CN104562793B - The method of the modified pigment dyeing of a kind of ramie fabric - Google Patents
The method of the modified pigment dyeing of a kind of ramie fabric Download PDFInfo
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- CN104562793B CN104562793B CN201510078073.7A CN201510078073A CN104562793B CN 104562793 B CN104562793 B CN 104562793B CN 201510078073 A CN201510078073 A CN 201510078073A CN 104562793 B CN104562793 B CN 104562793B
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- modified pigment
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- ramie fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 30
- 238000004043 dyeing Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 23
- 240000008564 Boehmeria nivea Species 0.000 title claims abstract description 22
- 239000000049 pigment Substances 0.000 title claims abstract description 14
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000004048 modification Effects 0.000 claims abstract description 14
- 238000012986 modification Methods 0.000 claims abstract description 14
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 3-chloro-2-hydroxypropyl trimethylammonium amine Chemical class 0.000 claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 6
- 230000001070 adhesive effect Effects 0.000 claims abstract description 6
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 6
- 239000003112 inhibitor Substances 0.000 claims abstract description 6
- 230000005012 migration Effects 0.000 claims abstract description 6
- 238000013508 migration Methods 0.000 claims abstract description 6
- 239000003973 paint Substances 0.000 claims abstract description 6
- 229920002545 silicone oil Polymers 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 15
- 238000002203 pretreatment Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 238000002386 leaching Methods 0.000 claims description 5
- 238000006386 neutralization reaction Methods 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 21
- 239000000835 fiber Substances 0.000 description 11
- 241000208202 Linaceae Species 0.000 description 7
- 235000004431 Linum usitatissimum Nutrition 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 3
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 3
- 235000009120 camo Nutrition 0.000 description 3
- 235000005607 chanvre indien Nutrition 0.000 description 3
- 239000011487 hemp Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 244000198134 Agave sisalana Species 0.000 description 1
- 235000011624 Agave sisalana Nutrition 0.000 description 1
- 241000722948 Apocynum cannabinum Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- SSDZRWBPFCFZGB-UHFFFAOYSA-N TCA-ethadyl Chemical compound ClC(Cl)(Cl)C(=O)OCCOC(=O)C(Cl)(Cl)Cl SSDZRWBPFCFZGB-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- LFZDEAVRTJKYAF-UHFFFAOYSA-L barium(2+) 2-[(2-hydroxynaphthalen-1-yl)diazenyl]naphthalene-1-sulfonate Chemical compound [Ba+2].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21.C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 LFZDEAVRTJKYAF-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
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Abstract
The present invention relates to the method for the modified pigment dyeing of a kind of ramie fabric, the present invention take ramee as raw material, through N hydroxymethyl acrylamide, 3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate, methyl acrylate modification, use that D type pigmented paint is red, adhesive, migration inhibitor, crosslinking agent, silicone oil and MgCl further
2the dye liquor of composition carries out pigment dyeing.Advantage of the present invention improves the dyeability of ramee, makes ramee in elongation, hooks strong, pliability, fatigue behaviour and dyeability and be all significantly improved.
Description
Technical field
The present invention relates to field of fabric producing technology, particularly fabric-modifying dyeing.
Background technology
Bast-fibre, as the most ancient textile fabric, is considered to the witness of human history.The flax fibre that flax spinning is contained comprises: flax, ramie, jute, sisal hemp, gombo hemp, hemp, bluish dogbane etc.Hygroscopicity is strong, rapid heat dissipation, and antiseptic and inhibiting bacteria function ability is strong, tone is soft, reproducible utilization, ecological, environmental protective ... numerous advantages characteristics, make hemp product from time immemorial to all existing among human lives now, developing, the development of flax product is also the embodiment of wisdom of humanity development simultaneously.
Flax fibre is because degree of crystallinity is high, the degree of orientation is high, little and the compact arranged aggregated structure in inclination angle, there is the defect of stainability difference, be embodied in dyestuff to fibrous inside diffusion slowly, dye-uptake is lower, low degree of fixation and COLOR FASTNESS difference etc., the dyeing tinctorial yield of a lot of flax fibre is not high, and the dark kind of part need carry out secondary dyeing just can reach Color.In Chinese invention patent " method of modifying of linen fibre " [CN1584183], disclose a kind of method that linen fibre modification is beneficial to dye, first linen fibre is put into the urea liquid that content is 50 ~ 300 grams per liters, soak into rear taking-up, then being heat 1 ~ 4 minute in the micro-wave oven of 300 ~ 400W in power output by linen fibre, is then heat in the micro-wave oven of 600 ~ 800W after 0.5 ~ 3 minute to take out in power output by linen fibre.Through modified linen fibre color depth with compare before modified and can improve more than 6%.
