive coating commonly used in prior art, usually, containing elements such as zinc, tin, copper, after long-time use, variable color may be caused or generate the objectionable impuritiess such as Red copper oxide.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide the antifouling anticorrosive coating of a kind of steel structure surface, there is good anti-pollution corrosion-proof effect, especially there is antibacterial effect, the film formed has good shock-resistance, can be widely used in many places and the apparatuses such as factory building, warehouse, residential building, hospital, office building, market, Waiting Lounge.
The present invention seeks to be achieved through the following technical solutions:
The antifouling anticorrosive coating of a kind of steel structure surface, comprises the component of following weight parts:
Preferably, described anti-soil degerming agent is the mixture of one or more in rhabarberone, Betulinic acid and methyl nonyl ketone.
Preferred further, described anti-soil degerming agent is made up of the component of following weight parts:
Rhabarberone 15-30 part,
Betulinic acid 10-30 part,
Methyl nonyl ketone 20-40 part.
Described solvent is preferably acetone, propyl alcohol or ethyl acetate.
Described film coalescence aid is preferably propandiol butyl ether, 1-Methoxy-2-propyl acetate or the mixture of the two, more preferably the mixture of propandiol butyl ether and 1-Methoxy-2-propyl acetate weight ratio 1:2-2:1.
In the present invention,
Supervinyi chloride resin is the product of the further chlorination of polyvinyl chloride.Relative density (20 DEG C) is 1.6g/cm 3, chlorinity is 61%-65%, and all there are production in the companies such as Jia Hong Chemical Co., Ltd. of Jinan City, the firm beautiful jade chemical industry of Law Firm Suzhou Jiangsu.Polyvinyl chloride (PVC) RESINS obtains through chlorinated with chlorine in the presence of solvent, has excellent molten Jie's characteristic, good electrical insulating property, thermoplasticity and film-forming properties, chemical property is very stable, corrosion-resistant, water-fast, nonflammable, ketone, hydrochloric ether, aromatic hydrocarbons, ester and part alcohols can be dissolved in.It is good membrane-forming agent.
Epoxy resin, is preferably bisphenol A type epoxy resin, i.e. propanepoxy resin, is obtained by dihydroxyphenyl propane and epoxy chloropropane.
Rhabarberone, chemistry Aloe-emodin by name, No. CAS: 481-72-1.
Betulinic acid, No. CAS: 472-15-1.
Methyl nonyl ketone, No. CAS: 112-12-9.
Butyl silicate, No. CAS: 4766-57-8.Be commonly used for linking agent.
Talcum powder, No. CAS: 14807-96-6.
Titanium dioxide, is preferably rutile-type.
Present invention also offers the preparation method of the antifouling anticorrosive coating of described steel structure surface, it comprises the following steps:
(1) take talcum powder, titanium dioxide and nano silicon by proportioning, after mixing, obtain mixed powder;
(2) take epoxy resin and supervinyi chloride resin by proportioning, after adding solvent, stir, then add the mixed powder that step (1) obtains wherein;
(3) add butyl silicate, anti-soil degerming agent, film coalescence aid successively in the mixture obtained to step (2), stir.
Contriver is found by great many of experiments, there is good anti-pollution corrosion-proof effect, especially have antibacterial effect, the film of formation has good shock-resistance, can be widely used in many places and the apparatuses such as factory building, warehouse, residential building, hospital, office building, market, Waiting Lounge.And not containing elements such as copper, tin, zinc in product, variable color can not occur after using the long period or produce toxic substance.
Also find under study for action, in the present invention, use the anti-soil degerming agent that rhabarberone, Betulinic acid and methyl nonyl ketone are composite, there is better anti-soil bacteria-eliminating efficacy, between several component, there is synergistic function.In addition, when using propandiol butyl ether, 1-Methoxy-2-propyl acetate as film coalescence aid simultaneously, the shock-resistance of the film of formation is better.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
The preparation method of the antifouling anticorrosive coating of steel structure surface described in embodiment, all carries out according to following steps:
(1) take talcum powder, titanium dioxide and nano silicon by proportioning, after mixing, obtain mixed powder;
(2) take epoxy resin and supervinyi chloride resin by proportioning, after adding solvent, stir, then add the mixed powder that step (1) obtains wherein;
(3) add butyl silicate, anti-soil degerming agent, film coalescence aid successively in the mixture obtained to step (2), stir.
Embodiment 1
Take each component according to embodiment 1 data corresponding in table 1, obtain the antifouling anticorrosive coating of steel structure surface of embodiment 1 according to preceding method.
