CN104532302A - Wet-process discharge type ore pulp electrolytic lead device - Google Patents
Wet-process discharge type ore pulp electrolytic lead device Download PDFInfo
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- CN104532302A CN104532302A CN201510012355.7A CN201510012355A CN104532302A CN 104532302 A CN104532302 A CN 104532302A CN 201510012355 A CN201510012355 A CN 201510012355A CN 104532302 A CN104532302 A CN 104532302A
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- electrolytic
- discharge type
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- storage barrel
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- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 45
- 239000007788 liquid Substances 0.000 claims abstract description 34
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 238000003860 storage Methods 0.000 claims abstract description 18
- 239000007791 liquid phase Substances 0.000 claims description 14
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 7
- 229920001195 polyisoprene Polymers 0.000 claims description 7
- 230000003028 elevating effect Effects 0.000 claims description 6
- 239000007790 solid phase Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 abstract description 8
- 238000007599 discharging Methods 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- 239000012528 membrane Substances 0.000 abstract 4
- 238000000265 homogenisation Methods 0.000 abstract 1
- 238000010408 sweeping Methods 0.000 abstract 1
- 230000001360 synchronised effect Effects 0.000 abstract 1
- 239000011133 lead Substances 0.000 description 28
- 239000000126 substance Substances 0.000 description 13
- 150000002500 ions Chemical class 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000009471 action Effects 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 238000002955 isolation Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000000866 electrolytic etching Methods 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses a wet-process discharge type ore pulp electrolytic lead device. An electrolytic membrane for containing ore pulp is arranged in an electrolytic tank body, and a stirring device is arranged in an electrolytic membrane cavity; the electrolytic membrane cavity is connected with the electrolytic tank body through an axial flow pump and a pipe; the electrolytic tank body is of a conic bottom structure, the conic bottom is provided with an axial stirring paddle and a spiral conveyor, and a knocking device is arranged outside the conic bottom; the conic bottom is connected with a temporary storage barrel through a collecting hopper, a discharging pump and a conveying pipe, a bib and a valve are arranged at the bottom of the temporary storage barrel, a filter net is arranged in the temporary storage barrel to be connected with a circulation pump, and an outlet of a pipe of the circulation pump is connected with the electrolytic membrane cavity. By means of the wet-process discharge type ore pulp electrolytic lead device, low-speed long-paddle large-area sweeping is adopted, so that coincident temperature density is achieved with low energy consumption; the knocking device and the spiral conveyor conduct synchronous and reasonable interruption starting, so that continuous tank bottom cleaning and sedimentation sponge lead discharging are achieved with low energy consumption; liquid circulation homogenization electrolysis is achieved through the axial flow pump and the pump, and the wet-process discharge type ore pulp electrolytic lead device is suitable for industrialization use and wide in prospect.
Description
Technical field
The present invention relates to the plumbous device of a kind of wet method discharge type in-pulp electrolysis, be especially applicable to electrolysis ore pulp and use.
Background technology
Electrolyzer is the key equipment supporting the electrolytic etching of metal industry such as lead, zinc, manganese, aluminium, but existing electrolyzer mostly can only electrolytic solution, and can not electrolysis ore pulp, namely first must be prepared into electrolytic solution before electrolysis and just can carry out electrolysis.
Breeze being prepared into electrolytic solution needs through multiple steps such as chemical combination, dissolving, press filtration and removal of impurities, the many costs of step are high, certain loss is also there is in preparation process, if breeze directly can be made in electrolyzer ore pulp to carry out electrolysis, just can significantly Simplified flowsheet, cut down the number of intermediate links, cost-saving and improve the yield of product.
In-pulp electrolysis essence is exactly in electrolyzer, add breeze and corresponding acid, electrolysis procedure is carried out after directly carrying out the combination reaction of breeze and acid, namely chemical combination and electrolysis is carried out simultaneously, the advantage of this operation is can significantly Simplified flowsheet, make chemical combination, removal of impurities, electrolysis completes jointly in groove, omit the operations such as press filtration, also a lot of reservoirs can be reduced the while of cost-effective, a large amount of sulfuric acid that electrolytic anode produces simultaneously can carry out constantly reacting making with breeze, lead in breeze constantly dissolves in the form of an ion, promote to obtain higher electrolytic lead quality and productive rate.
