CN104591350B - A kind of sewage environment friendly purification apparatus - Google Patents

A kind of sewage environment friendly purification apparatus Download PDF

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Publication number
CN104591350B
CN104591350B CN201510048624.5A CN201510048624A CN104591350B CN 104591350 B CN104591350 B CN 104591350B CN 201510048624 A CN201510048624 A CN 201510048624A CN 104591350 B CN104591350 B CN 104591350B
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Prior art keywords
electrode
reaction vessel
angle
positive
conductive plate
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CN201510048624.5A
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CN104591350A (en
Inventor
丰来国
章亚振
何长洲
王雅倩
李阳
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Yancheng Lanfeng Environmental Engineering Technology Co Ltd
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Yancheng Lanfeng Environmental Engineering Technology Co Ltd
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Priority to CN201610043548.3A priority Critical patent/CN105540753B/en
Priority to CN201510048624.5A priority patent/CN104591350B/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F1/46114Electrodes in particulate form or with conductive and/or non conductive particles between them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • C02F2001/46157Perforated or foraminous electrodes
    • C02F2001/46161Porous electrodes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

A kind of sewage degraded purifier, including reaction vessel and power supply;Described reaction vessel is by electrocatalytic oxidation by sewage purification, and described power supply is for providing electric current to described reaction vessel;Described reaction container bottom sets into the mouth of a river, and top arranges delivery port, is internally provided with multiple positive electrode and multiple auxiliary electrode;Described positive electrode and described auxiliary electrode have certain degree with horizontal plane.

