CN104559040A - Whisker reinforced plastic bottle cap masterbatch - Google Patents
Whisker reinforced plastic bottle cap masterbatch Download PDFInfo
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- CN104559040A CN104559040A CN201510041038.8A CN201510041038A CN104559040A CN 104559040 A CN104559040 A CN 104559040A CN 201510041038 A CN201510041038 A CN 201510041038A CN 104559040 A CN104559040 A CN 104559040A
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Abstract
The invention discloses a whisker reinforced plastic bottle cap masterbatch, which is composed of the following raw materials in parts by weight: 100-105 parts of ABS, 3-4 parts of calcium carbonate whiskers, 2-3 parts of potassium hexatitanate whiskers, 4-6 parts of furfural resin, 1-2 parts of aminopropyltriethoxysilane, 2-3 parts of tricalcium silicate, 1-2 parts of hexagonal boron nitride, 0.3-0.5 part of diacetone alcohol, 3-4 parts of dioctyl phthalate sebacate, 0.8-1 part of sodium lignin sulfonate, 0.6-1 part of graphite powder, 1-2 parts of diphenyl isophthalate, 0.7-1 part of zinc stearate, 1-2 parts of hydroxystearic acid, 0.6-1 part of sa-hao seed gum, 1-2 parts of calcium aluminate, 3-4 parts of toughening packing, and 0.6-1 part of 2-benzimidazolethiol. Packing such as calcium carbonate whiskers and potassium hexatitanate whiskers are added in the plastic bottle cap masterbatch disclosed by the invention, so that the masterbatch can achieve good heat insulation and wear-resisting and enhancement properties; the masterbatch is non-toxic, pollution-free and long in service life, and further improves the surface resistance of plastic bottle caps; and the masterbatch has strong heat resistance, and has no phenomena such as softening after being heated for a long time at high temperature.
Description
Technical field
The present invention relates generally to plastic cover field, particularly relates to a kind of crystal whisker excess weld metal plastic bottle closure masterbatch.
Background technology
There is a lot of deficiencies as the plastic cover of bottle in tradition, some much higher hards, easily cause unexpected injury to human body, have high temperature resistant, preservative property are bad, more serious is exactly stopping property difference, causes leakage, and easily threads off under pressure.
Summary of the invention
The object of the invention is just to provide a kind of crystal whisker excess weld metal plastic bottle closure masterbatch.
The present invention is achieved by the following technical solutions:
A kind of crystal whisker excess weld metal plastic bottle closure masterbatch, is characterized in that what it was made up of the raw material of following weight parts:
ABS100-105, calcium carbonate crystal whisker 3-4, crystal whisker of hexa potassium titanate 2-3, furfuryl resin 4-6, aminopropyl triethoxysilane 1-2, tricalcium silicate 2-3, hexagonal boron nitride 1-2, diacetone alcohol 0.3-0.5, SA dioctyl ester 3-4, sodium lignosulfonate 0.8-1, Graphite Powder 99 0.6-1, isophthalic acid ester 1-2, hard acid acid zinc 0.7-1, oxystearic acid 1-2, artemisia glue 0.6-1, calcium aluminate 1-2, toughness reinforcing filler 3-4,2-thiol group benzimidazolyl 0.6-1;
Described toughness reinforcing filler is made up of the raw material of following weight parts:
Graphene oxide 40-50, nano titanium oxide 1-2, tributyl citrate 1-2, polyvinyl butyral acetal 2-3, tripoly phosphate sodium STPP 6-10, tetraethoxy 1-2, needle-like nano calcium carbonate 0.4-1, deionized water 90-100, silane coupling agent KH560 0.1-0.2;
Preparation method is after graphene oxide and methyl methacrylate are uniformly mixed 20-30 minute, then adds graphene oxide, needle-like nano calcium carbonate, polyvinyl butyral acetal, is heated to 45-55 DEG C, stirs 10-20 minute, must stir material; Other remaining component mix and blend, after 10-20 minute, adds stirring material and mixes and get final product.
