CN104516049B - Linear luminophor - Google Patents
Linear luminophor Download PDFInfo
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- CN104516049B CN104516049B CN201410384534.9A CN201410384534A CN104516049B CN 104516049 B CN104516049 B CN 104516049B CN 201410384534 A CN201410384534 A CN 201410384534A CN 104516049 B CN104516049 B CN 104516049B
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- covering
- reflection layer
- fluorine resin
- resin
- layer
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0065—Manufacturing aspects; Material aspects
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/028—Optical fibres with cladding with or without a coating with core or cladding having graded refractive index
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0066—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form characterised by the light source being coupled to the light guide
- G02B6/007—Incandescent lamp or gas discharge lamp
- G02B6/0071—Incandescent lamp or gas discharge lamp with elongated shape, e.g. tube
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Planar Illumination Modules (AREA)
- Light Guides In General And Applications Therefor (AREA)
- Securing Globes, Refractors, Reflectors Or The Like (AREA)
- Road Signs Or Road Markings (AREA)
Abstract
There is provided it is a kind of not only can simply carry out to the installation operation of fixation and also using when luminescent properties are also excellent and Linear luminophor that also can efficiently be manufactured.The acrylic resin that selective refraction rate is 1.45~1.60 in sandwich layer (1) in such a way that the refringence of sandwich layer (1) and covering (2) becomes 0.01~0.15,The fluorine resin that selective refraction rate is 1.35~1.45 in covering (2),On the other hand,Become 0.05~1.0mm with maximum gauge,The total light transmittance of luminous ray becomes 60% or more,Haze value forms the covering (2) as 20%~90% mode,And then the fluorine resin for being imported with the functional group for assigning the cementability relative to defined non-fluorine resin is used in the covering (2),Simultaneously,The non-fluorine resin with the fluorine resin of the covering (2) with cementability is used in reflection layer (3),Adhesive linkage (4) is directly set on the reflection layer (3) and constitutes illuminator ontology R.
Description
Technical field
The present invention relates to a kind of improvement of Linear luminophor, and specifically, being related to one kind not only can simply carry out to quilt
The installation operation of fixture and using when luminescent properties it is also excellent and what can also efficiently be manufactured linear sends out
Body of light.
Background technology
It is well known that Linear luminophor as neon light is utilized in many lamp decorations, electricity decorations signboard seen in street,
But the neon light that ontology is made of glass tube is since illuminator itself is without flexibility, it is thus impossible to make illuminator bending and
Along the form of the bending section of mounting surface, the form of arbitrary figure, word.
Therefore, in the past, use, also developed with flexibility in order to freely be bent linear Linear luminophor
Optical-fiber type Linear luminophor, also to including the sandwich layer containing transparent acrylic resin and containing before applicant in this case
The Linear luminophor of the covering of translucent fluorine resin has carried out patent application (referring to patent document 1).
Moreover, applicant in this case also develops a kind of photism as described in Fig. 6 in above-mentioned document 1 in turn
The excellent Linear luminophor of energy passes through impermeable ming tree of the outside setting containing white or silver color of the covering in Linear luminophor
The reflection layer of fat can make light-emitting surface (circumferential surface for not forming reflection layer) to the position far from light source shine brightly.
But in the Linear luminophor with above-mentioned reflection layer, although in order to be bonded covering and reflection layer two
Fluorine resin has been used in layer, still, cannot directly have been carried out on the reflection layer of the fluorine resin containing Abherent two-sided
The attaching of adhesive tape, the coating of bonding agent, therefore, it is necessary to using embedded structure, locking (Department stop) structure and carry out Linear luminophor
Installation.
In addition, in order to which adhesive linkage is arranged on the peripheral surface of Linear luminophor, it is also considered that reflection layer and adhesive linkage it
Between setting have to the two of fluorine resin and non-fluorine system bonding agent cementability prime coat method, but when using this method,
It must be added to the process in the outside primer coating of reflection layer during fabrication, therefore, be easy to incur the variation of manufacture efficiency.
