CN104530880A - 一种智能调温节能型外墙用乳胶漆 - Google Patents

一种智能调温节能型外墙用乳胶漆 Download PDF

Info

Publication number
CN104530880A
CN104530880A CN201410768393.0A CN201410768393A CN104530880A CN 104530880 A CN104530880 A CN 104530880A CN 201410768393 A CN201410768393 A CN 201410768393A CN 104530880 A CN104530880 A CN 104530880A
Authority
CN
China
Prior art keywords
emulsion paint
year
winter
summer
energy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410768393.0A
Other languages
English (en)
Inventor
唐云
罗克川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201410768393.0A priority Critical patent/CN104530880A/zh
Publication of CN104530880A publication Critical patent/CN104530880A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/16—Halogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明提供了一种智能调温节能型外墙用乳胶漆配方，采用了具有温致变化吸收率和发射率性能的常温吸收发射常温可逆转换材料和热发射率可逆转换材料制成，可使冬冷夏热地区建筑物室内温度，在不消耗矿物能源的情况下冬季同比升高5-15℃、夏季同比下降5-15℃，具有良好的使用耐候性、更环保、使用寿命更长且材料更易制备，制作成本更低等特点。

Description

一种智能调温节能型外墙用乳胶漆
技术领域：
本发明涉及一种用于住房、办公室、公共场所室外墙体的涂装材料及其制备方法，属于材料科学与工程科学技术领域。
背景技术：
房屋的冬暖夏凉是人类自古以来追求的梦想，遗憾的是现实中往往出现冬冷夏热，房屋建筑本身由于自身的限制很难达到冬暖夏凉的作用。近代以来，随着科技进步，建筑行业也步入高速发展阶段，各种新技术，新材料成功的运用到建筑上，很大程度的改善了建筑的功能，人类的居住环境也越来越舒适。
此前的研究发现，材料日间暴晒效果主要受其太阳吸收率的影响，与发射率无关；材料夜间辐射致冷效果与发射率相关，与太阳吸收率无关。所以从调节建筑热舒适角度看，不同地区建筑对建筑材料热物性有不同的要求：寒冷地区要求材料高太阳吸收率，低发射率的性质；炎热地区要求材料具有低太阳吸收率，高发射率的性质；冬冷夏热地区，则要求材料在冬季具有高太阳吸收率，低发射率性质，到了夏季则转变为低太阳吸收率，高发射率性质。此前对常规建筑材料日间曝晒和夜间辐射致冷热效果进行了研究，从调节室内热环境看常规建材并不适合任何地区使用。由上可知，营造建筑热舒适环境需要一种在夏季能大量反射太阳辐射且能大量发射自身热量、到冬季应转换成能大量吸收太阳辐射且很少发射自身热量、且转换温度约为18℃(建筑热舒适温度)的建筑材料，即所谓空调型建筑材料。考虑到材料对太阳能的吸收和自身的热发射均发生于材料表面，因而，采用吸收发射常温可逆转换材料和热发射率可逆转换材料作为建筑外墙涂料能够取得“空调式”的效果。在近年来对于空调型建筑涂料的研制应用是一种综合趋势。
现有的空调型建筑涂料通常使用水溶性尿醛树脂作为粘结剂，并且选用的温度可逆转换材料种类太单一，因而存在热转换温度不稳定、可调温度范围偏小，采用的粘结剂长期释放甲醛，不利于环保。而且通常采用了三芳甲烷乙内酯作为吸收发射常温可逆转换材料，而三芳甲烷乙内酯不易制备，导致涂料制作成本较高。有鉴于此，需要提供一种更环保更经济的建筑涂料配方，使其更具有使用和推广价值。
发明内容
本发明的目的在于提供一种智能调温节能型外墙用乳胶漆配方，其最终得到的乳胶漆具有更好的使用耐候性且更环保、并且可调节的实际温度范围更宽、节能效果更显著、使用寿命更长且材料更易制备，制作成本更低等特点。
本发明的乳胶漆采用具有温致变化吸收率和发射率性能的常温温致发射率大幅度可逆变化材料和太阳光谱温致可逆吸收转换材料，所以可使冬冷夏热地区建筑物室内温度，在不消耗矿物能源的情况下冬季同比升高5-15℃、夏季同比下降5-15℃，大大节约建筑能耗。并且采用了硅丙乳液，不释放甲醛，环保性能更佳。
本发明的智能调温节能型外墙用乳胶漆采用的原料配方及配比如下表(1)所示：
(表1)
采用本发明的配方制得的乳胶漆，其具有如下优点：
(1)可调节的实际温度范围更宽，热转换温度在18～22℃，可调温度范围在±15℃，节能效果更显著；
(2)采用硅丙乳液作为粘接剂，更为环保；
(3)使用寿命长，可达20年以上；
(4)材料易得，更具使用与推广价值；
(5)产品符合国标GB/T 9755-2001的要求。
具体实施方式
实施例1
按照前述的配方，生产本发明所述的智能调温节能型外墙用乳胶漆，其中，各原材料用量质量百分比如下：
其中的分散剂、成膜助剂、助成膜剂、流平剂、增稠剂为常规的助剂，选用现有技术中常用的上述原料均可。
实施例2
按照前述的配方，生产本发明所述的智能调温节能型外墙用乳胶漆，其中，各原材料用量如下：
10、分散剂1kg、成膜助剂2kg、助成膜剂1kg、流平剂2kg、增稠剂1kg，(共计7kg)；11、水15kg。
其中的分散剂、成膜助剂、助成膜剂、流平剂、增稠剂为常规的助剂，选用现有技术中常用的上述原料均可。

