CN104517678B - A kind of electric automobile internal high pressure cable for connecting - Google Patents

A kind of electric automobile internal high pressure cable for connecting Download PDF

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Publication number
CN104517678B
CN104517678B CN201510027579.5A CN201510027579A CN104517678B CN 104517678 B CN104517678 B CN 104517678B CN 201510027579 A CN201510027579 A CN 201510027579A CN 104517678 B CN104517678 B CN 104517678B
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band
cable
conductor
outside
outer layer
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CN104517678A (en
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陈波瀚
刘焱鑫
张照阳
李金顶
刘杨
李玉凯
侯婉婷
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Jiangsu Zhongli Group Co Ltd
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Zhongli Technology Group Co Ltd
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Priority to CN201610254944.0A priority patent/CN105931706A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/0009Details relating to the conductive cores
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023Alloys based on aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/04Flexible cables, conductors, or cords, e.g. trailing cables
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/006Constructional features relating to the conductors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/22Halogen free composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Insulated Conductors (AREA)
  • Conductive Materials (AREA)

Abstract

The invention belongs to technical field of cables, relate to a kind of electric automobile internal high pressure cable for connecting, including conductor, the band being coated on outside conductor, the insulating barrier overlayed on outside band, the material of described insulating barrier is TPE or TPU, it is characterized in that described conductor is to be formed by many aluminum-alloy wires are stranded, described band is made up of core band and the outer layer band outside being positioned at core band, core band with first segment outside one direction is wound on conductor spirally, outer layer band with second section outside one direction is wound on core band spirally, core band and outer layer band around to contrary and first segment away from second section away from equal;First segment is away from being 3~6 times of core band width;The material of outer layer band is identical with the material of core band.The present invention has a following main beneficial effect: more soft, more flexible, be more easy to that construction, deadweight are lighter, cost is lower, more can electric current high pressure resistant, big, electrical Interference high temperature resistant, anti-;Flame retardant effect is more preferably, bending resistance is more excellent, it is safer to use.

