A kind of asphalt size, preparation method and its usage for the production of overlaying wet paving waterproof roll
Technical field
The invention belongs to modified asphalt technology field, being specifically related to a kind of asphalt size, preparation method and its usage for the production of overlaying wet paving waterproof roll.
Background technology
Pitch is a kind of product of Crude Oil Processing, at normal temperatures the thick liquid of black or chocolate or solid, and it is the organic material as a form of gel of a kind of brownish black, comprises rock asphalt, petroleum pitch, shale tar pitch and coal-tar pitch etc. four kinds.The main component of pitch is bituminous matter and resin, the compound of next oxygen, sulphur and the chlorine that have high boiling point mineral oil a small amount of.Pitch has gloss semi-solid state, and during low temperature, matter is crisp, and cohesiveness, water resistance and antiseptic property are fine.
Overlay/wet paving waterproof roll, be proposed by Chinese architecture material federation, specifically see GB/T23457-2009 standard.Pitch, be widely used in road, waterproofing work and anticorrosion on.But because pitch is not fine in performances such as high temperature resistant, resistance to flow, low temperature flexibility and weathering resistancies, make on effect, there is a lot of problem, such as waterproof roll low temperature flexibility, high temperature resistant and force of cohesion is not ideal enough, coiled material is very crisp at low temperatures to make waterproof roll factory coiled material, easily broken, there is trickling in temperature height, drippage is difficult to dyestripping, and force of cohesion is low can not provide the power with structure basal plane, easily departs from basal plane.
Modifying asphalt sizing material is admixture rubber, resin, high molecular polymer, levigate rubber powder or other fillers etc. are outer mixes crowded (properties-correcting agent) or takes, to measures such as pitch mild oxidation processing, to make pitch or asphaltic binder.In recent years, along with the widespread use of properties-correcting agent in pitch, be combined material modified with traditional asphalt, then add suitable softening oil, bitumen ductility and low temperature flexibility can be significantly improved, promote the cohesiveness of waterproof roll, resistance to low temperature and weathering resistance.
Summary of the invention
Based on this, the object of the present invention is to provide a kind of asphalt size for the production of overlaying wet paving waterproof roll, this modifying asphalt is used for overlay/wet paving waterproof roll major ingredient, the low temperature flexibility of waterproof roll, high temperature resistant and force of cohesion can be improved, there is excellent water resistance.
In order to achieve the above object, present invention employs following technical scheme:
For the production of the asphalt size overlaying wet paving waterproof roll, its mass percent accounted for by each component comprises:
Pitch 65 ~ 75%
Rubber oil 20 ~ 30%
SBS 5~10%。
The content of described pitch is such as 66%, 67%, 68%, 69%, 70%, 71%, 72%, 73% or 74%.
The content of described rubber oil is such as 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28% or 29%.
The content of described SBS is such as 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9% or 9.5%.
Preferably, the described asphalt size for the production of overlaying wet paving waterproof roll, its mass percent accounted for by each component comprises:
Pitch 69.62%
Rubber oil 25.33%
SBS 5.05%
Preferably, described pitch is PetroChina Company Limited.'s pitch, and preferred PetroChina Company Limited. 90# pitch is or/and PetroChina Company Limited. 70# pitch.
Preferably, described SBS is SBS791-H.
" comprising " of the present invention, mean it except described component, other components can also be comprised.
Such as described asphalt size can also comprise the tackifying resin of 3 ~ 4%, or/and, such as described asphalt size can also comprise the SBR of 4 ~ 5%, or/and, such as described asphalt size can also comprise the SBRS of 5 ~ 10%, or/and such as described asphalt size can also comprise the activated rubber powder of 5 ~ 10%, these other components give described asphalt size different characteristics.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... composition ".No matter which kind of composition asphalt size of the present invention comprises, and the mass percent sum of described asphalt size is 100%.
