CN104538360B - A kind of memory cell grid preparation method of flash memory - Google Patents

A kind of memory cell grid preparation method of flash memory Download PDF

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Publication number
CN104538360B
CN104538360B CN201410164074.9A CN201410164074A CN104538360B CN 104538360 B CN104538360 B CN 104538360B CN 201410164074 A CN201410164074 A CN 201410164074A CN 104538360 B CN104538360 B CN 104538360B
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gate structure
layer
etching
floating gate
grid
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CN104538360A (en
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秦伟
高慧慧
杨渝书
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Shanghai Huali Microelectronics Corp
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
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  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Non-Volatile Memory (AREA)
  • Semiconductor Memories (AREA)

Abstract

The invention discloses a kind of memory cell grid preparation method of flash memory, comprise the following steps:(1) in sequentially forming gate dielectric layer in a semiconductors coupling structure with fleet plough groove isolation structure, floating gate structure layer, dielectric layer and control gate structure sheaf between grid, and form patterning photoresist layer in control gate structure layer surface;(2) control gate structure sheaf is performed etching according to patterning photoresist layer, to remove part control gate structure sheaf;(3) etching is synchronized dielectric layer control gate structure sheaf, grid and floating gate structure layer, floating gate structure layer is had residual;(4) the floating gate structure layer of residual is performed etching using high selectivity etching technics, with complete floating gate structure layer.Because the present invention using dielectric layer the grid and the same step etching method of the floating gate structure, the lithographic method can effectively reduce the loss of shallow trench isolation region, technique is simple, saves the production time, improves production efficiency.

