CN104496198A - High-definition high-transmittance ultraviolet-resistant film and manufacturing method thereof - Google Patents
High-definition high-transmittance ultraviolet-resistant film and manufacturing method thereof Download PDFInfo
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- CN104496198A CN104496198A CN201410745247.6A CN201410745247A CN104496198A CN 104496198 A CN104496198 A CN 104496198A CN 201410745247 A CN201410745247 A CN 201410745247A CN 104496198 A CN104496198 A CN 104496198A
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- politics
- ultraviolet
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/74—UV-absorbing coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a high-definition high-transmittance ultraviolet-resistant film and a manufacturing method thereof. The high-definition high-transmittance ultraviolet-resistant film comprises the following raw materials in parts by weight: 80-100 parts of PET base materials, 20-25 parts of nanometer ATO powder, 1-2 parts of a dispersing agent TAZ-ND1 and 8-10 parts of a scratch-resistant agent. The method comprises the following corresponding manufacturing steps: mixing and fusing the raw materials, cooling, crystallizing, drying, fusing again, cooling, thereby obtaining the product. The process is simple and easy to control, the obtained product is transparent and clear, and the ultraviolet ray isolation rate is 100 percent.
Description
Technical field
The present invention relates to film and preparation method thereof, be specifically related to a kind of high aloof from politics and material pursuits antiultraviolet film and preparation method thereof.
Background technology
Ultraviolet is that a kind of wavelength ratio visible ray is short, but the electromagnetic radiation that wavelength ratio X-ray is long, wavelength is 10nm ~ 400nm, and energy, at 3eV ~ 124eV, has obvious chemical effect.Natural main ultraviolet line source is the sun, sunlight is shorter than 290nm ultraviolet through wavelength during atmospheric layer is absorbed by ozone in atmospheric layer, but along with the development of society, the ozonosphere in atmospheric layer is destroyed by a large amount of chemical substances, and ozonosphere total amount reduces gradually; In addition, various artificial light such as UV-lamp, computer, TV etc. all also produce ultraviolet.Excessive ultraviolet has following harm to human body: action of ultraviolet radiation, in eye, can cause conjunctivitis, keratitis, bring out cataract etc.; When skin, can there is solar dermatitis, erythema, blister etc. appear in skin in ultraviolet strong effect, serious even causes skin carcinoma; When action of ultraviolet radiation is in central nervous system, headache, dizziness, fervescence etc. can be there are.
In order to reduce the harm of ultraviolet to human body, the film of antiultraviolet usually can be pasted in the ultraviolet source of all kinds of generation.Public announcement of a patent application CN104130533 A relates to solar film of a kind of antiultraviolet and preparation method thereof, the solar film mentioning the antiultraviolet related in this application has excellent preventing ultraviolet effect, avoid the human-body fatigue caused by ultraviolet, electron membrane, automobile adhesive film, aircraft rupture disk can be used as, rete is clear, thoroughly can isolate ultraviolet.But the transparent sharpness relating to film is mentioned, and the effect do not reached it in a specific embodiment makes corresponding explanation, there is no its technical scheme of data supporting.Public announcement of a patent application CN103507351 A relates to a kind of fully anti-ultraviolet sun power thermal isolation film and preparation method thereof, the film primary structure related in this application comprises: scratch-resistant layer, main film, urethane glue-line, layer of nanomaterial, PET base material, glue-line is installed, glue-line protective membrane is installed, infrared shield rate reaches 90%, uvioresistant reaches 99%, there is the ability of effective shielding electromagnetic wave simultaneously, but do not relate to the transparent readability of film, in addition, also the effect do not reached it is in a specific embodiment made and is verified explanation accordingly, there is no its technical scheme of corresponding data supporting.Public announcement of a patent application CN104149451 A relates to a kind of antiultraviolet insulating car film, it comprises PET composite bed and ETFE rete, and be coated with antiultraviolet heat-insulating slurry between PET composite bed and ETFE rete, be coated with viscose between antiultraviolet heat-insulating slurry and two membranes.But its technological operation is loaded down with trivial details, wayward, in addition, only mentioning antiultraviolet insulating car film in summary of the invention can absorb ultraviolet, does not give respective description to concrete ability and ultraviolet resistance.
