CN104592572A - Wear-resistant rubber - Google Patents
Wear-resistant rubber Download PDFInfo
- Publication number
- CN104592572A CN104592572A CN201510029753.XA CN201510029753A CN104592572A CN 104592572 A CN104592572 A CN 104592572A CN 201510029753 A CN201510029753 A CN 201510029753A CN 104592572 A CN104592572 A CN 104592572A
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- China
- Prior art keywords
- parts
- kilograms
- oxide
- rubber
- wear
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Abstract
The invention discloses wear-resistant rubber relating to the technical field of rubber. The wear-resistant rubber is prepared from the following raw materials in parts by weight: main materials including 100 parts of natural rubber, 2-5 parts of zinc oxide, 10-25 parts of nano-clay, 10-20 parts of calcium oxide, 10-25 parts of iron oxide and 10-25 parts of aluminum oxide, and auxiliary materials including 2-10 parts of dithiocarbamate, 0.6-3.5 parts of polyethylene wax, 3-15 parts of paraffin and 5.6-9 parts of cured resin. By using the wear-resistant rubber, the problem of poor wear resistance of the existing rubber is solved.
Description
Technical field
The present invention relates to field of rubber technology, especially a kind of abrasive rubber.
Background technology
Rubber is often used as sole because of the characteristic with soft comfortable and safety and environmental protection, because sole wants grantee's body weight to produce phase mutual friction with ground, and this type of current rubber often runs into and wears no resistance and the high problem of price, therefore provide a kind of and there is environmental protection, wear-resisting and soft comfortable and the low-cost rubber being used for making sole is the problem that those skilled in the art need solution badly.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of abrasive rubber, and it can solve the problem of existing rubber abrasive-resistance difference.
In order to solve the problem, technical scheme of the present invention is: this abrasive rubber, adopts the raw material of following weight part:
Major ingredient: natural rubber: 100 parts; Zinc oxide: 2 parts to 5 parts; Nanoclay: 10 parts to 25 parts; Calcium oxide: 10 parts to 20 parts; Ferric oxide: 10 parts to 25 parts; Aluminum oxide: 10 parts to 25 parts;
Auxiliary material: dithiocar-bamate: 2 parts to 10 parts; Polyethylene wax: 0.6 part to 3.5 parts; Paraffin: 3 parts to 15 parts; Curing resin: 5.6 parts to 9 parts.
In technique scheme, scheme can also be more specifically: described abrasive rubber, adopts the raw material of following weight part:
Major ingredient: natural rubber: 100 parts; Zinc oxide: 3 parts to 4 parts; Nanoclay: 12 parts to 20 parts; Calcium oxide: 12 parts to 16 parts; Ferric oxide: 13 parts to 15 parts; Aluminum oxide: 13 parts to 20 parts;
Auxiliary material: dithiocar-bamate: 4 parts to 8 parts; Polyethylene wax: 1 part to 3 parts; Paraffin: 5 parts to 10 parts; Curing resin: 6.6 parts to 8 parts.
Further: described abrasive rubber, adopt the raw material of following weight part:
Major ingredient: natural rubber: 100 parts; Zinc oxide: 3.5 parts; Nanoclay: 16 parts; Calcium oxide: 16 parts; Ferric oxide: 14 parts; Aluminum oxide: 16 parts;
Auxiliary material: dithiocar-bamate: 6 parts; Polyethylene wax: 2 parts; Paraffin: 7 parts; Curing resin: 7.3 parts.
Owing to adopting technique scheme, the present invention has following beneficial effect:
1, be major ingredient owing to have employed natural rubber and add calcium oxide, ferric oxide, aluminum oxide, not only natural environmental-protective but also tool have good wearability and flexibility;
2, owing to adopting polyethylene wax as protective agent, the persistency of rubber, hardness and abrasion resistance can be improved;
3, sulfiding process temperature of the present invention is low, curing time is short, make rubber become the macromole of tridimensional network by the macromolecules cross-linking of linear structure, its anti-tensile of the rubber of output, surely stretch, wear-resisting performance is good.