For electrolytic lead, in-pulp electrolysis effectively can simplify hydrometallurgical processes process and reduce costs, but plumbous in-pulp electrolysis faces many difficulties in commercial application, such as realize in whole very long electrolyzer stable ore pulp suspension electrolysis, the homogenizing of ion concentration distribution, ore pulp reaction zone and electrolysis zone liquid circulate, the discharging depositing spongy lead etc., these technical problems not obtaining solving very well directly affects the application and development of the plumbous electrolysis tech of ore pulp.
Summary of the invention
The technical problem to be solved in the present invention overcomes the deficiencies in the prior art exactly, provides that a kind of structure is simple, the plumbous device of the wet method discharge type in-pulp electrolysis of perfect in shape and function.
For overcoming the deficiencies in the prior art, the present invention takes following technical scheme:
The plumbous device of a kind of wet method discharge type in-pulp electrolysis, comprises electrolyzer casing, public copper bar and electrolytic pole board, it is characterized in that: be provided with the electrolytic film placing ore pulp in electrolyzer casing, be provided with whipping appts in electrolytic film cavity; Electrolytic film cavity and electrolyzer casing have propeller pump and pipeline to be connected; Electrolyzer casing is cone bottom structure, the cone end, is provided with axial stirring paddle and spiral conveyer, and cone outside, the end is provided with knocker, and knocker is made up of rubber sphere, rope, rotary drum and rotating shaft, rotary drum connects elastic caoutchouc ball by rope, and shaft length and cell bottom appearance adapt to; The cone end, connects temporary storage barrel through aggregate bin, Send out pump, carrier pipe, is provided with valve and valve bottom temporary storage barrel, is provided with filter screen and connects recycle pump in temporary storage barrel, and the pipe outlet of pump connects electrolytic film cavity.
Described whipping appts is made up of motor and step-down gear, stir shaft and stirring rake.
Be provided with spiral separator below described temporary storage barrel, spiral separator is driven by motor and belt pulley and is provided with liquid-phase outlet and solid phase groove.
Described filter screen connects elevating lever, and the height being convenient to adjust filter screen carries out suction filtration liquid.
The pipe outlet of described recycle pump and and electrolytic film cavity between be also provided with barrel for storing liquid and control valve.
Be provided with removable fan near described electrolyzer casing, the wind of surfactant suspension spongy lead can be concentrated by fan, is convenient to eliminate suspend.
Electrolyzer casing can adopt propylene material to make, anticorrosion and resistance to certain temperature, pole plate is anode and cathode interval array mode, positive plate has more negative plate one piece and is convenient to all negative plate two sides and electrolysis can analyses lead, assembling made by the electrolytic film filter cloth of suitable order number and thickness, play isolation slag but by ion and liquid, realize electrolysis.
For stirring chemical combination system in electrolytic film cavity, in the scope of barrier film isolation, acid can constantly be reacted with breeze, and liquid and metal ion pass barrier film, cleaning tank room electrolysis lead bullion product and separate out on negative plate two sides.
Generally long about six meters, the plumbous device of type of production in-pulp electrolysis, can produce more spongy lead deposit electrolyte trench bottom with electrolysis, can be produced the gas flotation effect of separating out on a small quantity float on electrolyte surface by electrolysis.Spongy lead is different plumbous product, and can progressively export is that advantageous particularly continuous prodution is raised the efficiency, and the inhibition of barrier film also inhibits the homogenizing of tank room ionic concn, so the plumbous device of in-pulp electrolysis need break through these technical bottlenecks.
Micro-lift propeller pump starts can extract low ion concns liquid in tank room, is entered the chemical combination system in electrolytic film cavity by liquid circulation tube, and the acid that electrolysis produces also returns in electrolytic film cavity thereupon reacts chemical combination again; The input of liquid makes liquid level in electrolytic film cavity slightly rise, and promotes that pressure reduction is set up, and makes chemical combination in electrolytic film cavity produce high ion concentration liquid and can accelerate to enter tank room through electrolytic film, realize cyclic electrolysis function.