Claims (2)

1.一种智能调温节能型外墙用乳胶漆，所述的乳胶漆采用了具有温致变化吸收率和发射率性能的常温吸收发射常温可逆转换材料和热发射率可逆转换材料制成，可使冬冷夏热地区建筑物室内温度，在不消耗矿物能源的情况下冬季同比升高5-15℃、夏季同比下降5-15℃；其特征在于：所述乳胶漆按如下质量百分比配置而成：
2.根据权利要求1所述的智能调温节能型外墙用乳胶漆，其特征在于：所述的其它助剂选自分散剂、成膜助剂、助成膜剂、流平剂、增稠剂中的一种或几种。
CN201410768393.0A 2014-12-15 2014-12-15 一种智能调温节能型外墙用乳胶漆 Pending CN104530880A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410768393.0A CN104530880A (zh) 2014-12-15 2014-12-15 一种智能调温节能型外墙用乳胶漆

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410768393.0A CN104530880A (zh) 2014-12-15 2014-12-15 一种智能调温节能型外墙用乳胶漆

Publications (1)

Publication Number Publication Date
CN104530880A true CN104530880A (zh) 2015-04-22

Family

ID=52846523

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410768393.0A Pending CN104530880A (zh) 2014-12-15 2014-12-15 一种智能调温节能型外墙用乳胶漆

Country Status (1)

Country Link
CN (1) CN104530880A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312420A (zh) * 2017-07-05 2017-11-03 河北晨阳工贸集团有限公司 一种智能调节温度的相变外墙水漆及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1389523A (zh) * 2001-06-05 2003-01-08 同济大学 “空调型”建筑涂料
US20050064094A1 (en) * 2001-06-07 2005-03-24 Wojtysiak Conrad Stephen Radiative cooling surface coatings
CN1621459A (zh) * 2004-10-28 2005-06-01 中山大学 二氧化钒太阳热智能控温涂料
CN101812263A (zh) * 2010-04-16 2010-08-25 杭州美多乐化工有限公司 水性硅丙耐候自洁型乳胶涂料及其生产方法
CN103923543A (zh) * 2014-04-24 2014-07-16 哈尔滨理工大学 复合智能控温涂料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1389523A (zh) * 2001-06-05 2003-01-08 同济大学 “空调型”建筑涂料
US20050064094A1 (en) * 2001-06-07 2005-03-24 Wojtysiak Conrad Stephen Radiative cooling surface coatings
CN1621459A (zh) * 2004-10-28 2005-06-01 中山大学 二氧化钒太阳热智能控温涂料
CN101812263A (zh) * 2010-04-16 2010-08-25 杭州美多乐化工有限公司 水性硅丙耐候自洁型乳胶涂料及其生产方法
CN103923543A (zh) * 2014-04-24 2014-07-16 哈尔滨理工大学 复合智能控温涂料及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312420A (zh) * 2017-07-05 2017-11-03 河北晨阳工贸集团有限公司 一种智能调节温度的相变外墙水漆及其制备方法

Similar Documents

Publication Publication Date Title
Xu et al. Energy saving potential of a fresh air pre-cooling system using radiative sky cooling
CN104530880A (zh) 一种智能调温节能型外墙用乳胶漆
CN104164170A (zh) 低光高反射保温隔热粉末涂料
Arminda et al. Heat transfer through building envelope materials and their effect on indoor air temperatures in tropics
Wahab et al. Natural ventilation approach in designing urban tropical houses
CN101768382B (zh) 一种空调型建筑涂料
CN104058670B (zh) 一种建筑外墙隔热涂料及其制备方法
von Tils Effect of trees and greening of buildings on the indoor heating and cooling load–microscale numerical experiment
Huang et al. Investigation on energy-efficient retrofitting measures on commercial building external walls in cooling-dominate cities
Wang et al. Investigation on a passive solar house equipped with water thermal storage wall
CN202100175U (zh) 一种隔热百叶片
Thongtha et al. Integration of phase change material into fiber cement roof for reduction of heat accumulation in buildings
El Bakkush The effect of outdoor air temperature on the thermal performance of a residential building
CN101671502B (zh) 一种低吸收率高发射率涂料填料
Yurun et al. Construction and simulation of condensate water cooling glass facade.
Marino The optimal choice of the outside innovative surface finishes for buildings from a thermal and energetic point of view
Upadhyay Simplified climate information for building designers
Ahmad et al. The potential of evaporative cooling window system using labu sayong in tropical Malaysia: A review
CN109779003A (zh) 驱动型的节能建筑
Djamila Passive strategies of naturally ventilated residential houses in the equatorial humid tropics
Jeong et al. Preparation and Thermal Performance Evaluation of Heat Storage paint with MPCM for Reducing Urban Heat Island Effect
WO2002098997A1 (en) 'air conditioning type' construction coating and manufacturing process of the same
CN107267048A (zh) 一种多功能建筑涂料及其制备方法
Taher et al. Thermal response of a composite building envelope under the climatic conditions of Tunisia
CN100509677C (zh) 一种相变蓄热浮石岩保温板及其制备方法和应用

Legal Events

Date Code Title Description
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
DD01 Delivery of document by public notice

Addressee: Tang Yun

Document name: Notification of Publication and of Entering the Substantive Examination Stage of the Application for Invention

WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150422

WD01 Invention patent application deemed withdrawn after publication