A kind of sewage environment friendly purification apparatus
Technical field
The present invention relates to water treatment field, especially relate to sewage degraded purifier.
Background technology
China is the country that a little Chemical Manufacture is flourishing, and chemical products kind is many, the complex process related to, sewage
Big containing inorganic, organic salt volume, process this kind of sewage and be necessary for the processing method by various combinations.China organises at present
Work produces dispersion, is again little Chemical Manufacture, thus results in sewage dispersion, is unfavorable for processing.
People, through long-term endeavour, have established the technology of many purifying waste water processings, and conventional has Physical, chemistry
Method, bioanalysis etc., these methods are respectively arranged with its pluses and minuses, mostly to contaminant degradation not thoroughly, easily cause secondary pollution, equipment
Investment is big, operating cost is the most high.
Catalysis oxidation high-level oxidation technology is the new technology that water treatment field is risen, and it is by the side of chemically or physically chemistry
Pollutant in sewage is direct oxidation into inorganic matter by method, or is translated into the intermediate product of the easily biological-degradable of low toxicity.Electricity
Solving catalytic oxidation is a kind of sewage water treatment method improved on the basis of electrolysis process, and this method is for some difficulty
The sewage of reason achieves good effect.Catalytic and oxidative electrolysis technology method has: electricity flocculates, electrically floats, aoxidizes, is catalyzed and at electricity
The features such as the polar molecule effect under field condition.
In the patent of invention of 201010563370.8, it is proposed that a kind of three-diemsnional electrode electrocatalytic oxidation for sewage of degrading
Reactor, it is by arranging the positive and negative electrode of cross parallel in reaction vessel, using the zeolite granular in liquid as the 3rd electricity
Pole;During work, positive and negative electrode obtain electric energy, zeolite granular play granule electrode effect and play ion transformation make electrode week
Table and liquid produce substantial amounts of OH hydroxyl radical free radical ion, thus the pollutant of sewage is carried out catalysis oxidation, reach environmental protection
The purpose of water purification.But, in the invention, different layers positive and negative electrode is placed in parallel, and gap is relatively big, between different layers electrode
Liquid catalyst reaction not, affect clean-up effect.
Summary of the invention
As one aspect of the present invention, it is provided that a kind of sewage degraded purifier, including reaction vessel and power supply;Institute
Stating reaction vessel by electrocatalytic oxidation by sewage purification, described power supply is for providing electric current to described reaction vessel;Described instead
Answering container bottom to set into the mouth of a river, top arranges delivery port, is internally provided with multiple positive electrode and multiple auxiliary electrode;Wherein,
Described positive electrode and described auxiliary electrode have certain degree with horizontal plane.
Preferably, described power supply includes the first power supply to reaction vessel left end electrode power supply and to reaction vessel right-hand member
The second source of electrode power supply, the plurality of positive electrode and the plurality of negative electrode are divided into left and right two arrays of electrodes, a wherein said left side
One group of limit electrode is the first angle with the angle of horizontal plane, and one group of described the right electrode is the second angle with the angle of horizontal plane.
Preferably, described first angle and the second angle are respectively between 30 degree to 60 degree.
Preferably, the angle of described first angle and the second angle is different.
Preferably, the positive and negative electrode of the one group of electrode in the described left side crosses one another;The positive and negative electrode of the one group of electrode in described the right
Cross one another.
Preferably, one group of described left side electrode includes that multi-layered electrode, one group of described the right electrode include multi-layered electrode.
Preferably, left side conductive plate, right side conductive plate, the first middle conductive plate and second are set in described reaction vessel
Middle conductive plate;Described left side conductive plate is arc, and it connects the first power cathode by the first conducting wire;Described right side is led
Electroplax is arc, and it connects second source positive pole by the second conducting wire;Described first middle conductive plate is rectangle, and it leads to
Cross the 3rd conducting wire and connect the first positive source;Described second middle conductive plate is rectangle, and it passes through the 4th conducting wire
Connect second source negative pole.
Preferably, the liquid within described reaction vessel has zeolite granular for as the 3rd electrode.
Preferably, the dispenser throwing in zeolite granular is also included.
Preferably, described dispenser is different at the zeolite granular content of the different depth input of described reaction vessel.
Preferably, described dispenser is the most the closer to the zeolite granular of the region input of bottom at described reaction vessel.
