CN104562720A - Synthetic leather with noctilucent property - Google Patents

Synthetic leather with noctilucent property Download PDF

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Publication number
CN104562720A
CN104562720A CN201510005424.1A CN201510005424A CN104562720A CN 104562720 A CN104562720 A CN 104562720A CN 201510005424 A CN201510005424 A CN 201510005424A CN 104562720 A CN104562720 A CN 104562720A
Authority
CN
China
Prior art keywords
parts
noctilucence
synthetic leather
layer
noctilucent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510005424.1A
Other languages
Chinese (zh)
Inventor
胡文摇
汪炳安
蔡祥林
蔡振聪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shishi Longxiang Leather Co Ltd
Original Assignee
Shishi Longxiang Leather Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shishi Longxiang Leather Co Ltd filed Critical Shishi Longxiang Leather Co Ltd
Priority to CN201510005424.1A priority Critical patent/CN104562720A/en
Publication of CN104562720A publication Critical patent/CN104562720A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0838—Bright, glossy, shiny surface
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses synthetic leather with noctilucent property. The synthetic leather sequentially comprises a base layer, a resin layer, a noctilucent layer and a transparent film layer from the inside to the outside, wherein the noctilucent layer is formed by mixing 40-60 parts of acrylic resin, 1-5 parts of bentonite, 10-12 parts of xylene, 2-4 parts of butyl acetate, 20-50 parts of noctilucent powder, 10-20 parts of strontium aluminate excitant and 0.5-3 parts of auxiliaries. The synthetic leather with the noctilucent property disclosed by the invention is high in luminescent intensity, capable of continuously emitting light for more than 10 hours as long as absorbing any visible light for more than 10 minutes, sturdy and durable, and capable of being infinitely and cyclically used, thus breaking through the use limit of five or six hundreds.

