CN104592258B - Phenyl triiodide amine three triazole copper chloride coordination compound with potential fluorescent material and preparation method thereof - Google Patents
Phenyl triiodide amine three triazole copper chloride coordination compound with potential fluorescent material and preparation method thereof Download PDFInfo
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- -1 Phenyl triiodide amine Chemical class 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000463 material Substances 0.000 title claims abstract description 7
- 150000001875 compounds Chemical class 0.000 title abstract description 17
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims abstract description 33
- 150000001412 amines Chemical class 0.000 claims abstract description 24
- 239000013078 crystal Substances 0.000 claims abstract description 17
- 239000010949 copper Substances 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 230000005260 alpha ray Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 claims 1
- 238000012360 testing method Methods 0.000 abstract description 12
- 229910021591 Copper(I) chloride Inorganic materials 0.000 abstract description 5
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 abstract description 5
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 abstract description 5
- 238000009792 diffusion process Methods 0.000 abstract description 3
- 239000000975 dye Substances 0.000 description 14
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 14
- 239000000243 solution Substances 0.000 description 11
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- SNHMUERNLJLMHN-UHFFFAOYSA-N iodobenzene Chemical compound IC1=CC=CC=C1 SNHMUERNLJLMHN-UHFFFAOYSA-N 0.000 description 8
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 7
- 229910000027 potassium carbonate Inorganic materials 0.000 description 7
- 239000005751 Copper oxide Substances 0.000 description 6
- 229910000431 copper oxide Inorganic materials 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 238000005286 illumination Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 238000002447 crystallographic data Methods 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000019771 cognition Effects 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005564 crystal structure determination Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000001455 metallic ions Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- GRONZTPUWOOUFQ-UHFFFAOYSA-M sodium;methanol;hydroxide Chemical compound [OH-].[Na+].OC GRONZTPUWOOUFQ-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
The invention discloses phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl2]·CHCl3·0.7H2O} (<b>1</b>) structural motif as shown in Figure 1。Also disclose { [Cu (L) Cl simultaneously2]·CHCl3·0.7H2O} (<b>1</b>) preparation method of (L=tri-(4-triazole phenyl) amine)。It is to adopt " diffusion method ", i.e. CHCl3The L dissolved is placed in bottom test tube, CH3The CuCl that OH dissolves2·2H2O is placed in test tube top, seals the mouth of pipe。Room temperature spreads the brown branching shape crystal obtaining being suitable for X-ray single crystal diffraction two weeks。The present invention further discloses phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl2]·CHCl3·0.7H2O} (<b>1</b>) (L=tri-(4-triazole phenyl) amine) as the application of potential fluorescent material aspect。
Description
The present invention obtains the subsidy of state natural sciences fund general project (21471113), young top-notch personnel's support plan, Tianjin Education Commission general project (20140506), Tianjin Normal University's Middl-age and youth faculty Academic innovations propelling planning item (52XC1401), Tianjin State Scientific and Technological Commission general project (11JCYBJC03600) and Tianjin innovation team of institution of higher education training plan (TD12-5038)。
Technical field
The invention belongs to organic and Inorganic synthese technical field, relate to phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl2]·CHCl3·0.7H2The preparation method of O} (1) (L=tri-(4-triazole phenyl) amine) and the application as potential fluorescent material。
Background technology
1,2,4-triazole and derivant thereof have the coordination feature of pyrazoles and imidazoles concurrently, are the bridging ligands that coordination ability is stronger, have synthesized and characterized substantial amounts of monokaryon, multinuclear and multidimensional compound at present。These parts can with 1, nitrogen-atoms on 2 forms N1 with metallic ion coordination, N2-bridge gang mould formula, for 4 unsubstituted 1,2,4-triazole derivative can pass through 2, nitrogen-atoms on 4 forms N2, N4-bridge gang mould formula, this N2, N4-bridge gang mould formula is similar with N1, the N3-bridge gang mould formula of imidazoles in metalloenzyme。Specific use for triazole class compounds is also manifested by the design of molecular device, and it has been the vital step of device that synthesis has the metal complex of different dimension。
The present invention adopts " diffusion method ", i.e. CHCl3The L dissolved is placed in bottom test tube, CH3The CuCl that OH dissolves2·2H2O is placed in test tube top, seals the mouth of pipe。Room temperature spreads brown branching shape crystal { [Cu (L) Cl obtaining being suitable for X-ray single crystal diffraction two weeks2]·CHCl3·0.7H2O} (1) (L=tri-(4-triazole phenyl) amine)。This coordination compound is alternatively arranged as potential fluorescent material aspect and is applied。
Summary of the invention
A kind of phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl of offer is provided2]·CHCl3·0.7H2O} (1) (L=tri-(4-triazole phenyl) amine) monocrystalline and preparation method thereof。
Following technical scheme is current inventor provides for this:
Phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl2]·CHCl3·0.7H2The structural motif of O} (1) (L=tri-(4-triazole phenyl) amine) is as shown in Figure 1。
The present invention further discloses phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl2]·CHCl3·0.7H2O} (1) (L=tri-(4-triazole phenyl) amine) monocrystalline, it is characterised in that this mono-crystalline structures adopts APEXIICCD single crystal diffractometer, uses through graphite monochromatised Mok alpha ray (λ=0.71073?) for incident radiation, collect point diffraction with ω-2 θ scan mode, obtain cell parameter through least square refinement, utilize SHELXL-97 direct method to solve single crystal data from difference Fourier electron density map:
The crystallographic data of table 1. coordination compound 1
Phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl of the present invention2]·CHCl3·0.7H2The preparation method of O} (1) (L=tri-(4-triazole phenyl) amine) monocrystalline, its feature is adopting " diffusion method ", i.e. CHCl3The L dissolved is placed in bottom test tube, CH3The CuCl that OH dissolves2·2H2O is placed in test tube top, seals the mouth of pipe。Room temperature spreads two weeks to prepare this coordination compound
L。
One preferred example of the present invention:
Three (4-triazole phenyl) amine) preparation of (L)
Adopt " one kettle way " at polar solvent, three (4-iodobenzene) amine, 1H-1,2,4-triazoles, potassium carbonate and copper oxide are prepared in a heated condition；Wherein three (4-iodobenzene) amine: 1H-1,2,4-triazole: potassium carbonate: the mol ratio of copper oxide is 2:15:30:1；
Three (4-iodobenzene) amine 1H-1,2,4-triazole
The present invention is three (4-iodobenzene) amine preferably: 1H-1,2,4-triazole: potassium carbonate: the mol ratio of copper oxide is 2:15:30:1；Reaction temperature 80-200 DEG C, 12-120 hour response time。In polar solvent, adopt " one kettle way ", three (4-iodobenzene) amine, 1H-1,2,4-triazoles, potassium carbonate and copper oxide are prepared this organic compound in a heated condition；
Presently preferred embodiment
CHCl3(10mL) three (the 4-triazole phenyl) amine dissolved) (L) (0.1mmol) be placed in bottom test tube, CH3The CuCl that OH (4mL) dissolves2·2H2O (0.2mmol) is placed in test tube top, seals the mouth of pipe。Room temperature obtains being suitable for the brown branching shape crystal of X-ray single crystal diffraction after spreading two weeks。Productivity: 20%。Elementary analysis (C25H21.4Cl5CuN10O0.7) theoretical value (%): C, 42.06；H, 3.02；N, 19.62。Measured value: C, 42.09；H, 3.06；N, 19.59。
The present invention further discloses phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl2]·CHCl3·0.7H2O} (1) (L=tri-(4-triazole phenyl) amine) can be applied as potential fluorescent material aspect。
A kind of phenyl triiodide amine three triazole copper chloride coordination compound { [Cu (L) Cl disclosed by the invention2]·CHCl3·0.7H2O} (1) (L=tri-(4-triazole phenyl) amine) monocrystalline have the advantage that and being characterized in that:
(1) operation is simple and easy to do。
(2) reaction yield is high, and the purity of products obtained therefrom is high。
(3) { [Cu (L) Cl prepared by the present invention2]·CHCl3·0.7H2O} (1) (L=tri-(4-triazole phenyl) amine) production cost is low, and method is easy, is suitable for large-scale production。
Accompanying drawing explanation
Fig. 1: the crystal structure primitive figure of coordination compound 1。
Fig. 2: the two-dimensional layered structure figure of coordination compound 1。
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, and embodiment is only indicative, is in no way to be construed as the scope that it is intended to limit the present invention in any manner。Raw materials used three (4-iodobenzene) amine, 1H-1,2,4-triazole, potassium carbonate and copper oxide etc. are commercially available。All raw materials are all buy from chemical reagents corporation both domestic and external, it does not have through continuation purify but directly use。
Embodiment 1
Three (4-iodobenzene) amine: 1H-1,2,4-triazole: potassium carbonate: the mol ratio of copper oxide is 2:15:30:1
It is separately added into CuO (0.5mmol), potassium carbonate (15mmol), 1H-1 in equipped with tri-mouthfuls of round-bottomed flasks of 50mL of magneton, reflux condenser and thermometer, 2,4-triazole (5mmol), three (4-iodobenzene) amine (1mmol) and 20mLDMF。Start stirring 150oC, reacts 60 hours。Reactant liquor is down to room temperature after terminating by reaction, filters, and filtrate adds 100mL water, precipitates out a large amount of precipitation, sucking filtration, collects filter cake, three (4-triazole phenyl) amine (L)。Yield 78.3%。
Embodiment 2