Preferably, described dispenser comprises the liquid container of zeolite granular, and described liquid container is at described reaction vessel
Different depth has different delivery ports, for the zeolite granular in described liquid container is sent to described reaction vessel, described
Delivery port is the biggest at the region openings the closer to reaction container bottom.
Preferably, the plurality of positive electrode and multiple auxiliary electrode are the most intensive in the region the closer to reaction container bottom.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of embodiments of the invention.
Fig. 2 is the top view of the electrode group of embodiments of the invention.
Detailed description of the invention
Understandable for enabling the above-mentioned purpose of the present invention, feature and advantage to become apparent from, real with concrete below in conjunction with the accompanying drawings
The present invention is further detailed explanation to execute mode.
Seeing Fig. 1, the sewage degraded purifier of the present invention, including reaction vessel the 100, first power supply 201 and the second electricity
Source 202.Reaction vessel 100 use zeolite granular as the 3rd electrode, by electrocatalytic oxidation by sewage purification.Reaction vessel
100 include shell 110, be sticked shell 110 inwall insulation inwall 120 and can mounting or dismounting lid be connected on the lid on shell 110
130.Setting into the mouth of a river bottom reaction vessel 100, use sewage pipe 190 to access sewage, top arranges delivery port 150, and inside sets
It is equipped with multiple left end electrode group 310 and multiple right-hand member electrode group 320.It is provided with a cleaning bottom the shell 110 of reaction vessel 100
Mouthful, it is equiped with a cleaning dirt valve 140 at Butterworth Hatch, is used for when the components and parts cleaned in container, the liquid energy after cleaning
Discharge by cleaning dirt valve 140.Arranging circulating pump on reaction vessel 100, it passes through circulation pipe 170 by reaction vessel 100 end
The water in portion is evacuated to top and to undershoot, thus the liquid in abundant circulation stirring container, so that three-diemsnional electrode uniform particle suspends
In liquid.
See Fig. 1, multiple left end electrode groups 310 and multiple right-hand member electrode group 320 to include organizing parallel electrode group more, its
Middle left end electrode group 310 and left end electrode group 320 have a special angle respectively with horizontal plane, can be set by this special angle
It is between 30 degree to 60 degree, it is preferred that could be arranged to 45 degree.By such setting, make the difference in reaction vessel 100
The most all there is positive and negative electrode, thus add the efficiency of catalytic reaction, improve purifying property.
See Fig. 2, left side conductive plate 330, right side conductive plate the 340, first middle conductive plate are set in reaction vessel 100
350 and the second middle conductive plate 360.Left side conductive plate 330 is arc, and it connects the first electricity by the first conducting wire 370
Source negative pole;Right side conductive plate 340 is arc, and it connects second source positive pole by the second conducting wire 380;Conduction in the middle of first
Plate 350 is rectangle, and it connects the first positive source by the 3rd conducting wire 371;Second middle conductive plate 360 is rectangular
Shape, it connects second source negative pole by the 4th conducting wire 381.Wherein, the friendship parallel to each other of the positive and negative electrode in left electrodes
Fork;The positive and negative electrode intersection parallel to each other of right electrodes.Preferably, for fixed electrode, can arrange in reaction vessel 100
The fixing bar of fixing positive and negative electrode.
In technique scheme, the liquid within reaction vessel 100 has zeolite granular for as the 3rd electrode.
Preferably, it is also possible to be provided for throwing in the dispenser of zeolite granular.Owing to the sewage of reaction vessel 100 is by being positioned at entering of bottom
The mouth of a river enters, and flows out from the delivery port 150 being positioned at top, and at different depth, the degree of purification of sewage is different.Therefore, may be used
So that described dispenser is set to difference at the zeolite granular content of the different depth input of described reaction vessel.Preferably, institute
State dispenser the most the closer to the zeolite granular of the region input of bottom at described reaction vessel.Further preferred, permissible
The plurality of positive electrode and multiple auxiliary electrode are being arranged the most intensive the closer to the region of reaction container bottom.
Above-mentioned dispenser could be arranged to comprise the liquid container of zeolite granular, and described liquid container is at described reaction vessel
Different depth have different delivery ports, for the zeolite granular in described liquid container being sent to described reaction vessel, institute
State delivery port the biggest at the region openings the closer to reaction container bottom.
Certainly, the present invention also can have other various embodiments, in the case of without departing substantially from present invention spirit and essence thereof, ripe
Know those skilled in the art and can make various corresponding change and deformation according to the present invention, but these change and deformation accordingly
All should belong to the protection domain of the claims in the present invention.