CN105199182A - Polyolefin flame retardant - Google Patents
Polyolefin flame retardant Download PDFInfo
- Publication number
- CN105199182A CN105199182A CN201510726997.3A CN201510726997A CN105199182A CN 105199182 A CN105199182 A CN 105199182A CN 201510726997 A CN201510726997 A CN 201510726997A CN 105199182 A CN105199182 A CN 105199182A
- Authority
- CN
- China
- Prior art keywords
- flame retardant
- parts
- fire retardant
- retardant
- polyolefine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/12—Adsorbed ingredients, e.g. ingredients on carriers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/326—Magnesium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
Abstract
The invention provides a polyolefin flame retardant. The polyolefin flame retardant comprises effective components as follows: 1-5 parts of aluminum hydroxide, 10-15 parts of magnesium phosphate, 3-10 parts of ferric oxide and 30-80 parts of brucite powder. The components are supported on a carrier, and the flame retardant is formed. The polyolefin flame retardant has the benefits that the polyolefin flame retardant doesn't contain a halogen element, cannot pollute the environment, is low in cost and suitable for industrial production and has an excellent flame retardant property.
Description
Technical field
The invention belongs to olefin product technical field, especially relate to a kind of polyolefine fire retardant.
Background technology
Fire retardant, give the functional aid of combustible polymers flame retardancy, mainly for the Principle And Method of Flame Retardation Design of macromolecular material; Material after fire retardant processing, when being subject to extraneous burning things which may cause a fire disaster and attacking, effectively can stop, delay or stop flame transmission, thus reach fire-retardant effect.Fire retardant has broad variety, is divided into additive flame retardant and reactive flame retardant by using method.
Additive flame retardant joins in polymkeric substance by mechanical mix techniques, polymkeric substance is made to have flame retardant resistance, current additive flame retardant mainly contains organic fire-retardant and inorganic combustion inhibitor, halogenated flame retardant (organic chloride and organic bromide) and non-halogen.Organic is be representative with bromine system, phosphorus nitrogen system, nitrogen system and red phosphorus and compound some fire retardants, inorganic mainly antimonous oxide, magnesium hydroxide, aluminium hydroxide, the flame-retardant systems such as silicon system.
Reactive flame retardant is then participate in polyreaction as a kind of monomer, and therefore make polymkeric substance itself containing flame-retardant composition, its advantage affects less on polymer materials use properties, and flame retardant resistance is lasting.
Usually in polyolefine material is flame-retardant modified, the normal method adopted is additive flame retardant blending and modifying.
Polyolefine material is output and the maximum family macromolecule material of consumption in the world now, and along with people are to environment and inherently safe pay attention to day by day, flame retardant polyolefine material is a focus of researching and developing from now on.Therefore, polyolefine material fire retardant has good development potentiality and wide market outlook.
Summary of the invention
The object of this invention is to provide a kind of polyolefine fire retardant, not halogen-containing in fire retardant systems, be a kind of environmentally friendly fire retardant.
Technical scheme of the present invention is: polyolefine fire retardant of the present invention, comprises following effective constituent:
Aluminium hydroxide 1-5 part
Trimagnesium phosphate 10-15 part
Ferric oxide 3-10 part
Brucite powder 30-80 part;
Above combined composition load, on carrier, forms fire retardant.
Preferably, described carrier is silicon-dioxide, aluminium sesquioxide or gac.
The advantage that the present invention has and positively effect are:
1, fire retardant systems of the present invention, not containing halogen element, can not produce environment and pollute.
2, the addition of aluminium hydroxide is low, with low cost, is applicable to suitability for industrialized production.
3, superior flame retardant property.
Embodiment
Embodiment 1:
A kind of polyolefine fire retardant of the present embodiment, comprises following effective constituent:
5 parts, aluminium hydroxide
Trimagnesium phosphate 15 parts
Ferric oxide 10 parts
Brucite powder 70 parts;
Above combined composition mixing and stirring back loading, on carrier, forms fire retardant.
Preferably, described carrier is silicon-dioxide.
Embodiment 2:
A kind of polyolefine fire retardant of the present embodiment, comprises following effective constituent:
3 parts, aluminium hydroxide
Trimagnesium phosphate 15 parts
Ferric oxide 5 parts
Brucite powder 77 parts;
Above combined composition mixing and stirring back loading, on carrier, forms fire retardant.
Preferably, described carrier is aluminium sesquioxide.
Embodiment 3:
A kind of polyolefine fire retardant of the present embodiment comprises following effective constituent:
1 part, aluminium hydroxide
Trimagnesium phosphate 10 parts
Ferric oxide 9 parts
Brucite powder 80 parts;
Above combined composition mixing and stirring back loading, on carrier, forms fire retardant.
Preferably, described carrier is gac.
Embodiment 4:
A kind of polyolefine fire retardant of the present embodiment, comprises following effective constituent:
5 parts, aluminium hydroxide
Trimagnesium phosphate 10 parts
Ferric oxide 10 parts
Brucite powder 80 parts;
Above combined composition load, on carrier, forms fire retardant.
