CN106045321A - Method for preparing black glaze pigment with nickel-containing waste materials and black glaze pigment - Google Patents
Method for preparing black glaze pigment with nickel-containing waste materials and black glaze pigment Download PDFInfo
- Publication number
- CN106045321A CN106045321A CN201610376911.3A CN201610376911A CN106045321A CN 106045321 A CN106045321 A CN 106045321A CN 201610376911 A CN201610376911 A CN 201610376911A CN 106045321 A CN106045321 A CN 106045321A
- Authority
- CN
- China
- Prior art keywords
- nickel
- black glaze
- black
- discarded material
- waste materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses a method for preparing black glaze pigment with nickel-containing waste materials. The industrial nickel-containing waste materials are adopted, the black glaze pigment is prepared from, by weight, 50% of nickel-containing waste materials, 25%-35% of iron oxide red, 3%-8% of nickel oxide, 5%-15% of chromium oxide and 3%-8% of manganese oxide; the method includes the steps that the nickel-containing waste materials are calcined and subjected to ball milling ready for use, then the product and other components are prepared, mixed, calcined and smashed, and the product is obtained. The invention further discloses the black glaze pigment prepared with the preparing method. Cobalt-free black glaze pigment which is high in blackness, pure in color generation and stable can be prepared with the method.
Description
Technical field
The present invention relates to technical field of inorganic nonmetal, particularly related to one and utilized nickle contained discarded material to prepare black glaze
With method and the black glaze stain of colorant.
Background technology
Colorant is raw material indispensable in ceramic industry, and every kind of colorant has its ultimate-use (limiting service) temperature, when exceeding this
During temperature, the crystal structure of colorant plays pendulum, and is easily melted or reacts with other material and can not present pure
Color.Black glaze stain is a kind of colorant critically important in ornament materials, the decorative effect that black glaze is pure with it, dignified,
Extremely people's favor, is more considered as treasure by top grade decoration business.Showing according to modern study, those black glaze are all to exist with containing paint rock
Burning till in reducing flame, colour generation is the most unstable, and preparation technology especially firing process is difficult to control and grasp.Ceramic industry in modern age
Use Fe-Cr-Co-Mn systems black pigment i.e. to have cobalt black colorant to add in glaze more and obtain black glaze, though this is black pigment and glaze
Do not affected by firing atmosphere, but along with the continuous rising of Co2O3 price, production in enormous quantities and the application of this black material are subject to
Limit.Therefore, the production cost reducing black glaze stain becomes a kind of market demand.
Summary of the invention
The technical problem to be solved there is provided one utilize nickle contained discarded material to prepare blackness is high, colour generation is pure,
The method of the glaze stain of color without cobalt black of stable performance.Present invention also offers a kind of black glaze using this preparation method to prepare
Use colorant.
The technical problem to be solved is achieved by the following technical programs:
A kind of method utilizing nickle contained discarded material to prepare black glaze stain, uses industry nickle contained discarded material, and its percentage by weight forms
For: nickle contained discarded material 50%, iron oxide red 25 ~ 35%, nickel oxide 3 ~ 8%, chromium oxide 5 ~ 15% and manganese oxide 3 ~ 8%；Nickle contained discarded material is entered
Row calcining and ball milling standby, then with other component dispensings, mix, calcine and pulverize acquisition goods.
In the present invention, the nickel-containing catalyst used during described nickle contained discarded material is petroleum refining.
A kind of black glaze stain, it uses described method to prepare.
There is advantages that and petroleum refining employs nickel-containing catalyst, when catalyst activity becomes not
After waste material, because containing metals such as nickel, chrome green, ferrum, may utilize the raw material into producing ceramic glaze black pigment, its raw material sources
Extensively, cheap, turn waste into wealth, technological process is simple, and raw material is industrial chemicals, it is not necessary to use analytical pure, and it is raw
Producing cost is about the 2/3 of presently commercially available ceramic glaze black pigment；The colorant blackness that obtains through scientific compatibility is high (domestic greatly
What type ceramic pigment factory produced have, and cobalt black colorant blackness value is suitable), colour generation is pure, stable performance, can be widely applied to all kinds of pottery
The decoration of porcelain products.