Summary of the invention
The object of the invention is to the shortcoming overcoming prior art, a kind of high aloof from politics and material pursuits antiultraviolet film and preparation method thereof is provided.
Object of the present invention is achieved through the following technical solutions: a kind of high aloof from politics and material pursuits antiultraviolet film, and it is made up of the raw material of following weight part:
PET base material 80 ~ 100;
Nano ATO powder 20 ~ 25;
Dispersion agent TAZ-ND1 1 ~ 2;
Anti-scratch dose 8 ~ 10.
Described nano ATO powder is made up of weisspiessglanz and stannic oxide, and the weight ratio of weisspiessglanz and stannic oxide is 1:7 ~ 9.
Described anti-scratch dose is aluminum oxide or titanium oxide.
The making method of described a kind of high aloof from politics and material pursuits antiultraviolet film, it comprises the following steps:
(1) get PET base material, nano ATO powder, dispersion agent TAZ-ND1 and anti-scratch dose according to described weight part, at 90 ~ 110 DEG C, fusing 4 ~ 5h, stirs 2 ~ 3h, makes it mutually merge;
(2) placement of step (1) products therefrom is at room temperature cooled 3 ~ 5h, obtain xln, this xln is at room temperature used blower fan drying 5 ~ 6h;
(3) product that step (2) obtains being placed on temperature is 120 ~ 140 DEG C, melting 4 ~ 6h;
(4) extruded by the product that step (3) obtains with forcing machine, evenly at the drawn onto glass of cleaning, cooling 1 ~ 3h, obtains high aloof from politics and material pursuits antiultraviolet film.
The present invention has following beneficial effect: the stable performance of (1) nano ATO powder chemistry, little to the change of the physical properties that heat, this type of outside atmosphere of humidity cause, and can keep half property conductivity of a specified duration; Nano ATO powder is extremely weak to the specific absorption of visible light, very high to infrared rays, ultraviolet specific absorption, namely has high transmitance to visible light, has high isolated rate to infrared rays, ultraviolet; Product of the present invention, using nano ATO powder as one of raw material, imparts this film transparent conductivity, thermal insulation and corresponding anti-ultraviolet function.(2) the adding of dispersion agent TAZ-ND1, add the solvability of nano ATO powder, the ability and ultraviolet resistance of this film is strengthened, and ultraviolet completely cuts off rate and reaches 100%.(3) add anti-scratch dose in raw material, make film product of the present invention not easily scratch, can keep permanently effective.(4) technological process of the present invention is simple, is easy to control.(5) product of the present invention is transparent clear, can avoid the human-body fatigue caused by ultraviolet.
Embodiment
Below in conjunction with embodiment, the present invention will be further described, and protection scope of the present invention is not limited to the following stated.
embodiment 1:a kind of high aloof from politics and material pursuits antiultraviolet film, it is made up of the raw material of following weight part:
PET base material 80;
Nano ATO powder 20;
Dispersion agent TAZ-ND1 1;
Aluminum oxide 8.
Described nano ATO powder is made up of weisspiessglanz and stannic oxide, and the weight ratio of weisspiessglanz and stannic oxide is 1:7.
The making method of described a kind of high aloof from politics and material pursuits antiultraviolet film, it comprises the following steps:
(1) get PET base material, nano ATO powder, dispersion agent TAZ-ND1 and anti-scratch dose according to described weight part, at 90 DEG C, fusing 5h, stirs 2h, makes it mutually merge;
(2) placement of step (1) products therefrom is at room temperature cooled 3h, obtain xln, this xln is at room temperature used the dry 5h of blower fan;
(3) product that step (2) obtains being placed on temperature is 120 DEG C, melting 6h;
(4) extruded by the product that step (3) obtains with forcing machine, evenly at the drawn onto glass of cleaning, cooling 1h, obtains high aloof from politics and material pursuits antiultraviolet film.
Utilize spectrophotometer to carry out optical property detection, record: the ultraviolet ray transmissivity of the aloof from politics and material pursuits antiultraviolet film of this height is 0, and namely ultraviolet isolated rate is 100%; It is 90% that infrared rays completely cuts off rate; Visible light transmissivity is 88%.
embodiment 2:a kind of high aloof from politics and material pursuits antiultraviolet film, it is made up of the raw material of following weight part:
PET base material 100;
Nano ATO powder 25;
Dispersion agent TAZ-ND1 2;
Titanium oxide 10.