Description

A kind of electric automobile internal high pressure cable for connecting
Technical field
The invention belongs to electric automobile and technical field of cables, especially relate to a kind of electric automobile internal high pressure and connect use Cable, especially relates to use the cable of aluminium alloy conductor.
Background technology
It is a kind of for electric connection line, the primary high-voltage transmission for vehicle interior that automotive interior high pressure connects cable.Logical Letter power supply flexible cable does not require nothing more than has good flexibility, in order to convenient deposited in narrow space or when similar If, and require there is preferable anti-flammability, to adapt to higher fire-protection rating requirement.
The Application No. of our company: 2014104424205 and entitled: " a kind of electronic vapour with super soft aluminium conductor Connect cable and preparation method thereof with high pressure inside car ", Application No.: 2014104424313 and entitled: " there is super softness Connect cable and preparation method with high pressure inside the electric automobile of aluminium conductor ", Application No.: 2014104424328 and title For: in " the internal double sheath high pressure of electric automobile with ultra-soft aluminum conductor connect cable and preparation method " patent, use aluminium Conductor substitutes copper conductor, has reached to save the purpose of Zhi Jiangben;But, owing to the hardness of aluminium is the highest, although softness can be reached Purpose, but its tensile property is poor, is easier to creep, corrosion resistance and thermal expansion aspect not ideal enough.
The cable for car overwhelming majority uses copper conductor the most both at home and abroad, and copper conductor itself is heavier, and flexibility is poor; Communication power supply flexible cable is the most generally used to carry out substituting use.
Technical information about communication power supply flexible cable can be seen in, such as in disclosed Chinese patent literature CN201247632Y recommends have " fire-retardant, fire-resistant, the shielding anti-interference flexible cable of communication power supply ", CN201302849Y to be provided with " a kind of communication power supply flame-retardant refractory flexible electric cable ", CN202230791Y are disclosed " a kind of poly-second of communication power supply flame-proof cross-linking Alkene insulated cable ", CN202720953U introduce have " for the shoe flame-retardant shielding flexible cable of communication power supply ", CN202855416U discloses " communication power supply fire-resistant shield flexible cable " and disclosed " a kind of communication power supply of CN202601277U With flame-retardant flexible electric cable ", etc..
Although communication power supply flexible cable of the prior art is respectively arranged with corresponding technique effect, but exists following common Defect: (1) is owing to using stranded thin copper wire as conductor, its softness can not meet desired requirement.And due to Pliability difference and make bending radius be restricted, thus narrow space, by immovable object hinder so that talk in a roundabout way When the occasion at place etc is laid, easily affect speed of application, particularly in the occasion that the spaces such as vehicle are less;(2) due in skill Generally select the conductor using copper as flexible cable under art prejudice, thus do not only exist the blindness in terms of reasonable employment raw material, and And cause the manufacturing cost of flexible cable big;Its three, owing to copper density is big, therefore cable weight is heavier, thus not only logistics transportation, storehouse Cost in storage link is high, and workmen's labour intensity is big in laid processes, and consumed cost of labor is high.
In view of above-mentioned prior art, still there is necessity of improvement, made useful design for this applicant, define following The technical scheme that will introduce.
Summary of the invention
In order to solve the problems referred to above, it is an object of the invention to disclose a kind of electric automobile internal high pressure cable for connecting, it Realize by the following technical solutions.
In first embodiment of the present invention, a kind of electric automobile internal high pressure cable for connecting, including conductor, it is coated on Band outside conductor, the insulating barrier overlayed on outside band, the material of described insulating barrier is 125 DEG C of environmentally-friendly flame retardant thermoplastic elastomers TPE, the rated operational voltage of described cable is 1500V, Long-term service temperature≤125 DEG C of cable, environment temperature during cable laying Degree >=-40 DEG C, cable is continuous-stable working time >=6h at temperature is 175 DEG C, and the minimum bending radius of cable is outside cable 5 times of footpath, it is characterised in that described conductor is that the aluminum-alloy wire by many a diameter of 0.01~0.50mm is stranded, described The cross-sectional area of conductor is 1.5~120mm2;Described band is made up of core band and the outer layer band outside being positioned at core band, internal layer Band with first segment outside one direction is wound on conductor spirally, outer layer band with second section be wound on spirally away from one direction core band it Outward, core band and outer layer band around to contrary and first segment away from second section away from equal;First segment away from be core band width 3~ 6 times;The material of core band be thickness be 0.15~0.30mm waterstop or non-woven fabrics or glass fiber tape or mica tape or Thickness is the polyester belt of 0.03~0.10mm;The material of outer layer band is identical with the material of core band.