Electrolyzer axially long stirring rake slow circumvolve can strength of fluid and temperature between homogenizing pole plate, spongy lead can be concentrated to aggregate bin in groove cone bottom by spiral conveyer, be convenient to export, groove cone bottom gradient can deposit material not, gradient is crossed conference and is made that shape and structure is too high unfavorablely optimizes structure, so design knocker; Knocker is made up of rotating shaft and rotary drum, rotary drum connects elastic caoutchouc ball by rope, shaft length and cell bottom appearance adapt to, rotate with applicable rotating speed, elastic caoutchouc club is centrifuged effect and is connected to form emitting shape scatters with rope, knock bottom of electrolytic tank inclined-plane as countless yo-yos, promote that sedimentation spongy lead is concentrated to bottom land spiral conveyer, realize well exporting.
Knocker work can produce good oscillating action and active area is very large, any surface can be adapted to very well, if to axially and be radially optimized that spheroid mass, density, rope are long, Design of Rotation can obtain fabulous vibrated material liquid internal inclined-plane downslide action effect, and simple for structure, to equipment without any damage.
Spongy lead concentrates on hopper, concentrate and carry by Cemented filling temporary at temporary storage barrel by pump liquid stream, spongy lead sedimentation liquid phase can be convenient to control suction strainer height by strainer filtering, elevating lever and be convenient to liquid phase at utmost to absorb extraction, connect pump by pipeline and realize circulation, liquid phase is kept at barrel for storing liquid, return chemical combination system by Valve controlling, solid phase sedimentation is complete by control valve discharge opeing, opens valve and carries out spongy lead quickly discharging.
Adopt spiral continuous separating machine to the quick centrifugation of control valve conveying liquid, small end can obtain spongy lead and fall into hopper, and liquid phase is exported by spiral continuous separating machine liquid-phase outlet, carries out returning circulation.
Compared with prior art, beneficial effect of the present invention is also:
Low speed sweep leaf big area is swept more applicable long-time less energy-consumption and is stirred, and realizes cell liquid concentration-temperature and remains consistent; Knocker and spiral conveyer carry out synchronously rationally intermittently starting, and realize less energy-consumption and clear up bottom land continuously and sedimentation spongy lead exports; Propeller pump and pump two kinds of patterns are combined, and realize the electrolysis of liquid circulation homogenizing.
Present system is simple for structure rationally, be convenient to implement, and is especially applicable to industrialization and uses, have a extensive future.
Accompanying drawing explanation
Fig. 1 is two dimensional structure schematic diagram of the present invention.
Fig. 2 is left TV structure schematic diagram of the present invention.
Fig. 3 is the structural representation of knocker.
In figure, each label represents:
1, motor and step-down gear; 2, stir shaft; 3, stirring rake; 4, electrolytic film; 5, propeller pump; 6, electrolyzer casing; 7, axial stirring paddle; 8, spiral conveyer; 9, fan; 10, liquid circulation tube; 11, public copper bar; 12, electrolytic pole board; 13, knocker; 14, the electrolyzer cone end; 21, aggregate bin; 22, Send out pump; 23, carrier pipe; 24, temporary storage barrel; 25, valve; 26, valve; 27, motor and belt pulley; 28, spiral separator; 29, liquid-phase outlet; 30, solid phase groove; 31, filter screen; 32, elevating lever; 33, recycle pump; 34, pipeline; 35, barrel for storing liquid; 36, control valve; 41, rubber sphere; 42, rope; 43, rotary drum; 44, rotating shaft.
Embodiment
Now by reference to the accompanying drawings, the present invention is illustrated further.