The steel structure surface antifouling anticorrosive coating formula table unit of table 1: embodiment 1-6: kilogram
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Bisphenol A type epoxy resin 30 30 30 30 30 30
Supervinyi chloride resin 20 20 20 20 20 20
Talcum powder 4 4 4 4 4 4
Titanium dioxide 2 2 2 2 2 2
Nano silicon 0.5 0.5 0.5 0.5 0.5 0.5
Butyl silicate 6 6 6 6 6 6
Propandiol butyl ether 1.6 1.6 1.6 1.6 0.8 /
1-Methoxy-2-propyl acetate / / / / 0.8 1.6
Rhabarberone 0.3 0.7 0.6 / 0.3 0.3
Betulinic acid 0.3 0.3 / 0.6 0.3 0.3
Methyl nonyl ketone 0.4 / 0.4 0.4 0.4 0.4
Acetone 15 15 15 15 15 15
Embodiment 2
Take each component according to embodiment 2 data corresponding in table 1, according to method described in embodiment 1, obtain the antifouling anticorrosive coating of steel structure surface of embodiment 2.
Embodiment 3
Take each component according to embodiment 3 data corresponding in table 1, according to method described in embodiment 1, obtain the antifouling anticorrosive coating of steel structure surface of embodiment 3.
Embodiment 4
Take each component according to embodiment 4 data corresponding in table 1, according to method described in embodiment 1, obtain the antifouling anticorrosive coating of steel structure surface of embodiment 4.
Embodiment 5
Take each component according to embodiment 5 data corresponding in table 1, according to method described in embodiment 1, obtain the antifouling anticorrosive coating of steel structure surface of embodiment 5.
Embodiment 6
Take each component according to embodiment 6 data corresponding in table 1, according to method described in embodiment 1, obtain the antifouling anticorrosive coating of steel structure surface of embodiment 6.
Test case 1
Respectively performance test is carried out to the steel plate after the antifouling anticorrosive coating of the steel structure surface of embodiment 1-6 and film, film steel plate adopts spread coating, individual layer film is carried out to the surface of steel plate of long 1m, wide 0.5m, thick 0.05m, coating thickness is about 10 μm, test, testing standard and test result are in table 2.
The performance test table of table 2: embodiment 1-6
Note:
1. acid resistance measuring method: in 5%NaCl solution, add Glacial acetic acid, regulate pH to 3.1-3.3, every day sprays twice, each 10min, tests after 44 days;
2. stain resistance testing method: in test film surface coated マ ジ Star Network イ Application キ (registered trademark) (red and black), place 24 hours, with impregnation after the cloth wiping of ethanol, by range estimation, outward appearance is evaluated: 1 grade: there is no ink residue completely; 2 grades: have a little ink residue; 3 grades: have more ink residue
3. germ resistance testing method: under being placed in envrionment temperature 55 DEG C, relative humidity 85% environment, continuous observation.
Result shows, the antifouling anticorrosive coating of steel structure surface that embodiment 1-6 is obtained, there is good anti-pollution corrosion-proof effect, especially there is antibacterial effect, the film formed has good shock-resistance, can be widely used in many places and the apparatuses such as factory building, warehouse, residential building, hospital, office building, market, Waiting Lounge.And not containing elements such as copper, tin, zinc in product, variable color can not occur after using the long period or produce toxic substance.
Embodiment 1 is compared with embodiment 2-4, employ the anti-soil degerming agent that rhabarberone, Betulinic acid and methyl nonyl ketone are composite, there is better anti-soil bacteria-eliminating efficacy, between several component, there is synergistic function, when total amount is identical, than using, the combined effect of wherein any two groups is better.
In addition, embodiment 5 is compared with 6 with embodiment 1, and when using propandiol butyl ether, 1-Methoxy-2-propyl acetate as film coalescence aid, surface drying time is the shortest simultaneously, and the shock-resistance of the film of formation is better, and anti-corrosion effects is also better.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims (7)

1. the antifouling anticorrosive coating of steel structure surface, is characterized in that, comprises the component of following weight parts:
2. the antifouling anticorrosive coating of steel structure surface as claimed in claim 1, it is characterized in that, described film coalescence aid is propandiol butyl ether, 1-Methoxy-2-propyl acetate or the mixture of the two.
3. the antifouling anticorrosive coating of steel structure surface as claimed in claim 2, it is characterized in that, described film coalescence aid is the mixture of propandiol butyl ether and 1-Methoxy-2-propyl acetate weight ratio 1:2-2:1.
4. the antifouling anticorrosive coating of steel structure surface as claimed in claim 1, it is characterized in that, described anti-soil degerming agent is the mixture of one or more in rhabarberone, Betulinic acid and methyl nonyl ketone.
5. the antifouling anticorrosive coating of steel structure surface as claimed in claim 4, it is characterized in that, described anti-soil degerming agent is made up of the component of following weight parts:
Rhabarberone 15-30 part,
Betulinic acid 10-30 part,
Methyl nonyl ketone 20-40 part.
6. the antifouling anticorrosive coating of the steel structure surface according to any one of claim 1-5, is characterized in that, described solvent is acetone, propyl alcohol or ethyl acetate.
7. the preparation method of the antifouling anticorrosive coating of the steel structure surface according to any one of claim 1-6, is characterized in that, comprise the following steps:
(1) take talcum powder, titanium dioxide and nano silicon by proportioning, after mixing, obtain mixed powder;
(2) take epoxy resin and supervinyi chloride resin by proportioning, after adding solvent, stir, then add the mixed powder that step (1) obtains wherein;
(3) add butyl silicate, anti-soil degerming agent, film coalescence aid successively in the mixture obtained to step (2), stir.
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104927585A (en) * 2015-07-13 2015-09-23 上海金泛斯标识有限公司 Luminous paint for spray painted advertisements
CN105176286A (en) * 2015-08-18 2015-12-23 苏州赛斯德工程设备有限公司 Preparation method for marine anticorrosive paint
CN105348990A (en) * 2015-11-30 2016-02-24 芜湖成德龙过滤设备有限公司 Material composition and preparation method of corrosion-resistant coating
CN106282994A (en) * 2016-08-31 2017-01-04 苏州菲斯特电力科技有限公司 Power equipment low-voltage filter compensates complexes
CN106318106A (en) * 2015-06-15 2017-01-11 天长市开林化工有限公司 High flame-retardant epoxy resin heavy anticorrosive paint
CN106318130A (en) * 2015-06-15 2017-01-11 天长市开林化工有限公司 High-performance epoxy resin heavy anti-corrosion paint
CN106801451A (en) * 2017-02-27 2017-06-06 苏州科斯曼照明工程有限公司 A kind of maintenance process of Outdoor Fire Hydrant valve interior wall
CN107118693A (en) * 2017-04-11 2017-09-01 浙江洋铭工贸有限公司 One kind is used for die-casting aluminum heating radiator anticorrosive coating and preparation method thereof
CN107236339A (en) * 2016-07-04 2017-10-10 如皋长江科技产业有限公司 A kind of sports apparatus special anti-corrosion paint
CN107568969A (en) * 2017-07-27 2018-01-12 海盐派特普科技有限公司 One kind transmission rotary seat
CN108610892A (en) * 2018-05-05 2018-10-02 海南大学 A kind of ocean steel construction anticorrosion and antifouling water paint and preparation method thereof
CN109321054A (en) * 2018-09-25 2019-02-12 海南大学 A kind of preparation method of environmentally friendly marine anti-pollution anticorrosive paint
CN109337508A (en) * 2018-09-25 2019-02-15 海南大学 A kind of preparation method of marine anti-pollution anticorrosive paint
CN110028877A (en) * 2019-04-02 2019-07-19 安徽省欣雨环卫机械有限公司 A kind of sanitation cart environmental protection aromatic type antimicrobial coating and preparation method thereof

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CN103146283A (en) * 2011-12-07 2013-06-12 张庆之 Anticorrosion and antifouling material used for hull
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318106A (en) * 2015-06-15 2017-01-11 天长市开林化工有限公司 High flame-retardant epoxy resin heavy anticorrosive paint
CN106318130A (en) * 2015-06-15 2017-01-11 天长市开林化工有限公司 High-performance epoxy resin heavy anti-corrosion paint
CN104927585B (en) * 2015-07-13 2018-10-16 上海金泛斯标识有限公司 Luminous paint for jet-printed advertisements
CN104927585A (en) * 2015-07-13 2015-09-23 上海金泛斯标识有限公司 Luminous paint for spray painted advertisements
CN105176286A (en) * 2015-08-18 2015-12-23 苏州赛斯德工程设备有限公司 Preparation method for marine anticorrosive paint
CN105348990B (en) * 2015-11-30 2017-11-07 芜湖成德龙过滤设备有限公司 The preparation method of corrosion-resistant finishes material compositions and corrosion-resistant finishes
CN105348990A (en) * 2015-11-30 2016-02-24 芜湖成德龙过滤设备有限公司 Material composition and preparation method of corrosion-resistant coating
CN107236339A (en) * 2016-07-04 2017-10-10 如皋长江科技产业有限公司 A kind of sports apparatus special anti-corrosion paint
CN106282994A (en) * 2016-08-31 2017-01-04 苏州菲斯特电力科技有限公司 Power equipment low-voltage filter compensates complexes
CN106801451A (en) * 2017-02-27 2017-06-06 苏州科斯曼照明工程有限公司 A kind of maintenance process of Outdoor Fire Hydrant valve interior wall
CN107118693A (en) * 2017-04-11 2017-09-01 浙江洋铭工贸有限公司 One kind is used for die-casting aluminum heating radiator anticorrosive coating and preparation method thereof
CN107568969A (en) * 2017-07-27 2018-01-12 海盐派特普科技有限公司 One kind transmission rotary seat
CN108610892A (en) * 2018-05-05 2018-10-02 海南大学 A kind of ocean steel construction anticorrosion and antifouling water paint and preparation method thereof
CN109321054A (en) * 2018-09-25 2019-02-12 海南大学 A kind of preparation method of environmentally friendly marine anti-pollution anticorrosive paint
CN109337508A (en) * 2018-09-25 2019-02-15 海南大学 A kind of preparation method of marine anti-pollution anticorrosive paint
CN110028877A (en) * 2019-04-02 2019-07-19 安徽省欣雨环卫机械有限公司 A kind of sanitation cart environmental protection aromatic type antimicrobial coating and preparation method thereof

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