Description

A kind of synthetic leather of tool noctilucence
Technical field
A kind of artificial leather of the present invention, is specially a kind of synthetic leather of tool noctilucence.
Background technology
People often utilize the long-time luminous characteristic of the Noctilucent materials such as luminescent powder in real life, make weak illumination light source.
Noctilucence characteristic can be applied in most of entity products, these products after illumination is penetrated, if to get up after running into night or accidental power failure, lightning etc. phenomenon time, they still can continuous illumination, people are made to distinguish peripheral direction, for work and life bring great convenience.
Noctilucence leather is a kind of artificial leather, through special process process, and soft, good hand touch, bright-colored colour-fast, can arbitrarily to wash, cutting.
Luminous fabric, leather are applicable to process all kinds of rain gear, clothes, footwear, cap, handicraft, toy, sofa, curtain, cushion, pet pads and all kinds of case and bag leather goods, sports goods etc.
Along with the change of rhythm of life; increasing people does aerobic exercise at promotion low-carbon environment-friendly; the exploitation of noctilucence leather facilitates to be liked moving and good cycling gang; the position of the traffic participant bicycle of surrounding can well be reminded, the safety of the bicyclist when protection visual field is dim.
At present, mostly the producer of noctilucence leather is the way taking to be mixed into luminescent powder in the leather, although this way is simple, can not ensure fluorescent lifetime and access times, noctilucent function only can use five, 600 times, then needs to renovate to lasting use.
Summary of the invention
The technical problem to be solved in the present invention is the defect overcoming prior art, provides a kind of fluorescent lifetime long, can the synthetic leather of the repeatedly noctilucence of Reusability
In order to solve the problems of the technologies described above, the invention provides following technical scheme:
A synthetic leather for tool noctilucence, comprises basic unit, resin bed, noctilucence layer and transparent film layer from inside to outside successively; Described noctilucence layer is by acrylic resin 40 ~ 60 parts, and bentonite 1 ~ 5 part, dimethylbenzene 10 ~ 12 parts, butyl acetate, 2 ~ 4 parts, luminescent powder 20 ~ 50 parts, strontium aluminate exciting agent 10 ~ 20 parts, auxiliary agent 0.5 ~ 3 part mixes.Preferably, described noctilucence layer is by acrylic resin 50 parts, and bentonite 2 parts, dimethylbenzene 10 parts, butyl acetate 3 parts, luminescent powder 35 parts, strontium aluminate exciting agent 15 parts, auxiliary agent 1 part mixes.
Further, described auxiliary agent is luminescent powder auxiliary agent, defoamer and anti-settling agent.Described basic unit is cloth, nonwoven cloth, leatheret or ox-hide layer.Described resin bed is PU, PVC, PC, acrylic acid or nitro-resin.
Preferably, the particle diameter of described luminescent powder is 5 ~ 12 μm, and the sunset glow time is greater than 12h.
Further, the thickness of described noctilucence layer is 0.01 ~ 1mm.
The synthetic leather of noctilucence of the present invention, emphasis leather noctilucence layer is improved, make its luminous intensity high, as long as absorb any visible ray more than 10 minutes, just can in dark place continuous illumination more than 10 hours, and sturdy and durable, unlimitedly can recycle, breach the restriction that only can use five, 600 times.
Detailed description of the invention
Should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
embodiment 1
A synthetic leather for tool noctilucence, comprises non-woven substrate, PU resin bed, noctilucence layer and transparent film layer from inside to outside successively; Described noctilucence layer is by acrylic resin 40 parts, and bentonite 1 part, dimethylbenzene 10 parts, butyl acetate 2 parts, luminescent powder 20 parts, strontium aluminate exciting agent 10 parts, luminescent powder auxiliary agent 0.2 part, defoamer 0.15 part and anti-settling agent 0.15 part mix.The particle diameter of described luminescent powder is 5 μm, and the sunset glow time is greater than 12h.The thickness of described noctilucence layer is 1mm.
embodiment 2
A synthetic leather for tool noctilucence, comprises ox-hide layer basic unit, nitro-resin layer, noctilucence layer and transparent film layer from inside to outside successively; Described noctilucence layer is by acrylic resin 60 parts, bentonite 5 parts, dimethylbenzene 12 parts, butyl acetate 4 parts, luminescent powder 50 parts, strontium aluminate exciting agent 20 parts, luminescent powder auxiliary agent 1.5 parts, defoamer 0.5 part and anti-settling agent 1 part mix, the particle diameter of described luminescent powder is 12 μm, and the sunset glow time is greater than 12h, and the thickness of described noctilucence layer is 0.01mm.
embodiment 3
A synthetic leather for tool noctilucence, comprises leatheret basic unit, acrylate resin layer, noctilucence layer and transparent film layer from inside to outside successively; Described noctilucence layer is by acrylic resin 50 parts, and bentonite 2 parts, dimethylbenzene 10 parts, butyl acetate 3 parts, luminescent powder 30 parts, strontium aluminate exciting agent 14 parts, luminescent powder auxiliary agent 1 part, defoamer 0.5 part and anti-settling agent 0.3 part mix.The particle diameter of described luminescent powder is 8 μm, and the sunset glow time is greater than 12h.The thickness of described noctilucence layer is 0.5mm.
embodiment 4
A synthetic leather for tool noctilucence, comprises cloth basic unit, polyvinyl chloride resin layer, noctilucence layer and transparent film layer from inside to outside successively; Described noctilucence layer is by acrylic resin 50 parts, and bentonite 3 parts, dimethylbenzene 11 parts, butyl acetate 3 parts, luminescent powder 35 parts, strontium aluminate exciting agent 15 parts, luminescent powder auxiliary agent 0.5 part, defoamer 0.2 part and anti-settling agent 0.3 part mix.The particle diameter of described luminescent powder is 9 μm, and the sunset glow time is greater than 12h.The thickness of described noctilucence layer is 0.6mm.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (7)

1. a synthetic leather for tool noctilucence, is characterized in that, comprises basic unit, resin bed, noctilucence layer and transparent film layer successively from inside to outside; Described noctilucence layer is by acrylic resin 40 ~ 60 parts, and bentonite 1 ~ 5 part, dimethylbenzene 10 ~ 12 parts, butyl acetate 2 ~ 4 parts, luminescent powder 20 ~ 50 parts, strontium aluminate exciting agent 10 ~ 20 parts, auxiliary agent 0.5 ~ 3 part mixes.
2. the synthetic leather of a kind of tool noctilucence as claimed in claim 1, is characterized in that, described noctilucence layer is by acrylic resin 50 parts, bentonite 2 parts, dimethylbenzene 10 parts, butyl acetate 3 parts, luminescent powder 35 parts, strontium aluminate exciting agent 15 parts, auxiliary agent 1 part mixes.
3. the synthetic leather of a kind of tool noctilucence as claimed in claim 1 or 2, is characterized in that, described auxiliary agent is luminescent powder auxiliary agent, defoamer and anti-settling agent.
4. the synthetic leather of a kind of tool noctilucence as claimed in claim 1, is characterized in that, described basic unit is cloth, nonwoven cloth, leatheret or ox-hide layer.
5. the synthetic leather of a kind of tool noctilucence as claimed in claim 1, is characterized in that, described resin bed is PU, PVC, PC, acrylic acid or nitro-resin.
6. the synthetic leather of a kind of tool noctilucence as claimed in claim 1, is characterized in that, the particle diameter of described luminescent powder is 5 ~ 12 μm, and the sunset glow time is greater than 12h.
7. the synthetic leather of a kind of tool noctilucence as claimed in claim 1, is characterized in that, the thickness of described noctilucence layer is 0.01 ~ 1mm.
CN201510005424.1A 2015-01-07 2015-01-07 Synthetic leather with noctilucent property Pending CN104562720A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510005424.1A CN104562720A (en) 2015-01-07 2015-01-07 Synthetic leather with noctilucent property