The plumbous device of wet method discharge type in-pulp electrolysis, comprises electrolyzer casing 6, public copper bar 11 and electrolytic pole board 12, is provided with the electrolytic film 4 placing ore pulp, is provided with whipping appts in electrolytic film 4 cavity in electrolyzer casing 6 as shown in Figure 1, Figure 2 and Figure 3; Electrolytic film 4 cavity and electrolyzer casing 6 have propeller pump 5 and pipeline 10 to be connected; Electrolyzer casing 6 is the cone end 14 structure, the cone end 14, is provided with axial stirring paddle 7 and spiral conveyer 8, cone outside, the end is provided with knocker 13, knocker is made up of rubber sphere 41, rope 42, rotary drum 43 and rotating shaft 44, rotary drum 43 connects elastic caoutchouc ball 41 by rope 42, and shaft length and cell bottom appearance adapt to; The cone end 14, connects temporary storage barrel 24 through aggregate bin 21, Send out pump 22, carrier pipe 23, is provided with valve 25 and valve 26, is provided with filter screen 31 and connects recycle pump 33 in temporary storage barrel 24 bottom temporary storage barrel 24, and the pipe outlet of pump 33 connects electrolytic film 4 cavity.
Described whipping appts is made up of motor and step-down gear 1, stir shaft 2 and stirring rake 3.
Be provided with spiral separator 28 below described temporary storage barrel 24, spiral separator is driven by motor and belt pulley 27 and is provided with liquid-phase outlet 29 and solid phase groove 30.
Described filter screen 31 connects elevating lever 32, and the height being convenient to adjust filter screen 31 carries out suction filtration liquid.
The pipeline 34 of described recycle pump 33 export and and electrolytic film 4 cavity between be also provided with barrel for storing liquid 35 and control valve 36.
Be provided with removable fan 9 near described electrolyzer casing 6, the wind of surfactant suspension spongy lead can be concentrated by fan 9, is convenient to eliminate suspend.
Electrolyzer casing 6 can adopt propylene material to make, anticorrosion and resistance to certain temperature, pole plate is anode and cathode interval array mode, positive plate has more negative plate one piece and is convenient to all negative plate two sides and electrolysis can analyses lead, assembling made by electrolytic film 4 filter cloth of suitable order number and thickness, play isolation slag but by ion and liquid, realize electrolysis.
For stirring chemical combination system in electrolytic film 4 cavity, in the scope of barrier film isolation, acid can constantly be reacted with breeze, and liquid and metal ion pass barrier film 4, cleaning tank room electrolysis lead bullion product and separate out on negative plate two sides.
Generally long about six meters, the plumbous device of type of production in-pulp electrolysis, can produce more spongy lead deposit electrolyte trench bottom with electrolysis, can be produced the gas flotation effect of separating out on a small quantity float on electrolyte surface by electrolysis.Spongy lead is different plumbous product, and can progressively export is that advantageous particularly continuous prodution is raised the efficiency, and the inhibition of barrier film 4 also inhibits the homogenizing of tank room ionic concn, so the plumbous device of in-pulp electrolysis need break through these technical bottlenecks.
Micro-lift propeller pump 5 starts can extract low ion concns liquid in tank room, enters the chemical combination system in electrolytic film 4 cavity by liquid circulation tube 10, and the acid that electrolysis produces also returns in electrolytic film 4 cavity thereupon reacts chemical combination again; The input of liquid makes liquid level in electrolytic film 4 cavity slightly rise, and promotes that pressure reduction is set up, and makes chemical combination in electrolytic film 4 cavity produce high ion concentration liquid and can accelerate to enter tank room through electrolytic film 4, realize cyclic electrolysis function.
Electrolyzer axially long stirring rake 7 slow circumvolve can homogenizing pole plate 12 strength of fluids and temperature, spongy lead can be concentrated to aggregate bin 21 in groove cone bottom 14 by spiral conveyer 8, be convenient to export, groove cone bottom 14 gradients can deposit material not, gradient is crossed conference and is made that shape and structure is too high unfavorablely optimizes structure, so design knocker 13; Knocker is made up of rotating shaft 44 and rotary drum 43, rotary drum 43 connects elastic caoutchouc ball 41 by rope 42, shaft length and cell bottom appearance adapt to, rotate with applicable rotating speed, elastic caoutchouc ball 41 can be centrifuged effect and be connected to form emitting shape scatter with rope 42, knock bottom of electrolytic tank inclined-plane as countless yo-yos, promote that sedimentation spongy lead is concentrated to bottom land spiral conveyer 8, realize well exporting.
