CN1045867C - Anti-moth paper card - Google Patents
Anti-moth paper card Download PDFInfo
- Publication number
- CN1045867C CN1045867C CN93112463A CN93112463A CN1045867C CN 1045867 C CN1045867 C CN 1045867C CN 93112463 A CN93112463 A CN 93112463A CN 93112463 A CN93112463 A CN 93112463A CN 1045867 C CN1045867 C CN 1045867C
- Authority
- CN
- China
- Prior art keywords
- moth
- paper
- medicine
- paper card
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a mothproof paper card used for wool, cotton and silk fabrics. The active component of the present invention comprises dichloroethynyl pentachrysanthemate which is used as a main body, and a small amount of synergist and spice are added. Biological tests show that the present invention has an effective killing function on cloth moths, black carpet beetles and small cabinet beetles, which damage wool, cotton and silk fabrics. The present invention has no harmful effect on texture of wool, cotton and silk fabrics, and is a novel mothproof agent which can replace camphor and naphthalene products.
Description
Anti-moth paper card of the present invention relates to velvet apple fabric Mothproof camphor medicine.
In the application of modern household mothproofing agent, naphthalene and camphor are to use at most, most widely used medicine, but use for many years practice shows, is the camphor ball and the camphor goods of Main Ingredients and Appearance with the naphthalene, to damaging the curtain casemaking clothes moth Tineolabisselliella of velvet apple fabric, the stupid Anthrenus verbasci of roundlet skin, the stupid Attagenuspiceus of casting skin, killing effect is very poor, especially naphthalene is recognized the world over to the murder by poisoning of human body.From the eighties initial stage, developed country successively bans use of naphthalene as mothproofing agent.In the research of the novel mothproofing agent that replaces the naphthalene goods, a kind of with Vaporthrin (having another name called Empentrin, middle translated name aerosol chrysanthemum ester, alkynes valerate), the insect preservative paper of making is a kind of mothproof preferably product.Vaporthrin has the very strong power of knocking down to moths such as casemaking clothes moths, because its vapour pressure is higher, also can volatilize at normal temperatures, and therefore available blotting paper dipping is coated with layer of polyethylene or polypropylene film then on paper, drug slow is discharged (see
Portion starts the clear 60-2 of patent JP, and 799, the clear 60-161 of JP, 908).But show through our biologicall test, though the insect preservative paper of making of Vaporthrin has good effect to curtain casemaking clothes moth Tineole bisselliella, to China and Asia wool spinning product, the main moth of fur product---roundlet skin killing effect stupid and that casting skin is stupid is also undesirable.
The objective of the invention is to develop a kind of novel mothproofing agent that can replace camphor and naphthalene goods, a kind of mothproofing agent and manufacture method thereof with good mothproof killing action is provided.
The medicine of the anti-moth paper card that the present invention proposes is by be that the synergism medicine of main body interpolation 1.5-20% and the spices of 0.3-0.5% are formed with dichloro alkyne valerate (seeing structural formula).Synergism medicine comprises chemicals such as insecticide, plants essential oil and ethylene glycol monobutyl ether.Insecticide is decis or tetramethrin or unden or chlopyrifos.Plants essential oil is lavender oil or peppermint or carvol.
The anti-moth paper card that the present invention proposes, because the vapour pressure of dichloro alkyne valerate is low slightly, therefore the technology of the slowly-releasing of directly filming on the paper is not adopted in making of the present invention, method is as follows: at first with the insecticide of dichloro alkyne valerate and interpolation, chemicals such as plants essential oil and ethylene glycol monobutyl ether is mixed with certain density solution with organic solvent, the quantitative impregnated paper of solution with preparation, after treating solvent evaporates, respectively put up and down one identical with the filter paper size, one side scribbles the plastic-coated oil sealing paper of polyethylene film, to press with corresponding two bandings that filter paper intersects with plastic sealing machine at last, pressure is not sealed on both sides in addition, is convenient to drug.
The present invention is light except having, safety, free from environmental pollution outside, to the curtain casemaking clothes moth of badly damaged velvet apple silk fabric, roundlet khapra beetle and attagenus piceus demonstrate good killing effect, and velvet apple silk fabric quality is not had influence, are a kind of substituents of desirable naphthalene goods.Following comparative trial further confirms this good effect.