Description

A kind of memory cell grid preparation method of flash memory
Technical field
The present invention relates to the memory cell grid preparation method of a kind of semiconductor fabrication, more particularly to a kind of flash memory.
Background technology
Flash memory is non-volatile memory devices main currently on the market, is widely used in the number such as mobile phone, palm PC Code equipment.
As shown in figure 1, the grid of the memory cell areas of flash memory is by dielectric layer 2, floating gate knot between control gate structure sheaf 1, grid Structure layer 3, gate dielectric layer 4, silicon substrate 5, shallow-trench isolation plot structure 6 are formed.Conventional control gate lithographic method is:First controlled The etching of grid structure sheaf 1 processed, terminates in dielectric layer 2 between touching grid;Then by the control gate knot between floating gate structure layer 3 Structure layer 1 removes;Continue to etch dielectric layer 2 between gate dielectric layer 4 and grid;Finally etch floating gate structure layer 3.Due to floating gate knot There is ladder height in the side wall of structure layer 3, the step needs the enough time to remove gate dielectric layer 4 completely, and this can be caused necessarily The shallow-trench isolation loss of amount, while complex manufacturing.
Number of patent application is 200510126274.6 Chinese patent, discloses a kind of anisotropic polysilicon of raising and carves Etching technique, comprise the following steps:Through etching, pulse etching, pulse main etching, over etching.Wherein pulse main etching includes tool There is the first technique of the first radio-frequency pulse power, first gas flow, the pulse main etching also includes having the second radio frequency source arteries and veins The second technique of power, second gas flow is rushed, wherein the first technique and the second technique are alternately, in the second radio frequency source pulse Cycle is substantially carried out the generation of polymer and the protection of side wall;Polysilicon is substantially carried out in the first radio frequency source pulse period longitudinally to carve Erosion, the technical scheme reduce lateral etch rate, and with good longitudinal etching speed, pack etch rate and larger Etch area.It can thus be appreciated that during this mode etches, the first technique mainly carries out longitudinal etching, the second technique to polysilicon The generation of polymer and the protection of side wall are substantially carried out, the first technique alternately, improves longitudinal etching with the second technique Speed, horizontal etch rate is reduced, and cutd open so that forming good anisotropic etching during plasma etching Face, but floating gate structure layer and fleet plough groove isolation structure be by once etching shaping, actually floating gate structure layer with it is shallow A ladder height between groove isolation construction be present, the control gate made using such a mode, can to shallow trench isolation region or Person's floating gate layer causes damage, or shallow trench isolation region causes damage simultaneously with floating gate layer.
Number of patent application is 200310108277 Chinese patent, is disclosed a kind of for manufacturing flash memory control gate The improved method of packed structures formation process, it is characterised in that during the preceding road technique Integrated manufacture of flash memory, floating After dynamic formation, before control gate is formed, using following process:
(1) second of tunnel gate oxidation prerinse is carried out;(2) second of tunnel gate oxidation is carried out, forms SIO2/HTO/ SIO2Three-decker;(3) depositing polysilicon and its doping;(4) tungsten silicide thin film is deposited;(5) conventional photolithography is carried out, it is walked It is rapid as follows:(a) organic antireflection layer is coated;(b) photoresist is coated;(c) exposure is developed;(6) dry etching, its step is such as Under:(a) a step dry etching is carried out, its step is as follows:First carry out organic antireflection layer etching, then carry out tungsten silicide and Polysilicon film etches;(b) wet method, which is peeled off, removes photoresist.
The flash memory control gate for adopting this method the manufacturing has the advantage that and is the reduction of process complexity, drops Low production cost, shorten technological process and production time, that is, improve output, extraordinary technology stability;Obtain More preferable control gate packed structures pattern, so as to improve yield rate and reliability.It can be seen that improved method use is still Conventional photo-mask process and dry etching, equally can be high because of the ladder between floating gate structure layer and fleet plough groove isolation structure Degree, to shallow trench isolation region, either floating gate layer causes damage or shallow trench isolation region and floating gate layer while caused damage.To rear Continuous technique adversely affects, and finally influences the Performance And Reliability of semiconductor devices.
The content of the invention
The technical problem to be solved in the present invention is, for the drawbacks described above of prior art, there is provided a kind of technique is simple, shallow Groove isolated area loses the preparation method of the memory cell grid of small flash memory, improves performance of integrated circuits.
The technical proposal for solving the technical problem of the invention is as follows:
A kind of memory cell grid preparation method of flash memory, comprises the following steps:
Step 1, in sequentially forming gate dielectric layer in the semiconductors coupling structure that one has fleet plough groove isolation structure, float Grid structure sheaf, dielectric layer and control gate structure sheaf between grid, and form patterning photoresist layer in the control gate structure layer surface;