2, a preparation method for crystal whisker excess weld metal plastic bottle closure masterbatch as claimed in claim 1, is characterized in that comprising the following steps:
(1) sodium lignosulfonate is joined in 6-8 times of water, stir, add artemisia glue, be heated to 60-65 DEG C, add calcium carbonate crystal whisker, crystal whisker of hexa potassium titanate, insulated and stirred 6-10 minute, add aminopropyl triethoxysilane, 60-80 rev/min of dispersed with stirring 4-10 minute, adds Graphite Powder 99, continue to be stirred to water to do, dry 2-3 minute at 90-100 DEG C;
(2) get furfuryl resin, isophthalic acid ester, the mixing of SA dioctyl ester, add oxystearic acid after stirring, be uniformly mixed 5-7 minute at 60-80 DEG C, add diacetone alcohol, be stirred to normal temperature;
(3) each raw material after above-mentioned process is mixed with each raw material of residue, through melting mixing, extruding pelletization after stirring, obtain described masterbatch.
Advantage of the present invention is:
The toughness reinforcing filler that the present invention adds is based on graphene oxide, there is excellent tensile strength and toughness, through the process of ABS high glue powder, surface strength can be improved further, the polyvinyl butyral acetal improving methyl methacrylate introducing has excellent flexibility and flexibility, further increases toughening effect.
Plastic cover masterbatch of the present invention adds the filler such as calcium carbonate crystal whisker, crystal whisker of hexa potassium titanate, well heat insulation, wear-resisting, enhancement can be played, and nontoxic pollution-free, long service life, further increase the surface resistive of plastic bottle closure, and thermotolerance is strong, at high temperature long-time heating also there will not be the phenomenons such as softening.
Embodiment
Embodiment 1
A kind of crystal whisker excess weld metal plastic bottle closure masterbatch, is characterized in that what it was made up of the raw material of following weight parts:
The acid of ABS105, calcium carbonate crystal whisker 4, crystal whisker of hexa potassium titanate 3, furfuryl resin 6, aminopropyl triethoxysilane 1, tricalcium silicate 2, hexagonal boron nitride 2, diacetone alcohol 0.5, SA dioctyl ester 3, sodium lignosulfonate 0.8, Graphite Powder 99 0.6, isophthalic acid ester 2, hard acid zinc 0.7, oxystearic acid 1, artemisia glue 0.6, calcium aluminate 2, toughness reinforcing filler 3,2-thiol group benzimidazolyl 0.6;
Described toughness reinforcing filler is made up of the raw material of following weight parts:
Graphene oxide 50, nano titanium oxide 1, tributyl citrate 1, polyvinyl butyral acetal 3, tripoly phosphate sodium STPP 10, tetraethoxy 1-2, needle-like nano calcium carbonate 0.4, deionized water 100, silane coupling agent KH560 0.2;
Preparation method is after graphene oxide and methyl methacrylate are uniformly mixed 20-30 minute, then adds graphene oxide, needle-like nano calcium carbonate, polyvinyl butyral acetal, is heated to 45-55 DEG C, stirs 10-20 minute, must stir material; Other remaining component mix and blend, after 10-20 minute, adds stirring material and mixes and get final product.
A preparation method for crystal whisker excess weld metal plastic bottle closure masterbatch, comprises the following steps:
(1) sodium lignosulfonate is joined in 8 times of water, stir, add artemisia glue, be heated to 65 DEG C, add calcium carbonate crystal whisker, crystal whisker of hexa potassium titanate, insulated and stirred 10 minutes, add aminopropyl triethoxysilane, 80 revs/min of dispersed with stirring 10 minutes, add Graphite Powder 99, continue to be stirred to water to do, drying 2 minutes at 100 DEG C;
(2) get furfuryl resin, isophthalic acid ester, the mixing of SA dioctyl ester, add oxystearic acid after stirring, be uniformly mixed 7 minutes at 80 DEG C, add diacetone alcohol, be stirred to normal temperature;
(3) each raw material after above-mentioned process is mixed with each raw material of residue, through melting mixing, extruding pelletization after stirring, obtain described masterbatch.
Performance test:
Tensile strength MPa:40-42;
Shock strength J/m:120-124;
Vertical combustion rank UL-94: V0.
Claims (2)
1. a crystal whisker excess weld metal plastic bottle closure masterbatch, is characterized in that what it was made up of the raw material of following weight parts:
ABS100-105, calcium carbonate crystal whisker 3-4, crystal whisker of hexa potassium titanate 2-3, furfuryl resin 4-6, aminopropyl triethoxysilane 1-2, tricalcium silicate 2-3, hexagonal boron nitride 1-2, diacetone alcohol 0.3-0.5, SA dioctyl ester 3-4, sodium lignosulfonate 0.8-1, Graphite Powder 99 0.6-1, isophthalic acid ester 1-2, hard acid acid zinc 0.7-1, oxystearic acid 1-2, artemisia glue 0.6-1, calcium aluminate 1-2, toughness reinforcing filler 3-4,2-thiol group benzimidazolyl 0.6-1;
Described toughness reinforcing filler is made up of the raw material of following weight parts:
Graphene oxide 40-50, nano titanium oxide 1-2, tributyl citrate 1-2, polyvinyl butyral acetal 2-3, tripoly phosphate sodium STPP 6-10, tetraethoxy 1-2, needle-like nano calcium carbonate 0.4-1, deionized water 90-100, silane coupling agent KH560 0.1-0.2;
Preparation method is after graphene oxide and methyl methacrylate are uniformly mixed 20-30 minute, then adds graphene oxide, needle-like nano calcium carbonate, polyvinyl butyral acetal, is heated to 45-55 DEG C, stirs 10-20 minute, must stir material; Other remaining component mix and blend, after 10-20 minute, adds stirring material and mixes and get final product.
2. a preparation method for crystal whisker excess weld metal plastic bottle closure masterbatch as claimed in claim 1, is characterized in that comprising the following steps:
(1) sodium lignosulfonate is joined in 6-8 times of water, stir, add artemisia glue, be heated to 60-65 DEG C, add calcium carbonate crystal whisker, crystal whisker of hexa potassium titanate, insulated and stirred 6-10 minute, add aminopropyl triethoxysilane, 60-80 rev/min of dispersed with stirring 4-10 minute, adds Graphite Powder 99, continue to be stirred to water to do, dry 2-3 minute at 90-100 DEG C;
(2) get furfuryl resin, isophthalic acid ester, the mixing of SA dioctyl ester, add oxystearic acid after stirring, be uniformly mixed 5-7 minute at 60-80 DEG C, add diacetone alcohol, be stirred to normal temperature;
(3) each raw material after above-mentioned process is mixed with each raw material of residue, through melting mixing, extruding pelletization after stirring, obtain described masterbatch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510041038.8A CN104559040A (en) | 2015-01-27 | 2015-01-27 | Whisker reinforced plastic bottle cap masterbatch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510041038.8A CN104559040A (en) | 2015-01-27 | 2015-01-27 | Whisker reinforced plastic bottle cap masterbatch |
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| Publication Number | Publication Date |
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| CN104559040A true CN104559040A (en) | 2015-04-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510041038.8A Pending CN104559040A (en) | 2015-01-27 | 2015-01-27 | Whisker reinforced plastic bottle cap masterbatch |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885333A (en) * | 2016-05-09 | 2016-08-24 | 安徽江淮汽车股份有限公司 | Flame-retardant ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323695A (en) * | 2008-08-04 | 2008-12-17 | 四川省隆鑫科技包装有限公司 | ABS modified plastic for battle cap |
| CN103232669A (en) * | 2013-03-31 | 2013-08-07 | 青岛永卓真塑料制品有限公司 | Winebottle cap ABS plastic |
| CN103360656A (en) * | 2012-03-31 | 2013-10-23 | 中国石油化工股份有限公司 | Regenerated polyethylene composition and preparation method thereof |
| CN103570894A (en) * | 2013-10-16 | 2014-02-12 | 青岛华瑞胶业设备有限公司 | Environment-friendly ABS (acrylonitrile-butadiene-styrene) plastic bottle cap |
-
2015
- 2015-01-27 CN CN201510041038.8A patent/CN104559040A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101323695A (en) * | 2008-08-04 | 2008-12-17 | 四川省隆鑫科技包装有限公司 | ABS modified plastic for battle cap |
| CN103360656A (en) * | 2012-03-31 | 2013-10-23 | 中国石油化工股份有限公司 | Regenerated polyethylene composition and preparation method thereof |
| CN103232669A (en) * | 2013-03-31 | 2013-08-07 | 青岛永卓真塑料制品有限公司 | Winebottle cap ABS plastic |
| CN103570894A (en) * | 2013-10-16 | 2014-02-12 | 青岛华瑞胶业设备有限公司 | Environment-friendly ABS (acrylonitrile-butadiene-styrene) plastic bottle cap |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885333A (en) * | 2016-05-09 | 2016-08-24 | 安徽江淮汽车股份有限公司 | Flame-retardant ABS (acrylonitrile butadiene styrene) composite material and preparation method thereof |
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Application publication date: 20150429 |