Two of object of the present invention is to provide a kind of as above for the production of overlaying the wet preparation method spreading the asphalt size of waterproof roll, said method comprising the steps of:
SBS is added in pitch, 185 ~ 200 DEG C of high speed dispersion 4 ~ 5 hours, SBS is made to solve homogeneously in pitch, obtain stable rubber modified asphalt system, then temperature is regulated to be 165 ~ 175 DEG C (such as 166 DEG C, 167 DEG C, 168 DEG C, 169 DEG C, 170 DEG C, 171 DEG C, 172 DEG C, 173 DEG C or 174 DEG C), slowly adding rubber oil makes it move in rubber modified asphalt system, stirs, and obtains the asphalt size for the production of overlaying wet paving waterproof roll.
Preferably, described churning time is 30 ~ 40min.
Three of object of the present invention is to provide a kind of as above for the production of overlaying the wet purposes spreading the asphalt size of waterproof roll, and it is for the production of overlaying wet paving waterproof roll.
Compared with the prior art, the present invention has following beneficial effect:
Modifying asphalt sizing material of the present invention is relative to pitch, its ductility, softening temperature and penetration degree significantly improve, and low temperature flexibility in corresponding water-proof coiled material product, high temperature resistant and stripping performance (glue and glue, glue and aluminium sheet) also significantly improve, especially low temperature flexibility is more remarkable.
In addition, the present invention can also significantly reduce energy loss, material loss and cost of labor, and production cost is minimized, and product control is better held.
Embodiment
Technical scheme of the present invention is further illustrated below by embodiment.
Embodiment 1
For the production of the asphalt size overlaying wet paving waterproof roll, its mass percent accounted for by each component comprises:
The rich 90# pitch 69.62% of middle innage
Rubber oil 0# 25.33%
SBS791-H 5.05%。
As above for the production of overlaying the wet preparation method spreading the asphalt size of waterproof roll, said method comprising the steps of:
SBS is added in pitch, 185 ~ 200 DEG C of high speed dispersion 4 ~ 5 hours, SBS is solved homogeneously in pitch completely, prepare stable rubber modified asphalt system, then temperature is regulated to be 165 ~ 175 DEG C, slowly adding rubber oil makes it move in rubber modified asphalt system, stirs 30 ~ 40min, obtains the asphalt size for the production of overlaying wet paving waterproof roll.
Carry out performance test to above-mentioned asphalt size and the rich 90# pitch of middle innage for the production of overlaying wet paving waterproof roll, result is as shown in table 1:
Table 1
Physicals |
The rich 90# pitch of middle innage |
Embodiment 1 |
Softening temperature (DEG C) |
45.2 |
75 |
Ductility (50mm/min, 25 DEG C) |
178 |
312 |
Penetration degree (25 DEG C) |
91 |
25 |
By the asphalt size of embodiment 1 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 2:
Table 2
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-18 |
High temperature resistant DEG C |
75 |
Peel off (coiled material and aluminium sheet N/mm) |
1.78 |
Hold viscosity (min) |
Be greater than 60 |
Embodiment 2
All the other are identical with embodiment 1, except pitch is Guangzhou petrochemical industry 90# pitch.
Carry out performance test to embodiment 2 for the production of the asphalt size overlaying wet paving waterproof roll, result is as shown in table 3:
Table 3
Physicals |
Embodiment 2 |
Softening temperature (DEG C) |
73.5 |
Ductility (50mm/min, 25 DEG C) |
290 |
Penetration degree (25 DEG C) |
27 |
By the asphalt size of embodiment 2 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 4:
Table 4
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-16 |
High temperature resistant DEG C |
73 |
Peel off (coiled material and aluminium sheet N/mm) |
1.63 |
Embodiment 3
All the other are identical with embodiment 1, except oil based on rubber oil.
