Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of preparation method that with the addition of the toughener sand-cement slurry that can improve cement products intensity is provided.
For achieving the above object, the technical solution used in the present invention is as follows:
A preparation method for sand-cement slurry, is characterized in that:
Take raw material: cement 288g, cement intensifier 12g, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Above-mentioned raw materials is put into conical double ribbon to revolve in stirrer and stir, churning time is 50 minutes, obtains sand-cement slurry after stirring;
Described cement intensifier preparation method step is:
Step (1): according to dickite 30-40 part, montmorillonite 30-40 part, shale 20-30 part, calcite 10-20 part, diatomite 10-20 part, Calcium Fluoride (Fluorspan) 5-10 part, saltcake 5-10 part, polyvinyl alcohol 3-4 part, sodium-acetate 3-4 part, sodium carbonate 1-3 part, gypsum 2-4 part, water glass 2-3 part, aluminium powder 1-2 part, nitrocalcite 1-2 part proportioning prepare raw material
Step (2): dickite 30-40 part, montmorillonite 30-40 part, shale 20-30 part, calcite 10-20 part are carried out grinding in pulverizer, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards grinding thing is put into High Temperature Furnaces Heating Apparatus, carry out temperature control according to intensification at a slow speed, middling speed intensification and constant temperature three processes to fire: be warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours; To come out of the stove naturally cooling, after cooling in pulverizer grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): diatomite 10-20 part, Calcium Fluoride (Fluorspan) 5-10 part, saltcake 5-10 part are carried out grinding in pulverizer, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats afterwards to grinding thing, Heating temperature 700 DEG C, be incubated 2 hours, after cooling in pulverizer grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained mixture B loading in mechanical mixer, mechanically mixing 0.5 hour, pour polyvinyl alcohol 3-4 part, sodium-acetate 3-4 part, sodium carbonate 1-3 part afterwards into, gypsum 2-4 part, water glass 2-3 part, aluminium powder 1-2 part, nitrocalcite 1-2 part, then mechanically mixing 1 hour, obtain cement intensifier.
As preferably, the preparation method of described sand-cement slurry, described cement intensifier raw material is: dickite 35 parts, montmorillonite 35 parts, 25 parts, shale, 15 parts, calcite, 15 parts, diatomite, 8 parts, Calcium Fluoride (Fluorspan), 8 parts, saltcake, polyvinyl alcohol 3.5 parts, sodium-acetate 3.5 parts, 2 parts, sodium carbonate, 3 parts, gypsum, water glass 2.5 parts, aluminium powder 1.5 parts, 1.5 parts, nitrocalcite.
As preferably, the preparation method of described sand-cement slurry, described cement intensifier raw material is: dickite 32 parts, montmorillonite 37 parts, 22 parts, shale, 17 parts, calcite, 13 parts, diatomite, 7 parts, Calcium Fluoride (Fluorspan), 7 parts, saltcake, polyvinyl alcohol 3.2 parts, sodium-acetate 3.2 parts, 1.2 parts, sodium carbonate, 2.2 parts, gypsum, water glass 2.6 parts, aluminium powder 1.6 parts, 1.6 parts, nitrocalcite.
As preferably, the preparation method of described sand-cement slurry, described cement intensifier raw material is: dickite 37 parts, montmorillonite 34 parts, 27 parts, shale, 14 parts, calcite, 17 parts, diatomite, 6 parts, Calcium Fluoride (Fluorspan), 6 parts, saltcake, polyvinyl alcohol 3.9 parts, sodium-acetate 3.9 parts, 2 parts, sodium carbonate, 3 parts, gypsum, water glass 2.7 parts, aluminium powder 1.6 parts, 1.2 parts, nitrocalcite.
As preferably, the preparation method of described sand-cement slurry, described cement intensifier raw material is: dickite 30 parts, montmorillonite 40 parts, 20 parts, shale, 20 parts, calcite, 10 parts, diatomite, 10 parts, Calcium Fluoride (Fluorspan), 5 parts, saltcake, polyvinyl alcohol 4 parts, sodium-acetate 3 parts, 3 parts, sodium carbonate, 2 parts, gypsum, water glass 3 parts, aluminium powder 1 part, 2 parts, nitrocalcite.
As preferably, the preparation method of described sand-cement slurry, it is 0.9mm that step (2) obtains mixture A granularity size.
As preferably, the preparation method of described sand-cement slurry, it is 0.4mm that step (3) obtains mixture B granularity size.
As preferably, the preparation method of described sand-cement slurry, diatomite composition is: 80.2%SiO2,5.7%Al2O3,0.68%Fe2O3,1.1%CaO, 1.62%MgO, 10.7% loss on ignition.
As preferably, the preparation method of described sand-cement slurry, dickite composition is: 61.1%SiO
2, 31.3%Al
2o
3, 1.2%Fe
2o
3, 1.1%CaO, 0.5%MgO, 4.8% loss on ignition.