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510005424.1A CN104562720A (en) 2015-01-07 2015-01-07 Synthetic leather with noctilucent property

Publications (1)

Publication Number Publication Date
CN104562720A true CN104562720A (en) 2015-04-29

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106362928A (en) * 2016-08-30 2017-02-01 晋江市永建皮革制品有限公司 Friction-resisting bending-resistant leather capable of emitting light and production method thereof
CN107313265A (en) * 2016-04-27 2017-11-03 福建晋江新来发制革有限公司 It is a kind of to print the leather that noctilucence light shows pattern
CN108532315A (en) * 2017-03-02 2018-09-14 安安(中国)有限公司 A kind of production method of semi-transparent double-colored noctilucence TPU
CN111254715A (en) * 2020-01-17 2020-06-09 广东远华新材料股份有限公司 PVC (polyvinyl chloride) luminous pad and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2326607Y (en) * 1998-01-04 1999-06-30 肖志国 Luminous leather
KR100282016B1 (en) * 1998-12-24 2001-02-15 강경중 Synthetic leather with photoluminescent properties and its manufacturing method
CN201415585Y (en) * 2009-04-07 2010-03-03 晋江市夜视明反光材料有限公司 Novel night luminous stimulated leather
CN201459151U (en) * 2009-05-26 2010-05-12 李国君 Fishskin leather
CN202187228U (en) * 2011-06-18 2012-04-11 天守(福建)超纤科技股份有限公司 Noctilucent artificial leather
CN103015185A (en) * 2012-11-29 2013-04-03 上海华峰超纤材料股份有限公司 Wear-resistant superfine fiber napped leather and preparation method thereof
CN202945485U (en) * 2012-12-06 2013-05-22 安安(中国)有限公司 Novel synthetic leather with luminous property
CN203236784U (en) * 2013-04-25 2013-10-16 温州致富皮业有限公司 Novel leather

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2326607Y (en) * 1998-01-04 1999-06-30 肖志国 Luminous leather
KR100282016B1 (en) * 1998-12-24 2001-02-15 강경중 Synthetic leather with photoluminescent properties and its manufacturing method
CN201415585Y (en) * 2009-04-07 2010-03-03 晋江市夜视明反光材料有限公司 Novel night luminous stimulated leather
CN201459151U (en) * 2009-05-26 2010-05-12 李国君 Fishskin leather
CN202187228U (en) * 2011-06-18 2012-04-11 天守(福建)超纤科技股份有限公司 Noctilucent artificial leather
CN103015185A (en) * 2012-11-29 2013-04-03 上海华峰超纤材料股份有限公司 Wear-resistant superfine fiber napped leather and preparation method thereof
CN202945485U (en) * 2012-12-06 2013-05-22 安安(中国)有限公司 Novel synthetic leather with luminous property
CN203236784U (en) * 2013-04-25 2013-10-16 温州致富皮业有限公司 Novel leather

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107313265A (en) * 2016-04-27 2017-11-03 福建晋江新来发制革有限公司 It is a kind of to print the leather that noctilucence light shows pattern
CN106362928A (en) * 2016-08-30 2017-02-01 晋江市永建皮革制品有限公司 Friction-resisting bending-resistant leather capable of emitting light and production method thereof
CN108532315A (en) * 2017-03-02 2018-09-14 安安(中国)有限公司 A kind of production method of semi-transparent double-colored noctilucence TPU
CN111254715A (en) * 2020-01-17 2020-06-09 广东远华新材料股份有限公司 PVC (polyvinyl chloride) luminous pad and preparation method thereof
CN111254715B (en) * 2020-01-17 2022-12-06 广东远华新材料股份有限公司 PVC (polyvinyl chloride) luminous pad and preparation method thereof

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Application publication date: 20150429