CN104561703B - A kind of aluminum alloy materials with zinc-nickel element and Technology for Heating Processing thereof - Google Patents
A kind of aluminum alloy materials with zinc-nickel element and Technology for Heating Processing thereof Download PDFInfo
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- CN104561703B CN104561703B CN201510068838.9A CN201510068838A CN104561703B CN 104561703 B CN104561703 B CN 104561703B CN 201510068838 A CN201510068838 A CN 201510068838A CN 104561703 B CN104561703 B CN 104561703B
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/053—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent
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Abstract
The invention discloses a kind of aluminum alloy materials with admiro, the mass percent of aluminum alloy materials chemical composition is: C:0.012 0.015%, Si:2.25 2.28%, Se:0.06 0.08%, Cu:3.32 3.35%, Mg:0.12 0.14%, Mn:0.21 0.23%, Ni:15.23 15.25%, Zn:18.55 18.58%, Ti:0.27 0.29%, Fe:0.24 0.26%, B:0.024 0.028%, rare earth: 7.25 7.28%, remaining is Al and trace impurity；This aluminum alloy materials with admiro is long for not only service life, and intensity is high, also has the strongest rub resistance and decay resistance.
Description
Technical field
The present invention relates to door and window fields, a kind of aluminum alloy materials with zinc-nickel element and Technology for Heating Processing thereof.
Background technology
Along with the requirement of high strength alumin ium alloy is improved by every profession and trade day by day, and propose top load, lighting, high-strength, high-ductility, height
A series of requirements such as modulus, good corrosion resisting property and welding performance, and the range of application of aluminium alloy is increasingly wider, at each row
Playing vital effect in each industry, but to yet suffer from intensity low for current aluminium alloy, antioxygenic property is low, serious wear,
Service life is short, high in cost of production problem.
Summary of the invention
The technical problem to be solved is, for the shortcoming of above prior art, proposes a kind of aluminum with zinc-nickel element
Alloy material and Technology for Heating Processing thereof, this aluminum alloy materials with zinc-nickel element is long for not only service life, and intensity is high, peace
Good perfection, also has the strongest rub resistance and decay resistance；The Technology for Heating Processing of this offer, can not only reduce processing cost,
Shorten the process-cycle, and corrosion resistance and the welding performance of aluminium alloy can be improved, improve the quality of product.
In order to solve above-mentioned technical problem, the technical scheme is that and be accomplished by: one has zinc-nickel element
Aluminum alloy materials, the mass percent of aluminum alloy materials chemical composition is: C:0.012-0.015%, Si:2.25-2.28%,
Se:0.06-0.08%, Cu:3.32-3.35%, Mg:0.12-0.14%, Mn:0.21-0.23%, Ni:15.23-15.25%,
Zn:18.55-18.58%, Ti:0.27-0.29%, Fe:0.24-0.26%, B:0.024-0.028%, rare earth: 7.25-7.28%,
Remaining is Al and trace impurity；In rare earth, comprise following components by weight percentage: Gd:12.43-12.45%, Tm:
14.2-14.5%, Dy:3.6-3.8%, Yb:0.85-0.88%, Nd:8.53-8.55%, Pr:9.55-9.58%, surplus is
La。
Present invention also offers the Technology for Heating Processing of a kind of aluminum alloy materials with zinc-nickel element, this technique sequentially includes the following steps:
Step (1): rare earth is divided into three parts, first adds in boiler melt fine aluminium ingot the most in proportion, temperature at 425-428 DEG C,
Keeping 32-35min, carry out removing impurities matter and deoxidation, then furnace temperature rises to 508-510 DEG C, is sequentially placed into: C, Si, Se, Cu,
Mg, Mn element and first part of rare earth, be incubated 20-25min, then temperature risen to 556-558 DEG C, then be sequentially placed into Ni, Zn,
Ti, Fe element and second part of rare earth, be incubated 10-15min, finally heated to 600-605 DEG C, be sequentially added into B element and the 3rd
Part rare earth, is incubated 2-3h；
Step (2): again through LF stove refine, by Control for Kiln Temperature at 683-685 DEG C, the time is maintained at 3-6h, omnidistance nitrogen flushing
Gas agitating, makes chemical analysis reach component requirements, is de-gassed with vacuum degassing furnace, and degassing temperature is 642～645 DEG C, bleeds
Time is at 7-8h；
Step (3): carry out nitrogen protection molding at a temperature of 462～465 DEG C, keep the temperature at 220-225 DEG C after solidification,
Temperature retention time is 26-28h, and last air cooling is to room temperature；
Step (4): the parts forged are carried out a heat treatment: the parts forged are heated to 282-285 DEG C, insulation
30-35min, is then cooled to room temperature by water-cooled with the speed of 8-10 DEG C/s, is then heated to 295-298 DEG C, with oil cold with
11-13 DEG C/s is cooled to room temperature, finally cleans surface, checks size.
