CN104559476B - 一种环保易洗水彩墨水及其制备方法 - Google Patents
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Abstract
本发明涉及墨水技术领域，特别涉及一种环保易洗水彩墨水，其由以下重量份的原料制成：天然色素10～20份，茉莉花提取物1～5份，烷基糖苷3～9份，聚四氟乙烯粉1～7份，增稠剂20～30份，茶皂素7～15份，去离子水30～46份。本发明还提供了环保易洗水彩墨水的制备方法，主要工艺为升温混合搅拌均匀。本发明原料相互协同制备出环保易洗水彩墨水，安全、绿色天然，不含重金属成分，性价比高，制备工艺简单、成本低廉，味香色浓。
Description
技术领域
本发明涉及水彩墨水技术领域，特别涉及一种环保易洗水彩墨水。
背景技术
水彩墨水是一种用于儿童画笔的低粘度彩色墨水，它具有水分足，色彩鲜艳，轻盈明快的特点。水彩笔是一种广受学生欢迎的绘画工具，其主要特点是色彩鲜艳，品种多达24色。可随意选用描绘出色彩斑斓的图案，眼下市售水彩笔主要由染料或颜料制成，其主要缺点是学生在使用时，尤其是幼儿园、小学的学生在使用中不慎将色彩留在衣服上后，不易清洗，且染料、颜料中的重金属元素对幼小儿童易造成接触性迁移，影响健康。一般儿童、学生有咬吮的习惯，故吸入这些有害物质的机会比较大，而当体内不自觉长期过多地摄入这些有害物质时，在一定程度上会对人体产生危害，特别是对儿童和青少年的伤害，会发生急、慢性中毒，产生各种病状，如头晕、贫血、呕吐、精神不振、白血球.(视身体抵抗力不同而言)
公告号为CN102010633A的中国发明专利公开了一种染料型不干水彩墨水及其制造方法，该申请案公开了一种染料型不干水彩墨水组合物，其包括如下组分：(a)染料0.5-7.0重量份，(b)保湿剂10.0-15.0重量份，(c)防腐防霉剂0.05-0.3重量份，(d)助剂0.1-0.5重量份，(e)水77.2-84.35重量份；上述(a)-(e)组分的重量总和占组合物总重量的95-100％；所述(b)保湿剂为两组保湿剂组合而成的复配保湿剂，第一组保湿剂选自甘油、乙二醇、丙二醇、聚乙二醇、二甘醇、三甘醇、山梨醇的一种或几种；第二组保湿剂选自乳酸钠、透明质酸、吡咯烷酮羧酸、天然保湿因子(NMF)、氨基酸中的一种或几种；且第一组保湿剂与第二组保湿剂的重量比为(2-3)：1。其不足之处在于，在使用时不慎将色彩留在衣服上后，不易清洗，且染料、颜料中的重金属元素对幼小儿童易造成接触性迁移，影响健康。
公告号为CN103205161B的中国发明专利公开了一种环保易洗水彩墨水及其制备方法，该申请案公开了一种环保易洗水彩墨水，由以下重量百分比的组分组成：着色剂1-3％、润湿剂10-30％、光亮剂10-30％、表面活性剂1-3％、增稠剂15-25％、防腐剂0.5-2％、纯净水30-50％、缓蚀剂0.3-1％；所述着色剂为食用色素，所述缓蚀剂为苯丙三氮唑；所述润湿剂为乙二醇，光亮剂为甘油，表面活性剂为三乙醇胺，增稠剂为黄原胶与聚丙烯酰胺，防腐剂为苯甲酸钠；添加的黄原胶与聚丙烯酰胺按重量比为1:2-3。虽然在使用时不慎将色彩留在衣服上后，易清洗，但是原料中仍含有少量重金属，不慎将色彩留在衣服上清洗衣服后，三乙醇胺对水质有稍微的危害。
发明内容
本发明所要解决的技术问题是提供一种环保易洗水彩墨水，该水彩墨水环保，安全无毒，不含重金属物质。
为实现上述目的，本发明采用如下技术方案：
一种环保易洗水彩墨水，由以下重量份的原料制成：
本发明选用天然色素，环保无毒害，为常规市售产品，可为姜黄素、植物炭黑、叶绿素酮酸盐、胡萝卜素、辣椒橙色素等。
本发明所述的茉莉花提取物为常规市购产品，不仅具有提香作用，而且具有抗氧化防腐杀菌的作用。
本发明所述的聚四氟乙烯粉粒径为5～10μm。聚四氟乙烯粉具有优良的化学稳定性、耐腐蚀性、密封性、高润滑不粘性、电绝缘性和良好的抗老化耐力，聚四氟乙烯不吸潮，不燃，对氧、紫外线均极稳定，所以具有优异的耐候性，且无毒害，作为墨水的原料，使得墨水书写流畅耐久，性能稳定，不会堵塞笔头。
本发明所述的增稠剂为淀粉、明胶、琼脂、瓜尔胶、海藻酸钠中的一种，所用的增稠剂为天然增稠剂，对人体和环境无害。
本发明的烷基糖苷是由可再生资源天然脂肪醇和葡萄糖合成的，是一种性能较全面的新型非离子表面活性剂。它兼具普通非离子和阴离子表面活性剂的特性，具有高表面活性、良好的生态安全性和相溶性，是国际公认的首选“绿色”功能性表面活性剂。