On the other hand, also there is known imported the fluorine resin assigned with the functional group of the cementability of non-fluorine resin in the past
Material, the hose material for being bonded on non-fluorine resin, the fluorine resin being laminated and makes etc. (with reference to patent document 2,3), but
In Linear luminophor, the past does not see the optical property for efficiently using fluorine resin while the technology equipped with adhesive linkage.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2013-57924 bulletins
Patent document 2：Japanese Unexamined Patent Publication 2003-231718 bulletins
Patent document 3：Japanese Unexamined Patent Publication 10-311461 bulletins
Invention content
Problems to be solved by the invention
Therefore, the present invention is in view of problem as described above and the invention completed, it is intended that providing a kind of linear hair
Body of light, the Linear luminophor not only can simply carry out the installation operation to fixation, but also luminescent properties when use
Also excellent, and also can efficiently be manufactured.
Means for solving the problems
The means that the present inventor uses in order to solve the above problems are as described below.
That is, the present invention is characterized in that following aspect：Containing being constituted with lower layer：Sandwich layer 1, to contain transparent resin material
The clava of material, refractive index are bigger than air；Covering 2, to coat the body containing semi-transparent resin material of the sandwich layer 1, folding
Penetrate that rate is smaller than sandwich layer 1 and refractive index is bigger than air；Reflection layer 3 is formed in the outside of the covering 2, contains white or silver color
Opaque resin material；Adhesive linkage 4 is arranged in the outside of the reflection layer 3, meanwhile, with the refraction of sandwich layer 1 and covering 2
Rate difference as 0.01~0.15 mode in the sandwich layer 1 selective refraction rate be 1.45~1.60 acrylic resin,
The fluorine resin that selective refraction rate is 1.35~1.45 in the covering 2, on the other hand,
With maximum gauge become 0.05~1.0mm, luminous ray total light transmittance become 60% or more, haze value at
The covering 2 is formed for 20%~90% mode,
And then the functional group for having imported and having assigned the cementability relative to defined non-fluorine resin is used in the covering 2
Fluorine resin, meanwhile, using the non-fluorine resin with the fluorine resin of the covering 2 with cementability in reflection layer 3,
It is directly provided with adhesive linkage 4 on the reflection layer 3 and constitutes illuminator ontology R.
In addition, for above-mentioned adhesive linkage 4, double faced adhesive tape 41 can be attached on reflection layer 3 and formed, it is two-sided about this
Adhesive tape 41 can properly use the double faced adhesive tape for the acrylic acid series sticker for being coated with excellent heat resistance.
Moreover, about the fluorine resin used in above-mentioned covering 2, can select using optical property and with non-fluorine resin
Material excellent in adhesion, specifically, can properly use the hexafluoropropene for having imported functional group and tetrafluoroethene and
The copolymer of ethylene.It is explained, in the case where selecting the fluorine resin, it is preferable to use being imported with selected from carboxyl and carboxylate
At least one of functional group substance.
On the other hand, for the fluorine resin used in above-mentioned covering 2, being total in ethylene and tetrafluoroethene can also be used
Grafting is containing can be with the grafting of the functional group of the binding affinity group of the copolymer grafted and imparting cementability in polymers
The fluorine resin for closing object and manufacturing.Moreover, in such a situation it is preferred that using being imported with selected from carboxyl, carboxylic anhydride residue, epoxy group
And the fluorine resin of at least one of hydrolyzable silyl group functional group.
In addition, using the fluorine resin enumerated among the above, it is preferred to use with the bonding plane of these resins
The good polyamide series resin of congruence is as the non-fluorine resin used in above-mentioned reflection layer 3.
Moreover, about above-mentioned sandwich layer 1 and covering 2, it is configured to the section semicircle that there are planar portions in a part for peripheral surface
Shape, section half elliptic, section be fan-shaped or section rectangle, meanwhile, it is anti-in a manner of coating the planar portions of the covering 2 light to be arranged
Layer 3 is penetrated, and then adhesive linkage 4 is set on the outside, is easy that illuminator ontology R is made to be bent as a result, therefore, can make to being fixed
Object is easily installed.
Moreover, if the acrylic resin for the use of forming temperature being 190~250 DEG C in above-mentioned sandwich layer 1, in covering 2
The middle fluorine resin for the use of forming temperature being 230~300 DEG C, sandwich layer 1, covering 2 and reflection layer 3 are one by being coextruded forming
It is formed to body, is then efficiently manufactured in the case of mass production.
On the other hand, in the present invention, instead of the composition using above-mentioned illuminator ontology R, following structure can also be used
At：Using with the polyolefin cementability polymer with the cementability of the fluorine resin of covering 2 in reflection layer 3, it is not situated between
Enter prime coat and by the directly integration of the reflection layer 3 and adhesive linkage 4.