The technical scheme that the present invention limits further is:
The aforesaid aluminum alloy materials with zinc-nickel element, the mass percent of aluminum alloy materials chemical composition is: C:0.012%,
Si:2.25%, Se:0.06%, Cu:3.32%, Mg:0.12%, Mn:0.21%, Ni:15.23%, Zn:18.55%,
Ti:0.27%, Fe:0.24%, B:0.024%, rare earth: 7.25%, remaining is Al and trace impurity；In rare earth, by weight
Percentage ratio comprises following components: Gd:12.43%, Tm:14.2%, Dy:3.6%, Yb:0.85%, Nd:8.53%, Pr:9.55%,
Surplus is La.
The aforesaid aluminum alloy materials with zinc-nickel element, the mass percent of aluminum alloy materials chemical composition is: C:0.015%,
Si:2.28%, Se:0.08%, Cu:3.35%, Mg:0.14%, Mn:0.23%, Ni:15.25%, Zn:18.58%,
Ti:0.29%, Fe:0.26%, B:0.028%, rare earth: 7.28%, remaining is Al and trace impurity；In rare earth, by weight
Percentage ratio comprises following components: Gd:12.45%, Tm:14.5%, Dy:3.8%, Yb:0.88%, Nd:8.55%, Pr:9.58%,
Surplus is La.
The aforesaid aluminum alloy materials with zinc-nickel element, the mass percent of aluminum alloy materials chemical composition is: C:0.014%,
Si:2.27%, Se:0.07%, Cu:3.34%, Mg:0.13%, Mn:0.22%, Ni:15.24%, Zn:18.57%,
Ti:0.28%, Fe:0.25%, B:0.027%, rare earth: 7.26%, remaining is Al and trace impurity；In rare earth, by weight
Percentage ratio comprises following components: Gd:12.44%, Tm:14.3%, Dy:3.7%, Yb:0.86%, Nd:8.54%, Pr:9.57%,
Surplus is La.
The invention has the beneficial effects as follows: this has in the aluminum alloy materials of zinc-nickel element and adds Cu element and can increase the strong of aluminium alloy
Degree and antioxygenic property, improve service life；Adding Ni and Cr element, chromium can significantly improve intensity, hardness and wearability,
Chromium can improve again non-oxidizability and the corrosion resistance of aluminium alloy, and nickel can improve the intensity of aluminium alloy, and keep good plasticity and
Toughness.Nickel has higher corrosion resistance to soda acid, at high temperature has antirust and temperature capacity；Add Mg element and can improve its weldering
Connect performance, increase its corrosion resistance and intensity；Add Ti element, titanium and aluminum formation TiAl2 phase, non-when becoming crystallization
Spontaneous core, plays effect etc. of refinement cast sturcture and seam organization, and rare earth is divided into three parts is sequentially added into, can not only
The effect of crystal grain thinning in heat treatment process, increases its structural strength, moreover it is possible to improves its corrosion resistance and frictional behaviour, carries
In its service life high, reduce cost；The Technology for Heating Processing of this offer, can not only reduce processing cost, shortens the process-cycle, and
And corrosion resistance and the welding performance of aluminium alloy can be improved, improve the quality of product.
