CN104513440A - High temperature resistant plastic formula suitable for automotive interior - Google Patents
High temperature resistant plastic formula suitable for automotive interior Download PDFInfo
- Publication number
- CN104513440A CN104513440A CN201410698468.2A CN201410698468A CN104513440A CN 104513440 A CN104513440 A CN 104513440A CN 201410698468 A CN201410698468 A CN 201410698468A CN 104513440 A CN104513440 A CN 104513440A
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- CN
- China
- Prior art keywords
- plastic formula
- applicable
- fire retardant
- automotive trim
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
The invention discloses a high temperature resistant plastic formula suitable for automotive interior, the high temperature resistant plastic formula comprises the following components by mass: 68%-76% of polyvinyl chloride resin, 6%-8% of a smokeless flame retardant, 6%-17% of a modifier, 3%-7% of a heat stabilizer and 3%-12% of filler, and the smokeless flame retardant is melamine phosphate and zinc borate mixture. The plastic produced by the high temperature resistant plastic formula is flame retardant, and has smoke retardant effect, once the plastic is burnt, human body injury caused by smoke can be reduced, and the flame retardant grade of the plastic produced by optimal proportion is V-0.
Description
Technical field
A formula, particularly a kind of plastic formula.
Background technology
Automotive trim is generally adopted made of plastic, but during summer, solar exposure, causes vehicle interior temperature high, and Ruo Chenei has inflammable substance to catch fire, and produces the mishap that blast waits the harm people security of the lives and property; This just needs car interior trim to have certain flame retardant properties, and prior art is unresolved such problem also.
Summary of the invention
For solving the deficiencies in the prior art, the object of the present invention is to provide a kind of plastic formula with good flame retardant properties; Optimal proportion energy plastic flame grade V-0.
In order to realize above-mentioned target, the present invention adopts following technical scheme:
Be applicable to the High-temperature-resplastic plastic formula of automotive trim, comprise: polyvinyl chloride (PVC) RESINS, fire retardant, modification agent, thermo-stabilizer, weighting agent; The mass percent ratio of each component is respectively: polyvinyl chloride (PVC) RESINS 68%-76%, smokeless fire retardant 6%-8%, modification agent 6%-17%, thermo-stabilizer 3%-7%, weighting agent 3%-12%; Fire retardant is the mixture of melamine phosphate and zinc borate.
The aforesaid formula of flame-retardant plastic being applicable to automotive trim, the mass percent ratio of each component of fire retardant is: melamine phosphate 84%, zinc borate 16%.
The aforesaid formula of flame-retardant plastic being applicable to automotive trim, modification agent is acrylic acid class modification agent.
The aforesaid formula of flame-retardant plastic being applicable to automotive trim, thermo-stabilizer is thiol organotin.
The aforesaid formula of flame-retardant plastic being applicable to automotive trim, weighting agent is silicon-dioxide.
The aforesaid formula of flame-retardant plastic being applicable to automotive trim, the optimum quality percentage of each component is respectively: polyvinyl chloride (PVC) RESINS 74%, fire retardant 7%, modification agent 11%, thermo-stabilizer 4%, weighting agent 4%.
Usefulness of the present invention is: the invention provides a kind of plastic formula with good flame retardant properties, the plastics made are not only fire-retardant, and has the effect of resistance cigarette, reduces the injury of cigarette to the human body in car once burn; Optimal proportion energy plastic flame grade V-0.
Embodiment
Below in conjunction with specific embodiment, concrete introduction is done to the present invention.
Be applicable to the High-temperature-resplastic plastic formula of automotive trim, comprise: polyvinyl chloride (PVC) RESINS, fire retardant, modification agent, thermo-stabilizer, weighting agent; The mass percent ratio of each component is respectively: polyvinyl chloride (PVC) RESINS 68%-76%, smokeless fire retardant 6%-8%, modification agent 6%-17%, thermo-stabilizer 3%-7%, weighting agent 3%-12%; Fire retardant is the mixture of melamine phosphate and zinc borate.The mass percent ratio of each component of fire retardant is: melamine phosphate 84%, zinc borate 16%.Modification agent is acrylic acid class modification agent.Thermo-stabilizer is thiol organotin.Weighting agent is silicon-dioxide.Silicon-dioxide as the nontoxic few cigarette of weighting agent, fuel value is low, flame propagation velocity is slow; Zinc borate has smoke-suppressing.
The optimum quality percentage of each component is respectively: polyvinyl chloride (PVC) RESINS 74%, fire retardant 7%, modification agent 11%, thermo-stabilizer 4%, weighting agent 4%.
Embodiment 1:
Polyvinyl chloride (PVC) RESINS 68%, fire retardant 6%, modification agent 14%, thermo-stabilizer 3%, weighting agent 9%;
Embodiment 2:
Polyvinyl chloride (PVC) RESINS 74%, fire retardant 7%, modification agent 11%, thermo-stabilizer 4%, weighting agent 4%;
Embodiment 3:
Polyvinyl chloride (PVC) RESINS 76%, fire retardant 8%, modification agent 8%, thermo-stabilizer 5%, weighting agent 3%;
By the plastics that the formula of 3 embodiments is above made, carry out twice combustion testings of 10 seconds to sample, test result is as follows:
33 seconds first times of sample of embodiment 1 extinguish, and fall down without combustionmaterial, and second time is extinguished for 34 seconds, falls down without combustionmaterial.
