CN107083686A - A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase - Google Patents
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase Download PDFInfo
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- CN107083686A CN107083686A CN201710362183.5A CN201710362183A CN107083686A CN 107083686 A CN107083686 A CN 107083686A CN 201710362183 A CN201710362183 A CN 201710362183A CN 107083686 A CN107083686 A CN 107083686A
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- sodolin
- drying
- dyeing
- utilization
- catalase
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- 238000004043 dyeing Methods 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 32
- 102000016938 Catalase Human genes 0.000 title claims abstract description 31
- 108010053835 Catalase Proteins 0.000 title claims abstract description 31
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 57
- 238000001035 drying Methods 0.000 claims abstract description 52
- 239000011259 mixed solution Substances 0.000 claims abstract description 37
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 28
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 28
- 238000002525 ultrasonication Methods 0.000 claims abstract description 26
- 150000001413 amino acids Chemical class 0.000 claims abstract description 24
- 239000011592 zinc chloride Substances 0.000 claims abstract description 22
- 239000000243 solution Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 230000033228 biological regulation Effects 0.000 claims abstract description 10
- LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000004061 bleaching Methods 0.000 claims abstract description 9
- 238000007598 dipping method Methods 0.000 claims abstract description 9
- 238000007654 immersion Methods 0.000 claims abstract description 9
- 238000009991 scouring Methods 0.000 claims abstract description 9
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 18
- 238000010792 warming Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 8
- ATINCSYRHURBSP-UHFFFAOYSA-K neodymium(iii) chloride Chemical compound Cl[Nd](Cl)Cl ATINCSYRHURBSP-UHFFFAOYSA-K 0.000 claims description 2
- LHBNLZDGIPPZLL-UHFFFAOYSA-K praseodymium(iii) chloride Chemical compound Cl[Pr](Cl)Cl LHBNLZDGIPPZLL-UHFFFAOYSA-K 0.000 claims description 2
- BHXBZLPMVFUQBQ-UHFFFAOYSA-K samarium(iii) chloride Chemical compound Cl[Sm](Cl)Cl BHXBZLPMVFUQBQ-UHFFFAOYSA-K 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 description 16
- 241000208202 Linaceae Species 0.000 description 14
- 235000004431 Linum usitatissimum Nutrition 0.000 description 14
- 239000004744 fabric Substances 0.000 description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 206010016590 Fibrin deposition on lens postoperative Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/17—Halides of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprise the following steps：(1) sodolin after scouring and bleaching is handled is immersed in the mixed solution of catalase and surfactant, heated up, immersion continues to heat up, added potassium tert-butoxide regulation pH, continue to soak；(2) sodolin after processing is immersed in N NMAs and ZnCl2Mixed solution in, after ultrasonication, dry, bakee, wash, drying；(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, ultrasonication, dried, washed, drying；(4) in the sodolin dipping and citric acid solution that treat step (3), ultrasonication, drying after baking, is washed, drying.After sodolin is using method of the present invention processing, the dye-uptake of sodolin improves a lot, and sodolin uniform color, and color fastness is high.
Description
Technical field
The present invention relates to textile auxiliary field, locate before more particularly to a kind of Dyeing of Linen Fabric of utilization catalase
Reason method.
Background technology
Sodolin has a good moisture pick-up properties, rapid heat dissipation, well-pressed naturally, not static electrification, anti-mildew is pest-resistant to wait Optimality
Can, liked by consumers in general.The clothes that sodolin is made can more reduce the amount of sweat of human body than other fabrics, and
The absorption speed of sodolin is also faster several times than bafta, can be the sendible temperature reduction 4-8 degree of human body under normal temperature, be described as
" natural air conditioner ".Flax fiber is bast fiber, and straw diameter 1-3mm is distributed in the bast part of stem fiber bunchy.Flax
Fiber main comprise material is cellulose, and contains more hemicellulose and lignin.
The dyeing of flax fiber is similar to cotton fiber dyeing, is primarily referred to as dyestuff and occurs physics or chemical bond with fiber
The process for colouring flax fiber.For Color judge not only with reference to dye-uptake, to color evenness, color fastness is all
Need to investigate.Flax fiber has higher crystallinity and the degree of orientation in itself so that fiber is difficult to be swelled in dyeing course,
So as to cause dyestuff to receive larger resistance to fibrous inside diffusion.Again because flax fiber content of cellulose is relatively low, and contain
There is more hemicellulose, other impurity are also higher than cotton fiber.Because the influence of these impurity so that dyestuff oozes into fiber
It is thoroughly hindered, it is difficult to which that, with fibrin reaction, so that the dye-uptake of flax fiber is relatively low, dyefastness is poor.Due to flax
Stock-dye effect is poor, seriously constrains the exploitation of high-grade flax product.So before being carried out again before Dyeing of Linen Fabric to it
Processing, is extremely necessary with the Color for improving sodolin.