In second embodiment of the present invention, a kind of electric automobile internal high pressure cable for connecting, including conductor, it is coated on Band outside conductor, the insulating barrier overlayed on outside band, the material of described insulating barrier is 125 DEG C of environmentally-friendly flame retardant thermoplastic elastomers TPU, the rated operational voltage of described cable is 1500V, Long-term service temperature≤125 DEG C of cable, environment temperature during cable laying Degree >=-40 DEG C, cable is continuous-stable working time >=6h at temperature is 175 DEG C, and the minimum bending radius of cable is outside cable 5 times of footpath, it is characterised in that described conductor is that the aluminum-alloy wire by many a diameter of 0.01~0.50mm is stranded, described The cross-sectional area of conductor is 1.5~120mm2;Described band is made up of core band and the outer layer band outside being positioned at core band, internal layer Band with first segment outside one direction is wound on conductor spirally, outer layer band with second section be wound on spirally away from one direction core band it Outward, core band and outer layer band around to contrary and first segment away from second section away from equal;First segment away from be core band width 3~ 6 times;The material of core band be thickness be 0.15~0.30mm waterstop or non-woven fabrics or glass fiber tape or mica tape or Thickness is the polyester belt of 0.03~0.10mm;The material of outer layer band is identical with the material of core band.
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described The material of insulating barrier is can be also any material of the prior art, such as PE, halogen-free flameproof material etc..
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described Conductor is made up of multilayer, is formed by many aluminum-alloy wires are stranded, and the direction of lay between adjacent layer is contrary in every layer;Every layer Twisting pitch is 10~25 times of aluminum-alloy wire diameter in this layer.
Further, a kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is special Levy and be that described conductor is made up of multilayer, in adjacent layer: stranded than unlined aluminium B alloy wire of the twisting pitch of outer layer aluminum-alloy wire Pitch is big, and the twisting pitch of outer layer aluminum-alloy wire is 2~4 times of twisting pitch of unlined aluminium B alloy wire.
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described The thickness of insulating barrier be 0.5~3.0mm;More typical thickness be 0.5mm or 0.7mm or 0.8mm or 1.0mm or 1.5mm or 2.0mm or 3.0mm.
Therefore, the present invention has a following main beneficial effect: more soft, more flexible, be more easy to that construction, deadweight are lighter, become This is the lowest, more can electric current high pressure resistant, big, electrical Interference high temperature resistant, anti-;Flame retardant effect is more preferably, bending resistance is more excellent, use more Safety.
Accompanying drawing explanation
Fig. 1 is the perspective view after one section of stripping of embodiment 1 of the present invention.
Fig. 2 is the cross-sectional structure schematic diagram of embodiment 1.
Detailed description of the invention
Embodiment 1
Ask for an interview Fig. 1 and Fig. 2, a kind of electric automobile internal high pressure cable for connecting, including conductor 1, be coated on outside conductor 1 Band 2, the insulating barrier 3 overlayed on outside band 2, the material of described insulating barrier 3 is 125 DEG C of environmentally-friendly flame retardant thermoplastic elastomer TPE, The rated operational voltage of described cable is 1500V, Long-term service temperature≤125 DEG C of cable, environment temperature during cable laying >=- 40 DEG C, cable is continuous-stable working time >=6h at temperature is 175 DEG C, and the minimum bending radius of cable is the 5 of the outside diameter of cable Times, it is characterised in that described conductor 1 is that the aluminum-alloy wire by many a diameter of 0.01~0.50mm is stranded, described conductor Cross-sectional area be 1.5~120mm2;Described band 2 is made up of core band 22 and the outer layer band 21 outside being positioned at core band, interior Layer band is with first segment outside one direction is wound on conductor spirally, and outer layer band is wound on core band spirally with second section away from one direction Outside, core band and outer layer band around to contrary and first segment away from second section away from equal;First segment is away from being the 3 of core band width ~6 times;The material of core band be thickness be 0.15~0.30mm waterstop or non-woven fabrics or glass fiber tape or mica tape or Be thickness be the polyester belt of 0.03~0.10mm;The material of outer layer band is identical with the material of core band.
Embodiment 2