Description

A kind of sewage environment friendly purification apparatus
Technical field
The present invention relates to water treatment field, especially relate to sewage degraded purifier.
Background technology
China is the country that a little Chemical Manufacture is flourishing, and chemical products kind is many, the complex process related to, sewage Big containing inorganic, organic salt volume, process this kind of sewage and be necessary for the processing method by various combinations.China organises at present Work produces dispersion, is again little Chemical Manufacture, thus results in sewage dispersion, is unfavorable for processing.
People, through long-term endeavour, have established the technology of many purifying waste water processings, and conventional has Physical, chemistry Method, bioanalysis etc., these methods are respectively arranged with its pluses and minuses, mostly to contaminant degradation not thoroughly, easily cause secondary pollution, equipment Investment is big, operating cost is the most high.
Catalysis oxidation high-level oxidation technology is the new technology that water treatment field is risen, and it is by the side of chemically or physically chemistry Pollutant in sewage is direct oxidation into inorganic matter by method, or is translated into the intermediate product of the easily biological-degradable of low toxicity.Electricity Solving catalytic oxidation is a kind of sewage water treatment method improved on the basis of electrolysis process, and this method is for some difficulty The sewage of reason achieves good effect.Catalytic and oxidative electrolysis technology method has: electricity flocculates, electrically floats, aoxidizes, is catalyzed and at electricity The features such as the polar molecule effect under field condition.
In the patent of invention of 201010563370.8, it is proposed that a kind of three-diemsnional electrode electrocatalytic oxidation for sewage of degrading Reactor, it is by arranging the positive and negative electrode of cross parallel in reaction vessel, using the zeolite granular in liquid as the 3rd electricity Pole;During work, positive and negative electrode obtain electric energy, zeolite granular play granule electrode effect and play ion transformation make electrode week Table and liquid produce substantial amounts of OH hydroxyl radical free radical ion, thus the pollutant of sewage is carried out catalysis oxidation, reach environmental protection The purpose of water purification.But, in the invention, different layers positive and negative electrode is placed in parallel, and gap is relatively big, between different layers electrode Liquid catalyst reaction not, affect clean-up effect.
Summary of the invention
As one aspect of the present invention, it is provided that a kind of sewage degraded purifier, including reaction vessel and power supply;Institute Stating reaction vessel by electrocatalytic oxidation by sewage purification, described power supply is for providing electric current to described reaction vessel;Described instead Answering container bottom to set into the mouth of a river, top arranges delivery port, is internally provided with multiple positive electrode and multiple auxiliary electrode;Wherein, Described positive electrode and described auxiliary electrode have certain degree with horizontal plane.
Preferably, described power supply includes the first power supply to reaction vessel left end electrode power supply and to reaction vessel right-hand member The second source of electrode power supply, the plurality of positive electrode and the plurality of negative electrode are divided into left and right two arrays of electrodes, a wherein said left side One group of limit electrode is the first angle with the angle of horizontal plane, and one group of described the right electrode is the second angle with the angle of horizontal plane.
Preferably, described first angle and the second angle are respectively between 30 degree to 60 degree.
Preferably, the angle of described first angle and the second angle is different.
Preferably, the positive and negative electrode of the one group of electrode in the described left side crosses one another;The positive and negative electrode of the one group of electrode in described the right Cross one another.
Preferably, one group of described left side electrode includes that multi-layered electrode, one group of described the right electrode include multi-layered electrode.
Preferably, left side conductive plate, right side conductive plate, the first middle conductive plate and second are set in described reaction vessel Middle conductive plate;Described left side conductive plate is arc, and it connects the first power cathode by the first conducting wire;Described right side is led Electroplax is arc, and it connects second source positive pole by the second conducting wire;Described first middle conductive plate is rectangle, and it leads to Cross the 3rd conducting wire and connect the first positive source;Described second middle conductive plate is rectangle, and it passes through the 4th conducting wire Connect second source negative pole.
Preferably, the liquid within described reaction vessel has zeolite granular for as the 3rd electrode.
Preferably, the dispenser throwing in zeolite granular is also included.
Preferably, described dispenser is different at the zeolite granular content of the different depth input of described reaction vessel.
Preferably, described dispenser is the most the closer to the zeolite granular of the region input of bottom at described reaction vessel.
Preferably, described dispenser comprises the liquid container of zeolite granular, and described liquid container is at described reaction vessel Different depth has different delivery ports, for the zeolite granular in described liquid container is sent to described reaction vessel, described Delivery port is the biggest at the region openings the closer to reaction container bottom.
Preferably, the plurality of positive electrode and multiple auxiliary electrode are the most intensive in the region the closer to reaction container bottom.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of embodiments of the invention.
Fig. 2 is the top view of the electrode group of embodiments of the invention.
Detailed description of the invention
Understandable for enabling the above-mentioned purpose of the present invention, feature and advantage to become apparent from, real with concrete below in conjunction with the accompanying drawings The present invention is further detailed explanation to execute mode.
Seeing Fig. 1, the sewage degraded purifier of the present invention, including reaction vessel the 100, first power supply 201 and the second electricity Source 202.Reaction vessel 100 use zeolite granular as the 3rd electrode, by electrocatalytic oxidation by sewage purification.Reaction vessel 100 include shell 110, be sticked shell 110 inwall insulation inwall 120 and can mounting or dismounting lid be connected on the lid on shell 110 130.Setting into the mouth of a river bottom reaction vessel 100, use sewage pipe 190 to access sewage, top arranges delivery port 150, and inside sets It is equipped with multiple left end electrode group 310 and multiple right-hand member electrode group 320.It is provided with a cleaning bottom the shell 110 of reaction vessel 100 Mouthful, it is equiped with a cleaning dirt valve 140 at Butterworth Hatch, is used for when the components and parts cleaned in container, the liquid energy after cleaning Discharge by cleaning dirt valve 140.Arranging circulating pump on reaction vessel 100, it passes through circulation pipe 170 by reaction vessel 100 end The water in portion is evacuated to top and to undershoot, thus the liquid in abundant circulation stirring container, so that three-diemsnional electrode uniform particle suspends In liquid.
See Fig. 1, multiple left end electrode groups 310 and multiple right-hand member electrode group 320 to include organizing parallel electrode group more, its Middle left end electrode group 310 and left end electrode group 320 have a special angle respectively with horizontal plane, can be set by this special angle It is between 30 degree to 60 degree, it is preferred that could be arranged to 45 degree.By such setting, make the difference in reaction vessel 100 The most all there is positive and negative electrode, thus add the efficiency of catalytic reaction, improve purifying property.
See Fig. 2, left side conductive plate 330, right side conductive plate the 340, first middle conductive plate are set in reaction vessel 100 350 and the second middle conductive plate 360.Left side conductive plate 330 is arc, and it connects the first electricity by the first conducting wire 370 Source negative pole;Right side conductive plate 340 is arc, and it connects second source positive pole by the second conducting wire 380;Conduction in the middle of first Plate 350 is rectangle, and it connects the first positive source by the 3rd conducting wire 371;Second middle conductive plate 360 is rectangular Shape, it connects second source negative pole by the 4th conducting wire 381.Wherein, the friendship parallel to each other of the positive and negative electrode in left electrodes Fork;The positive and negative electrode intersection parallel to each other of right electrodes.Preferably, for fixed electrode, can arrange in reaction vessel 100 The fixing bar of fixing positive and negative electrode.
In technique scheme, the liquid within reaction vessel 100 has zeolite granular for as the 3rd electrode. Preferably, it is also possible to be provided for throwing in the dispenser of zeolite granular.Owing to the sewage of reaction vessel 100 is by being positioned at entering of bottom The mouth of a river enters, and flows out from the delivery port 150 being positioned at top, and at different depth, the degree of purification of sewage is different.Therefore, may be used So that described dispenser is set to difference at the zeolite granular content of the different depth input of described reaction vessel.Preferably, institute State dispenser the most the closer to the zeolite granular of the region input of bottom at described reaction vessel.Further preferred, permissible The plurality of positive electrode and multiple auxiliary electrode are being arranged the most intensive the closer to the region of reaction container bottom.
Above-mentioned dispenser could be arranged to comprise the liquid container of zeolite granular, and described liquid container is at described reaction vessel Different depth have different delivery ports, for the zeolite granular in described liquid container being sent to described reaction vessel, institute State delivery port the biggest at the region openings the closer to reaction container bottom.
Certainly, the present invention also can have other various embodiments, in the case of without departing substantially from present invention spirit and essence thereof, ripe Know those skilled in the art and can make various corresponding change and deformation according to the present invention, but these change and deformation accordingly All should belong to the protection domain of the claims in the present invention.