Invention effect
In the present invention, it in the plastic Linear luminophor that the outside of covering has reflection layer, is adopted in covering
With the special fluorine resin with the cementability with non-fluorine resin, and then using having bonding in the base material of reflection layer
The non-fluorine resin of property, it is possible thereby to directly attach or apply distributing double-sided adhesive tape, bonding agent in the outside of reflection layer.
Moreover, by forming adhesive linkage as described above, can be Nian Jie with fixation by Linear luminophor and simply pacify
Dress, therefore, can also facilitate the installation operation of fixation.In addition, in the present invention, in reflection layer and need not glue
It connects and prime coat is set between layer, therefore, be also not concerned about manufacturing process and complicate and manufacture efficiency is caused to reduce.
It is explained, due to having been used in above-mentioned reflection layer and the good non-fluorine system of the fluorine resin cementability of covering
Resin, accordingly it is also possible to prevent the splitting of covering and reflection layer.In addition, about reflection layer, if being coloured to white
Deng then the optical property of matrix resin will not produce a very large impact luminescent properties, therefore, will not make because of non-fluorine resin
With and cause luminescent properties to reduce.
On the other hand, can also make in reflection layer instead of using special fluorine resin in above-mentioned covering in addition
With the polyolefin cementability polymer excellent in adhesion with fluorine resin.Moreover, even if using the structure in the case of,
It can also be not provided with prime coat on the outside of reflection layer and adhesive linkage is directly set, therefore, effect similar to the above can be obtained
Fruit.
Therefore, according to the present invention it is possible to a kind of Linear luminophor that practicability is excellent be provided, not merely with fluorine resin
Optical property and obtain good luminescent properties, and the adhesive linkage of Linear luminophor can be attached to consolidated when in use
The surface of earnest and simply fix, therefore, practical utility value of the invention is very high.
Description of the drawings
Fig. 1 is the overall perspective view and end enlarged drawing for the structure for indicating the Linear luminophor in the embodiment of the present invention 1.
Specific implementation mode
" embodiment 1 "
The embodiment of the present invention 1 is illustrated based on Fig. 1.It is explained, is core with the instruction of symbol 1 in the figure
Layer is covering with the instruction of symbol 2.In addition, being reflection layer with the instruction of symbol 3, in addition, being bonding with the instruction of symbol 4
Layer.
[composition of Linear luminophor]
First, in embodiment 1, setting sandwich layer 1 (clava being made of transparent resin material) is used as illuminator ontology R
Light guide section, and then in the covering 2 (body being made of semi-transparent resin material) of the outside of the sandwich layer 1 setting thickness 0.2mm
As illumination region (referring to Fig.1).It is explained, in the present embodiment, transparent excellent gather has been used in the material of sandwich layer 1
Methyl methacrylate (PMMA).
Moreover, the hexafluoropropene and tetrafluoroethene and second for being imported with functional group are used in the material of above-mentioned covering 2 in turn
The copolymer (EFEP) of alkene adds 0.2wt% titanium dioxide as light diffusing particles in the fluorine resin material, is consequently formed
Translucent covering 2.It is explained, as the functional group imported in above-mentioned fluorine resin, can select selected from carboxyl, carboxylate
At least one of functional group.
Moreover, about above-mentioned sandwich layer 1, optical property is set to become refractive index 1.49, total light transmittance 93%, about covering
2, so that optical property is become refractive index 1.38, haze value 88.42%, total light transmittance 64.41%.In addition, with regard to above-mentioned sandwich layer 1
For the form of covering 2, be formed as cross sectional shape as half elliptic (the semicolumn bodily form of width 6.0mm, height 6.0mm
(か ま Pot こ shapes)).
Moreover, the planar portions of the peripheral surface of the covering 2 shaped in a manner of becoming half elliptic by above-mentioned cross sectional shape, with
The reflection layer 3 for the thickness 0.3mm being made of the opaque resin of white is arranged in the mode of cladding covering 2.It is explained, at this
In the matrix resin of reflection layer 3, using the good polyamide series resin of fluorine resin cementability with above-mentioned covering 2.
In addition, for above-mentioned reflection layer 3,1.0wt% titanium dioxide is added in resin.Moreover, will be equipped with above-mentioned
The illuminator ontology R of reflection layer 3 is fixed on light source (LED), research luminescent properties (luminous quantity, shine balance), as a result, with
There is no the illuminator of reflection layer 3, compared equipped with the illuminator of reflection layer 3 between sandwich layer 1 and covering 2, be can be obtained better
Good result.