Refer to Fig. 1 and Fig. 2, a kind of electric automobile internal high pressure cable for connecting, including conductor 1, be coated on outside conductor 1 Band 2, the insulating barrier 3 that overlayed on outside band 2, the material of described insulating barrier 3 is 125 DEG C of environmentally-friendly flame retardant thermoplastic elastomers TPU, the rated operational voltage of described cable is 1500V, Long-term service temperature≤125 DEG C of cable, environment temperature during cable laying Degree >=-40 DEG C, cable is continuous-stable working time >=6h at temperature is 175 DEG C, and the minimum bending radius of cable is outside cable 5 times of footpath, it is characterised in that described conductor 1 is that the aluminum-alloy wire by many a diameter of 0.01~0.50mm is stranded, institute The cross-sectional area stating conductor is 1.5~120mm2;Described band 2 is by core band 22 and outer layer band 21 structure outside being positioned at core band Becoming, core band is with first segment outside one direction is wound on conductor spirally, and outer layer band is wound on away from one direction spirally with second section Outside core band, core band and outer layer band around to contrary and first segment away from second section away from equal;First segment is away from being core band 3~6 times of width;The material of core band be thickness be waterstop or non-woven fabrics or glass fiber tape or the cloud of 0.15~0.30mm Master tape or the polyester belt that thickness is 0.03~0.10mm;The material of outer layer band is identical with the material of core band.
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described Conductor is made up of multilayer, is formed by many aluminum-alloy wires are stranded, and the direction of lay between adjacent layer is contrary in every layer;Every layer Twisting pitch is 10~25 times of aluminum-alloy wire diameter in this layer.
Further, a kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is special Levy and be that described conductor is made up of multilayer, in adjacent layer: stranded than unlined aluminium B alloy wire of the twisting pitch of outer layer aluminum-alloy wire Pitch is big, and the twisting pitch of outer layer aluminum-alloy wire is 2~4 times of twisting pitch of unlined aluminium B alloy wire.
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described The thickness of insulating barrier is 0.5~3.0mm;More typical thickness be 0.5mm or 0.7mm or 0.8mm or 1.0mm or 1.5mm or 2.0mm or 3.0mm.
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described The model of aluminum-alloy wire is 8A07 or 8030 or LHA1 or LHA2;The tensile strength of described aluminum-alloy wire is 120~155MPa, When little elongation at break is 8%, 20 DEG C, maximum resistivity is 29.7n Ω m.
A kind of electric automobile internal high pressure cable for connecting described in any of the above-described embodiment, it is characterised in that described Aluminum-alloy wire is made up of the raw material of following weight portion: silicon: 0.03~0.08 part, iron: 0.2~0.42 part, copper: 0.2~0.3 part, Magnesium: 0.06~0.2 part, zirconium: 0.1~0.3 part, zinc: 0.01~0.04 part, boron: 0.01~0.03 part, platinum: 0.01~0.05 part, Titanium: 0.01~0.1 part, tungsten: 0.01~0.05 part, manganese: 0.01~0.03 part, surplus be aluminium;Wherein, magnesium with silicon mass ratio is (1.50~2.00): 1;The tensile strength minimum of a value of described aluminum-alloy wire is 305MPa, minimum elongation at break is 3.8%, 20 DEG C Time maximum resistivity be 32.5n Ω m, the max line coefficient of expansion be 2.15 × 10-5(1/ DEG C), 20 DEG C time maximal density be 2.85g/cm3
In aluminum-alloy wire described above, zirconium and aluminium form three calorize zirconium compounds, enable aluminum alloy to middle recrystal grain and obtain Arrive effective refinement;Magnesium silicon ratio (1.50~2.00): 1, defines silication magnesium dioxide hardening constituent in enabling aluminum alloy to, for During the same subsequent heat treatment of aluminium alloy, this intensity of aluminum alloy and magnesium silicon are than compared with aluminium alloy not in this range after tested, Intensity improves 30~40MPa, and wherein magnesium silicon about improves 30MPa than intensity during 1.50:1, and magnesium silicon about improves than intensity during 2.00:1 31MPa, magnesium silicon improves 50MPa than intensity during 1.80:1, and magnesium silicon ratio is from 1.50:1 to 1.80:1, and intensity increases journey ascendant trend, Magnesium silicon ratio is from 2.00:1 to 1.80:1, and intensity increases journey ascendant trend, and described magnesium silicon ratio refers to mass ratio;Aluminium alloy described above In Si, the addition of platinum makes resistivity be greatly reduced.
Applicant has made detailed detection for the aluminum-alloy wire of formula as below, and described aluminum-alloy wire is by following weight portion Raw material is constituted: silicon: 0.05 part, iron: 0.2~0.42 part, copper: 0.2~0.3 part, magnesium: 0.09 part, zirconium: 0.1~0.3 part, zinc: 0.01~0.04 part, boron: 0.01~0.03 part, platinum: 0.01~0.05 part, titanium: 0.01~0.1 part, tungsten: 0.01~0.05 part, Manganese: 0.01~0.03 part, surplus be aluminium;I.e. magnesium and silicon mass ratio are 1.8:1;The tensile strength minimum of a value of the aluminum-alloy wire recorded When being 4.6%, 20 DEG C for 337MPa, minimum elongation at break maximum resistivity be 30.2n Ω m, the max line coefficient of expansion be 2.13 × 10-5(1/ DEG C), 20 DEG C time maximal density be 2.65g/cm3
Conductor in the cable of the present invention, has excellent acidproof, alkaline-resisting, water-fast and antioxygenic property, maintaining requirement pole Low, do not worry oxidation and etching problem;And there is extremely strong heat resistance, expand and be contracted in-100~300 DEG C of scopes It is not influenced by temperature.
