CN104449163A - Environment-friendly fireproof emulsion paint for exterior wall - Google Patents
Environment-friendly fireproof emulsion paint for exterior wall Download PDFInfo
- Publication number
- CN104449163A CN104449163A CN201310441387.XA CN201310441387A CN104449163A CN 104449163 A CN104449163 A CN 104449163A CN 201310441387 A CN201310441387 A CN 201310441387A CN 104449163 A CN104449163 A CN 104449163A
- Authority
- CN
- China
- Prior art keywords
- exterior wall
- emulsion paint
- environmental protection
- wall fireproof
- fireproof emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides an environment-friendly fireproof emulsion paint for an exterior wall. The environment-friendly fireproof emulsion paint for the exterior wall comprises chlorine resin, ammonium polyphosphate, diethylenetriamine pentaacetic acid, melamine, sodium nitrilo triacetate, monoammonium phosphate, a pure acrylic emulsion, a preservative, an inorganic packing, an organic fire retardant, expanded graphite and a foaming agent. The environment-friendly fireproof emulsion paint has the advantages that the burning characteristics of the material can be changed; the fire propagation is delayed; the fire resistance is improved; and combustion can also be blocked within a certain period of time.
Description
Technical field
The invention relates to external wall field of material technology, particularly relates to a kind of environmental protection exterior wall fireproof emulsion paint.
Background technology
Under the national conditions that Highrise buildings is more and more higher, we comprehensively spread out energy-conservation work and consciousness in residential construction area, comprehensively apply widely architectural having obtained at high-rise outer wall energy-saving and heat-insulating material, but the application of these materials also brings a little problem, it is exactly the defect of exterior wall fireproof, easy generation fire, and the rate of propagation of fire is also very fast, directly endangers the security of the lives and property of people.
Environmental protection exterior wall fireproof emulsion paint can play a fireproofing function, and why frie retardant coating can play fireproofing function, key factor in following some:
(1) frie retardant coating chance fire is heated, and releases non-flame properties rare gas element, can water down the oxygen in the inflammable gas and air of releasing when base material heated decomposes, suppress burning.
(2) frie retardant coating decomposes that is nitrogenous, phosphorus releases some living radical groups, is combined with organic free radical, interrupts chain reaction, reduces or stops burning.
(3) to meet fire expanded foamed for fire-proof dilatation, forms the expansion carbon-coating of spongy or cellular heat insulation, oxygen barrier, close protected base material, stop base burn.
(4) chemical actions such as the decomposition of the physical change such as softening, melting, expansion of coating and polymkeric substance, filler, auxiliary agent, evaporation and charing will absorb amount of heat, offset a part of external influence in the heat of object, thus retardation is risen to the temperature-rise period that is heated of ground.
The present invention is mixed with a kind of environmental protection exterior wall fireproof emulsion paint in conjunction with this several fp mechanism.
Summary of the invention
The problem that the invention will solve is a kind of environmental protection exterior wall fireproof emulsion paint, fire rapid spread problem during solution fire.
For solving the problems of the technologies described above, the technical scheme that the invention adopts is: a kind of environmental protection exterior wall fireproof emulsion paint, its constituent mass per-cent is: chlorine-containing resins 10-15%, ammonium polyphosphate 5-8%, diethylenetriamine pentaacetic acid 8-12%, ultrapas 12-20%, nitrilotriacetic acid sodium salt 5-10%, primary ammonium phosphate 8-16%, pure-acrylic emulsion 10-35%, sanitas 1-5%, mineral filler 5-15%, organic fire-retardant 5-8%, expanded graphite 10-18%, whipping agent 3-5%.
Described chlorine-containing resins is one or more in chlorinated rubber, chlorinated polyester, polyvinylidene dichloride, chlorination epoxy, polyvinyl chloride.
Organic fire-retardant be phosphorus-halogen, phosphorus-nitrogen, a hexabromo water prose style free from parallelism, ten bromo-antimonous oxides one or more.
Described mineral filler be asbestos powder, aluminum phosphate, titanium dioxide, glass powder, talcum powder, zinc oxide one or more.
Described sanitas be p-hydroxybenzoic acid, propylparaben, Sodium.alpha.-hydroxypropionate, sodium Diacetate one or more.
China's Properties of Fire-Proofing Coatings testing standard, the frie retardant coating quality test of China is carried out according to GB12441-2005.Finishing fire retardant paint technical requirements should meet table 1 specified requirement.
Table 1
Also has a kind of technical indicator of architectural fireproof paint, in table 2.
Table 2
The advantage that the invention has and positively effect are:
(1) coating can stop spreading of flint effectively, thus allow people again enough time leave hazardous location.
(2) can also play certain insulation effect after being coated with emulsion paint, be very important energy saving means in this guarantor of high level insulation effect.
Embodiment,
Embodiment 1
A kind of collocation method of environmental protection exterior wall fireproof emulsion paint, according to mass percent configuration, chlorinated polyester 5%, adjudicate two cases together ethene 5%, ammonium polyphosphate 8%, diethylenetriamine pentaacetic acid 8%, trimeric cyanamide 12%, nitrilotriacetic acid sodium salt 6%, primary ammonium phosphate 8%, pure-acrylic emulsion 23%, hydroxybenzoate 2%, titanium dioxide 2%, talcum powder 3%, a hexabromo water prose style free from parallelism 5%, expanded graphite 10%, whipping agent 3%.
Embodiment 2
A kind of collocation method of environmental protection exterior wall fireproof emulsion paint, according to mass percent configuration, polyvinylidene dichloride 10%, ammonium polyphosphate 8%, diethylenetriamine pentaacetic acid 8%, trimeric cyanamide 12%, nitrilotriacetic acid sodium salt 6%, primary ammonium phosphate 8%, pure-acrylic emulsion 23%, propylparaben 2%, aluminum phosphate 2%, zinc oxide 3%, a hexabromo water prose style free from parallelism 5%, expanded graphite 10%, whipping agent 3%.
