CN103287048B - Production method for composite household board with metal printing - Google Patents
Production method for composite household board with metal printing Download PDFInfo
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- CN103287048B CN103287048B CN201310199457.5A CN201310199457A CN103287048B CN 103287048 B CN103287048 B CN 103287048B CN 201310199457 A CN201310199457 A CN 201310199457A CN 103287048 B CN103287048 B CN 103287048B
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 90
- 239000002184 metal Substances 0.000 title claims abstract description 90
- 238000007639 printing Methods 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 39
- 239000002131 composite material Substances 0.000 title abstract description 3
- 238000011282 treatment Methods 0.000 claims abstract description 43
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000004677 Nylon Substances 0.000 claims abstract description 34
- 239000002253 acid Substances 0.000 claims abstract description 34
- 229920001778 nylon Polymers 0.000 claims abstract description 34
- 229920000728 polyester Polymers 0.000 claims abstract description 34
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 20
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 20
- 239000003822 epoxy resin Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 20
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 20
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims description 49
- 238000000576 coating method Methods 0.000 claims description 49
- 238000012545 processing Methods 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 40
- 230000037452 priming Effects 0.000 claims description 37
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims description 33
- 239000004094 surface-active agent Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 22
- 239000003973 paint Substances 0.000 claims description 18
- 238000002161 passivation Methods 0.000 claims description 18
- 239000002966 varnish Substances 0.000 claims description 18
- 239000013530 defoamer Substances 0.000 claims description 15
- 229920005749 polyurethane resin Polymers 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 13
- 238000005097 cold rolling Methods 0.000 claims description 12
- 238000005554 pickling Methods 0.000 claims description 12
- 238000012805 post-processing Methods 0.000 claims description 12
- 238000004381 surface treatment Methods 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 6
- 238000005246 galvanizing Methods 0.000 claims description 6
- 238000005098 hot rolling Methods 0.000 claims description 6
- 238000009500 colour coating Methods 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 abstract description 12
- 230000001070 adhesive effect Effects 0.000 abstract description 12
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 19
- 239000010959 steel Substances 0.000 description 19
- 239000003513 alkali Substances 0.000 description 15
- 230000006872 improvement Effects 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000005238 degreasing Methods 0.000 description 6
- 239000002086 nanomaterial Substances 0.000 description 6
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- 230000000694 effects Effects 0.000 description 5
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- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
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- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
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- 238000003287 bathing Methods 0.000 description 1
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- WYWUBDZUGFHUML-UHFFFAOYSA-N butanedioic acid dimethyl butanedioate Chemical compound OC(=O)CCC(O)=O.COC(=O)CCC(=O)OC WYWUBDZUGFHUML-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Abstract
The invention provides a production method for a composite household board with metal printing. According to the production method, an interface treatment layer is formed by a resin main body, a solvent, a pigment, a levelling agent, a defoaming agent, an accelerant and an anti-wear agent in a specific ratio, specially aiming at metal substrates coated with polyester primers and printing layers formed from polyester materials, wherein the resin main body is the mixture of epoxy resin and acrylic resin in the ratio of 1:(2.5 3.5) of parts by weight; the solvent is the mixture of isophorone and dimethyl nylon acid in the ratio of 1:(2.5 3.5) of parts by weight; the various ingredients of the interface treatment layer are interacted and matched, and great in performance in the aspects of levelling property, anti-wear property, promotion for the adhesive force between the printing layer and the substrate, and the like.
Description
Technical field
The present invention relates to a kind of production method of metal stamp compound household plate, belong to household plate manufacturing technology field.
Background technology
Existing household plate on the market often only considers its serviceability when designing, and ignores its aesthetic property.Applicant, through carefully studying, attempts coloured coating metallic plate to apply to household plate field, while the performances such as its original wearability of maintenance, to obtaining good visual effect.
Coloured coating metallic plate refers to that metal base first sloughs surperficial grease, after the external coating pre-treatments such as surface passivation through tandem mill, on metal substrate, apply the priming paint of special component again, eventually pass the roller coat of ink, spraying or serigraphy finally to form a kind of composite with coloured coating.At present, coloured coating metallic plate has a wide range of applications in fields such as constructure screen wall, door-plate and warming plates, but, still coloured coating metallic plate is not applied to the example in household plate.Main cause is: in the wear-resisting larger occasion to floor class, after ink forms coloured coating on priming paint, adhesive force between coloured coating and priming paint does not often reach requirement, thus make coloured coating metallic plate in use often occur the situation that coloured coating comes off, namely " fall to paint " phenomenon, thus have impact on the use aesthetic property of coloured coating metallic plate, destroy its visual effect.
