CN104540583A - 用于从轻质烃例如甲烷共同制备烯烃、炔和氢气的高效方法 - Google Patents

用于从轻质烃例如甲烷共同制备烯烃、炔和氢气的高效方法 Download PDF

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Publication number
CN104540583A
CN104540583A CN201380042840.8A CN201380042840A CN104540583A CN 104540583 A CN104540583 A CN 104540583A CN 201380042840 A CN201380042840 A CN 201380042840A CN 104540583 A CN104540583 A CN 104540583A
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China
Prior art keywords
stream
methane
hydrogen
circulation
carbon dioxide
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Pending
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CN201380042840.8A
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English (en)
Chinese (zh)
Inventor
A·内伊兹
R·B·詹姆斯
C·J·史蒂文斯
P·T·巴杰
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Universal Oil Products Co
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Universal Oil Products Co
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Publication of CN104540583A publication Critical patent/CN104540583A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/005—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor carried out at high temperatures, e.g. by pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/78—Processes with partial combustion
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C10G9/38—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours produced by partial combustion of the material to be cracked or by combustion of another hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C3/00—Combustion apparatus characterised by the shape of the combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • F23C6/042—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with fuel supply in stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00—Staged combustion
    • F23C2201/10—Furnace staging
    • F23C2201/102—Furnace staging in horizontal direction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380042840.8A 2012-08-21 2013-08-12 用于从轻质烃例如甲烷共同制备烯烃、炔和氢气的高效方法 Pending CN104540583A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261691369P 2012-08-21 2012-08-21
US61/691,369 2012-08-21
PCT/US2013/054469 WO2014031371A1 (en) 2012-08-21 2013-08-12 High efficiency processes for olefins, alkynes, and hydrogen co-production from light hydrocarbons such as methane

Publications (1)

Publication Number Publication Date
CN104540583A true CN104540583A (zh) 2015-04-22

Family

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Family Applications (1)

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CN201380042840.8A Pending CN104540583A (zh) 2012-08-21 2013-08-12 用于从轻质烃例如甲烷共同制备烯烃、炔和氢气的高效方法

Country Status (13)

Country Link
US (1) US20140058149A1 (https=)
EP (1) EP2888036B1 (https=)
CN (1) CN104540583A (https=)
AU (2) AU2013306230A1 (https=)
BR (1) BR112015003265A2 (https=)
CA (1) CA2880075C (https=)
EA (1) EA033837B1 (https=)
IN (1) IN2015DN00628A (https=)
MX (1) MX2015001602A (https=)
MY (1) MY177598A (https=)
SG (1) SG11201500565YA (https=)
WO (1) WO2014031371A1 (https=)
ZA (1) ZA201501240B (https=)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107530666A (zh) * 2015-06-23 2018-01-02 环球油品公司 热解反应器及其使用方法
CN110769926A (zh) * 2017-06-21 2020-02-07 环球油品有限责任公司 使用超音速流反应器的甲烷转化设备和工艺
CN113631503A (zh) * 2019-03-27 2021-11-09 西门子能源环球有限责任两合公司 产生气体产物的方法
CN114423517A (zh) * 2020-07-06 2022-04-29 沙伯环球技术有限公司 用于生产高价值化学产品的反应器系统
CN114634155A (zh) * 2020-12-15 2022-06-17 埃科纳能源公司 使用原料气反应器生产氢气和氮气的方法
US12012333B1 (en) 2022-12-19 2024-06-18 Ekona Power Inc. Methods and systems for adjusting inputs to a pyrolysis reactor to improve performance
US12151225B2 (en) 2018-12-10 2024-11-26 Ekona Power Inc. Method and reactor for producing one or more products

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US10029957B2 (en) 2012-08-21 2018-07-24 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
US10160697B2 (en) 2012-08-21 2018-12-25 Uop Llc Methane conversion apparatus and process using a supersonic flow reactor
WO2015077335A2 (en) 2013-11-19 2015-05-28 Carl Knowlen Supersonic shock wave reactors, and associated systems and methods
US9732015B2 (en) 2015-05-29 2017-08-15 Uop Llc Process for the selective hydrogenation of acetylene to ethylene
EP3313806B1 (en) * 2015-06-23 2021-02-24 Uop Llc Integrated pyrolysis and oxygenate to olefin process
GB2551314B (en) * 2016-06-06 2021-03-17 Kew Tech Limited Equilibium approach reactor
DK3472123T3 (da) 2016-06-18 2024-08-26 Think Tank 42 Pty Ltd Fremgangsmåde og system til carbonopsamling og -genanvendelse
US20200055731A1 (en) * 2016-10-26 2020-02-20 Sabic Global Technologies, B.V. Novel Process Integration of Methane or Higher Hydrocarbon Pyrolysis Step to Produce Ethylene and Methanol and/or Hydrogen
US10550731B2 (en) * 2017-01-13 2020-02-04 LLT International (Ireland) Ltd. Systems and methods for generating steam by creating shockwaves in a supersonic gaseous vortex
US11299442B2 (en) * 2020-03-31 2022-04-12 Uop Llc Process for producing acetylene and ethylene
US20220064083A1 (en) * 2020-05-26 2022-03-03 Uop Llc Integrated process for producing acetylene
WO2022189343A1 (en) * 2021-03-12 2022-09-15 Sabic Global Technologies B.V. Separation processes for pyrolysis products of annular jet vortex chamber reactor
JP7337301B1 (ja) * 2022-07-15 2023-09-01 三菱電機株式会社 カーボンナノチューブの製造方法及びカーボンナノチューブ製造システム
WO2024254646A1 (en) * 2023-06-16 2024-12-19 InfigoLabs Pty Ltd Combustor and pyrolysis component, assembly and related systems and methods, and calcination system and method
KR102936606B1 (ko) 2023-08-03 2026-03-11 한국생산기술연구원 순산소 연소 기반 메탄 열분해 장치