Compared with prior art, the present invention has following beneficial effect:
1, the preparation of base sample: adopt cement 300g, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Water consumption 120ml, and shaping 40 × 40 × 160mm test specimen, temperature 20 ± 2 DEG C, humidity is maintenance under the condition of more than 90%.
2, the preparation of test sample: adopt cement 288g, the cement intensifier 12g prepared, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Water consumption 120ml, and shaping 40 × 40 × 160mm test specimen, temperature 20 ± 2 DEG C, humidity is maintenance under the condition of more than 90%.
When obtained cement intensifier to be substituted cement component be 4 ﹪, sand-cement slurry ultimate compression strength is after testing: 3 days ultimate compression strength is 15.7MPa, 28 days ultimate compression strength is 40.1MPa, compared with the sand-cement slurry ultimate compression strength not adding cement intensifier under similarity condition, within 3 days, ultimate compression strength improves 3.7MPa, and within 28 days, ultimate compression strength improves 5.7MPa.Sand-cement slurry starting material of the present invention are easily purchased, and production technique is uncomplicated, are simply easy to produce product, conveniently also can evenly use in use procedure, meet the stability of producing, and improve production efficiency, provide cost savings.
Embodiment
Embodiment 1
A preparation method for sand-cement slurry, is characterized in that:
Take raw material: cement 288g, cement intensifier 12g, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Above-mentioned raw materials is put into conical double ribbon to revolve in stirrer and stir, churning time is 50 minutes, obtains sand-cement slurry after stirring;
Described cement intensifier preparation method step is:
Step (1): according to dickite 30 parts, montmorillonite 30 parts, 20 parts, shale, 10 parts, calcite, 10 parts, diatomite, 5 parts, Calcium Fluoride (Fluorspan), 5 parts, saltcake, polyvinyl alcohol 3 parts, sodium-acetate 3 parts, 1 part, sodium carbonate, 2 parts, gypsum, water glass 2 parts, aluminium powder 1 part, nitrocalcite 1 part of proportioning prepare raw material
Step (2): dickite 30 parts, montmorillonite 30 parts, 20 parts, shale, 10 parts, calcite are carried out grinding in pulverizer, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards High Temperature Furnaces Heating Apparatus is put into grinding thing, carry out temperature control according to intensification at a slow speed, middling speed intensification and constant temperature three processes to fire: be warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours; To come out of the stove naturally cooling, after cooling in pulverizer grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 10 parts, diatomite, 5 parts, Calcium Fluoride (Fluorspan), 5 parts, saltcake are carried out grinding in pulverizer, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats afterwards to grinding thing, Heating temperature 700 DEG C, be incubated 2 hours, after cooling in pulverizer grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained mixture B loading in mechanical mixer, mechanically mixing 0.5 hour, pour polyvinyl alcohol 3 parts, sodium-acetate 3 parts, 1 part, sodium carbonate afterwards into, 2 parts, gypsum, water glass 2 parts, aluminium powder 1 part, 1 part, nitrocalcite, then mechanically mixing 1 hour, obtain cement intensifier.
Embodiment 2
A preparation method for sand-cement slurry, is characterized in that:
Take raw material: cement 288g, cement intensifier 12g, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Above-mentioned raw materials is put into conical double ribbon to revolve in stirrer and stir, churning time is 50 minutes, obtains sand-cement slurry after stirring;
Described cement intensifier preparation method step is:
Step (1): according to dickite 40 parts, montmorillonite 40 parts, 30 parts, shale, 20 parts, calcite, 20 parts, diatomite, 10 parts, Calcium Fluoride (Fluorspan), 10 parts, saltcake, polyvinyl alcohol 4 parts, sodium-acetate 4 parts, 3 parts, sodium carbonate, 4 parts, gypsum, water glass 3 parts, aluminium powder 2 parts, nitrocalcite 2 parts of proportionings prepare raw material
Step (2): dickite 40 parts, montmorillonite 40 parts, 30 parts, shale, 20 parts, calcite are carried out grinding in pulverizer, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards High Temperature Furnaces Heating Apparatus is put into grinding thing, carry out temperature control according to intensification at a slow speed, middling speed intensification and constant temperature three processes to fire: be warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours; To come out of the stove naturally cooling, after cooling in pulverizer grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 20 parts, diatomite, 10 parts, Calcium Fluoride (Fluorspan), 10 parts, saltcake are carried out grinding in pulverizer, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats afterwards to grinding thing, Heating temperature 700 DEG C, be incubated 2 hours, after cooling in pulverizer grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained mixture B loading in mechanical mixer, mechanically mixing 0.5 hour, pour polyvinyl alcohol 4 parts, sodium-acetate 4 parts, 3 parts, sodium carbonate afterwards into, 4 parts, gypsum, water glass 3 parts, aluminium powder 2 parts, 2 parts, nitrocalcite, then mechanically mixing 1 hour, obtain cement intensifier.
