CN104561643A - Microalloy for electronic material - Google Patents

Microalloy for electronic material Download PDF

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Publication number
CN104561643A
CN104561643A CN201410816699.9A CN201410816699A CN104561643A CN 104561643 A CN104561643 A CN 104561643A CN 201410816699 A CN201410816699 A CN 201410816699A CN 104561643 A CN104561643 A CN 104561643A
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China
Prior art keywords
mass fraction
parts
microalloy
electronic material
impurity
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CN201410816699.9A
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Chinese (zh)
Inventor
张真
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Chun Yan Electronic Technology (suzhou) Co Ltd
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Chun Yan Electronic Technology (suzhou) Co Ltd
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Priority to CN201410816699.9A priority Critical patent/CN104561643A/en
Publication of CN104561643A publication Critical patent/CN104561643A/en
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Abstract

The invention discloses a microalloy for an electronic material. The microalloy comprises the following components in parts by mass: 5-15 parts of nickel, 1-10 parts of magnesium, 1-5 parts of zinc, 2-3 parts of titanium oxide, 2-5 parts of silicon oxide and the balance of Cu and unavoidable impurities, wherein the impurities account for less than 0.25% of the whole microalloy. The strength, the electrical conductivity and the bending processability of the electronic material made of the microalloy are greatly improved; the electronic material has excellent properties in aspects of stress relaxation and soldering wettability.

Description

A kind of electronic material microalloy
Technical field
The present invention relates to electronic applications, be specifically related to a kind of electronic material microalloy.
Background technology
For the copper alloy for electronic material for lead frame, terminal, connector etc., as the fundamental characteristics of goods, require that high intensity and high electroconductibility or thermal conductivity have both.And more require the miniaturization of electron device, highly integrated in recent years, therefore require raw-material thin plate, in lead frame, terminal, connector, increase, the narrow space lengthization of pin count etc. develop.Require the complicated of device shape further and improve the reliability in aggregate erection, therefore for the material used, except physical strength and excellent conductivity, also requiring good bending machining type.
Especially, for at middle copper alloys used such as flexible jumpers, in order to carry out high electric current, and junctor is not made to maximize, even if rear wallization also has good bendability, expect electric conductivity and about 650Mpa 0.2% yield strength above of more than 60%IACS.
In recent years, as copper alloy for electronic material, replacement phosphor bronze, brass etc. are in the past the solution strengthening type copper alloy of representative, from the view point of high strength and high conductivity, the usage quantity of time hardening copper alloy increases, and time hardening copper alloy carries out ageing treatment by the supersaturated solid solution of solution treatment, tiny precipitate is disperseed equably, while putting forward heavy alloyed intensity, reduce the solid solution element amount in copper, thus electroconductibility improves.Therefore, as the good mechanical performance such as intensity, elasticity, and the materials'use that electroconductibility, thermal conductivity are good.
It is generally acknowledged that the bendability of alloy is relevant with grain fineness number, grain fineness number is less, bending machining performance is more excellent, but, when being adjusted to little by grain fineness number, even if control manufacturing condition, also easily form the duplex grain structure of mixing non-recrystallization part, its result, produces the problem being called bendability and reducing.
Summary of the invention
Goal of the invention: for above-mentioned prior art Problems existing and deficiency, the object of this invention is to provide a kind of electronic material microalloy.
Technical scheme: the invention discloses a kind of electronic material microalloy, it comprises the silicon oxide of the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part and mass fraction 2-5 part; All the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
As further optimization of the present invention, the present invention comprises the Co of the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part, the silicon oxide of mass fraction 2-5 part, the silicochrome of mass fraction 1-5 part, the Ti of mass fraction 2-3 part and mass fraction 2-3 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
As further optimization of the present invention, the present invention comprises the Li of the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part, the silicon oxide of mass fraction 2-5 part, the Sn of mass fraction 1-2 part, the Mg of mass fraction 0.5-1 part and mass fraction 0.5-1 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
As further optimization of the present invention, the present invention comprises the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part, the silicon oxide of mass fraction 2-5 part, the Ti of mass fraction 2-3 part, the Fe of mass fraction 1.5-3.5 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Beneficial effect: the equilibrium according to the intensity of the electronic material of gained of the present invention, electroconductibility and bendability improves greatly, and electronic material of the present invention also demonstrates excellent characteristic in stress relaxation characteristics and braze wettability.
Embodiment
The present invention is illustrated further below in conjunction with embodiment.
Embodiment 1:
A kind of electronic material microalloy of the present embodiment, it comprises the nickel of mass fraction 5 parts, the magnesium of mass fraction 1 part, the zinc of mass fraction 1 part, the titanium oxide of mass fraction 2 parts and the silicon oxide of mass fraction 2 parts; All the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 2:
A kind of electronic material microalloy of the present embodiment, it comprises the nickel of mass fraction 15 parts, the magnesium of mass fraction 10 parts, the zinc of mass fraction 5 parts, the titanium oxide of mass fraction 3 parts and the silicon oxide of mass fraction 5 parts; All the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 3:
A kind of electronic material microalloy of the present embodiment, it comprises the nickel of mass fraction 10 parts, the magnesium of mass fraction 5 parts, the zinc of mass fraction 3 parts, the titanium oxide of mass parts 2 parts and the silicon oxide of mass fraction 3 parts; All the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 4:
A kind of electronic material microalloy of the present embodiment, comprise the nickel of mass fraction 5 parts, the magnesium of mass fraction 1 part, the zinc of mass fraction 1 part, the titanium oxide of mass fraction 2 parts, the silicon oxide of mass fraction 2 parts, the silicochrome of mass fraction 1 part, the Ti of mass fraction 2 parts and the Co of mass fraction 2 parts, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 5:
A kind of electronic material microalloy of the present embodiment, comprise the nickel of mass fraction 15 parts, the magnesium of mass fraction 10 parts, the zinc of mass fraction 5 parts, the titanium oxide of mass fraction 3 parts, the silicon oxide of mass fraction 5 parts, the silicochrome of mass fraction 5 parts, the Ti of mass fraction 3 parts and the Co of mass fraction 3 parts, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 6:
A kind of electronic material microalloy of the present embodiment, comprise the nickel of mass fraction 10 parts, the magnesium of mass fraction 5 parts, the zinc of mass fraction 3 parts, the titanium oxide of mass fraction 2 parts, the silicon oxide of mass fraction 3 parts, the silicochrome of mass fraction 3 parts, the Ti of mass fraction 3 parts and the Co of mass fraction 2 parts, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 7:
A kind of electronic material microalloy of the present embodiment, comprise the nickel of mass fraction 5 parts, the magnesium of mass fraction 1 part, the zinc of mass fraction 1 part, the titanium oxide of mass fraction 2 parts, the silicon oxide of mass fraction 2 parts, the Sn of mass fraction 1 part, the Mg of mass fraction 0.5 part and the Li of mass fraction 0.5 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 8:
A kind of electronic material microalloy of the present embodiment, comprise the nickel of mass fraction 15 parts, the magnesium of mass fraction 10 parts, the zinc of mass fraction 5 parts, the titanium oxide of mass fraction 3 parts, the silicon oxide of mass fraction 5 parts, the Sn of mass fraction 2 parts, the Mg of mass fraction 1 part and the Li of mass fraction 1 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 9:
A kind of copper alloy for electronic material of the present embodiment, comprise the nickel of mass fraction 10 parts, the magnesium of mass fraction 5 parts, the zinc of mass fraction 3 parts, the titanium oxide of mass fraction 2 parts, the silicon oxide of mass fraction 3 parts, the Sn of mass fraction 1 part, the Mg of mass fraction 0.5 part and the Li of mass fraction 0.5 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 10:
A kind of electronic material microalloy of the present embodiment, comprise the Fe of the nickel of mass fraction 5 parts, the magnesium of mass fraction 1 part, the zinc of mass fraction 1 part, the titanium oxide of mass fraction 2 parts, the silicon oxide of mass fraction 2 parts, the Ti of mass fraction 2 parts, mass fraction 1.5 parts, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 11:
A kind of electronic material microalloy of the present embodiment, comprise the Fe of the nickel of mass fraction 15 parts, the magnesium of mass fraction 10 parts, the zinc of mass fraction 5 parts, the titanium oxide of mass fraction 3 parts, the silicon oxide of mass fraction 5 parts, the Ti of mass fraction 3 parts, mass fraction 3.5 parts, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
Embodiment 12:
A kind of electronic material microalloy of the present embodiment, comprise the Fe of the nickel of mass fraction 10 parts, the magnesium of mass fraction 5 parts, the zinc of mass fraction 3 parts, the titanium oxide of mass fraction 2 parts, the silicon oxide of mass fraction 3 parts, the Ti of mass fraction 2 parts, mass fraction 2 parts, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.