Chinese patent CN200810039290.5 discloses a kind of dyeing pretreatment process of flax-cotton blend fabric, and it is special
Levy and be, comprise the following steps：1. flax-cotton blend fabric is immersed in 20~25 in the extraction solution that temperature is 80~95 DEG C
Minute.2. the blend fabric handled through step 1 is immersed in the soda bath that temperature is 90~100 DEG C 60 minutes.3. will be through
The blend fabric of step 2 processing is immersed in the acetum that temperature is 50~55 DEG C 10~15 minutes.4. it will be handled through step 3
Blend fabric to be immersed in temperature be 30 minutes in 80~85 DEG C of soda ash solution.The advantage of the invention is through above-mentioned pre-treatment
The close metachromia of flax-cotton blend fabric, color fastness and bright-colored degree all increase significantly.But the technique is for pure flax
The consumption of fabric need to be improved.
The content of the invention
It is an object of the invention to provide a kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, the party is used
After method processing, the dye-uptake of sodolin improves a lot, and sodolin uniform color, and color fastness is high.
To achieve the above object, the present invention uses following technical scheme：
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed in the mixed solution of catalase and surfactant,
It is warming up to after 30-50 DEG C, immersion 15-25min, is warming up to 80-90 DEG C of processing, it is 10-11 to add potassium tert-butoxide regulation pH, is continued
Soak 40-60min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, ultrasonic wave
Handle after 15-20min, drying, after 110 DEG C bakee, wash, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, ultrasonication
After 15-20min, 90-110 DEG C of drying is washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), after ultrasonication 15-20min,
Drying, after 110 DEG C bakee, is washed, drying.
It is preferred that, the surfactant is nonionic surface active agent.
It is preferred that, N hydroxymethyl acrylamide and ZnCl in the step (2)2Mixed solution in N- methylol acryloyls
Amine is the 3-5%, ZnCl of sodolin weight2Concentration is 0.1-0.2%.
It is preferred that, bath raio is 1 in the step (2):20.
It is preferred that, the concentration of the mixed solution middle rare earth of step (3) middle rare earth and amino acid is 40-55g/L, amino
The concentration of acid is 20g/L.
It is preferred that, bath raio is 1 in the step (3):30.
It is preferred that, the rare earth is praseodymium chloride, neodymium chloride, the mixture of samarium trichloride.
It is preferred that, the concentration of citric acid is 22-35g/L in the citric acid solution.
It is preferred that, bath raio is 1 in the step (4):50.
The invention has the advantages that,
(1) hydrogen peroxide of bleached rear residual is thoroughly removed using catalase, after reduction hydrogen peroxide is caused
The problem of phase dyeing is not good.Afterwards after unconventional potassium tert-butoxide regulation alkalescence, by hydrogen peroxide enzyme-deactivating, while flax can be caused
Fiber is in the modification that alkaline state is conducive to the later stage.
(2) flax fiber is modified respectively using N hydroxymethyl acrylamide and rare earth so that flax fiber is carried
Easy dyeing group, while the structure of flax fiber changes, is more easy to and dye contacts, improves dye-uptake and color fastness.
Embodiment
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed to the mixing of catalase and nonionic surface active agent
In solution, it is warming up to after 30 DEG C, immersion 15min, is warming up to 80 DEG C of processing, it is 10 to add potassium tert-butoxide regulation pH, continues to soak
40min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, N- hydroxyl first
Base acrylamide and ZnCl2Mixed solution in N hydroxymethyl acrylamide be sodolin weight 3%, ZnCl2Concentration is
0.1%, bath raio is 1:After 20, ultrasonication 15min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, rare earth and amino acid
The concentration of mixed solution middle rare earth be 40g/L, the concentration of amino acid is 20g/L, and bath raio is 1:30, ultrasonication 15min
Afterwards, 90 DEG C of drying, are washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), the concentration of citric acid is 22g/L, bath
Than for 1:After 50, ultrasonication 15min, drying after 110 DEG C bakee, is washed, drying.
By the sodolin of mistake treated by the present method, after the red B-2BF dyeing living of auspicious China's element, dye-uptake is 28%, color jail
Degree is significantly improved.
Embodiment 2
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed to the mixing of catalase and nonionic surface active agent
In solution, it is warming up to after 50 DEG C, immersion 25min, is warming up to 90 DEG C of processing, it is 11 to add potassium tert-butoxide regulation pH, continues to soak
40-60min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, N- hydroxyl first
Base acrylamide and ZnCl2Mixed solution in N hydroxymethyl acrylamide be sodolin weight 5%, ZnCl2Concentration is
0.2%, bath raio is 1:After 20, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, rare earth and amino acid
The concentration of mixed solution middle rare earth be 55g/L, the concentration of amino acid is 20g/L, and bath raio is 1:30, ultrasonication 20min
Afterwards, 110 DEG C of drying, are washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), the concentration of citric acid is 35g/L, bath
Than for 1:After 50, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying.