In the process that traditional activated dyestuff dyes to flax fibre, in order to improve dye-uptake and the degree of fixation of REACTIVE DYES, a large amount of sodium chloride or sodium sulphate must be added, and consumption reaches 30 ~ 150g/l.The use of a large amount of inorganic salts, cannot degrade and reclaim, very big to the negative effect of water quality and soil, causes the pollution to environment.
Summary of the invention
For above-mentioned defect, the object of the invention is to, provide the method for the modified pigment dyeing of a kind of ramie fabric, improve the dyeability of ramee, make ramee in elongation, hook strong, pliability, fatigue behaviour and dyeability and be all significantly improved.
For achieving the above object, technical scheme of the present invention is the method for the modified pigment dyeing of a kind of ramie fabric, and concrete steps are as follows:
(1) modification liquid (with parts by weight) is prepared:
N hydroxymethyl acrylamide 40-55
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate 20-30
Triethanolamine 60-90
Methyl acrylate 6-8
ZnCl
2 10-15
Water 100-150;
(2) grafting process: will bake 8min → washing → acid neutralization → washing → dry at ramie fabric → room temperature immersion → oven dry → 150 of pre-treatment DEG C, wherein, the consumption of modification liquid is 5%(owf.), bath raio 1:10-30;
(3) modified pigment dyeing: modified ramie step 2 prepared dyes, its dye liquor technical recipe following (in grams per liter):
The red 10-15 of D type pigmented paint
Adhesive 25-30
Migration inhibitor 10-12
Crosslinking agent 15-20
Silicone oil 3-5
MgCl
21-2
Water 80-100;
The technological process of described dyeing is that → drying → evaporate → soap → hot blast tentering oven dry → clot is rolled in grey cloth pre-treatment → bis-leaching two; Wherein, after grey cloth pre-treatment, liquid carrying rate is 70-75%, and even end to end, and after dye, pick-up is 90-95%; Padding temperature is room temperature; The speed of a motor vehicle is 20-40 m/min; When padding dye liquor, nip pressure is air pressure 147KPa, oil pressure 118KPa; Drying steam pressure is 49-147KPa, and each drying cylinder is gradually high successively.
Preferably, the consisting of (with parts by weight) of described modification liquid:
N hydroxymethyl acrylamide 50 parts
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate amine 25 parts
Triethanolamine 75 parts
Methyl acrylate 7 parts
ZnCl
212.5 parts
125 parts, water.
Preferably, tartaric acid adjust ph is used during described dyeing.
The invention has the advantages that: by the cation modifying to ramie fabric, improve the affinity between coating-fabric, improve the dye-uptake of coating to ramie fabric.Containing multiple hydroxyl in modifier molecules chain, reduce traditional low molecular weight linen modifier as the positive charge effect of Glytac reagent, and introduce in fabric abundant " dye seat ", improve the level-dyeing property of coating in modified ramie textile dyeing, make ramee in elongation, hook strong, pliability, fatigue behaviour and dyeability and be all significantly improved.
The inventive method is simple and feasible, does not need to build large production equipment, only needs simple textile fabric post processing equipment just can realize suitability for industrialized production, has investment of production few, and technique is simple, the features such as production cost is low.