Carry out performance test to embodiment 3 for the production of the asphalt size overlaying wet paving waterproof roll, result is as shown in table 5:
Table 5
Physicals |
Embodiment 3 |
Softening temperature (DEG C) |
72 |
Ductility (50mm/min, 25 DEG C) |
247 |
Penetration degree (25 DEG C) |
34 |
By the asphalt size of embodiment 3 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 6:
Table 6
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-19 |
High temperature resistant DEG C |
71 |
Peel off (coiled material and aluminium sheet N/mm) |
1.45 |
Hold viscosity (min) |
21 |
Embodiment 4
All the other are identical with embodiment 1, and except the rich 90# asphalt content of middle innage is 65%, rubber oil 0# is 30%, SBS791-H is 5%.
Carry out performance test for the production of the asphalt size overlaying wet paving waterproof roll with middle innage richness 90# pitch to embodiment 4, result is as shown in table 7:
Table 7
Physicals |
The rich 90# pitch of middle innage |
Embodiment 4 |
Softening temperature (DEG C) |
45.2 |
71 |
Ductility (50mm/min, 25 DEG C) |
178 |
342 |
Penetration degree (25 DEG C) |
91 |
40 |
By the asphalt size of embodiment 4 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 8:
Table 8
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-22 |
High temperature resistant DEG C |
73 |
Peel off (coiled material and aluminium sheet N/mm) |
1.54 |
Hold viscosity (min) |
Be greater than 60 |
Embodiment 5
All the other are identical with embodiment 1, and except the rich 90# asphalt content of middle innage is 75%, rubber oil 0# is 20%, SBS791-H is 5%.
Carry out performance test for the production of the asphalt size overlaying wet paving waterproof roll with middle innage richness 90# pitch to embodiment 5, result is as shown in table 9:
Table 9
Physicals |
The rich 90# pitch of middle innage |
Embodiment 5 |
Softening temperature (DEG C) |
45.2 |
77 |
Ductility (50mm/min, 25 DEG C) |
178 |
305 |
Penetration degree (25 DEG C) |
91 |
22 |
By the asphalt size of embodiment 5 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 10:
Table 10
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-15 |
High temperature resistant DEG C |
80 |
Peel off (coiled material and aluminium sheet N/mm) |
1.85 |
Hold viscosity (min) |
Be greater than 60 |
Embodiment 6
All the other are identical with embodiment 1, and except the rich 90# asphalt content of middle innage is 70%, rubber oil 0# is 20%, SBS791-H is 10%.
Carry out performance test for the production of the asphalt size overlaying wet paving waterproof roll with middle innage richness 90# pitch to embodiment 6, result is as shown in table 11:
Table 11
Physicals |
The rich 90# pitch of middle innage |
Embodiment 6 |
Softening temperature (DEG C) |
45.2 |
86 |
Ductility (50mm/min, 25 DEG C) |
178 |
376 |
Penetration degree (25 DEG C) |
91 |
18 |
By the asphalt size of embodiment 6 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 12:
Table 12
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-23 |
High temperature resistant DEG C |
87 |
Peel off (coiled material and aluminium sheet N/mm) |
2.11 |
Hold viscosity (min) |
Be greater than 60 |
Embodiment 7
All the other are identical with embodiment 1, and except the rich 90# asphalt content of middle innage is 65%, rubber oil 0# is 20%, SBS791-H be 10%, SBRS is 5%.
Carry out performance test for the production of the asphalt size overlaying wet paving waterproof roll with middle innage richness 90# pitch to embodiment 7, result is as shown in table 13:
Table 13
Physicals |
The rich 90# pitch of middle innage |
Embodiment 7 |
Softening temperature (DEG C) |
45.2 |
84 |
Ductility (50mm/min, 25 DEG C) |
178 |
370 |
Penetration degree (25 DEG C) |
91 |
19 |
By the asphalt size of embodiment 7 for the production of overlaying wet paving waterproof roll, carry out performance test to the waterproof roll obtained, result is as shown in table 14:
Table 14
Physical performance index |
Results of measuring |
Low temperature flexibility DEG C |
-22 |
High temperature resistant DEG C |
86 |
Peel off (coiled material and aluminium sheet N/mm) |
1.98 |
Hold viscosity (min) |
Be greater than 60 |
Applicant states, the present invention illustrates method detailed of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of ancillary component, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.