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CN1141622A (zh) * 1993-12-08 1997-01-29 化学研究及许可公司 烃类物流中的高度不饱和化合物的选择加氢
EP1288182A1 (de) * 2000-03-21 2003-03-05 Zakrytoe Aktsionernoe Obschestvo " Toplivnaya Kompaniya Sibur-Nizhny Novgorod" Verfahren zur direkten methanpyrolyse
CN1429798A (zh) * 2001-12-30 2003-07-16 中国科学院力学研究所 反向射流混合加热裂解装置及生产乙烯的方法
US20090042998A1 (en) * 2007-08-03 2009-02-12 Daiki Ataka Engineering Co., Ltd. Catalyst for methanation of carbon oxides, preparation method of the catalyst and process for the methanation
CN101849036A (zh) * 2007-05-04 2010-09-29 原则能源解决方案公司 由碳源和氢源生产烃
CN102239234A (zh) * 2008-12-08 2011-11-09 普拉加兹有限公司 用于制氢的系统

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CN1141622A (zh) * 1993-12-08 1997-01-29 化学研究及许可公司 烃类物流中的高度不饱和化合物的选择加氢
EP1288182A1 (de) * 2000-03-21 2003-03-05 Zakrytoe Aktsionernoe Obschestvo " Toplivnaya Kompaniya Sibur-Nizhny Novgorod" Verfahren zur direkten methanpyrolyse
CN1429798A (zh) * 2001-12-30 2003-07-16 中国科学院力学研究所 反向射流混合加热裂解装置及生产乙烯的方法
CN101849036A (zh) * 2007-05-04 2010-09-29 原则能源解决方案公司 由碳源和氢源生产烃
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CN102239234A (zh) * 2008-12-08 2011-11-09 普拉加兹有限公司 用于制氢的系统

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107530666A (zh) * 2015-06-23 2018-01-02 环球油品公司 热解反应器及其使用方法
CN110769926A (zh) * 2017-06-21 2020-02-07 环球油品有限责任公司 使用超音速流反应器的甲烷转化设备和工艺
US12151225B2 (en) 2018-12-10 2024-11-26 Ekona Power Inc. Method and reactor for producing one or more products
CN113631503A (zh) * 2019-03-27 2021-11-09 西门子能源环球有限责任两合公司 产生气体产物的方法
CN113631503B (zh) * 2019-03-27 2024-04-19 西门子能源环球有限责任两合公司 产生气体产物的方法
US12139413B2 (en) 2019-03-27 2024-11-12 Siemens Energy Global GmbH & Co. KG Method for generating a gas-product
CN114423517A (zh) * 2020-07-06 2022-04-29 沙伯环球技术有限公司 用于生产高价值化学产品的反应器系统
US11679370B2 (en) 2020-07-06 2023-06-20 Sabic Global Technologies B.V. Reactor system for the production of high value chemical products
US12263460B2 (en) 2020-07-06 2025-04-01 Sabic Global Technologies B.V. Reactor system for the production of high value chemical products
CN114634155A (zh) * 2020-12-15 2022-06-17 埃科纳能源公司 使用原料气反应器生产氢气和氮气的方法
US12157669B2 (en) 2020-12-15 2024-12-03 Ekona Power Inc. Methods of producing hydrogen and nitrogen using a feedstock gas reactor
US12012333B1 (en) 2022-12-19 2024-06-18 Ekona Power Inc. Methods and systems for adjusting inputs to a pyrolysis reactor to improve performance

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US20140058149A1 (en) 2014-02-27
AU2013306230A1 (en) 2015-02-19
CA2880075A1 (en) 2014-02-27
ZA201501240B (en) 2016-10-26
MY177598A (en) 2020-09-22
CA2880075C (en) 2018-01-16
EP2888036B1 (en) 2020-05-13
BR112015003265A2 (pt) 2017-08-08
EA201500262A1 (ru) 2015-07-30
EA033837B1 (ru) 2019-12-02
WO2014031371A1 (en) 2014-02-27
IN2015DN00628A (https=) 2015-06-26
AU2016250335A1 (en) 2016-11-10
SG11201500565YA (en) 2015-02-27
MX2015001602A (es) 2015-05-07
EP2888036A4 (en) 2016-05-11
EP2888036A1 (en) 2015-07-01

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