Certainly, as improving further, in the present invention, in any of the above-described embodiment, the material of belting layer is all right It it is wire such as copper cash or aluminium wire or aluminum-alloy wire or aluminum-magnesium alloy wire, core band and the outer layer band infall mode that uses knotting Connecting, the most aluminum-alloy wires of conductor can be stranded, it is also possible to is placed in parallel, and production so can be made more convenient, Meanwhile, conductor binding constraint is made to be integrated;Do not scatter during alternating bending.
In the present invention, owing to employing aluminum-alloy wire in conductor, aluminum-alloy wire can be accomplished than aluminium wire diameter more carefully still Intensity is higher, thus can the most stranded production, twisting speed is 3~5 times of aluminium wire, is 2~3 times of copper wire;Therefore cable More soft, more flexible, be more easy to lay in narrow space, more can high current capacity high pressure resistant, resistance to, high temperature resistant, more resistant to Acid/base/aqueous corrosion, will not aoxidize;There is less thermal coefficient of expansion, after making cable, expand and be contracted in-100~300 DEG C In the range of be not influenced by temperature, can keep integrated with insulating barrier;Creep-resistant property is more preferable.In the present invention, cable Insulating barrier uses 125 DEG C of environmentally-friendly flame retardant thermoplastic elastomer TPE or TPU, can effectively act as fire retardation, at electric automobile Using in narrow space, bending freely, has no that insulating barrier cracking phenomena occurs.
Thermoplastic elastomer (TPE) TPE(Thermoplastic Elastomer in the present invention) it is a kind of height with rubber Elasticity, high intensity, high resilience, having again can the material of feature of injection molding;The 125 DEG C of environmental protection flame retardants used in the application Thermoplastic elastomer (TPE) TPE can buy in companies such as LASTO, POLYONE.
TPU (Thermoplastic polyurethanes) entitled TPUE rubber;In the application The 125 DEG C of environmentally-friendly flame retardant thermoplastic elastomers used can join the limited public affairs of new material in LASTO, POLYONE, SK, Changshu Si Deng company buys.The TPU used in the application water resistance under muddiness is good, will not occur substantially in 1~2 year Hydrolysis;It addition, cable in use the application with do compatibility test with kerosene, gasoline, hydraulic oil, machine oil, lubricating oil etc., will In cable, other parts are all peeled off, and only remain insulating barrier, through the immersion of 90 days, do not find mutual erosion with oil product.
Applicant not only used TPE, TPU of the prior art, also developed a kind of halogen-free flame-retardant thermoplastic elastomer CABLE MATERIALS, for the insulating materials of the application, it is characterised in that described halogen-free flame-retardant thermoplastic elastomer electrical cable material is by following The raw material composition of weight portion: BS SBS:30 part;Poly-(2-ethyl-6 n-pro-pyls-Isosorbide-5-Nitrae-phenylene) ether: 40 parts;Polyethylene or polypropylene: 38 parts;Butylene: 25 parts;The model that is produced from commercially available Kelamayi is 4010 naphthenic base white oils: 15 parts; Tricresyl phosphate: 30 parts;Tissuemat E: 3 parts;Model is the cable jacket antioxidant of 1010: 0.5 part;Commercially available model For UV-360 ultraviolet-resistant absorbent: 0.8 part.
After tested, above-mentioned halogen flame-retardant thermoplastic elastomer electrical cable material density is 1.025g/cm-3, melt flow rate (MFR) be 11.8 g/10min, shore hardness are 83, hot strength is MPa, elongation at break is 14.4%, 135 DEG C × 168h degradation By, hot strength rate of change be 2.6%, 100 DEG C of thermal deformations be 1.8%, tear-proof value is 25 N/mm, resisted by 135 DEG C × 1h Split test, cracking resistance (130 DEG C, load 10kg, 3mm sample) are referred to by, oxygen by, (0/30)-40 DEG C of impact brittle test Number be 28%, 20 DEG C of specific insulations be 2.6 × 1016Ω m, dielectric strength are 32 MV/m, flame retardant rating is VW-1,130 DEG C × 1h cable thermal contraction is 0.2%, 45g/L oxalic acid solution, the acidproof rear elongation change rate of (23 ± 5) C, 168h is-2.3%, 40g/L sodium hydroxide solution, the alkaline-resisting rear change rate of strength of (23 ± 5) C, 168h is 1.2%, 40g/L sodium hydroxide solution, (23 The alkaline-resisting rear elongation change rate of ± 5) C, 168h is-4.2%, (80 ± 2) C, 7 × 24h heat-proof water change rate of strength is 0.04%, (80 ± 2) C, 7 × 24h heat-proof water elongation change rate is 0.35%, (85 ± 2) C, (85 ± 2) % humidity, 3000h aging after Elongation change rate is-1.8%;And when the cable of the present invention produces, the maximum stable process velocity of insulating barrier has reached 120 On m/min, property indices has all reached outstanding grade.
Cable in the present invention is placed on acid pH value be 5-6, alkaline ph value be 8-9 the aqueous solution in, after 30 days still Can normally use.
Therefore, the present invention has a following main beneficial effect: more soft, more flexible, be more easy to that construction, deadweight are lighter, become This is the lowest, more can electric current high pressure resistant, big, electrical Interference high temperature resistant, anti-;Flame retardant effect is more preferably, bending resistance is more excellent, use more Safety.
The present invention is not limited to above-mentioned preferred forms, it will be appreciated that the design of the present invention can be by other all shapes Formula is implemented to use, and they also fall within protection scope of the present invention.