Detailed description of the invention
The invention provides a kind of method utilizing nickle contained discarded material to prepare black glaze stain, it uses industry Nickel-bearing Waste
Material, its percentage by weight consists of: nickle contained discarded material 50%, iron oxide red 25 ~ 35%, nickel oxide 3 ~ 8%, chromium oxide 5 ~ 15% and oxidation
Manganese 3 ~ 8%；Carry out nickle contained discarded material calcining and ball milling be standby, then with other component dispensings, mix, calcine and pulverize acquisition system
Product.Described nickle contained discarded material is the nickel-containing catalyst used in petroleum refining.
Petroleum refining employs nickel-containing catalyst, after catalyst activity becomes waste material not because containing nickel, chrome green,
The metals such as ferrum, may utilize the raw material into producing ceramic glaze black pigment, and its raw material sources are wide, cheap, turn waste into wealth, work
Process flow is simple, and raw material is industrial chemicals, it is not necessary to use analytical pure, and its production cost is that presently commercially available ceramic glaze is used
About the 2/3 of black pigment；The colorant blackness that obtains through scientific compatibility high (domestic large size ceramic colorant factory produce have cobalt black
Colorant blackness value is suitable), colour generation is pure, stable performance, can be widely applied to the decoration of all kinds of ceramic product.
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It it not limitation of the invention.
Embodiment 1
A kind of method utilizing nickle contained discarded material to prepare black glaze stain, it uses the nickel-containing catalyst used in petroleum refining to make
For nickle contained discarded material, its percentage by weight consists of: nickle contained discarded material 50%, iron oxide red 30%, nickel oxide 5%, chromium oxide 10% and oxygen
Change manganese 5%；Nickle contained discarded material carries out calcining (calcining heat is 1000 DEG C) and to be milled to fineness be that 325 mesh are standby, then with other
Component dispensing, mixing, calcine and pulverize acquisition goods, wherein calcining heat is 1200 DEG C, is incubated 60min.
Add 3% the various embodiments described above black pigment in commercial barium system frit, add 0.3% carboxymethyl cellulose, warp
Wet grinding, crosses 200 mesh sieves, obtains ceramic glaze.This glaze is imposed on pottery model, through 1180 DEG C of high-temperature calcinations, insulation
10min, it is thus achieved that the glaze layer (L=28.18 a=0.48 b=-0.08) that black is pure, glaze bubble-free, pinprick, cracking phenomena.
Embodiment 2
A kind of method utilizing nickle contained discarded material to prepare black glaze stain, it uses the nickel-containing catalyst used in petroleum refining to make
For nickle contained discarded material, its percentage by weight consists of: nickle contained discarded material 55%, iron oxide red 25%, nickel oxide 5%, chromium oxide 10% and oxygen
Change manganese 5%；Nickle contained discarded material carries out calcining (calcining heat is 100 DEG C) and to be milled to fineness be that 325 mesh are standby, then with other
Component dispensing, mixing, calcine and pulverize acquisition goods, wherein calcining heat is 1230 DEG C, is incubated 60min.
Add 3% the various embodiments described above black pigment in commercial barium system frit, add 0.3% carboxymethyl cellulose, warp
Wet grinding, crosses 200 mesh sieves, obtains ceramic glaze.This glaze is imposed on pottery model, through 1180 DEG C of high-temperature calcinations, insulation
10min, it is thus achieved that black the most shallow the reddest glaze layer (L=29.15 a=0.56 b=-0.22), illustrates that its blackness of this colorant is low, black
Color is the purest.
Embodiment 3
A kind of method utilizing nickle contained discarded material to prepare black glaze stain, it uses the nickel-containing catalyst used in petroleum refining to make
For nickle contained discarded material, its percentage by weight consists of: nickle contained discarded material 45%, iron oxide red 35%, nickel oxide 5%, chromium oxide 10% and oxygen
Change manganese 5%；Nickle contained discarded material carries out calcining (calcining heat is 1000 DEG C) and to be milled to fineness be that 325 mesh are standby, then with other
Component dispensing, mixing, calcine and pulverize acquisition goods, wherein calcining heat is 1250 DEG C, is incubated 60min.