Embodiment
By embodiment, the present invention is described in further detail below:
Embodiment 1:
This abrasive rubber, adopts the raw material of following weight:
Major ingredient: natural rubber: 100 kilograms; Zinc oxide: 2 kilograms; Nanoclay: 10 kilograms; Calcium oxide: 10 kilograms; Ferric oxide: 25 kilograms; Aluminum oxide: 15 kilograms;
Auxiliary material: dithiocar-bamate: 2 kilograms; Polyethylene wax: 0.6 kilogram; Paraffin: 3 kilograms; Curing resin: 5.6 kilograms;
Comprise the steps:
A. first time is mixing: natural rubber, calcium oxide, ferric oxide, aluminum oxide, zinc oxide, nanoclay, polyethylene wax and dithiocar-bamate are added successively in Banbury mixer, then starting Banbury mixer, to carry out first time mixing, 60 seconds time, temperature is 50 DEG C;
B. second time is mixing: in the Banbury mixer of step A, add paraffin carry out mixing again, 75 seconds time, temperature is 85 DEG C, then cools binder removal;
C. sulfuration: the glue of step B is discharged to and tabletting machine adds curing resin again turns refining, 120 seconds time, bottom sheet and get final product.
Embodiment 2:
This abrasive rubber, adopts the raw material of following weight:
Major ingredient: natural rubber: 100 kilograms; Zinc oxide: 5 kilograms; Nanoclay: 25 kilograms; Calcium oxide: 20 kilograms; Ferric oxide: 15 kilograms; Aluminum oxide: 10 kilograms;
Auxiliary material: dithiocar-bamate: 10 kilograms; Polyethylene wax: 3.5 kilograms; Paraffin: 15 kilograms; Curing resin: 9 kilograms; All the other are all identical with embodiment one.
Embodiment 3:
This abrasive rubber, adopts the raw material of following weight:
Major ingredient: natural rubber: 100 kilograms; Zinc oxide: 3 kilograms; Nanoclay: 17 kilograms; Calcium oxide: 16 kilograms; Ferric oxide: 10 kilograms; Aluminum oxide: 25 kilograms;
Auxiliary material: dithiocar-bamate: 5 kilograms; Polyethylene wax: 2.5 kilograms; Paraffin: 8 kilograms; Curing resin: 7 kilograms; All the other are all identical with embodiment one.
Embodiment 4
This abrasive rubber, adopts the raw material of following weight:
Major ingredient: natural rubber: 100 kilograms; Zinc oxide: 3 kilograms; Nanoclay: 12 kilograms; Calcium oxide: 12 kilograms; Ferric oxide: 13 kilograms; Aluminum oxide: 13 kilograms;
Auxiliary material: dithiocar-bamate: 4 kilograms; Polyethylene wax: 1 kilogram; Paraffin: 5 kilograms; Curing resin: 6.6 kilograms; All the other are all identical with embodiment one.
Embodiment 5
This abrasive rubber, adopts the raw material of following weight:
Major ingredient: natural rubber: 100 kilograms; Zinc oxide: 4 kilograms; Nanoclay: 20 kilograms; Calcium oxide: 16 kilograms; Ferric oxide: 15 kilograms; Aluminum oxide: 20 kilograms;
Auxiliary material: dithiocar-bamate: 8 kilograms; Polyethylene wax: 3 kilograms; Paraffin: 10 kilograms; Curing resin: 8 kilograms; All the other are all identical with embodiment one.
Embodiment 6
This abrasive rubber, adopts the raw material of following weight:
Major ingredient: natural rubber: 100 kilograms; Zinc oxide: 3.5 kilograms; Nanoclay: 16 kilograms; Calcium oxide: 16 kilograms; Ferric oxide: 14 kilograms; Aluminum oxide: 16 kilograms;
Auxiliary material: dithiocar-bamate: 6 kilograms; Polyethylene wax: 2 kilograms; Paraffin: 7 kilograms; Curing resin: 7.3 kilograms; All the other are all identical with embodiment one.