In eight 1000ml round mouth glass jars, respectively put into full wool openpore and knit sheet (4 * 4cm) 4 put 5 curtain casemaking clothes moth larvas (4 make), 5 roundlet khapra beetle larvas (4 make) and 5 attagenus piceus larvas (7-9 makes) bad the knitting of wool white on the sheet.Cut 1.5 * 4cm small pieces from each mothproofing paper sample and put into the polyethylene film pouch of 2 * 4.5cm (end opening), with viscose paper it is sticked on inside wall of cylinder centre, the cylinder mouth is topped with 6 thick polychloroethylene films, place 25 ± 1 ℃, relative moisture is in the complete dark thermostatic chamber of 65-70%, observed once outside cylinder every 15 days, opened topped thin film inspection moth lethality and workprint in every month by the moth degree, the pastille scraps of paper are motionless, put into new wool sheet and moth then, test is continued in the topped back of cylinder mouth, finishes to 6th month.
In order to further specify good effect of the present invention, with commercially available refined naphthalene camphor ball, the insect preservative paper that camphor spirit piece and Japan produce removes refined naphthalene camphor ball and camphor spirit piece wrap up with air-permeable paper in contrast during biological test, and other are operated as hereinbefore.Check result such as table 1.
From top biologicall test as can be seen, insect preservative paper with Japanese Vaporthrin making, though the curtain casemaking clothes moth is had good effect, but the killing power of drug-resistant capability being imitated strong casting skin capsule and roundlet leather bag is relatively poor, has been not enough to suppress the moth food of these two kinds of khapra beetles in three month its drug effect of small container test.By contrast, the present invention is stronger to the power of knocking down and the killing power of attagenus piceus and roundlet khapra beetle, in the harm that still can suppress them in 4-6 month effectively of test.Mothproof ability of the present invention not only far surpasses the naphthalene camphor ball, and has surpassed Japanese mothproofing paper, has further embodied good effect of the present invention.
Following embodiment will be further described the technical scheme of anti-moth paper card of the present invention.
Embodiment 1, the anti-moth paper card medicine by dichloro alkyne valerate, ethylene glycol monobutyl ether, unden, spices is composite forms, its percentage by weight is 75: 20: 4.7: 0.3.
At first composite medicine is made 25% ethanol, one acetone (1: 1) solution, filter paper with 0.18mm thickness 10 * 15cm quantitatively floods, making every filter paper be subjected to dose is 500mg, after treating solvent evaporates, respectively put the polyethylene film plastic-coated oil sealing paper that an one side with the identical paper of filter paper size scribbles 2 thickness up and down, mould towards interior, press short both sides open-ended with two bandings that plastic sealing machine is long with 15cm.
Embodiment 2, the anti-moth paper card medicine by dichloro alkyne valerate, carvol, peppermint, decis is composite forms, its percentage by weight is 85: 8.2: 5: 1.8.At first composite medicine is mixed with 25% ethanol-acetone (1: 1) solution, paper card preparation method such as embodiment 1.
Embodiment 3, the anti-moth paper card medicine by dichloro alkyne valerate, chlopyrifos, spices is composite forms, its percentage by weight is 80: 19.5: 0.5, being subjected to dose is 500mg, at first composite medicine is mixed with 25% ethanol-acetone (1: 1) solution, other preparation methods such as embodiment 1.
Embodiment 4, and the anti-moth paper card medicine is by dichloro alkyne valerate, lavender oil, and tetramethrin is composite to form, and its percentage by weight is 75: 20: 5, and being subjected to dose is 500mg, preparation method such as embodiment 1.
Using above-mentioned prescription and aforementioned method of testing to measure them finds the mothproof effect of curtain casemaking clothes moth, roundlet khapra beetle, attagenus piceus, embodiment 3 mothproof effects are best, but embodiment 1, embodiment 2 and embodiment 4 have and well kill mothproof effect in the harm that also can suppress three kinds of moths in 4-6 month effectively of test.
