CN104529536A - Tin-based ceramic pigment and preparation method thereof - Google Patents
Tin-based ceramic pigment and preparation method thereof Download PDFInfo
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- CN104529536A CN104529536A CN201410793028.5A CN201410793028A CN104529536A CN 104529536 A CN104529536 A CN 104529536A CN 201410793028 A CN201410793028 A CN 201410793028A CN 104529536 A CN104529536 A CN 104529536A
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Abstract
The invention relates to a tin-based ceramic pigment and a preparation method thereof, belonging to the technical field of ceramic pigment processing. The tin-based ceramic pigment is prepared from the following components in parts by weight: 40-60 parts of refined tin, 50-80 parts of light calcium carbonate, 40-60 parts of common quartz powder, 1-10 parts of chromic oxide, 0.1-5 parts of an oxidant, and 0.1-2 parts of a mineralizer. The preparation method for the tin-based ceramic pigment comprises the following steps: mixing the refined tin, the light calcium carbonate, the common quartz powder and the oxidant in proportion to obtain a mixture, and then fusing, grinding, screening the mixture; then, adding the chromic oxide and the mineralizer to mix and grind for a second time to obtain a mixture II; roasting the mixture II at a high temperature, performing wet-grinding, washing, drying, mixing and packaging to obtain the tin-based ceramic pigment product. The ceramic film has the advantages of being low in cost, simple and short in flow, free of environmental pollution, and the like.
Description
Technical field
The present invention relates to a kind of tin base ceramic pigment and preparation method thereof, be specifically related to a kind of tin base ceramic pigment and preparation method thereof, belong to ceramic pigment processing technique field.
Background technology
Ceramic pigment rolls into a ball by coloring ion or proton the stable crystal with a fixed structure or the Solid solution being admittedly fused to stable crystalline network that are formed with other oxide compound.Ceramic pigment sold in the market is roughly synthetic.Synthetic colorant feature is: colorant crystal has stable structure, rich color; High-temperature stability and chemical stability good, the dissolving in glaze is less, and not easily reacts with some composition in glaze.The allotment of ceramic pigment and the toning of common drawing pigment have very large difference, and it dries through high temperature and burns before colour generation, and redeployed color is the final surperficial colouring effect of product, does not resemble common colorant and has visibility.Therefore, tuned plate personnel need to make the glaze of the ratio of colour mixture and the impact of burning till and use or base powder to judge accurately, particularly to abundant understanding and the proper use of colorant of this colorant kind character, as the ultimate-use temperature of colorant, the color development etc. in glaze or in base powder.
By the impact of the factor such as starting material, sintering curve after colorant calcining, there is certain difference in product each batch of final colouring effect, at this moment needs technician to allocate it, to ensure the consistence of front and back product shade.The content of allotment is mainly carried out demarcations sample to the product of every batch and is in harmonious proportion, and the final colouring effect to make before and after product batch stablizes and quality is protected.Along with the raising of people's living standard and the continuous lifting to the personalized grade of decorative art, be not singly qualitative to the requirement of ceramic product, especially to the floral designs of product, color shade has requirement, and existing colorant kind is limited after all.Therefore, need in routine duties to carry out technical allotment to meet the requirement of market to aspects such as colorant color, tones to existing product.Be that ceramic pigment is different from common pigments, it has numerous characteristics and affects the factor of its final colour generation, and the mixing color for it can be referred from the allotment of common pigments, but finally still will confirm to test.
Following problem is often encountered: 1. the appearance color of colorant is not exclusively the same with its color development in glaze in ceramic pigment actual allotment work; When 2. carrying out ratio allotment according to three primary colors theorem two kinds of colors, the not necessarily middle shade obtained; 3. the color development of same colorant in different glaze or base powder is not necessarily identical, overcome these difficult problems except will possessing certain mixing color knowwhy and working experience, also require that technology of mix colors personnel have sufficient awareness and understanding on the character of colorant and parent glaze (base powder) to the impact of its color development, only possessed these conditions, could better, carry out the allotment of ceramic pigment color more efficiently.