In addition, in the present embodiment, in above-mentioned sandwich layer 1, covering 2 and reflection layer 3, forming temperature is used in sandwich layer 1
Degree is 190~250 DEG C of acrylic resin, and it is 230~300 DEG C of fluorine resin that forming temperature is used in covering 2, together
When, it also therefore can be by three layers by altogether for 230~300 DEG C of polyamide using forming temperature in reflection layer 3
Extrusion molding and it is formed integrally.
Moreover, in the more lateral of above-mentioned reflection layer 3, the two sides for being directly attached to sheet substrate is coated with the double of sticker
Face adhesive tape 41 and form adhesive linkage 4.Thus, it is possible to which illuminator ontology R facilitates the installation of fixation.It is explained,
In the present embodiment, the double faced adhesive tape that acrylic acid series sticker is coated in the sheet substrate being made of Foamex has been used
41。
It may be mentioned that being coated with the double faced adhesive tape 41 of above-mentioned acrylic acid series sticker relative to metal (aluminium etc.), modeling
Expect that (polyamide etc.), glass, the cementability of timber and heat resistance, weatherability, water resistance aspect are excellent, can also make
Be coated with other than acrylic acid series carbamate system, epoxy, rubber series (EPDM, silicone etc.) sticker double faced adhesive tape
Band 41.
" embodiment 2 "
Then, is carried out to the embodiment of the present invention 2 following illustrate.In the embodiment 2, used in the material of covering 2
Grafting is containing can be with the binding affinity group of the copolymer grafted and tax on the copolymer (ETFE) of ethylene and tetrafluoroethene
The fluorine resin for giving the grafting compound of the functional group of cementability and manufacturing, other compositions are set as similarly to Example 1.It is tied
Fruit, similarly to Example 1, the light that can be constituted by the covering 2 being made of above-mentioned fluorine resin and by polyamide series resin are anti-
Layer 3 is penetrated to be bonded securely.
Be explained, about the ETFE used in above-mentioned covering 1, can use be imported with selected from carboxyl, carboxylic anhydride residue
(2 carboxyls in 1 molecule have carried out the residue of dehydrating condensation), carbonate group, phosphinylidyne be fluorine-based, epoxy group, hydroxyl, isocyanates
At least one of base, ester group, amide groups, aldehyde radical, amino, hydrolyzable silyl group, cyano functional group is as imparting and non-fluorine
It is the substance of the functional group of the cementability of resin.
Additionally, it is preferred that using in above-mentioned functional group, especially it is imported with selected from carboxyl, carboxylic anhydride residue, epoxy group, water
The ETFE of at least one of solution property silicyl, cyano functional group.
Moreover, in turn about the binding affinity group imported in above-mentioned ETFE, the combination (meeting for participating in free radical may be used
Close) or addition insatiable hunger and/or saturation alkyl, participate in necleophilic reaction amino, phenolic hydroxyl group etc..Alternatively, it is also possible to using work
For easy to produce free radical group peroxy (パ ー オ キ シ Application base), azo group etc..It is explained, it is ideally, excellent
Select group (especially end is with α, the organic group of β unsaturated double-bonds), peroxy, amino with carbon-to-carbon unsaturated bond.
Moreover, as the grafting compound being grafted with above-mentioned ETFE, preferably unsaturated polycarboxylic acid anhydride, unsaturated carboxylic acid,
Unsaturated compound containing epoxy group, unsaturated compound containing hydrolyzable silyl group, per-compound containing epoxy group etc..
It is explained, for above-mentioned unsaturated polycarboxylic acid anhydride, has：It is maleic anhydride, itaconic anhydride, citraconic anhydride, bicyclic
[2.2.1] hept-2-ene" -5,6- dicarboxylic anhydrides etc..In addition, in unsaturated carboxylic acid, have：Acrylic acid, methacrylic acid, Malaysia
Acid, monomethyl maleate, fumaric acid, itaconic acid, citraconic acid, butenoic acid, bicyclic [2.2.1] hept-2-ene" -5,6- dicarboxylic anhydrides
Deng.