In order to overcome " falling paint " phenomenon, people improve the component of interface ink one after another, attempt to improve by the composition of interface ink the good combination power realizing coloured coating and ground.Chinese patent literature CN200810054117.2 discloses a kind of code-spraying printing ink and preparation method thereof, is prepared from by weight by following raw material and solvent: modified rosin resin 15-35, nitrocotton 3-15, pigment or dyestuff 2-10, butanone 20-50, isopropyl alcohol 5-20, toluene 10-30.This ink ink is stablized, and have higher adhesion property, but less at the adhesive force on polyethylene and polypropylene material surface, adhesion-tight degree is poor, and the toluene adopting content larger in its ink formulations, the feature of environmental protection is poor on polyolefine material surface.
Chinese patent literature CN101698764A discloses a kind of high-adhesion benzene-free environmentally-friendly universal jet ink and preparation method thereof, this code-spraying printing ink is prepared from by following raw material and solvent according to percentage by weight: modified chlorinated polypropylene resin 5-10, composite resin 1-5, butanone 70-89, dyestuff 2-6, conductive auxiliary agent 0.5-1.5; Plasticizer 1-3, atoleine 0.5-1.5, other auxiliary agent 1-3.Not containing benzene in code-spraying printing ink component disclosed in the document, environmental friendliness, and this ink has higher adhesive force on polyethylene, polypropylene and metal substrate.But the adhesive force between this ink and polyesters ground is poor.
In sum, how coloured coating metallic plate is applied in household plate, and there is good adhesion to guarantee that the aesthetic property of household plate is the technical barrier also do not solved in prior art between the metal substrate making it and be coated with polyesters material.
Summary of the invention
Therefore, the technical problem to be solved in the present invention is to provide the production method between a kind of metal substrate making stamp and be coated with polyesters priming paint with the metal stamp compound household plate compared with high-bond.
For this reason, the invention provides a kind of production method of metal stamp compound household plate, comprise following steps:
(1) production stage of metal printing card, comprises following concrete steps:
A. the step of metallic plate is prepared;
B. at the priming paint of the surface of metallic plate coating polyesters composition, to form priming coat;
C. on described priming coat, the interface processing ink of special component is applied, to form interface processing layer;
D. on described interface processing layer, the stamp of polyester material is carried out, to form printed layer;
E. coating post processing is carried out to the metallic plate with printed layer, to form metal printing card;
(2) step of the metal printing card production compound household plate adopting step (1) to obtain;
Described interface processing layer in described step C is formed by the component of following parts by weight:
Resin body 35-50 part
Solvent 25-35 part
High molecular surfactant 15-20 part
Pigment 18-25 part
Levelling agent 0.2-0.3 part
Defoamer 0.1-0.3 part
Promoter 0.2-0.3 part
Anti-wear agent 0.1-0.2 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:2.5-3.5;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:2.5-3.5.
Further, the described interface processing layer in described step C is formed by the component of following parts by weight:
Resin body 40-45 part
Solvent 25-30 part
High molecular surfactant 15-18 part
Pigment 18-22 part
Levelling agent 0.2-0.25 part
Defoamer 0.2-0.3 part
Promoter 0.25-0.3 part
Anti-wear agent 0.1-0.15 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:3;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:3.
Described promoter is BOK-M-201 or BOK-M-206.
Described promoter is the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 25-33 part, the parts by weight of described hc-surfactant are 35-55 part, and the parts by weight of described nylon acid dimethyl ester are 20-65 part.
Described pigment is the one in R706, R900 or R902 of Du Pont China Holding Co., Ltd.'s production; Described levelling agent is B0K-L-301 or B0K-L-302; Described defoamer is BOK-X-401 or B0K-X-405; TX-10 or NP-9 that described high molecular surfactant provides for Helm AG; Described anti-wear agent is AF-29 or AF-30 that BASF AG produces.
The following steps of carrying out successively are specifically comprised: hot-rolling metal volume, described metallic coil carried out to chlorohydric acid pickling, the metallic coil after pickling carried out to cold-rolling treatment and form metallic plate, to the metallic plate continuous hot-dipping galvanizing process after cold rolling, thus get out described metallic plate in described steps A.
After described steps A and before described step B, carry out surface treatment to the metallic plate with priming coat, described surface treatment comprises ungrease treatment, cleaning treatment, drying and processing, Passivation Treatment and drying and processing more successively.