Embodiment 3
A preparation method for sand-cement slurry, is characterized in that:
Take raw material: cement 288g, cement intensifier 12g, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Above-mentioned raw materials is put into conical double ribbon to revolve in stirrer and stir, churning time is 50 minutes, obtains sand-cement slurry after stirring;
Described cement intensifier preparation method step is:
Step (1): according to dickite 35 parts, montmorillonite 35 parts, 25 parts, shale, 15 parts, calcite, 15 parts, diatomite, 8 parts, Calcium Fluoride (Fluorspan), 7 parts, saltcake, polyvinyl alcohol 3.5 parts, sodium-acetate 3.5 parts, 2 parts, sodium carbonate, 3 parts, gypsum, water glass 2.5 parts, aluminium powder 1.5 parts, nitrocalcite 1.5 parts of proportionings prepare raw material
Step (2): dickite 35 parts, montmorillonite 35 parts, 25 parts, shale, 15 parts, calcite are carried out grinding in pulverizer, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards High Temperature Furnaces Heating Apparatus is put into grinding thing, carry out temperature control according to intensification at a slow speed, middling speed intensification and constant temperature three processes to fire: be warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours; To come out of the stove naturally cooling, after cooling in pulverizer grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 15 parts, diatomite, 8 parts, Calcium Fluoride (Fluorspan), 7 parts, saltcake are carried out grinding in pulverizer, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats afterwards to grinding thing, Heating temperature 700 DEG C, be incubated 2 hours, after cooling in pulverizer grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained mixture B loading in mechanical mixer, mechanically mixing 0.5 hour, pour polyvinyl alcohol 3.5 parts, sodium-acetate 3.5 parts, 2 parts, sodium carbonate afterwards into, 3 parts, gypsum, water glass 2.5 parts, aluminium powder 1.5 parts, 1.5 parts, nitrocalcite, then mechanically mixing 1 hour, obtain cement intensifier.
Embodiment 4
A preparation method for sand-cement slurry, is characterized in that:
Take raw material: cement 288g, cement intensifier 12g, sand 750g, polypropylene fibre 4g, naphthalene water reducer 3g; Above-mentioned raw materials is put into conical double ribbon to revolve in stirrer and stir, churning time is 50 minutes, obtains sand-cement slurry after stirring;
Described cement intensifier preparation method step is:
Step (1): according to dickite 32 parts, montmorillonite 33 parts, 24 parts, shale, 16 parts, calcite, 13 parts, diatomite, 6 parts, Calcium Fluoride (Fluorspan), 6 parts, saltcake, polyvinyl alcohol 3.7 parts, sodium-acetate 3.7 parts, 1.4 parts, sodium carbonate, 2.4 parts, gypsum, water glass 2.6 parts, aluminium powder 1.6 parts, nitrocalcite 1.4 parts of proportionings prepare raw material
Step (2): dickite 32 parts, montmorillonite 33 parts, 24 parts, shale, 16 parts, calcite are carried out grinding in pulverizer, rotating speed is 120r/min, grinding 9 hours, grinding composition granule degree size is 1.2-1.4mm, afterwards High Temperature Furnaces Heating Apparatus is put into grinding thing, carry out temperature control according to intensification at a slow speed, middling speed intensification and constant temperature three processes to fire: be warming up at a slow speed 300 DEG C with the speed of 2 DEG C/min, be warming up to 800 DEG C with the speed middling speed of 5 DEG C/min afterwards, then constant temperature is incubated 3 hours; To come out of the stove naturally cooling, after cooling in pulverizer grinding 3 hours again, obtaining mixture A granularity size is 0.8-1mm,
Step (3): 13 parts, diatomite, 6 parts, Calcium Fluoride (Fluorspan), 6 parts, saltcake are carried out grinding in pulverizer, rotating speed is 100r/min, grinding 3 hours, obtaining compound particles granularity size is 0.6-0.8mm, heats afterwards to grinding thing, Heating temperature 700 DEG C, be incubated 2 hours, after cooling in pulverizer grinding 3 hours again, obtaining mixture B granularity size is 0.3-0.5mm
Step (4): step (2) is obtained mixture A and step (3) is obtained mixture B loading in mechanical mixer, mechanically mixing 0.5 hour, pour polyvinyl alcohol 3.7 parts, sodium-acetate 3.7 parts, 1.4 parts, sodium carbonate afterwards into, 2.4 parts, gypsum, water glass 2.6 parts, aluminium powder 1.6 parts, 1.4 parts, nitrocalcite, then mechanically mixing 1 hour, obtain cement intensifier.