01133266.2 manufacture method of openly knowing clearly a kind of tin base ceramic pigment, the method mainly substitutes traditional use " tindioxide production tin base ceramic pigment " with metallic tin, its technological process comprises metallic tin melting slag making, mixes operations such as moistening mill, calcining synthesis, burned material fragmentation, rinsing and drying, product is chrome tin pink series ceramic colorant, but higher to the requirement of equipment, cost of manufacture is high; The present invention for raw material, develops that a kind of technique is simple, with low cost, the tin base ceramic pigment of excellent property with refined tin, light calcium carbonate, common silica powder, chromium sesquioxide, oxygenant, mineralizer.
Summary of the invention
The object of this invention is to provide a kind of tin base ceramic pigment, this tin base ceramic pigment has the advantages such as with low cost, short flow, non-environmental-pollution.
In order to solve the problem, the technical solution adopted in the present invention is:
A kind of tin base ceramic pigment, is made up of the component of following weight part:
Refined tin 40 ~ 60 parts, light calcium carbonate 50 ~ 80 parts, common silica powder 40 ~ 60 parts, chromium sesquioxide 1 ~ 10 part, 0.1 ~ 5 part, oxygenant, mineralizer 0.1 ~ 2 part.
Refined tin 40 ~ 45 parts, light calcium carbonate 50 ~ 55 parts, common silica powder 40 ~ 45 parts, chromium sesquioxide 1 ~ 2 part, 0.1 ~ 0.5 part, oxygenant, mineralizer 0.1 ~ 0.5 part.
Refined tin 45 ~ 50 parts, light calcium carbonate 55 ~ 60 parts, common silica powder 45 ~ 50 parts, chromium sesquioxide 2 ~ 4 parts, 0.5 ~ 1 part, oxygenant, mineralizer 0.5 ~ 1 part.
Refined tin 50 ~ 60 parts, light calcium carbonate 60 ~ 65 parts, common silica powder 50 ~ 55 parts, chromium sesquioxide 4 ~ 5 parts, 2 ~ 3 parts, oxygenant, mineralizer 1 ~ 2 part.
Refined tin 45 ~ 60 parts, light calcium carbonate 65 ~ 70 parts, common silica powder 55 ~ 60 parts, chromium sesquioxide 6 ~ 8 parts, 4 ~ 5 parts, oxygenant, mineralizer 0.1 ~ 0.5 part.
Refined tin 50 ~ 60 parts, light calcium carbonate 70 ~ 75 parts, common silica powder 45 ~ 60 parts, chromium sesquioxide 8 ~ 10 parts, 0.1 ~ 1 part, oxygenant, mineralizer 1 ~ 2 part.
Refined tin 55 ~ 60 parts, light calcium carbonate 75 ~ 80 parts, common silica powder 50 ~ 60 parts, chromium sesquioxide 1 ~ 4 part, 0.1 ~ 2 part, oxygenant, mineralizer 0.5 ~ 1 part.
A preparation method for tin base ceramic pigment, comprises the steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
The present invention relative to the beneficial effect of prior art is:
The tin base ceramic pigment that the present invention prepares has the advantages such as with low cost, short flow, non-environmental-pollution.
Embodiment
Be described in further details the present invention below by embodiment, these embodiments are only used for the present invention is described, do not limit the scope of the invention.