Detailed description of the invention
The present invention is described in further detail below:
Embodiment 1
The present embodiment provides a kind of aluminum alloy materials with zinc-nickel element, and the mass percent of aluminum alloy materials chemical composition is: C:
0.012%, Si:2.25%, Se:0.06%, Cu:3.32%, Mg:0.12%, Mn:0.21%, Ni:15.23%, Zn:
18.55%, Ti:0.27%, Fe:0.24%, B:0.024%, rare earth: 7.25%, remaining is Al and trace impurity；In rare earth,
Comprise following components by weight percentage: Gd:12.43%, Tm:14.2%, Dy:3.6%, Yb:0.85%, Nd:8.53%,
Pr:9.55%, surplus is La；This embodiment additionally provides the Technology for Heating Processing of the aluminum alloy materials with zinc-nickel element, this work
Skill sequentially includes the following steps:
Step (1): rare earth is divided into three parts, adds fine aluminium ingot in boiler the most in proportion and melts, and temperature, at 425 DEG C, is protected
Holding 32min, carry out removing impurities matter and deoxidation, then furnace temperature rises to 508 DEG C, is sequentially placed into: C, Si, Se, Cu, Mg, Mn unit
Element and first part of rare earth, be incubated 20min, then temperature is risen to 556 DEG C, then is sequentially placed into Ni, Zn, Ti, Fe element and
Second part of rare earth, is incubated 10min, finally heated to 600 DEG C, is sequentially added into B element and the 3rd part of rare earth, is incubated 2h；
Step (2): again through LF stove refine, by Control for Kiln Temperature at 683 DEG C, the time is maintained at 3h, omnidistance nitrogen blowing stirring,
Making chemical analysis reach component requirements, be de-gassed with vacuum degassing furnace, degassing temperature is 642 DEG C, and pumpdown time is at 7h；
Step (3): carry out nitrogen protection molding at a temperature of 462 DEG C, keep the temperature at 220 DEG C after solidification, temperature retention time
For 26h, last air cooling is to room temperature；
Step (4): the parts forged carry out a heat treatment: the parts forged are heated to 282 DEG C, is incubated 30min,
Then it is cooled to room temperature by water-cooled with the speed of 8 DEG C/s, is then heated to 295 DEG C, be cooled to room with oil is cold with 11 DEG C/s
Temperature, finally cleans surface, checks size.
Embodiment 2
The present embodiment provides a kind of aluminum alloy materials with zinc-nickel element, and the mass percent of aluminum alloy materials chemical composition is: C:
0.015%, Si:2.28%, Se:0.08%, Cu:3.35%, Mg:0.14%, Mn:0.23%, Ni:15.25%, Zn:
18.58%, Ti:0.29%, Fe:0.26%, B:0.028%, rare earth: 7.28%, remaining is Al and trace impurity；In rare earth,
Comprise following components by weight percentage: Gd:12.45%, Tm:14.5%, Dy:3.8%, Yb:0.88%, Nd:8.55%,
Pr:9.58%, surplus is La；This embodiment additionally provides the Technology for Heating Processing of the aluminum alloy materials with zinc-nickel element, this work
Skill sequentially includes the following steps:
Step (1): rare earth is divided into three parts, adds fine aluminium ingot in boiler the most in proportion and melts, and temperature, at 428 DEG C, is protected
Holding 35min, carry out removing impurities matter and deoxidation, then furnace temperature rises to 510 DEG C, is sequentially placed into: C, Si, Se, Cu, Mg, Mn unit
Element and first part of rare earth, be incubated 25min, then temperature is risen to 558 DEG C, then is sequentially placed into Ni, Zn, Ti, Fe element and
Second part of rare earth, is incubated 15min, finally heated to 605 DEG C, is sequentially added into B element and the 3rd part of rare earth, is incubated 3h；
Step (2): again through LF stove refine, by Control for Kiln Temperature at 685 DEG C, the time is maintained at 6h, omnidistance nitrogen blowing stirring,
Making chemical analysis reach component requirements, be de-gassed with vacuum degassing furnace, degassing temperature is 645 DEG C, and pumpdown time is at 8h；
Step (3): carry out nitrogen protection molding at a temperature of 465 DEG C, keep the temperature at 225 DEG C after solidification, temperature retention time
For 28h, last air cooling is to room temperature；
Step (4): the parts forged carry out a heat treatment: the parts forged are heated to 285 DEG C, is incubated 35min,
Then it is cooled to room temperature by water-cooled with the speed of 10 DEG C/s, is then heated to 298 DEG C, with cold being cooled to 13 DEG C/s of oil
Room temperature, finally cleans surface, checks size.