The step to described interface processing layer infrared ray baking-curing is also comprised between described step D and described step e.
Coating post processing in described step e comprises following treatment process successively: coating coating varnish process and baking-curing process.
The step of carrying out successively as follows is specifically comprised: the metal printing card obtained described step (1) carries out step that scale cuts and the metal printing card punch forming after cutting scale to form the step of metal stamp compound household plate in described step (2).
The step of carrying out successively as follows is specifically comprised: the step described metal printing card that described step (1) obtains adds the step of sandwich layer, superposing the monochromatic color coating metallic plate of one deck on described sandwich layer and the step be engaged with described monochromatic precoated substrate roll-in by described metal printing card to form the metal stamp compound household plate with sandwich layer in described step (2).
Nano titanium oxide is added with in the coating varnish applied in described step e.
Polyesters printed layer of the present invention refers to and adopts polyester material to form printed layer, polyesters priming coat of the present invention refers to the priming coat adopting polyester material to be formed, in the present invention, the general polyester material that be applied to metal substrate on of described polyester material known by those skilled in the art.
The production method of metal stamp compound household plate provided by the invention has the following advantages:
The production method of metal stamp compound household plate provided by the invention, polyesters priming paint is adopted to form priming coat, polyester material is adopted to form printed layer, it is specially for the metal substrate being coated with polyesters priming paint, the resin body of special ratios, solvent, pigment, levelling agent, defoamer, promoter and anti-wear agent is adopted to form interface processing layer, wherein said resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:2.5-3.5, described solvent is the mixture of isophorone and nylon acid dimethyl ester, the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:2.5-3.5, the interphase interaction of each composition of interface processing layer, coordinate, at levelability, the aspect performances such as wearability and adhesive force raising are all good, especially nylon acid dimethyl ester is by butanedioic acid (succinic acid) dimethyl ester CH3OOC (CH2) 2COOCH3, dimethyl glutarate CH3OOC (CH2) 3COOCH3 and hexanedioic acid dimethyl ester CH3OOC (CH2) 4COOCH tri-kinds of solvent compositions, coordinate isophorone to form mixed solvent, to the resin body that epoxy resin and acrylic resin are formed, there is stronger solvability, be convenient to resin body entirety be cured on the surface of polyesters priming paint, meanwhile, the printed layer that polyester material is formed also well is solidified with polyesters priming coat under the effect of interface processing layer, and when resin body is solidified, high molecular surfactant forms cross-linked network respectively and between resin body and polyester material, mutual entanglement, thus make resin body and polyesters printed layer be attached to the surface of polyester material well, and then, in production method of the present invention, interface processing layer makes polyesters printed layer have higher adhesive force on the surface of polyester material.
Detailed description of the invention
Embodiment 1
The present embodiment provides a kind of production method of metal stamp compound household plate, comprises following steps: the production stage of (1) metal printing card, comprises following concrete steps:
A. the step of metallic plate is prepared, particularly, comprise the following steps of carrying out successively: hot-rolling metal volume, described metallic coil carried out to chlorohydric acid pickling, the metallic coil after pickling carried out to cold-rolling treatment and form metallic plate, to the metallic plate continuous hot-dipping galvanizing process after cold rolling, thus get out described metallic plate;
B. at the priming paint of the surface of metallic plate coating polyesters composition, to form priming coat;
C. on described priming coat, the interface processing ink of special component is applied, to form interface processing layer;
D. on described interface processing layer, carry out the stamp of polyester material, to form printed layer, at this, adopt UV spray-drawing process to carry out stamp;
E. carry out coating post processing to the metallic plate with printed layer, to form metal printing card, at this, described coating post processing comprises the following steps of carrying out successively: coating coating varnish process and baking-curing process again;
(2) step of the metal printing card production compound household plate adopting step (1) to obtain; Be specially: the metal printing card obtained described step (1) carries out step that scale cuts and the metal printing card punch forming after cutting scale to form the step of metal stamp compound household plate.
Described interface processing layer in described step C is formed by the component of following parts by weight:
Resin body 35 parts
Solvent 25 parts
High molecular surfactant 15 parts
Pigment 18 parts
Levelling agent 0.2 part
Defoamer 0.1 part
Promoter 0.2 part
Anti-wear agent 0.1 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:2.5;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:2.5;
The TX-10 that described high molecular surfactant provides for Helm AG;
Described promoter is BOK-M-201;
Described pigment is the R706 that Du Pont China Holding Co., Ltd. produces;
Described levelling agent is B0K-L-301;
Described defoamer is BOK-X-401;
Described anti-wear agent is the AF-29 that BASF AG produces.