Claims (4)

1. an electronic material microalloy, is characterized in that: it comprises the silicon oxide of the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part and mass fraction 2-5 part; All the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
2. a kind of electronic material microalloy according to claim 1, it is characterized in that: it comprises the Co of the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part, the silicon oxide of mass fraction 2-5 part, the silicochrome of mass fraction 1-5 part, the Ti of mass fraction 2-3 part and mass fraction 2-3 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
3. a kind of electronic material microalloy according to claim 1, it is characterized in that: it comprises the Li of the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part, the silicon oxide of mass fraction 2-5 part, the Sn of mass fraction 1-2 part, the Mg of mass fraction 0.5-1 part and mass fraction 0.5-1 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
4. a kind of electronic material microalloy according to claim 1, it is characterized in that: it comprises the nickel of mass fraction 5-15 part, the magnesium of mass fraction 1-10 part, the zinc of mass fraction 1-5 part, the titanium oxide of mass fraction 2-3 part, the silicon oxide of mass fraction 2-5 part, the Ti of mass fraction 2-3 part, the Fe of mass fraction 1.5-3.5 part, all the other are made up of Cu and inevitable impurity, and the content of impurity in whole microalloy is no more than 0.25%.
CN201410816699.9A 2014-12-25 2014-12-25 Microalloy for electronic material Pending CN104561643A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112187975A (en) * 2020-09-17 2021-01-05 淮安维嘉益集成科技有限公司 Application of WOFC2 material in manufacturing of FPC (flexible printed circuit) substrate of camera module

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101849027A (en) * 2007-11-05 2010-09-29 古河电气工业株式会社 Copper alloy sheet material
CN101981214A (en) * 2008-03-31 2011-02-23 古河电气工业株式会社 Copper alloy material for electric and electronic apparatuses, and electric and electronic components

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101849027A (en) * 2007-11-05 2010-09-29 古河电气工业株式会社 Copper alloy sheet material
CN101981214A (en) * 2008-03-31 2011-02-23 古河电气工业株式会社 Copper alloy material for electric and electronic apparatuses, and electric and electronic components

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112187975A (en) * 2020-09-17 2021-01-05 淮安维嘉益集成科技有限公司 Application of WOFC2 material in manufacturing of FPC (flexible printed circuit) substrate of camera module

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Application publication date: 20150429