Described nano ATO powder is made up of weisspiessglanz and stannic oxide, and the weight ratio of weisspiessglanz and stannic oxide is 1:9.
The making method of described a kind of high aloof from politics and material pursuits antiultraviolet film, it comprises the following steps:
(1) get PET base material, nano ATO powder, dispersion agent TAZ-ND1 and anti-scratch dose according to described weight part, at 110 DEG C, fusing 4h, stirs 3h, makes it mutually merge;
(2) placement of step (1) products therefrom is at room temperature cooled 5h, obtain xln, this xln is at room temperature used the dry 6h of blower fan;
(3) product that step (2) obtains being placed on temperature is 140 DEG C, melting 4h;
(4) extruded by the product that step (3) obtains with forcing machine, evenly at the drawn onto glass of cleaning, cooling 3h, obtains high aloof from politics and material pursuits antiultraviolet film.
Utilize spectrophotometer to carry out optical property detection, record: the ultraviolet ray transmissivity of the aloof from politics and material pursuits antiultraviolet film of this height is 0, and namely ultraviolet isolated rate is 100%; It is 91% that infrared rays completely cuts off rate; Visible light transmissivity is 91%.
embodiment 3:a kind of high aloof from politics and material pursuits antiultraviolet film, it is made up of the raw material of following weight part:
PET base material 88;
Nano ATO powder 22;
Dispersion agent TAZ-ND1 1.3;
Aluminum oxide 8.7.
Described nano ATO powder is made up of weisspiessglanz and stannic oxide, and the weight ratio of weisspiessglanz and stannic oxide is 1:8.
The making method of described a kind of high aloof from politics and material pursuits antiultraviolet film, it comprises the following steps:
(1) get PET base material, nano ATO powder, dispersion agent TAZ-ND1 and anti-scratch dose according to described weight part, at 96 DEG C, fusing 5h, stirs 2.5h, makes it mutually merge;
(2) placement of step (1) products therefrom is at room temperature cooled 4h, obtain xln, this xln is at room temperature used the dry 5.5h of blower fan;
(3) product that step (2) obtains being placed on temperature is 128 DEG C, melting 5h;
(4) extruded by the product that step (3) obtains with forcing machine, evenly at the drawn onto glass of cleaning, cooling 2.5h, obtains high aloof from politics and material pursuits antiultraviolet film.
Utilize spectrophotometer to carry out optical property detection, record: the ultraviolet ray transmissivity of the aloof from politics and material pursuits antiultraviolet film of this height is 0, and namely ultraviolet isolated rate is 100%; It is 93% that infrared rays completely cuts off rate; Visible light transmissivity is 90%.
embodiment 4:a kind of high aloof from politics and material pursuits antiultraviolet film, it is made up of the raw material of following weight part:
PET base material 95;
Nano ATO powder 23;
Dispersion agent TAZ-ND1 1.7;
Titanium oxide 9.2.
Described nano ATO powder is made up of weisspiessglanz and stannic oxide, and the weight ratio of weisspiessglanz and stannic oxide is 1:9.
The making method of described a kind of high aloof from politics and material pursuits antiultraviolet film, it comprises the following steps:
(1) get PET base material, nano ATO powder, dispersion agent TAZ-ND1 and anti-scratch dose according to described weight part, at 106 DEG C, fusing 4h, stirs 3h, makes it mutually merge;
(2) placement of step (1) products therefrom is at room temperature cooled 4h, obtain xln, this xln is at room temperature used the dry 6h of blower fan;
(3) product that step (2) obtains being placed on temperature is 135 DEG C, melting 4.5h;
(4) extruded by the product that step (3) obtains with forcing machine, evenly at the drawn onto glass of cleaning, cooling 2h, obtains high aloof from politics and material pursuits antiultraviolet film.
Utilize spectrophotometer to carry out optical property detection, record: the ultraviolet ray transmissivity of the aloof from politics and material pursuits antiultraviolet film of this height is 0, and namely ultraviolet isolated rate is 100%; It is 93% that infrared rays completely cuts off rate; Visible light transmissivity is 89%.