Add 3% the various embodiments described above black pigment in commercial barium system frit, add 0.3% carboxymethyl cellulose, warp
Wet grinding, crosses 200 mesh sieves, obtains ceramic glaze.This glaze is imposed on pottery model, through 1180 DEG C of high-temperature calcinations, insulation
10min, it is thus achieved that black the most shallow the reddest glaze layer (L=30.22 a=0.85 b=-0.14), illustrates that its blackness of this colorant is low, black
Color is the purest.
Embodiment described above only have expressed embodiments of the present invention, and it describes more concrete and detailed, but can not
Therefore the restriction to the scope of the claims of the present invention it is interpreted as, as long as using the skill that the form of equivalent or equivalent transformation is obtained
Art scheme, all should fall within the scope and spirit of the invention.
Claims (3)
1. utilize the method that nickle contained discarded material prepares black glaze stain, use industry nickle contained discarded material, its percentage by weight group
Become: nickle contained discarded material 50%, iron oxide red 25 ~ 35%, nickel oxide 3 ~ 8%, chromium oxide 5 ~ 15% and manganese oxide 3 ~ 8%；By nickle contained discarded material
Carry out calcining and ball milling be standby, then with other component dispensings, mix, calcine and pulverize acquisition goods.
The method utilizing nickle contained discarded material to prepare black glaze stain the most according to claim 1, it is characterised in that described contain
Nickel waste material is the nickel-containing catalyst used in petroleum refining.
3. a black glaze stain, it is characterised in that use the method for claim 1 to prepare.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376911.3A CN106045321A (en) | 2016-06-01 | 2016-06-01 | Method for preparing black glaze pigment with nickel-containing waste materials and black glaze pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376911.3A CN106045321A (en) | 2016-06-01 | 2016-06-01 | Method for preparing black glaze pigment with nickel-containing waste materials and black glaze pigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106045321A true CN106045321A (en) | 2016-10-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610376911.3A Pending CN106045321A (en) | 2016-06-01 | 2016-06-01 | Method for preparing black glaze pigment with nickel-containing waste materials and black glaze pigment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109456617A (en) * | 2018-11-21 | 2019-03-12 | 武汉科技大学 | A kind of black ceramic pigment and preparation method thereof |
| CN111662570A (en) * | 2020-05-25 | 2020-09-15 | 武汉科技大学 | Mixed spinel type black ceramic pigment and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040567A (en) * | 1988-08-23 | 1990-03-21 | 中国科学院山西煤炭化学研究所 | The treatment process of waste electroplating liquor containing chromium, waste residue |
| CN101696125A (en) * | 2009-11-02 | 2010-04-21 | 景德镇陶瓷学院 | Method for preparing cobalt-free black ceramic pigment by using copper ore tailings and product manufactured by using same |
| CN101993253A (en) * | 2009-08-28 | 2011-03-30 | 曹年生 | Black ceramic pigment |
| CN104108952A (en) * | 2014-07-03 | 2014-10-22 | 齐鲁工业大学 | Method for preparing black ceramic pigment by using leather making sludge and product |
-
2016
- 2016-06-01 CN CN201610376911.3A patent/CN106045321A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040567A (en) * | 1988-08-23 | 1990-03-21 | 中国科学院山西煤炭化学研究所 | The treatment process of waste electroplating liquor containing chromium, waste residue |
| CN101993253A (en) * | 2009-08-28 | 2011-03-30 | 曹年生 | Black ceramic pigment |
| CN101696125A (en) * | 2009-11-02 | 2010-04-21 | 景德镇陶瓷学院 | Method for preparing cobalt-free black ceramic pigment by using copper ore tailings and product manufactured by using same |
| CN104108952A (en) * | 2014-07-03 | 2014-10-22 | 齐鲁工业大学 | Method for preparing black ceramic pigment by using leather making sludge and product |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109456617A (en) * | 2018-11-21 | 2019-03-12 | 武汉科技大学 | A kind of black ceramic pigment and preparation method thereof |
| CN109456617B (en) * | 2018-11-21 | 2020-11-06 | 武汉科技大学 | Black ceramic pigment and preparation method thereof |
| CN111662570A (en) * | 2020-05-25 | 2020-09-15 | 武汉科技大学 | Mixed spinel type black ceramic pigment and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161026 |