CN104497883A - 一种水性环保易擦洗墙面漆 - Google Patents

一种水性环保易擦洗墙面漆 Download PDF

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CN104497883A
CN104497883A CN201410776508.0A CN201410776508A CN104497883A CN 104497883 A CN104497883 A CN 104497883A CN 201410776508 A CN201410776508 A CN 201410776508A CN 104497883 A CN104497883 A CN 104497883A
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water
wall paint
aqueous
agent
low
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CN201410776508.0A
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董善刚
王伯凤
刘永屏
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Qingdao Yiqun Paint Industry Group Co Ltd
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Qingdao Yiqun Paint Industry Group Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

本发明的一种水性环保易擦洗墙面漆的具体组分和重量比例是：水：15-25％；润湿剂：0.1-0.2％；分散剂：0.4-0.8％；消泡剂：0.3-0.8％；锐钛型钛白粉：10-15％；滑石粉：5-8％；重质碳酸钙：8-10％；轻钙：10-12％；水洗高岭土5-8％；硅酸铝1-2％；荷性胶联乳液5-10％；低气味材料：15-20％；流平剂：0.1-0.2％；防腐剂：0.1-0.2％；增稠剂：0.6-0.9％。本发明的目的是提供一种水性环保易擦洗墙面漆，该产品不仅具有低VOC含量、超高的耐水、耐碱、耐擦洗性能，还使漆膜具有疏水功能，能够更容易的擦拭掉上面的油渍、污渍，保持家居生活环境的美观。

Description

一种水性环保易擦洗墙面漆
技术领域 本发明涉及一种内墙涂料，特别涉及一种用于建筑物内外墙表面的保护和装饰，具有低VOC含量、高耐水、耐碱、耐擦洗的水性环保易擦洗墙面漆，属于化工涂料技术领域。
背景技术 在我国，内墙涂料经历了30多年的发展，已经逐渐取代了墙纸、壁布等墙面装饰材料，内墙涂料不单单起到保护、装饰墙体的作用，绿色、环保、多功能的内墙涂料越来越多的受到人们的喜爱。因此研发一种具有疏水功能的内墙乳胶漆是非常有必要的。
发明内容 本发明的目的是提供一种水性环保易擦洗墙面漆，该产品不仅具有低VOC含量、超高的耐水、耐碱、耐擦洗性能，还使漆膜具有疏水功能，能够更容易的擦拭掉上面的油渍、污渍，保持家居生活环境的美观。
本发明的一种水性环保易擦洗墙面漆的具体组分和重量比例是：水：15-25％；润湿剂：0.1-0.2％；分散剂：0.4-0.8％；消泡剂：0.3-0.8％；锐钛型钛白粉：10-15％；滑石粉：5-8％；重质碳酸钙：8-10％；轻钙：10-12％；水洗高岭土5-8％；硅酸铝1-2％；荷性胶联乳液5-10％；低气味材料：15-20％；流平剂：0.1-0.2％；防腐剂：0.1-0.2％；增稠剂：0.6-0.9％。
一般来说，内墙涂料在生产和使用过程中都有可能产生有害物质，造成对环境的污染，影响人类的健康，尤其是内墙涂料中的总有机挥发物含量，即通常所说的VOC含量对环境、人体健康直接造成危害。
本发明使用的乳液为新型特殊结构的有机硅氧烷改性聚合乳液，在干燥成膜中其中Si-OH之间以及和基材上的-OH-发生多重交联化学反应，可使涂层有极低的表面张力，能够保持极佳的疏水效果，耐沾污性能良好，并且与其他乳液有着良好的复配型，性能稳定。
本发明使用的低气味材料是一种由丙烯酸正丁酯和丙烯酸甲酯通过核壳共聚而形成的一种水性分散体细小胶乳，粘度低，无气味，不含氨水以及任何溶剂后增塑剂，拥有出色的颜填料相容性和粘结能力，在配方当中不需要添加任何成膜助剂，大大降低了该涂料产品中的有机挥发物含量。并且具有良好的耐水性和抗水解性能。
具体实施方式 下面是本发明的一个实施例。
本发明的一种水性环保易擦洗墙面漆的组成(重量百分比)及生产工艺为：
低速搅拌阶段依照顺序加入18份的去离子水、0.1份的润湿剂、0.6份聚丙烯酸胺盐分散剂、0.15份的消泡剂、16份的钛白粉、8份的重质碳酸钙、12份轻钙、5份滑石粉、5份水洗高岭土、2份硅酸铝，待全部加入后进入高速搅拌阶段，待搅拌均匀后高速研磨至细度≤30um，然后在低速搅拌下依次加入10份荷性胶联乳液、18份安固力低气味材料、0.15份的消泡剂、0.2份流平剂、0.15份的防腐剂、0.4份的增稠剂和0.25份增稠剂,4份的去离子水搅拌均匀，再低速搅拌10min,再经过检验、过滤、称重包装。
依据本发明制作的一种水性环保易擦洗墙面漆其各项指标均达到GB/T9756-2009关于合成树脂乳液内墙涂料所规定的要求以及GB 18582室内装饰装修材料内墙涂料中有害物质限量，具有超低的VOC含量，良好的耐擦洗性、耐水性和耐碱性，并且漆膜表面具有极低的表面张力，具有良好的疏水效果，对于墙体上沾染的油渍、污渍以及墨水等物质能够很容易的擦拭干净，有效的保持了室内环境的整洁美观，绿色环保，非常适合儿童使用。

Claims (3)

1.本发明的一种水性环保易擦洗墙面漆的具体组分和重量比例是：水：15-25％；润湿剂：0.1-0.2％；分散剂：0.4-0.8％；消泡剂：0.3-0.8％；锐钛型钛白粉：10-15％；滑石粉：5-8％；重质碳酸钙：8-10％；轻钙：10-12％；水洗高岭土5-8％；硅酸铝1-2％；荷性胶联乳液5-10％；低气味材料：15-20％；流平剂：0.1-0.2％；防腐剂：0.1-0.2％；增稠剂：0.6-0.9％。
2.根据权利要求1所述的一种水性环保易擦洗墙面漆，其特征是本发明的低气味材料是一种由丙烯酸正丁酯和丙烯酸甲酯通过核壳共聚而形成的一种水性分散体细小胶乳，粘度低，无气味。
3.根据权利要求1所述的一种水性环保易擦洗墙面漆，其特征是所使用的乳液为新型特殊结构的有机硅氧烷改性聚合乳液，性能稳定。
CN201410776508.0A 2014-12-15 2014-12-15 一种水性环保易擦洗墙面漆 Pending CN104497883A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236377A (zh) * 2017-07-15 2017-10-10 合肥皖水信息科技有限公司 一种易擦洗室内涂料的制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236377A (zh) * 2017-07-15 2017-10-10 合肥皖水信息科技有限公司 一种易擦洗室内涂料的制备方法

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Application publication date: 20150408