茶皂素属于三萜类皂甙，是一种性能优良的非离子型纯天然表面活性剂。它具有较强的发泡、乳化、分散、润湿等作用。
本发明还提供环保易洗水彩墨水的制备方法，制备方法如下：
将配制的占总量二分之一的去离子水加入搅拌釜内，使釜内水温保持在50～55℃，搅拌时加入天然色素和聚四氟乙烯粉，再依次加入茉莉花提取物、烷基糖苷、茶皂素和增稠剂，搅拌均质30～50min，最后加入余量的去离子水，再继续搅拌10～20min，降至室温，静置，过滤，即得到产品。
本发明的有益效果在于：
1、本发明选用的天然色素无毒无害，使用药食两用的茉莉花提取物具有提香抗氧化防腐作用，烷基糖苷兼具非离子和阴离子表面活性剂的特性，茶皂素具有较强的发泡、乳化、分散、润湿等作用，聚四氟乙烯粉具有高润滑作用，原料相互协同制备出环保易洗水彩墨水，安全、绿色天然，不含重金属成分，性价比高。
2、本发明制备工艺简单、成本低廉，味香色浓。
3、本发明生产的水彩墨水初写性能115mm正常出墨，划线325m不断线，往纯棉或化纤布料试验，将密集划线的布料浸入水中5～8分钟，墨水完全褪去。
具体实施方式
以下结合实施例对本发明作进一步说明，但本发明并不局限于这些实施例。
实施例1
将17重量份的去离子水加入搅拌釜内，使釜内水温保持在50℃，搅拌时加入15重量份姜黄素和7重量份粒径为5μm的聚四氟乙烯粉，再依次加入5重量份茉莉花提取物、3重量份烷基糖苷、15重量份茶皂素和23重量份淀粉，搅拌均质50min，最后加入剩余17重量份去离子水，再继续搅拌10，降至室温，静置，过滤，即得到产品。
实施例2
将20重量份的去离子水加入搅拌釜内，使釜内水温保持在52℃，搅拌时加入18重量份植物炭黑和5重量份粒径为6μm的聚四氟乙烯粉，再依次加入4重量份茉莉花提取物、4重量份烷基糖苷、11重量份茶皂素和27重量份明胶，搅拌均质45min，最后加入剩余20重量份去离子水，再继续搅拌15min，降至室温，静置，过滤，即得到产品。
实施例3
将19重量份的去离子水加入搅拌釜内，使釜内水温保持在53℃，搅拌时加入22重量份叶绿素酮酸盐和4重量份粒径为8μm的聚四氟乙烯粉，再依次加入3重量份茉莉花提取物、6重量份烷基糖苷、8重量份茶皂素和25重量份琼脂，搅拌均质40min，最后加入剩余19重量份去离子水，再继续搅拌15min，降至室温，静置，过滤，即得到产品。
实施例4
将15重量份的去离子水加入搅拌釜内，使釜内水温保持在54℃，搅拌时加入26重量份胡萝卜素和2重量份粒径为9μm的聚四氟乙烯粉，再依次加入2重量份茉莉花提取物、7重量份烷基糖苷、5重量份茶皂素和30重量份瓜尔胶，搅拌均质35min，最后加入剩余15重量份去离子水，再继续搅拌20min，降至室温，静置，过滤，即得到产品。
实施例5
将23重量份的去离子水加入搅拌釜内，使釜内水温保持在55℃，搅拌时加入30重量份辣椒橙色素和1重量份粒径为10μm的聚四氟乙烯粉，再依次加入1重量份茉莉花提取物、9重量份烷基糖苷、2重量份茶皂素和20重量份海藻酸钠，搅拌均质30min，最后加入剩余17重量份去离子水，再继续搅拌10min，降至室温，静置，过滤，即得到产品。
Claims (3)
1.一种环保易洗水彩墨水，其特征在于，由以下重量份的原料制成：
所述的环保易洗水彩墨水的制备方法为：将配制的占总量二分之一的去离子水加入搅拌釜内，使釜内水温保持在50～55℃，搅拌时加入天然色素和聚四氟乙烯粉，再依次加入茉莉花提取物、烷基糖苷、茶皂素和增稠剂，搅拌均质30～50min，最后加入余量的去离子水，再继续搅拌10～20min，降至室温，静置，过滤，即得到产品。
2.根据权利要求1所述的环保易洗水彩墨水，其特征在于：所述的聚四氟乙烯粉粒径为5～10μm。
3.根据权利要求1所述的环保易洗水彩墨水，其特征在于：所述的增稠剂为淀粉、明胶、琼脂、瓜尔胶、海藻酸钠中的一种。
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| CN101899240A (zh) * | 2009-05-25 | 2010-12-01 | 华东理工大学 | 采用复配表面活性剂的炭黑中性墨水及其制备方法 |
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