In the present embodiment, the coating varnish applied in described step e can be applied in floor known by those skilled in the art increases the general varnish of wearability.
Embodiment 2
The present embodiment provides a kind of production method of metal stamp compound household plate, comprises following steps: the production stage of (1) metal printing card, comprises following concrete steps:
A. the step of metallic plate is prepared, particularly, comprise the following steps of carrying out successively: hot-rolling metal volume, described metallic coil carried out to chlorohydric acid pickling, the metallic coil after pickling carried out to cold-rolling treatment and form metallic plate, to the metallic plate continuous hot-dipping galvanizing process after cold rolling, thus get out described metallic plate;
B. at the priming paint of the surface of metallic plate coating polyesters composition, to form priming coat;
C. on described priming coat, the interface processing ink of special component is applied, to form interface processing layer;
D. on described interface processing layer, carry out the stamp of polyester material, to form printed layer, at this, adopt UV spray-drawing process to carry out stamp;
E. carry out coating post processing to the metallic plate with printed layer, to form metal printing card, at this, described coating post processing comprises the following steps of carrying out successively: coating coating varnish process and baking-curing process again;
(2) step of the metal printing card production compound household plate adopting step (1) to obtain; Be specially: the metal printing card obtained described step (1) carries out step that scale cuts and the metal printing card punch forming after cutting scale to form the step of metal stamp compound household plate.
Described interface processing layer in described step C is formed by the component of following parts by weight:
Resin body 50 parts
Solvent 35 parts
High molecular surfactant 20 parts
Pigment 25 parts
Levelling agent 0.3 part
Defoamer 0.3 part
Promoter 0.3 part
Anti-wear agent 0.2 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:3.5;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:3.5;
The NP-9 that described high molecular surfactant provides for Helm AG;
Described promoter is BOK-M-206;
Described pigment is the R706 that Du Pont China Holding Co., Ltd. produces;
Described levelling agent is B0K-L-302;
Described defoamer is B0K-X-405;
Described anti-wear agent is the AF-30 that BASF AG produces;
The NP-9 that described high molecular surfactant provides for Helm AG.
Nano titanium oxide is added with in the coating varnish applied in described step e.
In the present embodiment, add nano titanium oxide in cleaning after, if Nano titanium dioxide can be formed protruding on the surface of varnish, namely form micro-nano structure, this micro-nano structure not only increases the wearability of wearing layer, and makes wearing layer have higher water resistance.
Embodiment 3
The present embodiment provides a kind of production method of metal stamp compound household plate, comprises following steps: the production stage of (1) metal printing card, comprises following concrete steps:
A. the step of metallic plate is prepared, particularly, comprise the following steps of carrying out successively: hot-rolling metal volume, described metallic coil carried out to chlorohydric acid pickling, the metallic coil after pickling carried out to cold-rolling treatment and form metallic plate, to the metallic plate continuous hot-dipping galvanizing process after cold rolling, thus get out described metallic plate;
B. at the priming paint of the surface of metallic plate coating polyesters composition, to form priming coat;
C. on described priming coat, the interface processing ink of special component is applied, to form interface processing layer;
D. on described interface processing layer, carry out the stamp of polyester material, to form printed layer, at this, adopt UV spray-drawing process to carry out stamp;
E. carry out coating post processing to the metallic plate with printed layer, to form metal printing card, at this, described coating post processing comprises the following steps of carrying out successively: coating coating varnish process and baking-curing process again;
(2) step of the metal printing card production compound household plate adopting step (1) to obtain; Be specially: the metal printing card obtained described step (1) carries out step that scale cuts and the metal printing card punch forming after cutting scale to form the step of metal stamp compound household plate.
Described interface processing layer in described step C is formed by the component of following parts by weight:
Resin body 40 parts
Solvent 30 parts
High molecular surfactant 18 parts
Pigment 22 parts
Levelling agent 0.25 part
Defoamer 0.2 part
Promoter 0.25 part
Anti-wear agent 0.15 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:3;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:3;
The NP-9 that described high molecular surfactant provides for Helm AG;
Described promoter is BOK-M-206;
Described pigment is the R900 that Du Pont China Holding Co., Ltd. produces;
Described levelling agent is B0K-L-302;
Described defoamer is B0K-X-405;
Described anti-wear agent is AF-30;
The NP-9 that described high molecular surfactant provides for Helm AG.
Nano titanium oxide is added with in the coating varnish applied in described step e.