Step 2, the control gate structure sheaf is performed etching according to the patterning photoresist layer, to remove the photoresistance The control gate structure sheaf above the floating gate structure layer in layer exposed region, and make on the fleet plough groove isolation structure The control gate structure sheaf of side has residual;
Step 3, dielectric layer and the floating gate structure layer the control gate structure sheaf (1), the grid are synchronized Etching, to remove the control gate knot of residual above the fleet plough groove isolation structure in the photoresist layer exposed region completely Structure layer, and remove completely at the top of the floating gate structure layer in the photoresist layer exposed region, the floating gate structure layer Dielectric layer between the grid of both sides, and the grid at the top of the fleet plough groove isolation structure in the photoresist layer exposed region are removed completely Dielectric layer, and the certain thickness floating gate structure layer in the photoresist layer exposed region is removed, and make the floating gate Structure sheaf has residual;
Step 4, the floating gate knot using high selectivity etching technics to the residual in the photoresist layer exposed region Structure layer performs etching, to remove the floating gate structure layer in the photoresist layer exposed region, and the shallow trench isolation junction completely The surface of structure is not etched
As further preferred embodiment, the etch period of step 2 of the present invention is 2s-5s so that the shallow ridges The remaining balance scope of control gate structure sheaf above recess isolating structure is 400
As further preferred embodiment, the etch period of step 3 of the present invention is 25s-35s, and etching temperature is 40 DEG C -60 DEG C so that the remaining balance scope of the floating gate structure layer is 200
As further preferred embodiment, for the present invention in the step 1, the material of the gate dielectric layer is oxidation Silicon, the material of the floating gate structure layer are polysilicon, and the material of dielectric layer is silica or silicon nitride between the grid, the control The material of grid structure sheaf processed is polysilicon.
As further preferred embodiment, the present invention in the step 3, the synchronous etching using have it is each to The plasma etching industrial of anisotropic etch ability.
As further preferred embodiment, plasma etching industrial of the present invention is to polysilicon, silica, silicon nitride Selection compare for 1:1:1.
As further preferred embodiment, the plasma source power of plasma etching industrial of the present invention is 600W- 900W, it is 80V-150V that bias, which sets scope, and etching air pressure range is 3-8MT, gas CF4, gas flow 100sccm.
As further preferred embodiment, the scope of the etch period of step 4 of the present invention is 20s-30s, etching The scope of speed is
As further preferred embodiment, in the step 4, the high selectivity etching technics uses the present invention Be HBr and O2Mixed gas, selection of the high selectivity etching technics to polysilicon and silica compare for 100:1.
As further preferred embodiment, HBr and O of the present invention2Mixed gas volume ratio be 100:1.
Above-mentioned technical proposal has the following advantages that or beneficial effect:
(1) because the etching mode that the present invention uses is that dielectric layer the grid and the floating gate structure are synchronized Lithographic method, the lithographic method can effectively reduce the loss of shallow trench isolation region, be beneficial to subsequent technique, and finally improve and partly lead The Performance And Reliability of body device.This method is used simultaneously, technique is simple, saves the production time, improves production efficiency.
(2) because the synchronous etching is using the plasma etching industrial with anisotropic etching ability.Can be to figure Shape accurately controls, and etching forming effect is good.
Brief description of the drawings
With reference to appended accompanying drawing, more fully to describe embodiments of the invention.However, appended accompanying drawing be merely to illustrate and Illustrate, and be not meant to limit the scope of the invention.
Fig. 1 is the etch process flow figure of control gate in the prior art;
Fig. 2 (a) is the structural representation of step 1 of the present invention;
Fig. 2 (b) is structural representation of the present invention after step 2 is handled;
Fig. 2 (c) is structural representation of the present invention after step 3 is handled;
Fig. 2 (d) is structural representation of the present invention after step 4 is handled.
Embodiment
The present invention provides a kind of memory cell grid preparation method of flash memory, and can be applied to technology node is 45/40nm's In technique;It can be applied in Flash technology platform.
The core concept of the present invention is the quarter by that will synchronize lithographic method to dielectric layer grid and floating gate structure Etching method can effectively reduce the loss of shallow trench isolation region, be beneficial to subsequent technique, and finally improve the performance of semiconductor devices And reliability.This method is used simultaneously, technique is simple, saves the production time, improves production efficiency.
The inventive method is described in detail below in conjunction with the accompanying drawings.
The invention will be further described with specific embodiment below in conjunction with the accompanying drawings, but not as limiting to the invention.
A kind of memory cell grid preparation method of flash memory, comprises the following steps:
Step 1, sequentially formed as Fig. 2 (a) is shown in a semiconductors coupling structure with fleet plough groove isolation structure 6 Gate dielectric layer 4, floating gate structure layer 3, dielectric layer 2 and control gate structure sheaf 1 between grid, and in the surface of control gate structure sheaf 1 Form patterning photoresist layer;
Step 2, as Fig. 2 (b) according to it is described patterning photoresist layer the control gate structure sheaf 1 is performed etching, with remove The control gate structure sheaf 1 positioned at the top of floating gate structure layer 3 in the photoresist layer exposed region, and make the shallow trench The control gate structure sheaf 1 of the top of isolation structure 6 has residual;
Step 3, if Fig. 2 (c) is dielectric layer 2 the control gate structure sheaf 1, the grid and the floating gate structure layer 3 Etching is synchronized, to remove the institute of the top of the fleet plough groove isolation structure 6 residual in the photoresist layer exposed region completely Control gate structure sheaf 1 is stated, and removes the top of the floating gate structure layer 3 in the photoresist layer exposed region, described completely Dielectric layer 2 between the grid of the both sides of floating gate structure layer 3, and remove completely the shallow trench in the photoresist layer exposed region every From the gate dielectric layer 4 at the top of structure 6, and remove the certain thickness floating gate structure layer in the photoresist layer exposed region 3, and the floating gate structure layer 3 is had residual;
Step 4, Fig. 2 (d) uses high selectivity etching technics to as described in the residual in the photoresist layer exposed region Floating gate structure layer 3 performs etching, to remove the floating gate structure layer 3 in the photoresist layer exposed region completely, and it is described shallow The surface of groove isolation construction 6 is not etched.
Pass through above step:The present invention first one have fleet plough groove isolation structure semiconductors coupling structure on according to Secondary formation gate dielectric layer, floating gate structure layer, dielectric layer and control gate structure sheaf between grid, and formed in control gate structure layer surface Pattern photoresist layer;Then the etching of the control gate structure sheaf above floating gate structure layer in photoresist layer exposed region, And the control gate structure sheaf above fleet plough groove isolation structure is set to have residual;Then dielectric layer grid and floating gate structure are carried out same Step etching, and floating gate structure layer is had residual;Finally using high selectivity etching technics to residual in photoresist layer exposed region The floating gate structure layer stayed performs etching, to remove the floating gate structure layer in removing photoresistance layer exposed region completely.Due to the present invention The etching mode of use is to synchronize lithographic method to dielectric layer grid and floating gate structure, and the lithographic method can effectively subtract The loss of few shallow trench isolation region, it is beneficial to subsequent technique, and finally improves the Performance And Reliability of semiconductor devices.Use simultaneously This method, technique is simple, saves the production time, improves production efficiency.
As further preferred embodiment, the etch period of step 2 of the present invention is 2s-5s so that the shallow ridges The remaining balance scope of the control gate structure sheaf 1 of the top of recess isolating structure 6 is
As further preferred embodiment, the etch period of step 3 of the present invention is 25s-35s, and etching temperature is 40 DEG C -60 DEG C so that the remaining balance scope of the floating gate structure layer 3 is
As further preferred embodiment, in the present invention in step 1, the material of the gate dielectric layer 4 is oxidation Silicon, the material of the floating gate structure layer 3 are polysilicon, and the material of dielectric layer 2 is silica or silicon nitride or two between the grid The mixed layer of silica silicon nitride silica, the material of the control gate structure sheaf 1 is polysilicon.
As further preferred embodiment, in the present invention in step 3, synchronous etching is carved using having anisotropy The plasma etching industrial of erosion ability, it is good that forming effect can be etched to the accurate control of figure.
As further preferred embodiment, plasma etching industrial is to polysilicon, silica, silicon nitride in the present invention Selection ratio is 1:1:1, polysilicon, silica, silicon nitride can be performed etching simultaneously, improve the degree of accuracy of etching.
As further preferred embodiment, the plasma source power of plasma etching industrial is 600W- in the present invention 900W, it is 80V-150V that bias, which sets scope, and etching air pressure range is 3-8MT, gas CF4, gas flow 100sccm.
As further preferred embodiment, the scope of the etch period of step 4 is 20s-30s in the present invention, etching speed The scope of rate is
As further preferred embodiment, in the present invention in step 4, high selectivity etching technics is using HBr With O2Mixed gas.Selection of the high selectivity etching technics to polysilicon and silica is compared for 100:1, the high selectivity Etching technics can ensure that shallow trench isolation region will not be performed etching, and shallow trench isolation region will not be caused damage.
As further preferred embodiment, HBr and O in the present invention2Mixed gas volume ratio be 100:1.
Preferred embodiments of the present invention are these are only, not thereby limit embodiments of the present invention and protection domain, it is right For those skilled in the art, it should can appreciate that and all be replaced with being equal made by description of the invention and diagramatic content Change and obviously change resulting scheme, should be included in protection scope of the present invention.