Claims (4)
1. a high aloof from politics and material pursuits antiultraviolet film, it is characterized in that, it is made up of the raw material of following weight part:
PET base material 80 ~ 100;
Nano ATO powder 20 ~ 25;
Dispersion agent TAZ-ND1 1 ~ 2;
Anti-scratch dose 8 ~ 10.
2. a kind of high aloof from politics and material pursuits antiultraviolet film according to claim 1, it is characterized in that, described nano ATO powder is made up of weisspiessglanz and stannic oxide, and the weight ratio of weisspiessglanz and stannic oxide is 1:7 ~ 9.
3. a kind of high aloof from politics and material pursuits antiultraviolet film according to claim 1, it is characterized in that, described anti-scratch dose is aluminum oxide or titanium oxide.
4. the making method of a kind of high aloof from politics and material pursuits antiultraviolet film according to claim 1, it is characterized in that, it comprises the following steps:
(1) get PET base material, nano ATO powder, dispersion agent TAZ-ND1 and anti-scratch dose according to described weight part, at 90 ~ 110 DEG C, fusing 4 ~ 5h, stirs 2 ~ 3h, makes it mutually merge;
(2) placement of step (1) products therefrom is at room temperature cooled 3 ~ 5h, obtain xln, this xln is at room temperature used blower fan drying 5 ~ 6h;
(3) product that step (2) obtains being placed on temperature is 120 ~ 140 DEG C, melting 4 ~ 6h;
(4) extruded by the product that step (3) obtains with forcing machine, evenly at the drawn onto glass of cleaning, cooling 1 ~ 3h, obtains high aloof from politics and material pursuits antiultraviolet film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410745247.6A CN104496198A (en) | 2014-12-09 | 2014-12-09 | High-definition high-transmittance ultraviolet-resistant film and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410745247.6A CN104496198A (en) | 2014-12-09 | 2014-12-09 | High-definition high-transmittance ultraviolet-resistant film and manufacturing method thereof |
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| CN104496198A true CN104496198A (en) | 2015-04-08 |
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| CN201410745247.6A Pending CN104496198A (en) | 2014-12-09 | 2014-12-09 | High-definition high-transmittance ultraviolet-resistant film and manufacturing method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001797A (en) * | 2015-06-30 | 2015-10-28 | 苏州博利迈新材料科技有限公司 | Anti-ultraviolet vehicle-mounted nano film for vehicle glass and preparation method of nano film |
| CN109666357A (en) * | 2018-12-06 | 2019-04-23 | 天津中亚慧通科技有限公司 | A kind of preparation method of the scratch resistant anti-dazzling film of automobile anti-pollution |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101423634A (en) * | 2008-12-18 | 2009-05-06 | 江南大学 | Method for preparing multifunctional nano composite material |
| CN101468397A (en) * | 2007-12-29 | 2009-07-01 | 中国船舶重工集团公司第七二五研究所 | Method for preparing ATO conductive powder using nano antimony oxide and tin oxide powder |
| CN102977559A (en) * | 2012-09-21 | 2013-03-20 | 江西科为薄膜新型材料有限公司 | PET film having high heat-insulation function |
-
2014
- 2014-12-09 CN CN201410745247.6A patent/CN104496198A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101468397A (en) * | 2007-12-29 | 2009-07-01 | 中国船舶重工集团公司第七二五研究所 | Method for preparing ATO conductive powder using nano antimony oxide and tin oxide powder |
| CN101423634A (en) * | 2008-12-18 | 2009-05-06 | 江南大学 | Method for preparing multifunctional nano composite material |
| CN102977559A (en) * | 2012-09-21 | 2013-03-20 | 江西科为薄膜新型材料有限公司 | PET film having high heat-insulation function |
Non-Patent Citations (1)
| Title |
|---|
| 卓昌明主编: "《塑料应用技术手册》", 31 January 2013, 机械工业出版社出版 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001797A (en) * | 2015-06-30 | 2015-10-28 | 苏州博利迈新材料科技有限公司 | Anti-ultraviolet vehicle-mounted nano film for vehicle glass and preparation method of nano film |
| CN109666357A (en) * | 2018-12-06 | 2019-04-23 | 天津中亚慧通科技有限公司 | A kind of preparation method of the scratch resistant anti-dazzling film of automobile anti-pollution |
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Application publication date: 20150408 |
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