Claims (1)

1. an electric automobile internal high pressure cable for connecting, the band including conductor, being coated on outside conductor, is overlayed on outside band Insulating barrier, the material of described insulating barrier is halogen-free flame-retardant thermoplastic elastomer electrical cable material, the rated operational voltage of described cable For 1500V, Long-term service temperature≤125 DEG C of cable, environment temperature >=-40 DEG C during cable laying, cable is 175 DEG C in temperature Lower continuous-stable working time >=6h, the minimum bending radius of cable is 5 times of the outside diameter of cable, it is characterised in that described conductor is Aluminum-alloy wire by many a diameter of 0.01~0.50mm is stranded, and the cross-sectional area of described conductor is 1.5~120mm2; Described band is made up of core band and the outer layer band outside being positioned at core band, and core band is wound on away from one direction spirally with first segment Outside conductor, outer layer band with second section outside one direction is wound on core band spirally, core band and outer layer band around to contrary And first segment away from second section away from equal;First segment is away from being 3~6 times of core band width;The material of core band is that thickness is The waterstop of 0.15~0.30mm;The material of outer layer band is identical with the material of core band;The model of described aluminum-alloy wire is 8A07 Or 8030 or LHA1 or LHA2, the tensile strength of described aluminum-alloy wire is 120~155MPa, minimum elongation at break is 8%, 20 DEG C time maximum resistivity be 29.7n Ω m;Described halogen-free flame-retardant thermoplastic elastomer electrical cable material, by the raw material of following weight portion Composition: BS SBS:30 part;Poly-(2-ethyl-6 n-pro-pyls-Isosorbide-5-Nitrae-phenylene) ether: 40 parts;Polyethylene Or polypropylene: 38 parts;Butylene: 25 parts;The model that is produced from commercially available Kelamayi is 4010 naphthenic base white oils: 15 parts;Tricresol phosphate Ester: 30 parts;Tissuemat E: 3 parts;Model is the cable jacket antioxidant of 1010: 0.5 part;Commercially available model is that UV-360 resists Ultra-violet absorber: 0.8 part.
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CN201610255281.4A Division CN105788713A (en) 2015-01-20 2015-01-20 High-voltage cable
CN201610254870.0A Division CN105702372A (en) 2015-01-20 2015-01-20 Cable for high-voltage connection
CN201610254869.8A Division CN105741957A (en) 2015-01-20 2015-01-20 Aluminium alloy wire for cable, halogen-free flame-retardant thermoplastic elastomer cable material, and cable

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Address after: 215542 Jiangsu city of Suzhou province Changshou City Shajiabang town southeast of Changshu Development Zone, No. 8 Chang kunlu

Patentee after: Jiangsu Zhongli group Limited by Share Ltd

Address before: 215542 Jiangsu city of Suzhou province Changshou City Shajiabang town southeast of Changshu Development Zone, No. 8 Chang kunlu

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Assignee: CHANGSHU LIXING PHOTOELECTRIC SCIENCE & TECHNOLOGY CO., LTD.

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Denomination of invention: Cable for high-voltage connection inside electric automobile

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