By the sodolin of mistake treated by the present method, after the red B-2BF dyeing living of auspicious China's element, dye-uptake is 30%, color jail
Degree is significantly improved.
Embodiment 3
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed to the mixing of catalase and nonionic surface active agent
In solution, it is warming up to after 30 DEG C, immersion 25min, is warming up to 80 DEG C of processing, it is 11 to add potassium tert-butoxide regulation pH, continues to soak
40min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, N- hydroxyl first
Base acrylamide and ZnCl2Mixed solution in N hydroxymethyl acrylamide be sodolin weight 5%, ZnCl2Concentration is
0.1%, bath raio is 1:After 20, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, rare earth and amino acid
The concentration of mixed solution middle rare earth be 40g/L, the concentration of amino acid is 20g/L, and bath raio is 1:30, ultrasonication 20min
Afterwards, 90 DEG C of drying, are washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), the concentration of citric acid is 35g/L, bath
Than for 1:After 50, ultrasonication 15min, drying after 110 DEG C bakee, is washed, drying.
By the sodolin of mistake treated by the present method, after the red B-2BF dyeing living of auspicious China's element, dye-uptake is 33%, color jail
Degree is significantly improved.
Embodiment 4
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed to the mixing of catalase and nonionic surface active agent
In solution, it is warming up to after 50 DEG C, immersion 15min, is warming up to 90 DEG C of processing, it is 10 to add potassium tert-butoxide regulation pH, continues to soak
60min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, N- hydroxyl first
Base acrylamide and ZnCl2Mixed solution in N hydroxymethyl acrylamide be sodolin weight 3%, ZnCl2Concentration is
0.2%, bath raio is 1:After 20, ultrasonication 15min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, rare earth and amino acid
The concentration of mixed solution middle rare earth be 55g/L, the concentration of amino acid is 20g/L, and bath raio is 1:30, ultrasonication 15min
Afterwards, 110 DEG C of drying, are washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), the concentration of citric acid is 22g/L, bath
Than for 1:After 50, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying.
By the sodolin of mistake treated by the present method, after the red B-2BF dyeing living of auspicious China's element, dye-uptake is 35%, color jail
Degree is significantly improved.
Embodiment 5
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed to the mixing of catalase and nonionic surface active agent
In solution, it is warming up to after 40 DEG C, immersion 20min, is warming up to 85 DEG C of processing, it is 10 to add potassium tert-butoxide regulation pH, continues to soak
50min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, N- hydroxyl first
Base acrylamide and ZnCl2Mixed solution in N hydroxymethyl acrylamide be sodolin weight 4%, ZnCl2Concentration is
0.1%, bath raio is 1:After 20, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, rare earth and amino acid
The concentration of mixed solution middle rare earth be 45g/L, the concentration of amino acid is 20g/L, and bath raio is 1:30, ultrasonication 20min
Afterwards, 110 DEG C of drying, are washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), the concentration of citric acid is 28g/L, bath
Than for 1:After 50, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying.
By the sodolin of mistake treated by the present method, after the red B-2BF dyeing living of auspicious China's element, dye-uptake is 32%, color jail
Degree is significantly improved.
Embodiment 6
A kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, comprises the following steps：
(1) sodolin after scouring and bleaching is handled is immersed to the mixing of catalase and nonionic surface active agent
In solution, it is warming up to after 45 DEG C, immersion 25min, is warming up to 90 DEG C of processing, it is 11 to add potassium tert-butoxide regulation pH, continues to soak
50min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, N- hydroxyl first
Base acrylamide and ZnCl2Mixed solution in N hydroxymethyl acrylamide be sodolin weight 5%, ZnCl2Concentration is
0.1%, bath raio is 1:After 20, ultrasonication 15min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, rare earth and amino acid
The concentration of mixed solution middle rare earth be 52g/L, the concentration of amino acid is 20g/L, and bath raio is 1:30, ultrasonication 20min
Afterwards, 100 DEG C of drying, are washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), the concentration of citric acid is 33g/L, bath
Than for 1:After 50, ultrasonication 20min, drying after 110 DEG C bakee, is washed, drying.
By the sodolin of mistake treated by the present method, after the red B-2BF dyeing living of auspicious China's element, dye-uptake is 30%, color jail
Degree is significantly improved.