Embodiment 3
A kind of collocation method of environmental protection exterior wall fireproof emulsion paint, according to mass percent configuration, chlorinated polyester 10%, ammonium polyphosphate 8%, diethylenetriamine pentaacetic acid 8%, trimeric cyanamide 12%, nitrilotriacetic acid sodium salt 6%, primary ammonium phosphate 8%, pure-acrylic emulsion 23%, Sodium.alpha.-hydroxypropionate 2%, asbestos powder 5%, a hexabromo water prose style free from parallelism 5%, expanded graphite 10%, whipping agent 3%.
Prepare the emulsion paint of embodiment 1,2,3, according to " finishing fire retardant paint " GB12441-2005, test, the results are shown in Table 3
Table 3
Preparation embodiment 4,5,6, according to the form below proportioning configures,
| Raw material | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Chlorine-containing resins | 10 | 12 | 13 |
| Ammonium polyphosphate | 5 | 7 | 8 |
| Diethylenetriamine pentaacetic acid | 12 | 9 | 8 |
| Ultrapas | 18 | 15 | 13 |
| Nitrilotriacetic acid sodium salt | 6 | 6 | 5 |
| Primary ammonium phosphate | 12 | 8 | 11 |
| Pure-acrylic emulsion | 12 | 17 | 16 |
| Sanitas | 1 | 1 | 1 |
| Mineral filler | 6 | 5 | 6 |
| Organic fire-retardant | 5 | 7 | 6 |
| Expanded graphite | 10 | 10 | 10 |
| Whipping agent | 3 | 3 | 3 |
Be mixed with embodiment 4,5,6 to carry out combustion testing and the results are shown in Table 4
Table 4
Can find out from above-mentioned table and can play fireproofing function by a kind of environmental protection exterior wall fireproof emulsion paint that this law is invented, leave valuable time escape can to you people when fire spread.
Claims (5)
1. an environmental protection exterior wall fireproof emulsion paint, it is characterized in that, its constituent mass per-cent is: chlorine-containing resins 10-15%, ammonium polyphosphate 5-8%, diethylenetriamine pentaacetic acid 8-12%, ultrapas 12-20%, nitrilotriacetic acid sodium salt 5-10%, primary ammonium phosphate 8-16%, pure-acrylic emulsion 10-35%, sanitas 1-5%, mineral filler 5-15%, organic fire-retardant 5-8%, expanded graphite 10-18%, whipping agent 3-5%.
2. a kind of environmental protection exterior wall fireproof emulsion paint according to claim 1, is characterized in that: described chlorine-containing resins is one or more in chlorinated rubber, chlorinated polyester, polyvinylidene dichloride, chlorination epoxy, polyvinyl chloride.
3. a kind of environmental protection exterior wall fireproof emulsion paint according to claim 1, is characterized in that: organic fire-retardant be phosphorus-halogen, phosphorus-nitrogen, a hexabromo water prose style free from parallelism, ten bromo-antimonous oxides one or more.
4. a kind of environmental protection exterior wall fireproof emulsion paint according to claim 1, is characterized in that: described mineral filler be asbestos powder, aluminum phosphate, titanium dioxide, glass powder, talcum powder, zinc oxide one or more.
5. according to claim a kind of environmental protection exterior wall fireproof emulsion paint, is characterized in that: described sanitas be p-hydroxybenzoic acid, propylparaben, Sodium.alpha.-hydroxypropionate, sodium Diacetate one or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310441387.XA CN104449163A (en) | 2013-09-24 | 2013-09-24 | Environment-friendly fireproof emulsion paint for exterior wall |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310441387.XA CN104449163A (en) | 2013-09-24 | 2013-09-24 | Environment-friendly fireproof emulsion paint for exterior wall |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104449163A true CN104449163A (en) | 2015-03-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310441387.XA Pending CN104449163A (en) | 2013-09-24 | 2013-09-24 | Environment-friendly fireproof emulsion paint for exterior wall |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104449163A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107858864A (en) * | 2017-10-29 | 2018-03-30 | 贵州铜仁华毅新型材料科技有限公司 | A kind of fire-retardant honeycomb paper core and preparation method thereof |
| CN108690434A (en) * | 2017-02-24 | 2018-10-23 | 天长市安德丽节能建材有限公司 | A kind of water-proofing anticracking coating |
| CN111635686A (en) * | 2020-07-21 | 2020-09-08 | 湖北巴乐福化工科技有限公司 | Fireproof paint for interior wall and processing method thereof |
| CN113372745A (en) * | 2021-06-22 | 2021-09-10 | 叶侨兴 | Original ecological environment-friendly building material preservative and preparation method thereof |
-
2013
- 2013-09-24 CN CN201310441387.XA patent/CN104449163A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108690434A (en) * | 2017-02-24 | 2018-10-23 | 天长市安德丽节能建材有限公司 | A kind of water-proofing anticracking coating |
| CN107858864A (en) * | 2017-10-29 | 2018-03-30 | 贵州铜仁华毅新型材料科技有限公司 | A kind of fire-retardant honeycomb paper core and preparation method thereof |
| CN111635686A (en) * | 2020-07-21 | 2020-09-08 | 湖北巴乐福化工科技有限公司 | Fireproof paint for interior wall and processing method thereof |
| CN113372745A (en) * | 2021-06-22 | 2021-09-10 | 叶侨兴 | Original ecological environment-friendly building material preservative and preparation method thereof |
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Application publication date: 20150325 |