Claims (3)
1. an abrasive rubber, is characterized in that: the raw material adopting following weight part:
Major ingredient: natural rubber: 100 parts; Zinc oxide: 2 parts to 5 parts; Nanoclay: 10 parts to 25 parts; Calcium oxide: 10 parts to 20 parts; Ferric oxide: 10 parts to 25 parts; Aluminum oxide: 10 parts to 25 parts;
Auxiliary material: dithiocar-bamate: 2 parts to 10 parts; Polyethylene wax: 0.6 part to 3.5 parts; Paraffin: 3 parts to 15 parts; Curing resin: 5.6 parts to 9 parts.
2. abrasive rubber according to claim 1, is characterized in that: the raw material adopting following weight part:
Major ingredient: natural rubber: 100 parts; Zinc oxide: 3 parts to 4 parts; Nanoclay: 12 parts to 20 parts; Calcium oxide: 12 parts to 16 parts; Ferric oxide: 13 parts to 15 parts; Aluminum oxide: 13 parts to 20 parts;
Auxiliary material: dithiocar-bamate: 4 parts to 8 parts; Polyethylene wax: 1 part to 3 parts; Paraffin: 5 parts to 10 parts; Curing resin: 6.6 parts to 8 parts.
3. abrasive rubber according to claim 1 and 2, is characterized in that: the raw material adopting following weight part:
Major ingredient: natural rubber: 100 parts; Zinc oxide: 3.5 parts; Nanoclay: 16 parts; Calcium oxide: 16 parts; Ferric oxide: 14 parts; Aluminum oxide: 16 parts;
Auxiliary material: dithiocar-bamate: 6 parts; Polyethylene wax: 2 parts; Paraffin: 7 parts; Curing resin: 7.3 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510029753.XA CN104592572A (en) | 2015-01-21 | 2015-01-21 | Wear-resistant rubber |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510029753.XA CN104592572A (en) | 2015-01-21 | 2015-01-21 | Wear-resistant rubber |
Publications (1)
Publication Number | Publication Date |
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CN104592572A true CN104592572A (en) | 2015-05-06 |
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Family Applications (1)
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CN201510029753.XA Pending CN104592572A (en) | 2015-01-21 | 2015-01-21 | Wear-resistant rubber |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105646958A (en) * | 2016-02-17 | 2016-06-08 | 柳州市乾阳机电设备有限公司 | Wear-resisting rubber and preparation method thereof |
CN106566004A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566002A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566003A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566001A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Abrasion resisting rubber for sports equipment |
CN106566006A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566005A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566008A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for exercise equipment |
CN109679178A (en) * | 2018-12-27 | 2019-04-26 | 无锡市兰翔胶业有限公司 | A kind of high-wearing feature rubber roller |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU1733441A1 (en) * | 1989-12-14 | 1992-05-15 | Всесоюзный Научно-Исследовательский И Конструкторско-Технологический Институт Асбестовых Технических Изделий | Composition for producing lining materials |
CN102417621A (en) * | 2011-11-25 | 2012-04-18 | 芜湖风雪橡胶有限公司 | Wear resistant undersole rubber material for shoes |
CN104004234A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
-
2015
- 2015-01-21 CN CN201510029753.XA patent/CN104592572A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU1733441A1 (en) * | 1989-12-14 | 1992-05-15 | Всесоюзный Научно-Исследовательский И Конструкторско-Технологический Институт Асбестовых Технических Изделий | Composition for producing lining materials |
CN102417621A (en) * | 2011-11-25 | 2012-04-18 | 芜湖风雪橡胶有限公司 | Wear resistant undersole rubber material for shoes |
CN104004234A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106566004A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566002A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566003A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566001A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Abrasion resisting rubber for sports equipment |
CN106566006A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566005A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for sports equipment |
CN106566008A (en) * | 2015-10-10 | 2017-04-19 | 如皋市启润运动用品有限公司 | Wear-resistant rubber for exercise equipment |
CN105646958A (en) * | 2016-02-17 | 2016-06-08 | 柳州市乾阳机电设备有限公司 | Wear-resisting rubber and preparation method thereof |
CN109679178A (en) * | 2018-12-27 | 2019-04-26 | 无锡市兰翔胶业有限公司 | A kind of high-wearing feature rubber roller |
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Application publication date: 20150506 |
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