Claims (9)

1. the memory cell grid preparation method of a kind of flash memory, it is characterised in that comprise the following steps:
Step 1, in sequentially forming gate dielectric layer (4) in the semiconductors coupling structure that one has fleet plough groove isolation structure (6), float Moving grid structure sheaf (3), dielectric layer (2) and control gate structure sheaf (1) between grid, and formed in control gate structure sheaf (1) surface Pattern photoresist layer;
Step 2, the control gate structure sheaf (1) is performed etching according to the patterning photoresist layer, to remove the photoresist layer The control gate structure sheaf (1) above the floating gate structure layer (3) in exposed region, and make the shallow trench isolation junction Control gate structure sheaf (1) above structure (6) has residual;
Step 3, dielectric layer (2) the control gate structure sheaf (1), the grid and the floating gate structure layer (3) are carried out same Step etching, to remove the control of residual above the fleet plough groove isolation structure (6) in the photoresist layer exposed region completely Grid structure sheaf (1) processed, and remove completely at the top of the floating gate structure layer (3) in the photoresist layer exposed region, be described Dielectric layer (2) between the grid of floating gate structure layer (3) both sides, and the shallow ridges in the photoresist layer exposed region is removed completely Gate dielectric layer (4) at the top of recess isolating structure (6), and remove the certain thickness floating in the photoresist layer exposed region Grid structure sheaf (3), and the floating gate structure layer (3) is had residual;
Step 4, the floating gate structure layer using high selectivity etching technics to the residual in the photoresist layer exposed region (3) perform etching, to remove the floating gate structure layer (3) in the photoresist layer exposed region completely, and the shallow trench is isolated The surface of structure (6) is not etched;
Wherein, the etch period of the step 2 is 2s-5s so that the control gate knot above the fleet plough groove isolation structure (6) The remaining balance scope of structure layer (1) is
A kind of 2. memory cell grid preparation method of flash memory according to claim 1, it is characterised in that the step 3 Etch period be 25s-35s, etching temperature is 40 DEG C -60 DEG C so that the remaining balance scope of the floating gate structure layer (3) For
3. the memory cell grid preparation method of a kind of flash memory according to claim 1, it is characterised in that in the step In one, the material of the gate dielectric layer (4) is silica, and the material of the floating gate structure layer (3) is polysilicon, between the grid The material of dielectric layer (2) is silica or silicon nitride, and the material of the control gate structure sheaf (1) is polysilicon.
4. the memory cell grid preparation method of a kind of flash memory according to claim 3, it is characterised in that in the step In rapid three, the synchronous etching is using the plasma etching industrial with anisotropic etching ability.
A kind of 5. memory cell grid preparation method of flash memory according to claim 4, it is characterised in that:The plasma Selection of the etching technics to polysilicon, silica, silicon nitride is compared for 1:1:1.
A kind of 6. memory cell grid preparation method of flash memory according to claim 4, it is characterised in that:The plasma The plasma source power of etching technics is 600W-900W, and it is 80V-150V that bias, which sets scope, and etching air pressure range is 3-8MT, Gas is CF4, gas flow 100sccm.
A kind of 7. memory cell grid preparation method of flash memory according to claim 1, it is characterised in that:The step 4 The scope of etch period be 20s-30s, the scope of etch rate is
A kind of 8. memory cell grid preparation method of flash memory according to claim 3, it is characterised in that:In the step In four, the high selectivity etching technics is using HBr and O2Mixed gas, the high selectivity etching technics is to polycrystalline The selection of silicon and silica is compared for 100:1.
A kind of 9. memory cell grid preparation method of flash memory according to claim 8, it is characterised in that:The HBr and O2 Mixed gas volume ratio be 100:1.
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CN108133887B (en) * 2017-12-04 2019-07-02 扬州国宇电子有限公司 Flattening method based on deep etching
CN113097211A (en) * 2020-01-09 2021-07-09 联华电子股份有限公司 Non-volatile memory element and its manufacturing method

Citations (2)

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Publication number Priority date Publication date Assignee Title
US6153469A (en) * 1998-07-13 2000-11-28 Samsung Electronics, Co., Ltd. Method of fabricating cell of flash memory device
CN103077925A (en) * 2011-10-25 2013-05-01 中芯国际集成电路制造(上海)有限公司 Manufacturing method for memory

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US20030054608A1 (en) * 2001-09-17 2003-03-20 Vanguard International Semiconductor Corporation Method for forming shallow trench isolation in semiconductor device

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US6153469A (en) * 1998-07-13 2000-11-28 Samsung Electronics, Co., Ltd. Method of fabricating cell of flash memory device
CN103077925A (en) * 2011-10-25 2013-05-01 中芯国际集成电路制造(上海)有限公司 Manufacturing method for memory

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