Table 1 1000ml container is tested mothproof result
* Japan's product insect preservative paper is 10 * 15cm, and every insect preservative paper effective volume is 25 liters
| Sample | Sample size and pastille are put | Checked in first month | Checked in second month | Check March | |||||||||
| Curtain casemaking clothes moth lethality | The attagenus piceus lethality | Roundlet khapra beetle lethality | Workprint is by the moth degree | Curtain casemaking clothes moth lethality | The attagenus piceus lethality | Roundlet khapra beetle lethality | Workprint is by the moth degree | Curtain casemaking clothes moth lethality | The attagenus piceus lethality | Roundlet khapra beetle lethality | Workprint is by the moth degree | ||
| Blank | 0 | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage |
| The camphor spirit piece | 1g | 60 | 20 | 0 | The moth duck eye | 60 | 0 | 0 | Eat into big hole | 20 | 0 | 0 | Eat into big hole |
| The refined naphthalene camphor ball | 1g | 40 | 20 | 0 | Eat into big hole | 60 | 0 | 0 | Eat into big hole | 20 | 0 | 0 | Eat into big hole |
| Japan produces insect preservative paper | 6cm 2 * | 100 | 80 | 40 | There is not the moth evil | 100 | 60 | 0 | The light moth in surface | 100 | 20 | 0 | The moth duck eye |
| Pure Chinese and Western aerosol chrysanthemum ester paper card | 6cm 2 20mg | 100 | 60 | 40 | There is not the moth evil | 100 | 40 | 40 | There is not the moth evil | 100 | 60 | 20 | The light moth in surface |
| Example 2 of the present invention | 6cm 2 20mg | 100 | 60 | 40 | There is not the moth evil | 100 | 100 | 60 | There is not the moth evil | 100 | 80 | 40 | There is not the moth evil |
| Example 3 of the present invention | 6cm 2 20mg | 100 | 60 | 60 | There is not the moth evil | 100 | 100 | 80 | There is not the moth evil | 100 | 100 | 100 | There is not the moth evil |
Continuous table 1 1000ml container is tested mothproof result
The structural formula dichloro alkyne valerate
| Check April | Check May | Check June | ||||||||||
| Curtain casemaking clothes moth lethality | The attagenus piceus lethality | Roundlet khapra beetle lethality | Workprint is by the moth degree | Curtain casemaking clothes moth lethality | The attagenus piceus lethality | Roundlet khapra beetle lethality | Workprint is by the moth degree | Curtain casemaking clothes moth lethality | The attagenus piceus lethality | Roundlet khapra beetle lethality | Workprint is by the moth degree | |
| Blank | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage |
| The camphor spirit piece | 0 | 0 | 0 | Eat into big hole | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage |
| The refined naphthalene camphor ball | 0 | 0 | 0 | Eat into big hole | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage |
| Japan produces insect preservative paper | 100 | 0 | 0 | Eat into big hole | 0 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage |
| Pure Chinese and Western aerosol chrysanthemum ester | 100 | 20 | 0 | The moth duck eye | 20 | 0 | 0 | Heavy damage | 0 | 0 | 0 | Heavy damage |
| Example 2 of the present invention | 100 | 60 | 20 | There is not the moth evil | 100 | 40 | 0 | There is not the moth evil | 80 | 40 | 0 | The light moth in surface |
| Example 3 of the present invention | 100 | 100 | 60 | There is not the moth evil | 100 | 100 | 40 | There is not the moth evil | 100 | 80 | 20 | There is not the moth evil |
Claims (5)
1, a kind of anti-moth paper card comprises impregnated paper, it is characterized in that Department of Pharmacy on this impregnated paper based on dichloro alkyne valerate, and adds the synergism medicine of 1.5-20%.
2, anti-moth paper card according to claim 1 is characterized in that said synergism medicine is insecticide or plants essential oil or ethylene glycol monobutyl ether.
3, anti-moth paper card according to claim 2 is characterized in that said insecticide is decis or tetramethrin or unden or chlopyrifos.
4, anti-moth paper card according to claim 2 is characterized in that said plants essential oil is lavender oil or peppermint or carvol.