Claims (9)
1. a kind of Dyeing of Linen Fabric pre-treating method of utilization catalase, it is characterised in that：Comprise the following steps：
(1) sodolin after scouring and bleaching is handled is immersed in the mixed solution of catalase and surfactant, heating
To 30-50 DEG C, after immersion 15-25min, 80-90 DEG C of processing is warming up to, it is 10-11 to add potassium tert-butoxide regulation pH, continues to soak
40-60min；
(2) sodolin after processing is immersed in N hydroxymethyl acrylamide and ZnCl2Mixed solution in, ultrasonication
After 15-20min, drying after 110 DEG C bakee, is washed, drying；
(3) sodolin that step 2 was modified is impregnated in the mixed solution of rare earth and amino acid, ultrasonication 15-
After 20min, 90-110 DEG C of drying is washed, drying；
(4) in the sodolin dipping and citric acid solution that treat step (3), after ultrasonication 15-20min, drying,
After 110 DEG C bakee, wash, drying.
2. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
Surfactant is stated for nonionic surface active agent.
3. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
State N hydroxymethyl acrylamide and ZnCl in step (2)2Mixed solution in N hydroxymethyl acrylamide be sodolin weight
3-5%, ZnCl2Concentration is 0.1-0.2%.
4. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
It is 1 to state bath raio in step (2):20.
5. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
The concentration for stating the mixed solution middle rare earth of step (3) middle rare earth and amino acid is 40-55g/L, and the concentration of amino acid is 20g/L.
6. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
It is 1 to state bath raio in step (3):30.
7. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
Rare earth is stated for praseodymium chloride, neodymium chloride, the mixture of samarium trichloride.
8. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
The concentration for stating citric acid in citric acid solution is 22-35g/L.
9. the Dyeing of Linen Fabric pre-treating method of utilization catalase according to claim 1, it is characterised in that：Institute
It is 1 to state bath raio in step (4):50.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107558259A (en) * | 2017-09-29 | 2018-01-09 | 张新文 | Fiber treatment modifying agent and its method of modifying |
| CN107700245A (en) * | 2017-09-29 | 2018-02-16 | 张新文 | The online modified technique of fiber |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075760A (en) * | 1992-09-17 | 1993-09-01 | 王利民 | Rare-earth dyeing assistant and preparation technology thereof |
| CN1839224A (en) * | 2003-08-21 | 2006-09-27 | 克莱里安特财务(Bvi)有限公司 | Multifunctional textile-pretreating agent |
| CN101498074A (en) * | 2009-03-02 | 2009-08-05 | 北京铜牛集团有限公司 | Method for manufacturing Chinese hemp multi-component covering type two-sided knit fabric |
| CN101608399A (en) * | 2008-06-20 | 2009-12-23 | 东华大学 | One dyeing pretreatment process that grows flax cotton blended fabric |
| CN103911867A (en) * | 2014-04-02 | 2014-07-09 | 江南大学 | Method for improving color fastness of protein fiber product through enzymic method |
| CN104562793A (en) * | 2015-02-14 | 2015-04-29 | 叶澄 | Method of pigment dyeing after modifying ramie fiber fabric |
| CN104831564A (en) * | 2015-03-25 | 2015-08-12 | 苏州威尔德工贸有限公司 | An accelerating agent used for printing and dyeing of linen and a using method thereof |
| CN106223040A (en) * | 2016-07-27 | 2016-12-14 | 林志刚 | A kind of seat cushions sodolin |
-
2017
- 2017-05-22 CN CN201710362183.5A patent/CN107083686A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1075760A (en) * | 1992-09-17 | 1993-09-01 | 王利民 | Rare-earth dyeing assistant and preparation technology thereof |
| CN1839224A (en) * | 2003-08-21 | 2006-09-27 | 克莱里安特财务(Bvi)有限公司 | Multifunctional textile-pretreating agent |
| CN101608399A (en) * | 2008-06-20 | 2009-12-23 | 东华大学 | One dyeing pretreatment process that grows flax cotton blended fabric |
| CN101498074A (en) * | 2009-03-02 | 2009-08-05 | 北京铜牛集团有限公司 | Method for manufacturing Chinese hemp multi-component covering type two-sided knit fabric |
| CN103911867A (en) * | 2014-04-02 | 2014-07-09 | 江南大学 | Method for improving color fastness of protein fiber product through enzymic method |
| CN104562793A (en) * | 2015-02-14 | 2015-04-29 | 叶澄 | Method of pigment dyeing after modifying ramie fiber fabric |
| CN104831564A (en) * | 2015-03-25 | 2015-08-12 | 苏州威尔德工贸有限公司 | An accelerating agent used for printing and dyeing of linen and a using method thereof |
| CN106223040A (en) * | 2016-07-27 | 2016-12-14 | 林志刚 | A kind of seat cushions sodolin |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107558259A (en) * | 2017-09-29 | 2018-01-09 | 张新文 | Fiber treatment modifying agent and its method of modifying |
| CN107700245A (en) * | 2017-09-29 | 2018-02-16 | 张新文 | The online modified technique of fiber |
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Application publication date: 20170822 |