Embodiment 3
The present embodiment provides a kind of aluminum alloy materials with zinc-nickel element, and the mass percent of aluminum alloy materials chemical composition is: C:
0.014%, Si:2.27%, Se:0.07%, Cu:3.34%, Mg:0.13%, Mn:0.22%, Ni:15.24%, Zn:
18.57%, Ti:0.28%, Fe:0.25%, B:0.027%, rare earth: 7.26%, remaining is Al and trace impurity；In rare earth,
Comprise following components by weight percentage: Gd:12.44%, Tm:14.3%, Dy:3.7%, Yb:0.86%, Nd:8.54%,
Pr:9.57%, surplus is La；This embodiment additionally provides the Technology for Heating Processing of the aluminum alloy materials with zinc-nickel element, this work
Skill sequentially includes the following steps:
Step (1): rare earth is divided into three parts, adds fine aluminium ingot in boiler the most in proportion and melts, and temperature, at 427 DEG C, is protected
Holding 33min, carry out removing impurities matter and deoxidation, then furnace temperature rises to 509 DEG C, is sequentially placed into: C, Si, Se, Cu, Mg, Mn unit
Element and first part of rare earth, be incubated 24min, then temperature is risen to 557 DEG C, then is sequentially placed into Ni, Zn, Ti, Fe element and
Second part of rare earth, is incubated 13min, finally heated to 604 DEG C, is sequentially added into B element and the 3rd part of rare earth, is incubated 2h；
Step (2): again through LF stove refine, by Control for Kiln Temperature at 684 DEG C, the time is maintained at 5h, omnidistance nitrogen blowing stirring,
Making chemical analysis reach component requirements, be de-gassed with vacuum degassing furnace, degassing temperature is 643 DEG C, and pumpdown time is at 7h；
Step (3): carry out nitrogen protection molding at a temperature of 464 DEG C, keep the temperature at 224 DEG C after solidification, temperature retention time
For 27h, last air cooling is to room temperature；
Step (4): the parts forged carry out a heat treatment: the parts forged are heated to 283 DEG C, is incubated 32min,
Then it is cooled to room temperature by water-cooled with the speed of 9 DEG C/s, is then heated to 296 DEG C, be cooled to room with oil is cold with 12 DEG C/s
Temperature, finally cleans surface, checks size.
So by the technical scheme of embodiment, a kind of aluminum alloy materials with zinc-nickel element and Technology for Heating Processing thereof are proposed, should
The aluminum alloy materials with zinc-nickel element is long for not only service life, and intensity is high, and safety is good, also has the strongest rub resistance
And decay resistance；The Technology for Heating Processing of this offer, can not only reduce processing cost, shortens the process-cycle, and can improve aluminum
The corrosion resistance of alloy and welding performance, improve the quality of product.
Above example is only the technological thought that the present invention is described, it is impossible to limit protection scope of the present invention with this, every according to this
The technological thought that invention proposes, any change done on the basis of technical scheme, within each falling within scope.
Claims (4)
1. an aluminum alloy materials with zinc-nickel element, it is characterised in that: the percent mass of described aluminum alloy materials chemical composition
Ratio is: C:0.012-0.015%, Si:2.25-2.28%, Se:0.06-0.08%, Cu:3.32-3.35%, Mg:0.12-0.14%,
Mn:0.21-0.23%, Ni:15.23-15.25%, Zn:18.55-18.58%, Ti:0.27-0.29%, Fe:0.24-0.26%,
B:0.024-0.028%, rare earth: 7.25-7.28%, remaining is Al and trace impurity；
In described rare earth, comprise following components by weight percentage:Gd: 12.43-12.45%,Tm: 14.2-14.5%,Dy:
3.6-3.8%,Yb: 0.85-0.88%,Nd: 8.53-8.55%,Pr: 9.55-9.58%, surplus is La；
Wherein having the Technology for Heating Processing of the aluminum alloy materials of zinc-nickel element, this technique sequentially includes the following steps:
Step (1): rare earth is divided into three parts, first adds in boiler melt fine aluminium ingot the most in proportion, temperature at 425-428 DEG C,
Keeping 32-35min, carry out removing impurities matter and deoxidation, then furnace temperature rises to 508-510 DEG C, is sequentially placed into: C, Si, Se, Cu,
Mg, Mn element and first part of rare earth, be incubated 20-25min, then temperature risen to 556-558 DEG C, then be sequentially placed into Ni, Zn,
Ti, Fe element and second part of rare earth, be incubated 10-15min, finally heated to 600-605 DEG C, be sequentially added into B element and the 3rd
Part rare earth, is incubated 2-3h；
Step (2): again through LF stove refine, by Control for Kiln Temperature at 683-685 DEG C, the time is maintained at 3-6h, omnidistance nitrogen flushing
Gas agitating, makes chemical analysis reach component requirements, is de-gassed with vacuum degassing furnace, and degassing temperature is 642～645 DEG C, bleeds
Time is at 7-8h；
Step (3): carry out nitrogen protection molding at a temperature of 462～465 DEG C, keep the temperature at 220-225 DEG C after solidification,
Temperature retention time is 26-28h, and last air cooling is to room temperature；
Step (4): the parts forged are carried out a heat treatment: the parts forged are heated to 282-285 DEG C, insulation
30-35min, is then cooled to room temperature by water-cooled with the speed of 8-10 DEG C/s, is then heated to 295-298 DEG C, with oil cold with
11-13 DEG C/s is cooled to room temperature, finally cleans surface, checks size.