In the present embodiment, add nano titanium oxide in cleaning after, if Nano titanium dioxide can be formed protruding on the surface of varnish, namely form micro-nano structure, this micro-nano structure not only increases the wearability of wearing layer, and makes wearing layer have higher water resistance.
Embodiment 4
The present embodiment provides a kind of production method of metal stamp compound household plate, comprises following steps: (1)
The production stage of metal printing card, comprises following concrete steps:
A. the step of metallic plate is prepared, particularly, comprise the following steps of carrying out successively: hot-rolling metal volume, described metallic coil carried out to chlorohydric acid pickling, the metallic coil after pickling carried out to cold-rolling treatment and form metallic plate, to the metallic plate continuous hot-dipping galvanizing process after cold rolling, thus get out described metallic plate;
B. at the priming paint of the surface of metallic plate coating polyesters composition, to form priming coat;
C. on described priming coat, the interface processing ink of special component is applied, to form interface processing layer;
D. on described interface processing layer, carry out the stamp of polyester material, to form printed layer, at this, adopt UV spray-drawing process to carry out stamp;
E. carry out coating post processing to the metallic plate with printed layer, to form metal printing card, at this, described coating post processing comprises the following steps of carrying out successively: coating coating varnish process and baking-curing process again;
(2) step of the metal printing card production compound household plate adopting step (1) to obtain; Be specially: the metal printing card obtained described step (1) carries out step that scale cuts and the metal printing card punch forming after cutting scale to form the step of metal stamp compound household plate.
Described interface processing layer in described step C is formed by the component of following parts by weight:
Resin body 43 parts
Solvent 28 parts
High molecular surfactant 16 parts
Pigment 21 parts
Levelling agent 0.22 part
Defoamer 0.23 part
Promoter 0.28 part
Anti-wear agent 0.17 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:2.8;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:2.7;
The NP-9 that described high molecular surfactant provides for Helm AG;
Described promoter is BOK-M-206;
Described pigment is the R900 that Du Pont China Holding Co., Ltd. produces;
Described levelling agent is B0K-L-302;
Described defoamer is B0K-X-405;
Described anti-wear agent is AF-30;
The NP-9 that described high molecular surfactant provides for Helm AG.
Nano titanium oxide is added with in the coating varnish applied in described step e.
In the present embodiment, add nano titanium oxide in varnish after, if Nano titanium dioxide can be formed protruding on the surface of varnish, namely form micro-nano structure, this micro-nano structure not only increases the wearability of wearing layer, and makes wearing layer have higher water resistance.
In addition, the function that the varnish being added with nano titanium oxide has kill bacteria, eliminates electrostatic, reduces flooring contamination by dust; There is the characteristics such as fire prevention, waterproof, protection against the tide, insect protected, mildew-resistant, cold-hot.
Embodiment 5
The present embodiment is the improvement on embodiment 1 basis, it is from the uniquely different of embodiment 1, the promoter of selecting is different, in the present embodiment, described promoter is the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 25 parts, and the parts by weight of described hc-surfactant are 35 parts, and the parts by weight of described nylon acid dimethyl ester are 65 parts.
Embodiment 6
The present embodiment is the improvement on embodiment 2 basis, it is from the uniquely different of embodiment 2, the promoter of selecting is different, in the present embodiment, described promoter is the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 33 parts, and the parts by weight of described hc-surfactant are 55 parts, and the parts by weight of described nylon acid dimethyl ester are 60 parts.
Embodiment 7
The present embodiment is the improvement on embodiment 3 basis, they are uniquely different from embodiment 3 is, the promoter of selecting is different, in the present embodiment, described promoter is the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 30 parts, and the parts by weight of described hc-surfactant are 40 parts, and the parts by weight of described nylon acid dimethyl ester are 65 parts.
Embodiment 8
The present embodiment is the improvement on embodiment 1 basis, from the uniquely different of embodiment 1, it is that described promoter is different, in the present embodiment, described promoter is the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 33 parts, the parts by weight of described hc-surfactant are 55 parts, and the parts by weight of described nylon acid dimethyl ester are 60 parts.
Embodiment 9
The present embodiment is the improvement on embodiment 1 basis, from the uniquely different of embodiment 1, it is that described promoter is different, in the present embodiment, described promoter is the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 30 parts, the parts by weight of described hc-surfactant are 40 parts, and the parts by weight of described nylon acid dimethyl ester are 65 parts.