Detailed description of the invention
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment one:
(1) modification liquid (with parts by weight) is prepared:
N hydroxymethyl acrylamide 40
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate 20
Triethanolamine 60
Methyl acrylate 6
ZnCl
2 10
Water 100;
(2) grafting process: will bake 8min → washing → acid neutralization → washing → dry at ramie fabric → room temperature immersion → oven dry → 150 of pre-treatment DEG C, wherein, the consumption of modification liquid is 5%(owf.), bath raio 1:10;
(3) modified pigment dyeing: modified ramie step 2 prepared dyes, its dye liquor technical recipe following (in grams per liter):
D type pigmented paint red 10
Adhesive 25
Migration inhibitor 10
Crosslinking agent 15
Silicone oil 3
MgCl
21
Water 80;
The technological process of described dyeing is that → drying → evaporate → soap → hot blast tentering oven dry → clot is rolled in grey cloth pre-treatment → bis-leaching two; Wherein, after grey cloth pre-treatment, liquid carrying rate is 70%, and even end to end, and after dye, pick-up is 90%; Padding temperature is room temperature; The speed of a motor vehicle is 20 ms/min; When padding dye liquor, nip pressure is air pressure 147KPa, oil pressure 118KPa; Drying steam pressure is 49KPa, and each drying cylinder is gradually high successively.
Embodiment two:
(1) modification liquid (with parts by weight) is prepared:
N hydroxymethyl acrylamide 55
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate 30
Triethanolamine 90
Methyl acrylate 8
ZnCl
2 15
Water 150;
(2) grafting process: will bake 8min → washing → acid neutralization → washing → dry at ramie fabric → room temperature immersion → oven dry → 150 of pre-treatment DEG C, wherein, the consumption of modification liquid is 5%(owf.), bath raio 1:30;
(3) modified pigment dyeing: modified ramie step 2 prepared dyes, its dye liquor technical recipe following (in grams per liter):
D type pigmented paint red 15
Adhesive 30
Migration inhibitor 12
Crosslinking agent 20
Silicone oil 5
MgCl
22
Water 100;
The technological process of described dyeing is that → drying → evaporate → soap → hot blast tentering oven dry → clot is rolled in grey cloth pre-treatment → bis-leaching two; Wherein, after grey cloth pre-treatment, liquid carrying rate is 75%, and even end to end, and after dye, pick-up is 95%; Padding temperature is room temperature; The speed of a motor vehicle is 40 ms/min; When padding dye liquor, nip pressure is air pressure 147KPa, oil pressure 118KPa; Drying steam pressure is 147KPa, and each drying cylinder is gradually high successively.
Embodiment three:
(1) modification liquid (with parts by weight) is prepared:
N hydroxymethyl acrylamide 50 parts
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate amine 25 parts
Triethanolamine 75 parts
Methyl acrylate 7 parts
ZnCl
212.5 parts
125 parts, water;
(2) grafting process: will bake 8min → washing → acid neutralization → washing → dry at ramie fabric → room temperature immersion → oven dry → 150 of pre-treatment DEG C, wherein, the consumption of modification liquid is 5%(owf.), bath raio 1:20;
(3) modified pigment dyeing: modified ramie step 2 prepared dyes, its dye liquor technical recipe following (in grams per liter):
D type pigmented paint red 12
Adhesive 28
Migration inhibitor 11
Crosslinking agent 17
Silicone oil 4
MgCl
21.5
Water 90;
The technological process of described dyeing is that → drying → evaporate → soap → hot blast tentering oven dry → clot is rolled in grey cloth pre-treatment → bis-leaching two; Wherein, after grey cloth pre-treatment, liquid carrying rate is 73%, and even end to end, and after dye, pick-up is 93%; Padding temperature is room temperature; The speed of a motor vehicle is 30 ms/min; When padding dye liquor, nip pressure is air pressure 147KPa, oil pressure 118KPa; Drying steam pressure is 100KPa, and each drying cylinder is gradually high successively.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (3)
1. a method for the modified pigment dyeing of ramie fabric, is characterized in that:
(1) modification liquid (with parts by weight) is prepared:
N hydroxymethyl acrylamide 40-55
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate 20-30
Triethanolamine 60-90
Methyl acrylate 6-8
ZnCl
2 10-15
Water 100-150;
(2) grafting process: will bake 8min → washing → acid neutralization → washing → dry at ramie fabric → room temperature immersion → oven dry → 150 of pre-treatment DEG C, wherein, the consumption of modification liquid is about 5%(owf.), bath raio 1:10-30;
(3) modified pigment dyeing: modified ramie prepared by step (2) is dyeed, its dye liquor technical recipe following (in grams per liter):
The red 10-15 of D type pigmented paint
Adhesive 25-30
Migration inhibitor 10-12
Crosslinking agent 15-20
Silicone oil 3-5
MgCl
21-2
Water 80-100;
The technological process of described dyeing is that → drying → evaporate → soap → hot blast tentering oven dry → clot etc. is rolled in grey cloth pre-treatment → bis-leaching two; Wherein, after grey cloth pre-treatment, liquid carrying rate is 70-75%, and even end to end, and after dye, pick-up is 90-95%; Padding temperature is room temperature; The speed of a motor vehicle is 20-40 m/min; When padding dye liquor, nip pressure is air pressure 147KPa, oil pressure 118KPa; Drying steam pressure is 49-147KPa, and each drying cylinder is gradually high successively.