The aluminum alloy materials with zinc-nickel element the most according to claim 1, it is characterised in that: described aluminum alloy materials
The mass percent studied point is: C:0.012%, Si:2.25%, Se:0.06%, Cu:3.32%, Mg:0.12%, Mn:
0.21%, Ni:15.23%, Zn:18.55%, Ti:0.27%, Fe:0.24%, B:0.024%, rare earth: 7.25%, its
Remaining is Al and trace impurity；
In described rare earth, comprise following components by weight percentage:Gd: 12.43%,Tm: 14.2%,Dy: 3.6%,Yb: 0.85%,Nd: 8.53%,Pr: 9.55%, surplus is La.
The aluminum alloy materials with zinc-nickel element the most according to claim 1, it is characterised in that: described aluminum alloy materials
The mass percent studied point is: C:0.015%, Si:2.28%, Se:0.08%, Cu:3.35%, Mg:0.14%, Mn:
0.23%, Ni:15.25%, Zn:18.58%, Ti:0.29%, Fe:0.26%, B:0.028%, rare earth: 7.28%, its
Remaining is Al and trace impurity；
In described rare earth, comprise following components by weight percentage:Gd: 12.45%,Tm: 14.5%,Dy: 3.8%,Yb: 0.88%,Nd: 8.55%,Pr: 9.58%, surplus is La.
The aluminum alloy materials with zinc-nickel element the most according to claim 1, it is characterised in that: described aluminum alloy materials
The mass percent studied point is: C:0.014%, Si:2.27%, Se:0.07%, Cu:3.34%, Mg:0.13%, Mn:
0.22%, Ni:15.24%, Zn:18.57%, Ti:0.28%, Fe:0.25%, B:0.027%, rare earth: 7.26%, its
Remaining is Al and trace impurity；
In described rare earth, comprise following components by weight percentage:Gd: 12.44%,Tm: 14.3%,Dy: 3.7%,Yb: 0.86%,Nd: 8.54%,Pr: 9.57%, surplus is La.
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| CN201510068838.9A CN104561703B (en) | 2015-02-10 | 2015-02-10 | A kind of aluminum alloy materials with zinc-nickel element and Technology for Heating Processing thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US3637441A (en) * | 1968-04-08 | 1972-01-25 | Aluminum Co Of America | Aluminum-copper-magnesium-zinc powder metallurgy alloys |
| JPH036345A (en) * | 1989-06-02 | 1991-01-11 | Daido Metal Co Ltd | Aluminum-base alloy for sliding use excellent in fatigue resistance and seizure resistance |
| US8409497B2 (en) * | 2009-10-16 | 2013-04-02 | United Technologies Corporation | Hot and cold rolling high strength L12 aluminum alloys |
| CN102108463B (en) * | 2010-01-29 | 2012-09-05 | 北京有色金属研究总院 | Aluminium alloy product suitable for manufacturing structures and preparation method |
| CN103233148B (en) * | 2012-08-23 | 2016-01-20 | 北京有色金属研究总院 | One is applicable to structure-function integration Al-alloy products and preparation method |
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Effective date of registration: 20161008 Address after: 215104 Suzhou, Wuzhong District Yue Creek Street, Swan Road, No. 10 Applicant after: Suzhou Jing Yuan oil pressure Machinery Co., Ltd. Address before: 215156, Suzhou, Jiangsu province Wuzhong District Xu town and Feng Road, No. 388 Applicant before: Dragon Lord door and window company limited of Suzhou City |
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