Embodiment 10
The present embodiment is the improvement on enforcement 7 basis, they are uniquely different from embodiment 7 is: in the present embodiment, after described steps A and before described step B, carry out surface treatment to the metallic plate with priming coat, described surface treatment comprises ungrease treatment, cleaning treatment, drying and processing, Passivation Treatment and drying and processing more successively.Particularly: ungrease treatment, employing concentration is that the alkali lye of 1%, temperature 50-65 degree carries out degreasing, and to remove greasy dirt and the dust of belt steel surface, the ratio of alkali lye total alkali and free alkali is less than 2.5; Cleaning treatment, adopt the desalted water of 50-65 degree to rinse the belt steel surface after degreasing, to remove the remaining alkali lye of belt steel surface, the pH value of flushing water is less than 7.8; Drying and processing, adopt the moisture of the hot blast of 75-85 degree to the belt steel surface remnants after cleaning to carry out drying, hot blast is heated by vapor heat exchanger; Passivation Treatment, adopts chromium point to be treatment fluid between 22-32 to the belt steel surface after clean and carries out Passivation Treatment, to increase adhesive force and the antiseptic property of band steel and priming paint; Drying and processing again, adopts electrical heating baking oven to carry out drying process to the surface after Passivation Treatment, to strengthen passivation effect, and plate face baking temperature 72-85 degree.
Embodiment 11
The present embodiment is the improvement on enforcement 8 basis, they are uniquely different from embodiment 8 is: in the present embodiment, after described steps A and before described step B, carry out surface treatment to the metallic plate with priming coat, described surface treatment comprises ungrease treatment, cleaning treatment, drying and processing, Passivation Treatment and drying and processing more successively.Particularly: ungrease treatment, employing concentration is that the alkali lye of 1%, temperature 50-65 degree carries out degreasing, and to remove greasy dirt and the dust of belt steel surface, the ratio of alkali lye total alkali and free alkali is less than 2.5; Cleaning treatment, adopt the desalted water of 50-65 degree to rinse the belt steel surface after degreasing, to remove the remaining alkali lye of belt steel surface, the pH value of flushing water is less than 7.8; Drying and processing, adopt the moisture of the hot blast of 75-85 degree to the belt steel surface remnants after cleaning to carry out drying, hot blast is heated by vapor heat exchanger; Passivation Treatment, adopts chromium point to be treatment fluid between 22-32 to the belt steel surface after clean and carries out Passivation Treatment, to increase adhesive force and the antiseptic property of band steel and priming paint; Drying and processing again, adopts electrical heating baking oven to carry out drying process to the surface after Passivation Treatment, to strengthen passivation effect, and plate face baking temperature 72-85 degree.
Embodiment 12
The present embodiment is the improvement on enforcement 9 basis, they are uniquely different from embodiment 9 is: in the present embodiment, after described steps A and before described step B, carry out surface treatment to the metallic plate with priming coat, described surface treatment comprises ungrease treatment, cleaning treatment, drying and processing, Passivation Treatment and drying and processing more successively.Particularly: ungrease treatment, employing concentration is that the alkali lye of 1%, temperature 50-65 degree carries out degreasing, and to remove greasy dirt and the dust of belt steel surface, the ratio of alkali lye total alkali and free alkali is less than 2.5; Cleaning treatment, adopt the desalted water of 50-65 degree to rinse the belt steel surface after degreasing, to remove the remaining alkali lye of belt steel surface, the pH value of flushing water is less than 7.8; Drying and processing, adopt the moisture of the hot blast of 75-85 degree to the belt steel surface remnants after cleaning to carry out drying, hot blast is heated by vapor heat exchanger; Passivation Treatment, adopts chromium point to be treatment fluid between 22-32 to the belt steel surface after clean and carries out Passivation Treatment, to increase adhesive force and the antiseptic property of band steel and priming paint; Drying and processing again, adopts electrical heating baking oven to carry out drying process to the surface after Passivation Treatment, to strengthen passivation effect, and plate face baking temperature 72-85 degree.
Embodiment 13
The present embodiment is the improvement on embodiment 1 basis, they are uniquely different from embodiment 1 is, the concrete steps of described step (2) are different, in the present embodiment, the step of carrying out successively as follows is specifically comprised in described step (2): the step described metal printing card that described step (1) obtains adds the step of sandwich layer, superposing the monochromatic color coating metallic plate of one deck on described sandwich layer and the step be engaged with described monochromatic precoated substrate roll-in by described metal printing card to form the metal stamp compound household plate with sandwich layer.
Therefore, the present embodiment obtains the metal stamp compound household plate with the sandwich layer between metal printing card and monochromatic precoated substrate.In the present embodiment, described sandwich layer is polyurethane material.