5, a kind of preparation method of anti-moth paper card, be that first synergism medicine with dichloro alkyne valerate and interpolation is mixed with solution with organic solvent, solution impregnation with above-mentioned preparation is subjected to medicine filter paper again, after it is characterized in that treating a solvent evaporates that is subjected on the medicine filter paper, put one thereon respectively and scribble the plastic-coated oil sealing paper of polyethylene film with the identical one side of filter paper size, mould face in, corresponding two bandings of plastic-coated oil sealing paper are pressed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93112463A CN1045867C (en) | 1993-06-18 | 1993-06-18 | Anti-moth paper card |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93112463A CN1045867C (en) | 1993-06-18 | 1993-06-18 | Anti-moth paper card |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1079607A CN1079607A (en) | 1993-12-22 |
| CN1045867C true CN1045867C (en) | 1999-10-27 |
Family
ID=4990072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93112463A Expired - Fee Related CN1045867C (en) | 1993-06-18 | 1993-06-18 | Anti-moth paper card |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1045867C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111374147A (en) * | 2018-12-27 | 2020-07-07 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing prallethrin and propoxur |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS602799A (en) * | 1983-06-18 | 1985-01-09 | 大日本除虫菊株式会社 | Insect-proof paper |
| JPS60161908A (en) * | 1984-01-31 | 1985-08-23 | Katsuta Yoshio | Insecticidal material for cloth |
-
1993
- 1993-06-18 CN CN93112463A patent/CN1045867C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS602799A (en) * | 1983-06-18 | 1985-01-09 | 大日本除虫菊株式会社 | Insect-proof paper |
| JPS60161908A (en) * | 1984-01-31 | 1985-08-23 | Katsuta Yoshio | Insecticidal material for cloth |
Non-Patent Citations (1)
| Title |
|---|
| 中国化工学会农药学会第五届会论文集 1989.10. 1 《炔成氯酯和几种常用防蛀剂对黑皮蠹幼虫的熏蒸效果》尹希英,孙兵,邵广凤,天津 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1079607A (en) | 1993-12-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Hebeish et al. | Preparation of durable insect repellent cotton fabric: Limonene as insecticide | |
| Surendhiran et al. | Fabrication of high stability active nanofibers encapsulated with pomegranate peel extract using chitosan/PEO for meat preservation | |
| López‐Velázquez et al. | Gelatin–chitosan–PVA hydrogels and their application in agriculture | |
| US11598047B2 (en) | Process for producing fibrous material with antimicrobial properties | |
| Farias et al. | Electrospun polymer nanofibers as seed coatings for crop protection | |
| CN101591858B (en) | Anti-mosquito cloth and manufacturing method thereof | |
| US20030003126A1 (en) | Insecticide-impregnated fabric and method of production | |
| CN109077947A (en) | A kind of medical ophthalmology cold compress dressing and preparation method thereof | |
| CN1045867C (en) | Anti-moth paper card | |
| CN108135169A (en) | There is the compound and composition for knocking down or eating blood inhibitory activity for insect pest | |
| DE2721427C2 (en) | Process for making a food casing from cellulose | |
| Hassan | Enhanced insect-resistance, UV protection, and antibacterial and antistatic properties exhibited by wool fabric treated with polyphenols extracted from mango seed kernel and feijoa peel | |
| KR100769852B1 (en) | Mothproof and antifungal treatment composition for textile and textile treatment method using said composition | |
| DE69907538T2 (en) | Tissue protection agent against pests | |
| Pascual-Villalobos et al. | New application of guayule resin in controlled release formulations | |
| JPH1087409A (en) | Repellent and exterminator of epidermoptid | |
| CN107788106A (en) | A kind of nonwoven fabric base composite fresh-keeping material and preparation method thereof | |
| CN105019229A (en) | Preparation method of silver-carrying antibacterial blended fabric | |
| Abdel-Mohdy et al. | Repellency of controlled-release treated-cotton fabrics based on permethrin and bioallethrin against mosquitoes | |
| JPH07316003A (en) | Wash-resistant repellent for blood-sucking vermin for textile product | |
| KR20230099512A (en) | Insect repellent composition derived from a natural product containing cinnamon | |
| JP3750878B2 (en) | Insect repellent fibers and insect repellent fiber products | |
| CN107468540B (en) | Cleaning material suitable for cleaning face and preparation method thereof | |
| JP3887053B2 (en) | Antibacterial fiber product and its manufacturing method | |
| US20110104224A1 (en) | Textile Finishing For Insect Repellency |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |