CN104556899A - Colored polymer cement waterproof paint - Google Patents

Colored polymer cement waterproof paint Download PDF

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Publication number
CN104556899A
CN104556899A CN201410818270.3A CN201410818270A CN104556899A CN 104556899 A CN104556899 A CN 104556899A CN 201410818270 A CN201410818270 A CN 201410818270A CN 104556899 A CN104556899 A CN 104556899A
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China
Prior art keywords
parts
component
waterproof paint
polymer cement
cement waterproof
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CN201410818270.3A
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Chinese (zh)
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CN104556899B (en
Inventor
沈恒
王会元
熊卫锋
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HUIZHOU DONGFANG YUHONG BUILDING MATERIALS CO Ltd
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HUIZHOU DONGFANG YUHONG BUILDING MATERIALS CO Ltd
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Abstract

The invention relates to a colored polymer cement waterproof paint which consists of a component A and a component B, wherein the component A is prepared from the following raw materials in parts by weight: 80-85 parts of a polymer emulsion, 1-2 parts of a functional auxiliary and 5-10 parts of water; the component B is prepared from the following raw materials in parts by weight: 1-1.5 parts of a slow-release toner, 10-15 parts of re-dispersible rubber powder, 300-320 parts of cement and 650-670 parts of 400-mesh quartz powder. The colored polymer cement waterproof paint provided by the invention fully meets the relevant standard performance requirements and is environment-friendly and colored. An experiment proves that the colored polymer cement waterproof paint can reach 300 percent in maximum elongation at break and 3.2 MP in maximum tensile strength and is waterproof; the relevance ratio of free formaldehyde, ammonia, benzene/ methylbenzene/dimethylbenzene/ethylbenzene is zero, and the content of a volatile organic compound is less than 10 g/L.

Description

A kind of after stain polymer cement waterproof paint
Technical field
The present invention relates to a kind of polymer cement waterproof paint, be specifically related to a kind of environment-friendly type after stain polymer cement waterproof paint.
Background technology
Polymer cement waterproof paint is a kind of organic liquid material formed with the polymer emulsions such as polyacrylate dispersion, ethylene-vinyl acetate copolymer emulsion and various additive, and the inorganic powder that the mineral filler such as cement, quartz sand, light water-ground limestone and various additive form is by rational proportion, compounded one two component, aqueous architectural waterproof paint.But polymer cement waterproof paint generally adopts the color of cement, i.e. grey or white, the color relation of such coating is very single, can not meet the requirement of client to coating different colours; Or in powder just colour developing when making.
Such as, prior art CN201110174717.4 discloses a kind of colored polymer cement underwater paint, be made up of powder and liquid material, powder comprises: inert inorganic powder 1-4 part, pigment 0.001-0.01 part, containing aqueous solution 0.5-1 part of polymer emulsion 10%-20%, cement 1-7 part, dispersion agent 0.002-0.01 part; Liquid material comprises: polymer emulsion 0.5-0.9 part, water 0.1-0.5 part, defoamer 0.01-0.003 part.This invention overcomes the color distortion that common double component coating brings because of proportion scale difference, and polymer cement waterproof paint colorize is really realized.But what powder was made is colored powder, and tensile strength, unit elongation reduce relatively, need to add defoamer simultaneously.CN201310190741.6 discloses a kind of Green polymer cement waterproof paint, is made up: polyacrylic ester 110 parts, 65 parts, styrene-butadiene rubber(SBR), 5 parts, calcium carbonate, lignocellulose 8 parts, silica powder 5 parts, cement 65 parts, dispersion agent 15 parts, defoamer 5 parts, cobalt titanium phthalocyanine 0.05 part, 15 parts, calcium carbonate, membrane-forming agent 4 parts, silane coupling agent 15 parts of following component according to weight proportion stirring.Although in this invention, pigment is uniformly dispersed in coating, elegant in appearance; But green a kind of color can only be realized, the requirement of client to coating different colours can not be met, and also need to add defoamer.
Summary of the invention
Technical problem to be solved by this invention is, provides the polymer cement waterproof paint of a kind of environment-friendly type, after stain.
The technical scheme that the present invention solves the employing of its technical problem is: a kind of after stain polymer cement waterproof paint, is made up of component A and B component, and wherein, component A, B component are made up of the raw material of following parts by weight respectively,
Component A:
Polymer emulsion 80 ~ 85 parts,
Functional aid 1 ~ 2 part,
5 ~ 10 parts, water;
B component:
Further, described polymer emulsion is selected from polyacrylate dispersion or/and ethylene-vinyl acetate copolymer emulsion, and its second-order transition temperature is-15 degree.
Further, described functional aid is selected from waterborne organic silicon emulsion defoamer.
Further, described slowly-releasing toner is selected from the hollow structure toner of a kind of particle size range at 20 microns.
Further, described re-dispersible glue powder is selected from acrylate re-dispersible glue powder, and its particle size range is at 0.2 ~ 0.5 micron.
Further, described cement is selected from 32.5 white portland cements.
During application, component A and B component stir according to 1: 1 ~ 1.5 ratios, can use.
Preferably, the preparation method of a kind of after stain polymer cement waterproof paint of the present invention, by polymer emulsion, functional aid and water, mixes, obtains component A; A frequency-conversion agitator is added by after constant warm and humid air feed equipment aerating and humidification stirring after being weighed by proportioning toner weighing balance by slowly-releasing toner, put in No. two frequency-conversion agitators, add to stir after re-dispersible glue powder being weighed by the metering of proportioning rubber powder simultaneously and form addition material, all render in No. three frequency-conversion agitators afterwards, then join mix and blend in No. three frequency-conversion agitators after white cement and silica powder being weighed by proportioning weighing balance, obtain B component.Wherein, with three frequency conversion powder lot dispersing machine laminar distributions, the superiors' dispersion machine provides at a slow speed specified moisture air to enter dispersion storehouse by air-supply pipeline, is responsible for humidification and the aerating of slowly-releasing toner; Middle level dispersion machine is responsible for aerating dispersion and the toner absorption of re-dispersible glue powder; The blending dispersion of the finished product is responsible for by bottom dispersion machine.
After the present invention, coloured polymer cement waterproof paint is by utilizing the absorption in advance of slowly-releasing toner surface electrostatic interaction and re-dispersible glue powder, and by selecting rubber powder size, rubber powder can be realized closely wrap up at slowly-releasing toner surface, make toner not represent color in powder state system; In product operational phase, by the mixing of liquid material and powder, capture rubber powder by emulsion, toner is discharged in solution, and a kind of not containing the environment-friendly type of defoamer, the polymer cement waterproof paint of after stain of pre-set color is showed in exhibition.The present invention is formed as the waterproof paint of specific colour when applying, and is coated in the surface of cement matrix, after the moisture evaporation of polymer emulsion and hydrated cementitious film forming, forms a firmly waterproof entirety, can reach impervious waterproof requirement in interface; The destruction in the movable gap of film self-strength and elastic barrier outside atmosphere and basic unit can be utilized simultaneously.
Experiment proves, after the present invention, coloured polymer cement waterproof paint elongation at break reaches as high as 300%, and tensile strength reaches as high as 3.2MPa, and waterproof; Free formaldehyde, ammonia, benzene/methylbenzene/dimethylbenzene/ethylbenzene recall rate are zero, and volatile organic matter content is less than 10g/L, can provide the product with personal color feature simultaneously.
Accompanying drawing explanation
Fig. 1 is the specific equipment schema of preparation B component.
Embodiment:
Below in conjunction with embodiment, the present invention is illustrated further, but embodiment of the present invention is not limited thereto.
Embodiment 1:
The polymer emulsion of 85 weight parts, 1 weight part functional aid, 5 weight parts waters are mixed, obtains component A product; 1 weight part slowly-releasing toner is entered after a frequency-conversion agitator carries out aerating and humidification, render in No. two frequency-conversion agitators, adsorb with 20 weight part re-dispersible glue powders premix in No. two frequency-conversion agitators and form addition material, then throw in in No. three frequency-conversion agitators, add in 300 weight part white cements and 670 weight part silica powders in No. three frequency-conversion agitators simultaneously and mix, obtain B component product; Component A and B component are applied according to 1: 1 ratio.
Embodiment 2
By the polymer emulsion of 80 weight parts, 1 weight part functional aid and 10 weight parts waters, mix, obtain component A product; 1.5 weight slowly-releasing toners are entered after a frequency-conversion agitator carries out aerating and humidification, render in No. two frequency-conversion agitators, adsorb with 20 weight part re-dispersible glue powders premix in No. two frequency-conversion agitators and form addition material, then throw in in No. three frequency-conversion agitators, add in 320 weight part white cements and 650 weight part silica powders in No. three frequency-conversion agitators simultaneously and mix, obtain B component product; Component A and B component are applied according to 1: 1.5 ratio.
Environment-friendly type after stain polymer cement waterproof paint prepared by above-described embodiment 1 ~ 2 is carried out elongation at break, tensile strength, watertightness measure of merit, testing method is according to GB/T 23445-2009 polymer cement waterproof paint detection method, and mechanical experimental results is in table 1.
Table 1 mechanical experimental results
Project Elongation at break (%) Tensile strength (MPa) Watertightness (0.3MPa, 30min)
Embodiment 1 300 1.80 Waterproof
Embodiment 2 150 3.20 Waterproof
Environment-friendly type after stain polymer cement waterproof paint prepared by above-described embodiment 1 ~ 2 is carried out free formaldehyde, ammonia, benzene/methylbenzene/dimethylbenzene/ethylbenzene, volatile organic matter content measuring, testing method is according to limits of harmful substances detection method in JC1066-2008 building water-proof paint, and harmful substance contents test result is in table 2.
Table 2 harmful substance contents test result
Above-described embodiment is two kinds of typical cases of embodiments of the present invention; but embodiments of the present invention do not limit by above-described embodiment; the change made under other any does not deviate from spirit of the present invention and principle, modification, substitute, simplify and all should be equivalent embodiment, be included within protection scope of the present invention.

Claims (6)

1. an after stain polymer cement waterproof paint, is characterized in that, is made up of component A and B component, and wherein, component A, B component are made up of the raw material of following parts by weight respectively,
Component A:
Polymer emulsion 80 ~ 85 parts,
Functional aid 1 ~ 2 part,
5 ~ 10 parts, water;
B component:
2. after stain polymer cement waterproof paint according to claim 1, is characterized in that, described polymer emulsion is selected from polyacrylate dispersion or/and ethylene-vinyl acetate copolymer emulsion, and its second-order transition temperature is-15 degree.
3. after stain polymer cement waterproof paint according to claim 1, is characterized in that, described functional aid is selected from waterborne organic silicon emulsion defoamer.
4. after stain polymer cement waterproof paint according to claim 1, is characterized in that, described slowly-releasing toner is selected from the hollow structure toner of a kind of particle size range at 20 microns.
5. after stain polymer cement waterproof paint according to claim 1, is characterized in that, described re-dispersible glue powder is selected from acrylate re-dispersible glue powder, and its particle size range is at 0.2 ~ 0.5 micron.
6. after stain polymer cement waterproof paint according to claim 1, is characterized in that, described cement is selected from 32.5 white portland cements.
CN201410818270.3A 2014-12-23 2014-12-23 A kind of after stain polymer cement waterproof paint Active CN104556899B (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062281A (en) * 2015-08-17 2015-11-18 惠州东方雨虹建筑材料有限责任公司 I-type environment-friendly two-component polymer cement waterproof paint and preparation method
CN105130321A (en) * 2015-07-10 2015-12-09 昆明风行防水材料有限公司 Polymer cement waterproofing coating capable of being used in low temperature environment
CN106010058A (en) * 2016-06-30 2016-10-12 广西梧州龙鱼漆业有限公司 Superhigh-elasticity water-resistant paint and preparation method thereof
CN106673537A (en) * 2016-12-15 2017-05-17 江门市蓬江区文森装饰材料有限公司 Water-based cement paint
CN107892530A (en) * 2017-12-20 2018-04-10 安徽力峰建材科技有限公司 A kind of preparation method of low smell color tile grout
CN109279831A (en) * 2017-07-20 2019-01-29 惠州市固硕宝建材有限公司 A kind of colour rigid polymer waterproof mortar
CN111592827A (en) * 2020-05-25 2020-08-28 潍坊石花化工建材有限公司 High-strength nanoscale polymer cement waterproof coating and preparation method thereof
CN111908493A (en) * 2020-08-04 2020-11-10 江西广源化工有限责任公司 Additive for producing calcium carbonate by wet method and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1266738A (en) * 1999-03-12 2000-09-20 樱花彩色产品株式会社 Powdered microcapsules and their preparing process
JP2007230805A (en) * 2006-02-28 2007-09-13 Paratex Japan:Kk Waterproof material
CN102329112A (en) * 2011-06-27 2012-01-25 浙江鲁班建筑防水有限公司 Colored polymer cement underwater paint
CN102424554A (en) * 2011-09-14 2012-04-25 同济大学 Colored decorative mortar with excellent performance
CN103601441A (en) * 2013-10-31 2014-02-26 德高(广州)建材有限公司 Carbonization-resistant waterproof slurry
WO2014065684A1 (en) * 2012-10-22 2014-05-01 Secil S.A.- Companhia Geral De Cal E Cimento White or colored cementitious coating with hydrochromatic properties