Embodiment 14
The present embodiment is the improvement on embodiment 10 basis, it is from the uniquely different of embodiment 10, the concrete steps of described step (2) are different, in the present embodiment, the step of carrying out successively as follows is specifically comprised in described step (2): the step described metal printing card that described step (1) obtains adds the step of sandwich layer, superposing the monochromatic color coating metallic plate of one deck on described sandwich layer and the step be engaged with described monochromatic precoated substrate roll-in by described metal printing card to form the metal stamp compound household plate with sandwich layer.
Therefore, the present embodiment obtains the metal stamp compound household plate with the sandwich layer between metal printing card and monochromatic precoated substrate.In the present embodiment, described sandwich layer is rock wool.
The metallic plate adopted in above-described embodiment 1-14 is steel plate, certainly, also can adopt other metallic plates close with plate property.
The household plate that above-described embodiment 1-14 obtains can be used as Bedroom Floor, kitchen floor, bathing room floor, balcony floors, household wallboard, windowsill, household ceiling board etc.
Adopt the method in above-described embodiment 1-14 to produce and obtain 14 parts of metal stamp compound household plates, the test of pencil hardness test, 180 degree of bend tests and reverse impact is done respectively to these 14 parts of floors, records test effect data in table 1.
Table 1 embodiment 1-14 the performance test results
| Pencil hardness | Bending property | Reverse impact | |
| Embodiment 1 | Equal 6H | 1T | 11J |
| Embodiment 2 | Be greater than 6H | 0.8T | 13J |
| Embodiment 3 | Be greater than 6H | 0.9T | 12J |
| Embodiment 4 | Be greater than 6H | 0.7T | 14J |
| Embodiment 5 | Be greater than 6H | 0.8T | 13J |
| Embodiment 6 | Be greater than 6H | 0.6T | 15J |
| Embodiment 7 | Be greater than 6H | 0.6T | 13J |
| Embodiment 8 | Be greater than 6H | 0.7T | 13J |
| Embodiment 9 | Be greater than 6H | 0.8T | 13J |
| Embodiment 10 | Be greater than 6H | 0T | 15J |
| Embodiment 11 | Be greater than 6H | 0T | 14J |
| Embodiment 12 | Be greater than 6H | 0.7T | 14J |
| Embodiment 13 | Be greater than 6H | 0.7T | 15J |
| Embodiment 14 | Be greater than 6H | 0.7T | 15J |
As can be seen from upper table 1, the metal stamp compound household plate that above-described embodiment 1-14 obtains, in pencil hardness test, general performance is for being more than or equal to 6H; Under 180 degree of bend tests, general performance is the performance being more than or equal to 0T and being less than 1T; In reverse impact test, general performance is the performance being more than or equal to 11J, thus the metal stamp compound household plate utilizing production method of the present invention to obtain has good wearability, and printed layer has higher adhesive force.
In addition, as can be seen from Table 1, embodiment 10 has best adhesive force.
Obviously, above-described embodiment is only for clearly example being described, and the restriction not to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without the need to also giving all embodiments.And thus the apparent change of extending out or variation be still within protection scope of the present invention.
Claims (9)
1. the production method of metal stamp compound household plate, comprises following steps:
Step (1), the production stage of metal printing card, comprises following concrete steps:
A. the step of metallic plate is prepared;
B. at the priming paint of the surface of metallic plate coating polyesters composition, to form priming coat;
C. on described priming coat, the interface processing ink of special component is applied, to form interface processing layer;
D. on described interface processing layer, the stamp of polyester material is carried out, to form printed layer;
E. coating post processing is carried out to the metallic plate with printed layer, to form metal printing card;
Step (2), the step of the metal printing card production compound household plate adopting step (1) to obtain;
It is characterized in that:
Described interface processing layer in described step C comprises the component of following parts by weight:
Resin body 35-50 part
Solvent 25-35 part
High molecular surfactant 15-20 part
Pigment 18-25 part
Levelling agent 0.2-0.3 part
Defoamer 0.1-0.3 part
Promoter 0.2-0.3 part
Anti-wear agent 0.1-0.2 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:2.5-3.5;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:2.5-3.5;
Described promoter is BOK-M-201 or BOK-M-206, or be the composition of the retarder thinner that polyurethane resin, hc-surfactant and nylon acid dimethyl ester are made, the parts by weight of described polyurethane resin are 25-33 part, the parts by weight of described hc-surfactant are 35-55 part, and the parts by weight of described nylon acid dimethyl ester are 20-65 part;
Described pigment is the one in R706, R900 or R902 of Du Pont China Holding Co., Ltd.'s production; Described levelling agent is B0K-L-301 or B0K-L-302; Described defoamer is BOK-X-401 or B0K-X-405; TX-10 or NP-9 that described high molecular surfactant provides for Helm AG; Described anti-wear agent is AF-29 or AF-30 that BASF AG produces.