Knocker 13 work can produce good oscillating action and active area is very large, any surface can be adapted to very well, if to axially and be radially optimized that spheroid mass, density, rope are long, Design of Rotation can obtain fabulous vibrated material liquid internal inclined-plane downslide action effect, and simple for structure, to equipment without any damage.
Spongy lead concentrates on hopper 21, concentrate and carry by Cemented filling temporary at temporary storage barrel 24 by pump 22 liquid stream, spongy lead sedimentation liquid phase can be filtered by filter screen 31, elevating lever 32 is convenient to control suction strainer 31 and is highly convenient to liquid phase at utmost to absorb extraction, connect pump 33 by pipeline and realize circulation, liquid phase is kept at barrel for storing liquid 35, control to return chemical combination system by valve 36, solid phase sedimentation is complete by valve 26 discharge opeing, opens valve 25 and carries out spongy lead quickly discharging.
Adopt the quick centrifugation of spiral continuous separating machine 28 pairs of control valve 26 conveying liquids, small end can obtain spongy lead and fall into hopper 30, and liquid phase is exported by spiral continuous separating machine liquid-phase outlet 29, carries out returning circulation.
Above-mentioned just preferred embodiment of the present invention, not does any pro forma restriction to the present invention.Any those of ordinary skill in the art, when not departing from technical solution of the present invention scope, can utilize the technology contents of above-mentioned announcement to make many possible variations and modification to technical solution of the present invention, or being revised as the Equivalent embodiments of equivalent variations.Therefore, every content not departing from technical solution of the present invention, according to the technology of the present invention essence to any simple modification made for any of the above embodiments, equivalent variations and modification, all should drop in the scope of technical solution of the present invention protection.
Claims (6)
1. the plumbous device of wet method discharge type in-pulp electrolysis, comprises electrolyzer casing, public copper bar and electrolytic pole board, it is characterized in that: be provided with the electrolytic film placing ore pulp in electrolyzer casing, be provided with whipping appts in electrolytic film cavity; Electrolytic film cavity and electrolyzer casing have propeller pump and pipeline to be connected; Electrolyzer casing is cone bottom structure, the cone end, is provided with axial stirring paddle and spiral conveyer, and cone outside, the end is provided with knocker, and knocker is made up of rubber sphere, rope, rotary drum and rotating shaft, rotary drum connects elastic caoutchouc ball by rope, and shaft length and cell bottom appearance adapt to; The cone end, connects temporary storage barrel through aggregate bin, Send out pump, carrier pipe, is provided with valve and valve bottom temporary storage barrel, is provided with filter screen and connects recycle pump in temporary storage barrel, and the pipe outlet of pump connects electrolytic film cavity.
2. the plumbous device of wet method discharge type in-pulp electrolysis according to claim 1, is characterized in that: described whipping appts is made up of motor and step-down gear, stir shaft and stirring rake.
3. the plumbous device of wet method discharge type in-pulp electrolysis according to claim 1 and 2, it is characterized in that: be provided with spiral separator below described temporary storage barrel, spiral separator is driven by motor and belt pulley and is provided with liquid-phase outlet and solid phase groove.
4. the plumbous device of wet method discharge type in-pulp electrolysis according to claim 1, is characterized in that: described filter screen connects elevating lever, and the height being convenient to adjust filter screen carries out suction filtration liquid.
5. the plumbous device of wet method discharge type in-pulp electrolysis according to claim 1, is characterized in that: the pipe outlet of described recycle pump and and electrolytic film cavity between be also provided with barrel for storing liquid and control valve.