In addition, for above-mentioned unsaturated compound containing epoxy group, there are glycidyl acrylate, Glycidyl methacrylate sweet
Grease, glycidyl ether (ア Network リ グ リ シ ジ ル エ ー テ Le) etc..In addition, as insatiable hunger containing hydrolyzable silyl group
And compound, it is preferably bonded with vinyl, allyl, methacryloxyalkyl, acryloxyalkyl on the silicon atoms
Deng the compound of organic group 1 and the hydrolization groups 2~3 such as alkoxy, acyl group containing unsaturated group.Especially in silicon
The case where organic group 1 and at least one, preferably 2~3 hydrolization groups containing unsaturated group are bonded on atom
Under, remaining group is preferably the low alkyl groups such as methyl.
In addition, as specific unsaturated compound containing hydrolyzable silyl group, can enumerate：Vinyl trimethoxy silicon
Alkane, vinyltriethoxysilane, vinyltriacetoxy silane, vinyl three ('beta '-methoxy ethyoxyl) silane etc..
Moreover, in above-mentioned per-compound, have：Diacyl peroxide class, ketone peroxide class, hydroperoxides
Class, hydroperoxide type, peroxycarbonates class etc..In addition, as per-compound, the grafting chemical combination of preferred polymers type
Object.
" embodiment 3 "
Then, is carried out to the embodiment of the present invention 3 following illustrate.In the embodiment 3, using not leading in covering 2
Enter the ETFE of functional group, meanwhile, in reflection layer 3, glued using having the polyolefin of cementability with the fluorine resin of covering 2
Connecing property polymer (being Sumitomo Chemical system " BONDFAST (ボ Application De フ ァ ー ス ト, registered trademark) " in the present embodiment), is not situated between
Enter prime coat and by the directly integration of the reflection layer 3 and adhesive linkage 4.
In the case of using above-mentioned composition, it is also bonded covering 2 and reflection layer 3 and reflection layer 3 and adhesive linkage securely
4, it therefore, is not concerned about and splitting etc. occurs, adhesive linkage 3 can be made to be attached with fixation and be easy to carry out illuminator ontology
The installation of R.It is explained, in the present embodiment, adhesive linkage 4 is formed in the surface coating adhesive of reflection layer 3, as viscous
Agent is connect, the bonding agents such as epoxy, acrylic acid series, carbamate system, rubber series may be used.
[disbonded test of Linear luminophor]
Then, to use disbonded test that the Linear luminophor of above-described embodiment 1~3 carries out as a result, carrying out following say
It is bright.In the disbonded test, the Linear luminophor of above-described embodiment 1~3 is attached to the substrate of ABS resin, further
The substrate is fixed on to the state of the platform of universal testing machine along vertical direction pull-up Linear luminophor, visual confirmation substrate and line
The adhesive strength of shape illuminator.It is explained, disbonded test condition is set as：Test speed (pull-up speed)：200mm/min, examination
Test ambient temperature humidity：23 ± 2 DEG C of 50 ± 10%RH.
As a result, can be confirmed：The Linear luminophor of above-described embodiment 1~3 shows the number of peel strength 20N or more
Value, can be obtained sufficient adhesive strength.It is explained, in order to be compared with these Linear luminophors, in reflection layer 3
Disbonded test, but the fitting of the double faced adhesive tape to reflection layer 3 have also been attempted using there is the Linear luminophor of general fluororesin
Itself cannot be carried out.
The present invention is probably constituted as described above, but be not only by the content limited in the embodiment recorded, can be in " right
Made various changes in the record of claim ", for example, in sandwich layer 1 can use refractive index it is bigger than air 1.45~1.60
Acrylic resin, can not only enumerate polymethyl methacrylate, but also polyethyl methacrylate, poly- first can be enumerated
Base n-butyl acrylate, polyisobutyl methacrylate, polymethyl tert-butyl acrylate, polymethylacrylic acid 2- ethylhexyls
Deng.It is explained, at this point, selecting material in a manner of becoming 0.01~0.15 with the refringence of covering 2.
In addition, the material about above-mentioned covering 2, it can also use that refractive index is smaller than sandwich layer 1 and refractive index is bigger than air
1.35~1.45 fluorine resin can also use the function for having imported and having assigned the cementability relative to defined non-fluorine resin
The substance in addition to EFEP, ETFE of group.It is explained, the feelings of polyolefin cementability polymer is used in reflection layer 3
Under condition, the fluorine resin for not importing functional group can also be selected.