Preferably, described carrier is aluminium sesquioxide.
Above four embodiments of the present invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should still belong within patent covering scope of the present invention.
Claims (2)
1. a polyolefine fire retardant, is characterized in that: comprise following effective constituent:
Aluminium hydroxide 1-5 part
Trimagnesium phosphate 10-15 part
Ferric oxide 3-10 part
Brucite powder 30-80 part;
Above combined composition load, on carrier, forms fire retardant.
2. a kind of polyolefine fire retardant according to claim 1, is characterized in that: described carrier is silicon-dioxide, aluminium sesquioxide or gac.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510726997.3A CN105199182A (en) | 2015-10-28 | 2015-10-28 | Polyolefin flame retardant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510726997.3A CN105199182A (en) | 2015-10-28 | 2015-10-28 | Polyolefin flame retardant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105199182A true CN105199182A (en) | 2015-12-30 |
Family
ID=54947160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510726997.3A Pending CN105199182A (en) | 2015-10-28 | 2015-10-28 | Polyolefin flame retardant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105199182A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633897A (en) * | 2016-12-31 | 2017-05-10 | 铜陵华科电子材料有限公司 | Formula of halogen-free flame-retardant aid |
| CN109265751A (en) * | 2018-08-21 | 2019-01-25 | 南京林业大学 | A kind of activated carbon fiber-loaded composite nanometer flame retardant and method for coating |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1869113A (en) * | 2006-06-09 | 2006-11-29 | 沈阳化工学院 | Halogenless composite fire retardant for polyolefine plastic |
-
2015
- 2015-10-28 CN CN201510726997.3A patent/CN105199182A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1869113A (en) * | 2006-06-09 | 2006-11-29 | 沈阳化工学院 | Halogenless composite fire retardant for polyolefine plastic |
Non-Patent Citations (3)
| Title |
|---|
| 姚守信: "《无机精细化工》", 31 March 1994 * |
| 欧育湘: "《实用阻燃技术》", 31 January 2002 * |
| 葛世成: "《塑料阻燃实用技术》", 29 February 2004 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633897A (en) * | 2016-12-31 | 2017-05-10 | 铜陵华科电子材料有限公司 | Formula of halogen-free flame-retardant aid |
| CN109265751A (en) * | 2018-08-21 | 2019-01-25 | 南京林业大学 | A kind of activated carbon fiber-loaded composite nanometer flame retardant and method for coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103408891A (en) | High-molecular flame-retardant foam material and preparation method thereof | |
| CN103524896A (en) | Halogen-free insulated cable material for irradiation crosslinking EPCV photovoltaics at temperature of 125 DEG C and preparation method | |
| CN104513420B (en) | A kind of Halogen no red phosphorus heat-shrinkable T bush and preparation method thereof | |
| CN109593266B (en) | Ultralow-smoke-density halogen-free flame-retardant cable material and preparation method thereof | |
| CN104292601A (en) | Oil-proof low-smoke and non-halogen fire-retardant cable material and preparation method thereof | |
| CN104341676A (en) | Novel low-smoke zero halogen flame-retardant cable material | |
| CN104387645A (en) | Low-smoke halogen-free flame retardant cable material | |
| CN105199182A (en) | Polyolefin flame retardant | |
| CN106496920B (en) | low smoke density ABS resin and preparation method thereof | |
| CN104829959A (en) | Flame retardant plastic | |
| CN103881190A (en) | Halogen-free flame-retardant polyethylene material and preparation method thereof | |
| CN103849022A (en) | Glass fiber reinforced halogen-free flame retardant polyethylene powder and preparation method thereof | |
| CN106751380A (en) | A kind of halogen-free flame retardants and flame-proof ABS plastics and preparation method thereof | |
| CN105111617A (en) | Non-halogen flame-retardant resin material for wires and cables | |
| CN105111764A (en) | Environment-friendly flame-retardant type wood-plastic composite and preparation method thereof | |
| CN105038056A (en) | Low-smoke zero-halogen cable material and preparation method thereof | |
| CN103881287A (en) | Environment-friendly flame-retardant ABS (Acrylonitrile Butadiene Styrene) material and preparation method thereof | |
| CN103709589A (en) | Mica-ABS (Acrylonitrile Butadiene Styrene) flame-retardant insulation material and preparation method thereof | |
| CN104829967A (en) | Anticorrosive flame-retardant plastic and preparation method thereof | |
| CN105418975A (en) | Halogen-free and low-smoke flame retardant for preparing polyethylene material | |
| CN105504473A (en) | Sheath material for low-smoke halogen-free flame-retardant power line and preparation method thereof | |
| CN103450592A (en) | Environmentally-friendly flame retardant sheath material | |
| CN105524435A (en) | Formula of low-smoke zero-halogen sheath for power cable | |
| CN104004258A (en) | Low-smoke halogen-free flame-retardant ethylene-vinyl acetate copolymer resin | |
| CN102924794A (en) | Halogen-free flame retardant modified plastic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20151230 |
|
| WD01 | Invention patent application deemed withdrawn after publication |