6. the plumbous device of wet method discharge type in-pulp electrolysis according to claim 1 or 5, is characterized in that: be provided with removable fan near described electrolyzer casing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510012355.7A CN104532302B (en) | 2015-01-12 | 2015-01-12 | Wet method discharge type in-pulp electrolysis lead device |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510012355.7A CN104532302B (en) | 2015-01-12 | 2015-01-12 | Wet method discharge type in-pulp electrolysis lead device |
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| CN104532302A true CN104532302A (en) | 2015-04-22 |
| CN104532302B CN104532302B (en) | 2016-08-24 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107923057A (en) * | 2015-05-13 | 2018-04-17 | 艾库伊金属有限公司 | Electro-deposition lead composition, production method and purposes |
| CN109317006A (en) * | 2018-10-30 | 2019-02-12 | 安溪迈速则机械设计有限公司 | The medicament jar agitator of high-turbidity seawater desalination |
| US10316420B2 (en) | 2015-12-02 | 2019-06-11 | Aqua Metals Inc. | Systems and methods for continuous alkaline lead acid battery recycling |
| US10340561B2 (en) | 2013-11-19 | 2019-07-02 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
| US10793957B2 (en) | 2015-05-13 | 2020-10-06 | Aqua Metals Inc. | Closed loop systems and methods for recycling lead acid batteries |
| CN112064062A (en) * | 2020-11-10 | 2020-12-11 | 矿冶科技集团有限公司 | Method for preparing crude lead by waste lead plaster without pre-desulfurization combined electrolysis |
| CN112159670A (en) * | 2020-10-03 | 2021-01-01 | 王小莉 | Coke oven filling device |
| US11028460B2 (en) | 2015-05-13 | 2021-06-08 | Aqua Metals Inc. | Systems and methods for recovery of lead from lead acid batteries |
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| CN204385306U (en) * | 2015-01-12 | 2015-06-10 | 吉首大学 | The plumbous device of wet method discharge type in-pulp electrolysis |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10340561B2 (en) | 2013-11-19 | 2019-07-02 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
| US11239507B2 (en) | 2013-11-19 | 2022-02-01 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
| US10665907B2 (en) | 2013-11-19 | 2020-05-26 | Aqua Metals Inc. | Devices and method for smelterless recycling of lead acid batteries |
| CN107923057B (en) * | 2015-05-13 | 2020-07-14 | 艾库伊金属有限公司 | Electrodeposited lead compositions, methods of production and uses |
| US10689769B2 (en) | 2015-05-13 | 2020-06-23 | Aqua Metals Inc. | Electrodeposited lead composition, methods of production, and uses |
| CN107923057A (en) * | 2015-05-13 | 2018-04-17 | 艾库伊金属有限公司 | Electro-deposition lead composition, production method and purposes |
| US10793957B2 (en) | 2015-05-13 | 2020-10-06 | Aqua Metals Inc. | Closed loop systems and methods for recycling lead acid batteries |
| US11028460B2 (en) | 2015-05-13 | 2021-06-08 | Aqua Metals Inc. | Systems and methods for recovery of lead from lead acid batteries |
| US10316420B2 (en) | 2015-12-02 | 2019-06-11 | Aqua Metals Inc. | Systems and methods for continuous alkaline lead acid battery recycling |
| US11072864B2 (en) | 2015-12-02 | 2021-07-27 | Aqua Metals Inc. | Systems and methods for continuous alkaline lead acid battery recycling |
| CN109317006A (en) * | 2018-10-30 | 2019-02-12 | 安溪迈速则机械设计有限公司 | The medicament jar agitator of high-turbidity seawater desalination |
| CN112159670A (en) * | 2020-10-03 | 2021-01-01 | 王小莉 | Coke oven filling device |
| CN112064062A (en) * | 2020-11-10 | 2020-12-11 | 矿冶科技集团有限公司 | Method for preparing crude lead by waste lead plaster without pre-desulfurization combined electrolysis |
| CN112064062B (en) * | 2020-11-10 | 2021-02-12 | 矿冶科技集团有限公司 | Method for preparing crude lead by waste lead plaster without pre-desulfurization combined electrolysis |
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| Publication number | Publication date |
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| CN104532302B (en) | 2016-08-24 |
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