Moreover, if the maximum gauge of above-mentioned covering 2 is the range of 0.05~1.0mm, full light can be taken into account and penetrated
Rate and mist degree rate can obtain at this point, if the total light transmittance of covering 2 is 60% or more, haze value is 20%~90%
To the good lateral emitting of balance.
Moreover, in above-mentioned covering 2, it can also be added in the resin of layer be used as light scattering on the outside using multilayered structure
The metallics such as titanium dioxide, the silicon dioxide granule of particle, nonmetallic inorganic particulate.Alternatively, it is also possible to by including inside
3 layers or more of resin layer of layer and outer layer constitutes covering 2.
On the other hand, in addition about above-mentioned sandwich layer 1 and the cross sectional shape of covering 2, as long as in the part tool of peripheral surface
Have the shape of planar portions, even if not being then section half elliptic, for example, it is also possible to be configured to that section is semicircle, section is fan-shaped or
Section rectangle.In addition, in this case, reflection layer 3 is arranged in a manner of coating the planar portions of covering 2, and then on the outside
Form adhesive linkage 4.
In addition, about above-mentioned reflection layer 3, can be formed by the opaque resin material of white or silver color, in covering 2
In the case of using the fluorine resin for being imported with functional group, there can be reactive non-fluorine system tree from imported functional group
It freely selects and uses in fat.In addition, about the polyolefin cementability polymer used in reflection layer 3, can also make
With the substance other than being used in embodiment, any substance belongs to the technical scope of the present invention.
Industrial applicability
In recent years, in that case of carrying out the importing of LED in lamp decoration, electricity decorations signboard etc., threadiness of the invention shines
Body is only fixed a LED just and can made it in end and shone with threadiness, moreover, for luminescent properties, usability is excellent has
Technology, therefore, industrial utility value are very high.
The explanation of symbol
1 sandwich layer
2 coverings
3 reflection layers
4 adhesive linkages
41 double faced adhesive tapes
R illuminator ontologies
Claims (6)
1. a kind of Linear luminophor, which is characterized in that contain：Sandwich layer (1) is the clava containing transparent resin material, folding
It is bigger than air to penetrate rate；Covering (2), to coat the body for including semi-transparent resin material of the sandwich layer (1), refractive index compares sandwich layer
(1) small and refractive index is bigger than air；Reflection layer (3) is formed in the outside of the covering (2)；And adhesive linkage (4), it sets
The outside in the reflection layer (3) is set,
And then selection is rolled in the sandwich layer (1) in such a way that the refringence of sandwich layer (1) and covering (2) becomes 0.01~0.15
Penetrate the acrylic resin that rate is 1.45~1.60, the fluorine system tree that selective refraction rate is 1.35~1.45 in the covering (2)
Fat, on the other hand,
The covering (2) with maximum gauge become 0.05~1.0mm, luminous ray total light transmittance become 60% or more,
Haze value is formed as 20%~90% mode,
And then it is used in the covering (2) and is imported with the functional group for assigning the cementability relative to defined non-fluorine resin
Fluorine resin, meanwhile, the non-fluorine system tree with the fluorine resin of the covering (2) with cementability is used in reflection layer (3)
Fat is directly provided with adhesive linkage (4) on the reflection layer (3),
It has been imported in the fluorine resin wherein used in covering (2) and has been selected from least one of carboxyl and carboxylate functional group,
The non-fluorine resin used in reflection layer (3) is polyamide series resin.
2. Linear luminophor according to claim 1, which is characterized in that attach double faced adhesive tape on reflection layer (3)
(41) adhesive linkage (4) is formd.
3. Linear luminophor according to claim 2, which is characterized in that used acrylic acid series in double faced adhesive tape (41)
Sticker.
4. Linear luminophor described in any one of claim 1 to 3, which is characterized in that the fluorine system used in covering (2)
Resin is the copolymer of hexafluoropropene and tetrafluoroethene and ethylene that be imported with functional group.
5. Linear luminophor according to claim 1, which is characterized in that sandwich layer (1) and covering (2) are configured in peripheral surface
A part there is section semicircle of planar portions, section half elliptic, section sector or section rectangle, meanwhile, to coat
Reflection layer (3) is arranged in the mode for stating the planar portions of covering (2), and then forms adhesive linkage (4) on the outside.