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1266738A (en) * 1999-03-12 2000-09-20 樱花彩色产品株式会社 Powdered microcapsules and their preparing process
JP2007230805A (en) * 2006-02-28 2007-09-13 Paratex Japan:Kk Waterproof material
CN102329112A (en) * 2011-06-27 2012-01-25 浙江鲁班建筑防水有限公司 Colored polymer cement underwater paint
CN102424554A (en) * 2011-09-14 2012-04-25 同济大学 Colored decorative mortar with excellent performance
WO2014065684A1 (en) * 2012-10-22 2014-05-01 Secil S.A.- Companhia Geral De Cal E Cimento White or colored cementitious coating with hydrochromatic properties
CN103601441A (en) * 2013-10-31 2014-02-26 德高(广州)建材有限公司 Carbonization-resistant waterproof slurry

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105130321A (en) * 2015-07-10 2015-12-09 昆明风行防水材料有限公司 Polymer cement waterproofing coating capable of being used in low temperature environment
CN105130321B (en) * 2015-07-10 2018-05-29 昆明风行防水材料有限公司 A kind of polymer cement waterproof paint that can be used under low temperature environment
CN105062281A (en) * 2015-08-17 2015-11-18 惠州东方雨虹建筑材料有限责任公司 I-type environment-friendly two-component polymer cement waterproof paint and preparation method
CN106010058A (en) * 2016-06-30 2016-10-12 广西梧州龙鱼漆业有限公司 Superhigh-elasticity water-resistant paint and preparation method thereof
CN106673537A (en) * 2016-12-15 2017-05-17 江门市蓬江区文森装饰材料有限公司 Water-based cement paint
CN109279831A (en) * 2017-07-20 2019-01-29 惠州市固硕宝建材有限公司 A kind of colour rigid polymer waterproof mortar
CN107892530A (en) * 2017-12-20 2018-04-10 安徽力峰建材科技有限公司 A kind of preparation method of low smell color tile grout
CN111592827A (en) * 2020-05-25 2020-08-28 潍坊石花化工建材有限公司 High-strength nanoscale polymer cement waterproof coating and preparation method thereof
CN111908493A (en) * 2020-08-04 2020-11-10 江西广源化工有限责任公司 Additive for producing calcium carbonate by wet method and preparation method and application thereof

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