26 seconds first times of sample of embodiment 2 extinguish, and fall down without combustionmaterial, and second time is extinguished for 25 seconds, falls down without combustionmaterial.
35 seconds first times of sample of embodiment 3 extinguish, and fall down without combustionmaterial, and second time is extinguished for 36 seconds, falls down without combustionmaterial.
According to plastic flame grade: V-0: carry out twice combustion testings of 10 seconds to sample, flame extinguished in 30 seconds; Combustionmaterial can not be had to fall down.V-1: after carrying out twice combustion testings of 10 seconds to sample, flame extinguished in 60 seconds; Under can not combustionmaterial being had.
Show that embodiment 1,3 flame retardant rating is V-1, embodiment 2 flame retardant rating is V-0, and embodiment 2 is optimal proportion.
The invention provides a kind of plastic formula with good flame retardant properties, the plastics made are not only fire-retardant, and have the effect of resistance cigarette, reduce the injury of cigarette to the human body in car once burn; Optimal proportion energy plastic flame grade V-0.
More than show and describe ultimate principle of the present invention, principal character and advantage.The technician of the industry should understand, and above-described embodiment does not limit the present invention in any form, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, and all drops in protection scope of the present invention.
Claims (6)
1. be applicable to the High-temperature-resplastic plastic formula of automotive trim, comprise: polyvinyl chloride (PVC) RESINS, fire retardant, modification agent, thermo-stabilizer, weighting agent; The mass percent ratio of each component is respectively: polyvinyl chloride (PVC) RESINS 68%-76%, smokeless fire retardant 6%-8%, modification agent 6%-17%, thermo-stabilizer 3%-7%, weighting agent 3%-12%; Above-mentioned fire retardant is the mixture of melamine phosphate and zinc borate.
2. the High-temperature-resplastic plastic formula being applicable to automotive trim according to claim 1, is characterized in that, the mass percent ratio of each component of above-mentioned fire retardant is: melamine phosphate 84%, zinc borate 16%.
3. the High-temperature-resplastic plastic formula being applicable to automotive trim according to claim 1, is characterized in that, above-mentioned modification agent is acrylic acid class modification agent.
4. the High-temperature-resplastic plastic formula being applicable to automotive trim according to claim 1, is characterized in that, above-mentioned thermo-stabilizer is thiol organotin.
5. the High-temperature-resplastic plastic formula being applicable to automotive trim according to claim 1, is characterized in that, above-mentioned weighting agent is silicon-dioxide.
6. the High-temperature-resplastic plastic formula being applicable to automotive trim according to claim 1, is characterized in that, the optimum quality percentage of each component is respectively: polyvinyl chloride (PVC) RESINS 74%, fire retardant 7%, modification agent 11%, thermo-stabilizer 4%, weighting agent 4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410698468.2A CN104513440A (en) | 2014-11-28 | 2014-11-28 | High temperature resistant plastic formula suitable for automotive interior |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410698468.2A CN104513440A (en) | 2014-11-28 | 2014-11-28 | High temperature resistant plastic formula suitable for automotive interior |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104513440A true CN104513440A (en) | 2015-04-15 |
Family
ID=52789327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410698468.2A Pending CN104513440A (en) | 2014-11-28 | 2014-11-28 | High temperature resistant plastic formula suitable for automotive interior |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104513440A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349586A (en) * | 2015-07-23 | 2017-01-25 | 王金青 | Flame retardant PVC plastic for automobile interior decoration |
| CN109957188A (en) * | 2017-12-26 | 2019-07-02 | 江苏环宇汽车零部件有限公司 | A kind of vehicle inside decoration fire proofing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1439674A (en) * | 2003-03-18 | 2003-09-03 | 四川大学 | Polyvinyl chloride reinforcing and tougheness improving modifier and preparation and application thereof |
| CN102850691A (en) * | 2012-08-08 | 2013-01-02 | 佛山市天安塑料有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
| CN103059438A (en) * | 2011-10-20 | 2013-04-24 | 常熟市筑紫机械有限公司 | Flame retardant cross-linked polyvinyl chloride wire and cable material |
-
2014
- 2014-11-28 CN CN201410698468.2A patent/CN104513440A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1439674A (en) * | 2003-03-18 | 2003-09-03 | 四川大学 | Polyvinyl chloride reinforcing and tougheness improving modifier and preparation and application thereof |
| CN103059438A (en) * | 2011-10-20 | 2013-04-24 | 常熟市筑紫机械有限公司 | Flame retardant cross-linked polyvinyl chloride wire and cable material |
| CN102850691A (en) * | 2012-08-08 | 2013-01-02 | 佛山市天安塑料有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349586A (en) * | 2015-07-23 | 2017-01-25 | 王金青 | Flame retardant PVC plastic for automobile interior decoration |
| CN109957188A (en) * | 2017-12-26 | 2019-07-02 | 江苏环宇汽车零部件有限公司 | A kind of vehicle inside decoration fire proofing |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150415 |
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| RJ01 | Rejection of invention patent application after publication |