2. the method for the modified pigment dyeing of ramie fabric according to claim 1, is characterized in that: consisting of (with parts by weight) of described modification liquid:
N hydroxymethyl acrylamide 50 parts
3-chloro-2-hydroxypropyl trimethylammonium amine hydrochlorate amine 25 parts
Triethanolamine 75 parts
Methyl acrylate 7 parts
ZnCl
212.5 parts
125 parts, water.
3. the method for the modified pigment dyeing of a kind of ramie fabric according to claim 1, its feature: use tartaric acid adjust ph during described dyeing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510078073.7A CN104562793B (en) | 2015-02-14 | 2015-02-14 | The method of the modified pigment dyeing of a kind of ramie fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510078073.7A CN104562793B (en) | 2015-02-14 | 2015-02-14 | The method of the modified pigment dyeing of a kind of ramie fabric |
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| Publication Number | Publication Date |
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| CN104562793A CN104562793A (en) | 2015-04-29 |
| CN104562793B true CN104562793B (en) | 2015-11-04 |
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|---|---|---|---|
| CN201510078073.7A Expired - Fee Related CN104562793B (en) | 2015-02-14 | 2015-02-14 | The method of the modified pigment dyeing of a kind of ramie fabric |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105108861A (en) * | 2015-09-02 | 2015-12-02 | 安徽省蓼源贸易有限责任公司 | Bamboo craft dyeing method |
| CN107083686A (en) * | 2017-05-22 | 2017-08-22 | 苏州凯邦生物技术有限公司 | A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase |
| CN107700245A (en) * | 2017-09-29 | 2018-02-16 | 张新文 | The online modified technique of fiber |
| CN107558259A (en) * | 2017-09-29 | 2018-01-09 | 张新文 | Fiber treatment modifying agent and its method of modifying |
| CN109112857A (en) * | 2018-07-20 | 2019-01-01 | 石狮市聚祥漂染有限公司 | A method of improving reactive dye dark color friction fastness |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225602A (en) * | 2007-12-18 | 2008-07-23 | 苏州大学 | Fibrilia grafting amination modifying process |
| CN101545201A (en) * | 2009-04-24 | 2009-09-30 | 西南大学 | Ramie fabric dyeing property modifier and modifying method thereof |
| CN103410018A (en) * | 2013-08-22 | 2013-11-27 | 齐齐哈尔大学 | Flax/wool one-bath homochromatic dyeing process |
-
2015
- 2015-02-14 CN CN201510078073.7A patent/CN104562793B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225602A (en) * | 2007-12-18 | 2008-07-23 | 苏州大学 | Fibrilia grafting amination modifying process |
| CN101545201A (en) * | 2009-04-24 | 2009-09-30 | 西南大学 | Ramie fabric dyeing property modifier and modifying method thereof |
| CN103410018A (en) * | 2013-08-22 | 2013-11-27 | 齐齐哈尔大学 | Flax/wool one-bath homochromatic dyeing process |
Non-Patent Citations (2)
| Title |
|---|
| 亚麻棉涂料浸染工艺研究（上）;童卓萍;《染整技术》;20050331;第27卷(第5期);第1-4页 * |
| 国内苎麻纤维化学改性现状研究;徐海燕;《河南工程学院学报（自然科学版）》;20120330;第24卷(第21期);第20-24页 * |
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Effective date of registration: 20160323 Address after: 226100, Haimen, Jiangsu, Nantong goods long Zhenhai Zhenhai village twenty-three, No. 16 Patentee after: Tang Qun Address before: 311800 Zhejiang city in Shaoxing Province, Zhuji City, East Street and East Road No. 469 Patentee before: Li Hailan |
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