CN104591582B - A kind of preparation method of the cement intensifier that can improve cement products intensity - Google Patents

A kind of preparation method of the cement intensifier that can improve cement products intensity Download PDF

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CN104591582B
CN104591582B CN201510049388.9A CN201510049388A CN104591582B CN 104591582 B CN104591582 B CN 104591582B CN 201510049388 A CN201510049388 A CN 201510049388A CN 104591582 B CN104591582 B CN 104591582B
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CN104591582A (en
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黄通
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Shandong Yongyuan Co ltd
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Shandong Forever Residential Industrial Technology Co Ltd
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Abstract

The present invention discloses the preparation method of a kind of cement intensifier that can improve cement products intensity, it is characterized in that: described cement intensifier raw material is: dickite, montmorillonite, shale, calcite, kieselguhr, calcium fluoride, Natrii Sulfas, polyvinyl alcohol, sodium acetate, sodium carbonate, Gypsum Fibrosum, sodium silicate, aluminium powder, calcium nitrate, the reinforcing agent raw material of the present invention is easily purchased, production technology is uncomplicated, simply it is readily produced product, facilitate during use and can uniformly use, meet the stability produced, and improve production efficiency, provide cost savings.

Description

A kind of preparation method of the cement intensifier that can improve cement products intensity
Technical field
The present invention relates to the preparation method of a kind of cement intensifier, i.e. can improve the preparation method of the cement intensifier of cement products intensity, belong to building material manufacture field.
Background technology
It is known that cement is one of major product of building cementing material, cement is by the portland cement clinker made after the mixing of the mineral raw material such as limestone, fire coal, iron powder and clay, then adds Gypsum Fibrosum in grog and make through levigate.Along with the fast development of China's economy, cement consumption is being multiplied, and therefore, the mineral raw material consumption such as limestone, fire coal, iron powder and clay increases day by day, and mineral resources constantly reduce.At present, under guaranteeing strength of cement premise, cement production plants man is suitably incorporated some mixed materials by technological means; thus reach to save mineral resources; reducing cement cost, the purpose of protection environment, wherein mixed material is mainly some cheap slag, ashes, flyash etc..But being limited by strength of cement standard-required, said mixture material mixes consumption and is typically not to be exceeded 20%, and otherwise, strength of cement can substantially reduce.While how increasing mixture incorporation consumption in cement further by technological means, strength of cement not only will not decline, and can increase on the contrary, thus reduces cement cost further, and saving the energy is the new problem that cement industry faces.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that the preparation method of a kind of cement intensifier that can improve cement products intensity.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of preparation method of the cement intensifier that can improve cement products intensity, it is characterised in that:
Described preparation method step is:
Step (1): according to dickite 32 parts, montmorillonite 33 parts, 24 parts of shale, 16 parts of calcite, 13 parts of kieselguhr, 6 parts of calcium fluoride, 6 parts of Natrii Sulfas, polyvinyl alcohol 3.7 parts, sodium acetate 3.7 parts, sodium carbonate 1.4 parts, 2.4 parts of Gypsum Fibrosum, sodium silicate 2.6 parts, aluminium powder 1.6 parts, 1.4 parts of proportionings of calcium nitrate prepare raw material
Step (2): dickite 32 parts, montmorillonite 33 parts, 24 parts of shale, 16 parts of calcite are carried out grinding in flour mill, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put in high temperature furnace, carry out temperature control fire according to intensification at a slow speed, gentle three processes of constant temperature of middling speed liter: being warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours;Come out of the stove natural cooling, after cooling in flour mill grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 13 parts of kieselguhr, 6 parts of calcium fluoride, 6 parts of Natrii Sulfas are carried out grinding in flour mill, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats grinding thing afterwards, heating-up temperature 700 DEG C, it is incubated 2 hours, after cooling in flour mill grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained in mixture B loading mechanical mixer, mechanical mixture 0.5 hour, pour polyvinyl alcohol 3.7 parts, sodium acetate 3.7 parts, sodium carbonate 1.4 parts afterwards into, 2.4 parts of Gypsum Fibrosum, sodium silicate 2.6 parts, aluminium powder 1.6 parts, calcium nitrate 1.4 parts, then mechanical mixture 1 hour, obtain reinforcing agent.
A kind of preparation method of the cement intensifier that can improve cement products intensity, it is characterised in that:
Described preparation method step is:
Step (1): according to dickite 37 parts, montmorillonite 37 parts, 28 parts of shale, 19 parts of calcite, 18 parts of kieselguhr, 9 parts of calcium fluoride, 8 parts of Natrii Sulfas, polyvinyl alcohol 3.8 parts, sodium acetate 3.8 parts, sodium carbonate 1.6 parts, 3 parts of Gypsum Fibrosum, sodium silicate 2.7 parts, aluminium powder 1.6 parts, 1.6 parts of proportionings of calcium nitrate prepare raw material
Step (2): dickite 37 parts, montmorillonite 37 parts, 28 parts of shale, 19 parts of calcite are carried out grinding in flour mill, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put in high temperature furnace, carry out temperature control fire according to intensification at a slow speed, gentle three processes of constant temperature of middling speed liter: being warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours;Come out of the stove natural cooling, after cooling in flour mill grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 18 parts of kieselguhr, 9 parts of calcium fluoride, 8 parts of Natrii Sulfas are carried out grinding in flour mill, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats grinding thing afterwards, heating-up temperature 700 DEG C, it is incubated 2 hours, after cooling in flour mill grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained in mixture B loading mechanical mixer, mechanical mixture 0.5 hour, pour polyvinyl alcohol 3.8 parts, sodium acetate 3.8 parts, sodium carbonate 1.6 parts afterwards into, 3 parts of Gypsum Fibrosum, sodium silicate 2.7 parts, aluminium powder 1.6 parts, calcium nitrate 1.6 parts, then mechanical mixture 1 hour, obtain reinforcing agent.
As preferably, the preparation method of the described cement intensifier that can improve cement products intensity, it is 0.9mm that step (2) obtains mixture A granularity size.
As preferably, the preparation method of the described cement intensifier that can improve cement products intensity, it is 0.4mm that step (3) obtains mixture B granularity size.
As preferably, the preparation method of the described cement intensifier that can improve cement products intensity, kieselguhr composition is (weight): 80.2%SiO2,5.7%Al2O3,0.68%Fe2O3,1.1%CaO, 1.62%MgO, 10.7% loss on ignition.
As preferably, the preparation method of the described reinforcing agent that can improve cement products intensity, dickite composition is (weight): 61.1%SiO2、31.3%Al2O3、1.2%Fe2O3, 1.1%CaO, 0.5%MgO, 4.8% loss on ignition.
Compared with prior art, there is advantages that
1, the preparation of base sample: using cement 300g, sand 750g, water consumption 120ml, and molding 40 × 40 × 160mm test specimen, temperature 20 ± 2 DEG C, humidity is maintenance under conditions of more than 90%.
2, the preparation of test specimen: using cement 288g, the cement intensifier 12g prepared, sand 750g, water consumption 120ml, and molding 40 × 40 × 160mm test specimen, temperature 20 ± 2 DEG C, humidity is maintenance under conditions of more than 90%.
When being 4 by prepared cement intensifier replacement cement component, strength of cement is after testing: 3 days comprcssive strength is 15.7MPa, 28 days comprcssive strength is 40.1MPa, compared with the strength of cement not adding cement intensifier under similarity condition, within 3 days, comprcssive strength improves 3.7MPa, and within 28 days, comprcssive strength improves 5.7MPa.The cement intensifier raw material of the present invention is easily purchased, and production technology is uncomplicated, is simply readily produced product, facilitates and can uniformly use during use, meets the stability produced, and improves production efficiency, provides cost savings.
Detailed description of the invention
Embodiment 1
A kind of preparation method of the cement intensifier that can improve cement products intensity, it is characterised in that:
Described preparation method step is:
Step (1): according to dickite 32 parts, montmorillonite 33 parts, 24 parts of shale, 16 parts of calcite, 13 parts of kieselguhr, 6 parts of calcium fluoride, 6 parts of Natrii Sulfas, polyvinyl alcohol 3.7 parts, sodium acetate 3.7 parts, sodium carbonate 1.4 parts, 2.4 parts of Gypsum Fibrosum, sodium silicate 2.6 parts, aluminium powder 1.6 parts, 1.4 parts of proportionings of calcium nitrate prepare raw material
Step (2): dickite 32 parts, montmorillonite 33 parts, 24 parts of shale, 16 parts of calcite are carried out grinding in flour mill, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put in high temperature furnace, carry out temperature control fire according to intensification at a slow speed, gentle three processes of constant temperature of middling speed liter: being warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours;Come out of the stove natural cooling, after cooling in flour mill grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 13 parts of kieselguhr, 6 parts of calcium fluoride, 6 parts of Natrii Sulfas are carried out grinding in flour mill, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats grinding thing afterwards, heating-up temperature 700 DEG C, it is incubated 2 hours, after cooling in flour mill grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained in mixture B loading mechanical mixer, mechanical mixture 0.5 hour, pour polyvinyl alcohol 3.7 parts, sodium acetate 3.7 parts, sodium carbonate 1.4 parts afterwards into, 2.4 parts of Gypsum Fibrosum, sodium silicate 2.6 parts, aluminium powder 1.6 parts, calcium nitrate 1.4 parts, then mechanical mixture 1 hour, obtain reinforcing agent.
Embodiment 2
A kind of preparation method of the cement intensifier that can improve cement products intensity, it is characterised in that:
Described preparation method step is:
Step (1): according to dickite 37 parts, montmorillonite 37 parts, 28 parts of shale, 19 parts of calcite, 18 parts of kieselguhr, 9 parts of calcium fluoride, 8 parts of Natrii Sulfas, polyvinyl alcohol 3.8 parts, sodium acetate 3.8 parts, sodium carbonate 1.6 parts, 3 parts of Gypsum Fibrosum, sodium silicate 2.7 parts, aluminium powder 1.6 parts, 1.6 parts of proportionings of calcium nitrate prepare raw material
Step (2): dickite 37 parts, montmorillonite 37 parts, 28 parts of shale, 19 parts of calcite are carried out grinding in flour mill, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put in high temperature furnace, carry out temperature control fire according to intensification at a slow speed, gentle three processes of constant temperature of middling speed liter: being warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours;Come out of the stove natural cooling, after cooling in flour mill grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 18 parts of kieselguhr, 9 parts of calcium fluoride, 8 parts of Natrii Sulfas are carried out grinding in flour mill, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats grinding thing afterwards, heating-up temperature 700 DEG C, it is incubated 2 hours, after cooling in flour mill grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained in mixture B loading mechanical mixer, mechanical mixture 0.5 hour, pour polyvinyl alcohol 3.8 parts, sodium acetate 3.8 parts, sodium carbonate 1.6 parts afterwards into, 3 parts of Gypsum Fibrosum, sodium silicate 2.7 parts, aluminium powder 1.6 parts, calcium nitrate 1.6 parts, then mechanical mixture 1 hour, obtain reinforcing agent.

Claims (4)

1. the preparation method of the cement intensifier that can improve cement products intensity, it is characterised in that:
Described preparation method step is:
Step (1): according to dickite 32 parts, montmorillonite 33 parts, 24 parts of shale, 16 parts of calcite, 13 parts of kieselguhr, 6 parts of calcium fluoride, 6 parts of Natrii Sulfas, polyvinyl alcohol 3.7 parts, sodium acetate 3.7 parts, sodium carbonate 1.4 parts, 2.4 parts of Gypsum Fibrosum, sodium silicate 2.6 parts, aluminium powder 1.6 parts, 1.4 parts of proportionings of calcium nitrate prepare raw material
Step (2): dickite 32 parts, montmorillonite 33 parts, 24 parts of shale, 16 parts of calcite are carried out grinding in flour mill, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put in high temperature furnace, carry out temperature control fire according to intensification at a slow speed, gentle three processes of constant temperature of middling speed liter: being warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours;Come out of the stove natural cooling, after cooling in flour mill grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 13 parts of kieselguhr, 6 parts of calcium fluoride, 6 parts of Natrii Sulfas are carried out grinding in flour mill, rotating speed is 100r/min, grinding 3 hours, obtaining grinding composition granule degree size is 0.6-0.8mm, heats grinding thing afterwards, heating-up temperature 700 DEG C, it is incubated 2 hours, after cooling in flour mill grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained in mixture B loading mechanical mixer, mechanical mixture 0.5 hour, pour polyvinyl alcohol 3.7 parts, sodium acetate 3.7 parts, sodium carbonate 1.4 parts afterwards into, 2.4 parts of Gypsum Fibrosum, sodium silicate 2.6 parts, aluminium powder 1.6 parts, calcium nitrate 1.4 parts, then mechanical mixture 1 hour, obtain reinforcing agent.
2. the preparation method of the cement intensifier that can improve cement products intensity, it is characterised in that:
Described preparation method step is:
Step (1): according to dickite 37 parts, montmorillonite 37 parts, 28 parts of shale, 19 parts of calcite, 18 parts of kieselguhr, 9 parts of calcium fluoride, 8 parts of Natrii Sulfas, polyvinyl alcohol 3.8 parts, sodium acetate 3.8 parts, sodium carbonate 1.6 parts, 3 parts of Gypsum Fibrosum, sodium silicate 2.7 parts, aluminium powder 1.6 parts, 1.6 parts of proportionings of calcium nitrate prepare raw material
Step (2): dickite 37 parts, montmorillonite 37 parts, 28 parts of shale, 19 parts of calcite are carried out grinding in flour mill, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put in high temperature furnace, carry out temperature control fire according to intensification at a slow speed, gentle three processes of constant temperature of middling speed liter: being warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours;Come out of the stove natural cooling, after cooling in flour mill grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 18 parts of kieselguhr, 9 parts of calcium fluoride, 8 parts of Natrii Sulfas are carried out grinding in flour mill, rotating speed is 100r/min, grinding 3 hours, obtaining grinding composition granule degree size is 0.6-0.8mm, heats grinding thing afterwards, heating-up temperature 700 DEG C, it is incubated 2 hours, after cooling in flour mill grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained in mixture B loading mechanical mixer, mechanical mixture 0.5 hour, pour polyvinyl alcohol 3.8 parts, sodium acetate 3.8 parts, sodium carbonate 1.6 parts afterwards into, 3 parts of Gypsum Fibrosum, sodium silicate 2.7 parts, aluminium powder 1.6 parts, calcium nitrate 1.6 parts, then mechanical mixture 1 hour, obtain reinforcing agent.
Can improve the preparation method of the cement intensifier of cement products intensity the most as claimed in claim 1, it is 0.9mm that step (2) obtains mixture A granularity size.
Can improve the preparation method of the cement intensifier of cement products intensity the most as claimed in claim 1, it is 0.4mm that step (3) obtains mixture B granularity size.
CN201510049388.9A 2014-02-23 2014-02-23 A kind of preparation method of the cement intensifier that can improve cement products intensity Expired - Fee Related CN104591582B (en)

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CN105236789A (en) * 2015-10-28 2016-01-13 雷志刚 Manufacturing method of inorganic reinforcing agent for gypsum products
CN105645824A (en) * 2016-01-19 2016-06-08 王金奎 Efficient cement fortifier and preparation method
CN105948562A (en) * 2016-04-30 2016-09-21 李程 Additive material for manufacturing cement-base plate
CN106477952A (en) * 2016-09-13 2017-03-08 广西大学 A kind of cement intensifier and preparation method thereof
CN107899073B (en) * 2017-12-27 2021-03-30 北京大学第一医院 Bone cement, preparation method and application thereof
WO2024082203A1 (en) * 2022-10-20 2024-04-25 衡阳市银利实业有限公司 Cement reinforcer and preparation method therefor

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101696096A (en) * 2009-10-30 2010-04-21 南京永能新材料有限公司 Liquid cement grinding additive
CN102173633A (en) * 2011-03-04 2011-09-07 攀枝花九鼎建材有限责任公司 Activator for improving reactivity of fly ash in cement
CN102731010A (en) * 2012-07-25 2012-10-17 广东省建筑材料研究院 Reinforced premix mortar moisture-retention thickening agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101696096A (en) * 2009-10-30 2010-04-21 南京永能新材料有限公司 Liquid cement grinding additive
CN102173633A (en) * 2011-03-04 2011-09-07 攀枝花九鼎建材有限责任公司 Activator for improving reactivity of fly ash in cement
CN102731010A (en) * 2012-07-25 2012-10-17 广东省建筑材料研究院 Reinforced premix mortar moisture-retention thickening agent and preparation method thereof

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