2. the production method of metal stamp compound household plate according to claim 1, is characterized in that: the described interface processing layer in described step C comprises the component of following parts by weight:
Resin body 40-45 part
Solvent 25-30 part
High molecular surfactant 15-18 part
Pigment 18-22 part
Levelling agent 0.2-0.25 part
Defoamer 0.2-0.3 part
Promoter 0.25-0.3 part
Anti-wear agent 0.1-0.15 part
Wherein,
Described resin body is the mixture of epoxy resin and acrylic resin, and the ratio of weight and number of described epoxy resin and acrylic resin is 1:3;
Described solvent is the mixture of isophorone and nylon acid dimethyl ester, and the ratio of weight and number of described isophorone and described nylon acid dimethyl ester is 1:3.
3. the production method of metal stamp compound household plate according to claim 1 and 2, it is characterized in that: in described steps A, specifically comprise the following steps of carrying out successively: hot-rolling metal volume, described metallic coil carried out to chlorohydric acid pickling, the metallic coil after pickling carried out to cold-rolling treatment and form metallic plate, to the metallic plate continuous hot-dipping galvanizing process after cold rolling, thus get out described metallic plate.
4. the production method of metal stamp compound household plate according to claim 1 and 2, it is characterized in that: after described steps A and before described step B, carry out surface treatment to the metallic plate with priming coat, described surface treatment comprises ungrease treatment, cleaning treatment, drying and processing, Passivation Treatment and drying and processing more successively.
5. the production method of metal stamp compound household plate according to claim 1 and 2, is characterized in that: between described step D and described step e, also comprise the step of described interface processing layer being carried out to infrared ray baking-curing.
6. the production method of metal stamp compound household plate according to claim 1 and 2, is characterized in that: the coating post processing in described step e comprises following treatment process successively: coating coating varnish process and baking-curing process.
7. the production method of metal stamp compound household plate according to claim 1 and 2, is characterized in that: specifically comprise the step of carrying out successively as follows in described step (2): the metal printing card obtained described step (1) carries out step that scale cuts and the metal printing card punch forming after cutting scale to form the step of metal stamp compound household plate.
8. the production method of metal stamp compound household plate according to claim 1 and 2, is characterized in that: specifically comprise the step of carrying out successively as follows in described step (2): the step described metal printing card that described step (1) obtains adds the step of sandwich layer, superposing the monochromatic color coating metallic plate of one deck on described sandwich layer and the step be engaged with described monochromatic precoated substrate roll-in by described metal printing card to form the metal stamp compound household plate with sandwich layer.
9. the production method of metal stamp compound household plate according to claim 6, is characterized in that: be added with nano titanium oxide in the coating varnish applied in described step e.
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| CN105925152A (en) * | 2016-05-09 | 2016-09-07 | 江苏凯特尔新型复合饰材有限公司 | Production process of metal printing plate roll coated with nano ceramic paint in advance |
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| JPH0860061A (en) * | 1994-08-26 | 1996-03-05 | Sakata Corp | Ink composition for metal printing |
| JPH09176531A (en) * | 1995-12-21 | 1997-07-08 | Dainippon Ink & Chem Inc | Ink for jet printer |
| JP2003089758A (en) * | 2001-09-18 | 2003-03-28 | Merck Ltd | High color saturation thin leaf-shaped pigment covered with semi-transparent metal thin foil |
| CN101077676B (en) * | 2006-05-23 | 2011-09-21 | 海尔集团公司 | Printing decoration metallic plate capable of panel beating and manufacturing method thereof |
| CN102040885B (en) * | 2009-10-15 | 2013-08-21 | 比亚迪股份有限公司 | Printing ink composite and preparation method thereof and stainless steel workpiece |
| CN101912839A (en) * | 2010-02-10 | 2010-12-15 | 常熟华冶薄板有限公司 | Continuous processing method of printed color coated steel plates at normal temperature |
| CN102408779B (en) * | 2010-09-24 | 2013-10-02 | 比亚迪股份有限公司 | Printing ink composition and preparation method thereof and stainless steel workpiece |
| CN102529554B (en) * | 2010-12-21 | 2014-07-30 | 耿凯 | Color printed steel plate continuous production process |
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