Claims (4)

1. a sewage degraded purifier, including reaction vessel and power supply;Described reaction vessel passes through electrocatalytic oxidation by dirt Water warfare, described power supply is for providing electric current to described reaction vessel;Described reaction container bottom sets into the mouth of a river, and top is arranged Delivery port, is internally provided with multiple positive electrode and multiple negative electrode;It is characterized in that: the plurality of positive electrode and described many Individual negative electrode is arranged along described reaction vessel vertical direction;Described positive electrode and described negative electrode have specific with horizontal plane Angle, so that differing heights all has positive and negative electrode in reaction vessel;Described power supply includes supplying to reaction vessel left end electrode Electricity the first power supply and give reaction vessel right-hand member electrode power supply second source, the plurality of positive electrode and the plurality of negative electricity Pole is divided into left and right two arrays of electrodes, and wherein one group of left side electrode is the first angle with the angle of horizontal plane, one group of the right electrode and water The angle of plane is the second angle;Liquid within described reaction vessel has zeolite granular for as the 3rd electrode;Throw Putting the dispenser of zeolite granular, described dispenser is different at the zeolite granular content of the different depth input of described reaction vessel; Described first angle and the second angle are respectively between 30 degree to 60 degree;Left side conductive plate, right side are set in described reaction vessel Conductive plate, the first middle conductive plate and the second middle conductive plate;Described left side conductive plate is arc, and it passes through the first conductor wire Road connects the first power cathode;Described right side conductive plate is arc, and it connects second source positive pole by the second conducting wire;Institute Stating the first middle conductive plate is rectangle, and it connects the first positive source by the 3rd conducting wire;Conduction in the middle of described second Plate is rectangle, and it connects second source negative pole by the 4th conducting wire.
Sewage the most according to claim 1 degraded purifier, it is characterised in that: described first angle and the second angle Angle is different.
Sewage the most according to claim 2 degraded purifier, it is characterised in that: the positive negative electricity of the one group of electrode in the described left side Pole crosses one another;The positive and negative electrode of the one group of electrode in described the right crosses one another.
Sewage the most according to claim 3 degraded purifier, it is characterised in that: one group of described left side electrode includes multilayer Electrode, one group of described the right electrode includes multi-layered electrode.
CN201510048624.5A 2015-01-30 2015-01-30 A kind of sewage environment friendly purification apparatus Active CN104591350B (en)

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CN201610043548.3A CN105540753B (en) 2015-01-30 2015-01-30 A kind of sewage degradation purifier
CN201510048624.5A CN104591350B (en) 2015-01-30 2015-01-30 A kind of sewage environment friendly purification apparatus

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019046743A1 (en) * 2017-08-31 2019-03-07 Chevron U.S.A. Inc. Devices and methods for the remediation of groundwater

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN101125695A (en) * 2007-08-03 2008-02-20 重庆大学 Pulse electric floatation generating method and generating device thereof
CN101549897A (en) * 2008-12-30 2009-10-07 中冶赛迪工程技术股份有限公司 Electrolytic gas float wastewater treatment device
CN102101707A (en) * 2010-11-26 2011-06-22 方明环保科技(漳州)有限公司 Three-dimensional electrode electro-catalytic oxidation reactor for degrading sewage
CN203715341U (en) * 2014-02-24 2014-07-16 诚恳 Skew plate electrofloatation oil water separating device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1354140A (en) * 2000-11-17 2002-06-19 中国科学院生态环境研究中心 Catalytic electrolytic waste water treatment equipment
CN101125695A (en) * 2007-08-03 2008-02-20 重庆大学 Pulse electric floatation generating method and generating device thereof
CN101549897A (en) * 2008-12-30 2009-10-07 中冶赛迪工程技术股份有限公司 Electrolytic gas float wastewater treatment device
CN102101707A (en) * 2010-11-26 2011-06-22 方明环保科技(漳州)有限公司 Three-dimensional electrode electro-catalytic oxidation reactor for degrading sewage
CN203715341U (en) * 2014-02-24 2014-07-16 诚恳 Skew plate electrofloatation oil water separating device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019046743A1 (en) * 2017-08-31 2019-03-07 Chevron U.S.A. Inc. Devices and methods for the remediation of groundwater

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CN104591350A (en) 2015-05-06
CN105540753B (en) 2018-09-21

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Inventor after: Feng Laiguo

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