CHCl3(10mL) three (the 4-triazole phenyl) amine dissolved) (L) (0.1mmol) be placed in bottom test tube, CH3The CuCl that OH (4mL) dissolves2·2H2O (0.2mmol) is placed in test tube top, seals the mouth of pipe。Room temperature obtains being suitable for the brown branching shape crystal of X-ray single crystal diffraction after spreading two weeks。Productivity: 20%。Elementary analysis (C25H21.4Cl5CuN10O0.7) theoretical value (%): C, 42.06；H, 3.02；N, 19.62。Measured value: C, 42.09；H, 3.06；N, 19.59。
Embodiment 3
Crystal structure determination adopts APEXIICCD single crystal diffractometer, uses through graphite monochromatised Mok alpha ray (λ=0.71073?) for incident radiation, collect point diffraction with ω-2 θ scan mode, obtain cell parameter through least square refinement, utilize software to solve crystal structure from difference Fourier electron density map, and through Lorentz lorentz and polarity effect correction。All of H atom is synthesized by difference Fourier and determines through desirable position calculation。Detailed axonometry data are in Table 1。Structural motif is shown in Fig. 1, and one-dimensional catenary structure is shown in Fig. 2。
The crystallographic data of table 1. coordination compound 1
Embodiment 4
The concrete instance that dyestuff or luminous agent use
Method: the PARSTAT2273 electrochemical workstation that differentiated pulse volt-ampere (DPV) the curve negotiating Princeton Applied Research Laboratory of dye solution is developed is measured。The DPV test of solution adopts three-electrode system, and glass-carbon electrode is working electrode, and auxiliary electrode is platinum plate electrode, homemade Ag/AgNO3Electrode is reference electrode；Electrolyte is the acetonitrile solution of 0.1mol L-1TBAP。Reduce reversible point to for interior mark with Oxidation of Ferrocene, obtains the corrected value between test system and standard hydrogen electrode system。
Monochromatic incident illumination photoelectric transformation efficiency (IPCE) describes DSCs photoelectric transformation efficiency under monochromatic light effect, is the ratio of the electron number transferring to external circuit and incident illumination subnumber。During measurement, using 500W xenon lamp as light source, incident illumination obtains the monochromatic light under different wave length λ through the multifunctional assembled grating spectrograph of WDS-5 type；Monochromatic light exposure, in the light anode of battery, is read current value I by Keithley2400 digital sourcemeter。Monochromatic good fortune illumination is measured by USB4000plug-and-play Miniature optical linear light spectrometer。
Step: in order to have any actual knowledge of dyestuff at TiO2Adsorbance on film, by dye sensitization TiO2(geometric area is about 1cm to nanometer crystal film2) it is immersed in 10mL0.01mol L-1Sodium hydroxide methanol solution in overnight, treat that dyestuff solves the absorbance of attached mensuration solution completely。Wash one's face and rinse one's mouth according to absorbance and molar absorptivity and can calculate the adsorbance of dyestuff on unit are nanometer crystal film。The adsorbance of this coordination compound is 5.8 × 10-4mol/cm2。
Result: compared with the methanol solution of dyestuff, dyestuff is at TiO2Absorption spectrum on film all substantially broadens and red shift。This shows that dye molecule is at TiO2Define first and tail J-aggregation。From the operation principle of DSCs, spectrum broadening that dye aggregation causes and red shift are highly beneficial for the widening of photoelectric respone scope of dyestuff。But meanwhile, dye aggregation cognition is substantially reduced its electron injection efficiency, thus causing the degraded performance of DSCs。So, in dye solution, generally add coadsorbent suppress the gathering of dyestuff。This coordination compound is in methanol solution and at TiO2The fluorometric investigation of the purple solution on membrane electrode adopts 2.5 × 10-5The methanol solution of mol/L, maximum emission wavelength is positioned at 575nm。
After the preferred embodiment described in detail, it is familiar with this skilled worker to be clearly understood that, various change and amendment can be carried out under without departing from above-mentioned claim and spirit, all any simple modification, equivalent variations and modifications above example made according to the technical spirit of the present invention, belong to the scope of technical solution of the present invention。And the present invention is not also by the restriction of example embodiment in description。
Claims (1)
1. triphenylamine three triazole copper chloride complex monocrystal preparation as the application in potential fluorescent material, it is characterised in that this mono-crystalline structures adopt APEXIICCD single crystal diffractometer, use through graphite monochromatised Mok alpha ray, λ=0.71073?For incident radiation, collect point diffraction with ω-2 θ scan mode, obtain cell parameter through least square refinement, utilize software to solve single crystal data from difference Fourier electron density map:
The molecular formula of wherein said triazole copper chloride complex monocrystal is [Cu (L) Cl2]·CHCl3·0.7H2O, L=tri-(1H-1,2,4 triazole phenyl) amine。
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| 三（三氮唑）苯柔性配体配位自组装;王宏亮;《中国优秀硕士学位论文全文数据库工程科技I辑》;20110115(第01期);第4章 * |
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