embodiment 1
A kind of tin base ceramic pigment, is made up of the component of following weight part:
Refined tin 40 parts, light calcium carbonate 50 parts, common silica powder 40 parts, chromium sesquioxide 2 parts, 0. 5 parts, oxygenant, mineralizer 0. 2 parts;
Its preparation method, comprises the following steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
embodiment 2
A kind of tin base ceramic pigment, is made up of the component of following weight part:
Refined tin 45 parts, light calcium carbonate 55 parts, common silica powder 45 parts, chromium sesquioxide 8 parts, 0. 5 parts, oxygenant, mineralizer 0.5 part;
Its preparation method, comprises the following steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
embodiment 3
A kind of tin base ceramic pigment, is made up of the component of following weight part:
Refined tin 50 parts, light calcium carbonate 60 parts, common silica powder 50 parts, chromium sesquioxide 6 parts, 4 parts, oxygenant, mineralizer 1 part;
Its preparation method, comprises the following steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
embodiment 4
A kind of tin base ceramic pigment, is made up of the component of following weight part:
Refined tin 55 parts, light calcium carbonate 70 parts, common silica powder 55 parts, chromium sesquioxide 5 parts, 5 parts, oxygenant, mineralizer 2 parts;
Its preparation method, comprises the following steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
embodiment 5
A kind of tin base ceramic pigment, is made up of the component of following weight part:
Refined tin 60 parts, light calcium carbonate 80 parts, common silica powder 60 parts, chromium sesquioxide 7 parts, 3 parts, oxygenant, mineralizer 1.5 parts;
Its preparation method, comprises the following steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
Claims (9)
1. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 40 ~ 60 parts, light calcium carbonate 50 ~ 80 parts, common silica powder 40 ~ 60 parts, chromium sesquioxide 1 ~ 10 part, 0.1 ~ 5 part, oxygenant, mineralizer 0.1 ~ 2 part.
2. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 40 ~ 45 parts, light calcium carbonate 50 ~ 55 parts, common silica powder 40 ~ 45 parts, chromium sesquioxide 1 ~ 2 part, 0.1 ~ 0.5 part, oxygenant, mineralizer 0.1 ~ 0.5 part.
3. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 45 ~ 50 parts, light calcium carbonate 55 ~ 60 parts, common silica powder 45 ~ 50 parts, chromium sesquioxide 2 ~ 4 parts, 0.5 ~ 1 part, oxygenant, mineralizer 0.5 ~ 1 part.
4. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 50 ~ 60 parts, light calcium carbonate 60 ~ 65 parts, common silica powder 50 ~ 55 parts, chromium sesquioxide 4 ~ 5 parts, 2 ~ 3 parts, oxygenant, mineralizer 1 ~ 2 part.
5. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 45 ~ 60 parts, light calcium carbonate 65 ~ 70 parts, common silica powder 55 ~ 60 parts, chromium sesquioxide 6 ~ 8 parts, 4 ~ 5 parts, oxygenant, mineralizer 0.1 ~ 0.5 part.
6. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 50 ~ 60 parts, light calcium carbonate 70 ~ 75 parts, common silica powder 45 ~ 60 parts, chromium sesquioxide 8 ~ 10 parts, 0.1 ~ 1 part, oxygenant, mineralizer 1 ~ 2 part.
7. a tin base ceramic pigment, is characterized in that: be made up of the component of following weight part:
Refined tin 55 ~ 60 parts, light calcium carbonate 75 ~ 80 parts, common silica powder 50 ~ 60 parts, chromium sesquioxide 1 ~ 4 part, 0.1 ~ 2 part, oxygenant, mineralizer 0.5 ~ 1 part.
8. according to a kind of tin base ceramic pigment described in claim 1 ~ 7, it is characterized in that: described refined tin purity >=99.9%, described light calcium carbonate purity >=97%, described common silica powder purity >=97%.
9. a preparation method for tin base ceramic pigment, is characterized in that: comprise the steps:
After refined tin, light calcium carbonate, common silica powder, oxygenant are mixed in proportion, carry out melting grinding, screening, add chromium sesquioxide subsequently and mineralizer carries out mixing and regrind, then through 1320 DEG C of calcinings, profit mill, washing, dry, hybrid packed after obtain tin base ceramic pigment product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410793028.5A CN104529536A (en) | 2014-12-20 | 2014-12-20 | Tin-based ceramic pigment and preparation method thereof |
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| CN201410793028.5A CN104529536A (en) | 2014-12-20 | 2014-12-20 | Tin-based ceramic pigment and preparation method thereof |
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| CN104529536A true CN104529536A (en) | 2015-04-22 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1408676A (en) * | 2001-09-19 | 2003-04-09 | 云南锡业集团有限责任公司研究设计院 | Process for producing tin base ceramic pigment |
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- 2014-12-20 CN CN201410793028.5A patent/CN104529536A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1408676A (en) * | 2001-09-19 | 2003-04-09 | 云南锡业集团有限责任公司研究设计院 | Process for producing tin base ceramic pigment |
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Application publication date: 20150422 |