6. Linear luminophor according to claim 1, which is characterized in that in the sandwich layer (1) using forming temperature be 190~
250 DEG C of acrylic resin, the fluorine resin for the use of forming temperature being 230~300 DEG C in covering (2), sandwich layer (1), packet
Layer (2) and reflection layer (3) are integrally formed by forming by being coextruded.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-202389 | 2013-09-27 | ||
| JP2013202389A JP5888788B2 (en) | 2013-09-27 | 2013-09-27 | Linear illuminant and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104516049A CN104516049A (en) | 2015-04-15 |
| CN104516049B true CN104516049B (en) | 2018-07-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410384534.9A Active CN104516049B (en) | 2013-09-27 | 2014-08-07 | Linear luminophor |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5888788B2 (en) |
| KR (1) | KR101631853B1 (en) |
| CN (1) | CN104516049B (en) |
| TW (1) | TWI561869B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10197722B2 (en) * | 2015-09-02 | 2019-02-05 | Fukuvi Chemical Industry Co., Ltd. | Flexible linear light emitting element and a method of producing the same |
| JP7083336B2 (en) * | 2017-03-31 | 2022-06-10 | フクビ化学工業株式会社 | Peripheral light emitting type thermoplastic resin molded body |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101858527A (en) * | 2010-05-17 | 2010-10-13 | 鹤山丽得电子实业有限公司 | Ultrathin flexible lamp band |
| CN202075439U (en) * | 2011-03-11 | 2011-12-14 | 北京君鹏鑫新技术开发有限公司 | Linear luminophor |
| CN102401264A (en) * | 2011-07-22 | 2012-04-04 | 苏州晶雷光电照明科技有限公司 | LED (light-emitting diode) soft lamp strip |
| CN102673024A (en) * | 2011-03-11 | 2012-09-19 | 北京君鹏鑫新技术开发有限公司 | Linear luminous body and manufacturing method thereof |
| JP2013057924A (en) * | 2011-08-18 | 2013-03-28 | Fukuvi Chem Ind Co Ltd | Optical fiber type linear luminous body |
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| JPS62265605A (en) * | 1986-05-13 | 1987-11-18 | Mitsui Petrochem Ind Ltd | Optical fiber having clad part essentially consisting of fluorine polymer |
| JPH0720323A (en) * | 1993-07-02 | 1995-01-24 | Mitsubishi Rayon Co Ltd | Lighting plastic optical fiber |
| JPH10311461A (en) | 1997-05-12 | 1998-11-24 | Asahi Glass Co Ltd | Fuel hose |
| US6123442A (en) * | 1997-10-24 | 2000-09-26 | Minnesota Mining And Manufacturing Company | Articles with diffuse reflection of light from light fibers |
| JP4096291B2 (en) * | 2002-02-13 | 2008-06-04 | 旭硝子株式会社 | Fluorine-containing copolymer |
| EP1558951A1 (en) * | 2002-10-21 | 2005-08-03 | Plastic Inventions and Patents, Inc. | Compound optical and electrical conductors, and connectors therefor |
| JPWO2008032724A1 (en) * | 2006-09-14 | 2010-01-28 | 東レ株式会社 | Optical waveguide film |
| JP5184437B2 (en) * | 2009-05-15 | 2013-04-17 | 旭化成イーマテリアルズ株式会社 | Multicore plastic optical fiber bare wire and cable |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101858527A (en) * | 2010-05-17 | 2010-10-13 | 鹤山丽得电子实业有限公司 | Ultrathin flexible lamp band |
| CN202075439U (en) * | 2011-03-11 | 2011-12-14 | 北京君鹏鑫新技术开发有限公司 | Linear luminophor |
| CN102673024A (en) * | 2011-03-11 | 2012-09-19 | 北京君鹏鑫新技术开发有限公司 | Linear luminous body and manufacturing method thereof |
| CN102401264A (en) * | 2011-07-22 | 2012-04-04 | 苏州晶雷光电照明科技有限公司 | LED (light-emitting diode) soft lamp strip |
| JP2013057924A (en) * | 2011-08-18 | 2013-03-28 | Fukuvi Chem Ind Co Ltd | Optical fiber type linear luminous body |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI561869B (en) | 2016-12-11 |
| JP2015069808A (en) | 2015-04-13 |
| KR20150035381A (en) | 2015-04-06 |
| JP5888788B2 (en) | 2016-03-22 |
| TW201512586A (en) | 2015-04-01 |
| KR101631853B1 (en) | 2016-06-20 |
| CN104516049A (en) | 2015-04-15 |
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