CN101831126A - Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material - Google Patents

Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material Download PDF

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Publication number
CN101831126A
CN101831126A CN 201010169715 CN201010169715A CN101831126A CN 101831126 A CN101831126 A CN 101831126A CN 201010169715 CN201010169715 CN 201010169715 CN 201010169715 A CN201010169715 A CN 201010169715A CN 101831126 A CN101831126 A CN 101831126A
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Prior art keywords
protective material
malignant melanoma
optical protective
ultraviolet
additive
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CN 201010169715
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CN101831126B (en
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袁敏华
陈晓
袁涛
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Zhejiang Purple Light Technology Co Ltd
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Individual
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Abstract

The invention relates to a fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material. The optical protective material is characterized by comprising the following materials in percentage by weight: 0.010 to 30.000 weight percent of additive and the balance of base stock, wherein the additive is a fluorescent whitening agent and/or an ultraviolet absorber, and also No.beta-1 decomposition antireflective agent, color-changing agent and/or toner can be added into the additive and the base stock. The optical protective material has the effect of full ultraviolet protection, namely 100 percent of ultraviolet UV400 protection, can prevent harmful light from causing human body to generate malignant melanoma, avoid human fatigue, furniture color change and embrittlement caused by the harmful light, particularly has better advanced protective effect on infants, students and young ladies, and can protect tender skin and slow down the aging process.

Description

Whole anti-UV antifatigue and anti-malignant melanoma optical protective material
Technical field
The present invention relates to a kind of improvement of optical protective material, specifically refer to a kind of whole anti-UV antifatigue and anti-malignant melanoma optical protective material.
Background technology
Ultraviolet ray is the short invisible light of a kind of wavelength ratio visible light, and wavelength region: 280nm-400nm has significant chemical effect.Ultraviolet ray is not merely from sunlight, and various artificial lights also can produce certain ultraviolet ray as UV-lamp, computer, TV etc.Excessive uviolizing has certain injury to people's skin and eyes, and ultraviolet ray can destroy the human skin cell, causes wrinkle, color spot, make skin prematurely senile, produce sunburn and sunburn when serious, or the solar keratosis of skin and mucous membrane, canceration caused.Ultraviolet irradiation also can hurt the Langerhans cell in the epidermis simultaneously, and the main effect of L cell is to unite the external attack of antagonism with the T cell, so just can destroy the human immune system, and immunological competence is descended.The harmful light that ultraviolet ray is produced can cause human-body fatigue, furniture variable color and embrittlement, and is especially even more serious to child, student and Ms's injury, and the harmful light irradiation causes human body to produce malignant melanoma the most at last for a long time.
In order to prevent the injury of ultraviolet ray to human body, people research and develop and have made multiple antiultraviolet technology and product.For example: notification number is the Chinese invention patent application of CN1594646 disclosed " a kind of hydrophobic and ultraviolet radiation preventing transparent film and preparation thereof ", and it is to adopt magnetron sputtering method to prepare the hydrophobic and ultraviolet radiation preventing transparent film of nitrogen-doped titanium dioxide.Notification number is that the Chinese invention patent application of CN1951850 disclosed " ultraviolet ray screening film-plating glass and manufacture method thereof " is to adopt the high temperature pyrolysis spraying method to make ultraviolet ray screening film-plating glass, but this coated glass has reduced the transmitance of visible light, and does not reach the effect of fully anti-ultraviolet.At present also do not have a kind of material or film under the situation that does not influence light transmission, transparency and sharpness, can reach the effect of real fully anti-ultraviolet.
Summary of the invention
Technical problem to be solved by this invention be the present situation at prior art provide a kind of can whole anti-UV antifatigue and anti-malignant melanoma optical protective material.
Another technical problem to be solved by this invention is whole anti-UV antifatigue and the anti-malignant melanoma optical protective material that the variable color of a kind of energy is provided at the present situation of prior art.
The present invention adds the additive that accounts for base-material total amount 0.010-30.000wt% on the raw material basis that makes habitual optical protective material, better, can add β-1# and decompose transparent agent and improve the phase solubility of additive in base-material, thereby under the prerequisite of the not original light transmission of loss material, sharpness, give performances such as its fully anti-ultraviolet, antifatigue, variable color.
The present invention solves the problems of the technologies described above the technical scheme that is adopted: this whole anti-UV antifatigue and anti-malignant melanoma optical protective material is characterized in that comprising:
Additive 0.010-30.000wt%
The base-material surplus
The each component sum is 100wt%; Wherein, described additive is selected from white dyes and/or UV light absorber, and both mix when using, and white dyes and UV light absorber can be mixed by arbitrary proportion.
In order to improve the intermiscibility of additive and base-material, improve the product sharpness, the β-1# that can also add 0.001-0.150wt% in the such scheme decomposes transparent agent.
Described base-material can be selected all material that can make optical protective material in the prior art for use, preferably, can be selected from acrylic polymer, PET, PVC, PVB, PC, PVP, PS, PU or glass.
Described white dyes can be selected white dyess such as dibenzoxazine class, diphenylethyllene benzene class and distyryl biphenyl class for use.Preferably, can select 2 for use, two (the 5-tertiary butyl-2-benzoxazolyl) thiophene or 2,2 of 5-'-(4,4 '-diphenylethyllene) dibenzoxazine.
Described UV light absorber also claims the UV absorption agent, can be selected from 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-the diamyl phenyl) benzotriazole, 2-(2 '-hydroxyl-5 '-the Te octyl phenyl) benzotriazole, 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2H-benzotriazole-2-yl)-6-(dodecyl)-4-methylphenol, Octabenzone, 2-hydroxyl-4-methoxy benzophenone, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole or ether aldehyde.
Described additive can also comprise colour-changing agent, the consumption of colour-changing agent can decide according to the thickness of prepared material and the amount of base-material, its consumption can be 0.010-20.000wt%, and amount ranges is 0.100-10.000wt% preferably, preferred 0.200-4.000wt%.
Described colour-changing agent can be selected from photosensitive colour-changing agent and/or temperature sensing color changing agent.Can select sensitization discoloration MC powder, sensitization discoloration PS powder, sensitization discoloration OP powder, sensitization discoloration aqueous emulsion etc. preferably for use.
Practical situation with base-material can also selectivity add toner as required, be pigment, the addition of toner also is that the thickness according to the amount of base-material and prepared material decides, and the addition of toner is generally 0.001-2.000wt%, and amount ranges is 0.005-1.500wt% preferably.
In the such scheme, preferably, the consumption of described additive can be 0.100-15.000wt%, preferred 0.200-8.000wt%; Described β-1# decomposes the preferred 0.005-0.010wt% of consumption of transparent agent.
Utilize the prepared material of prescription of the present invention can thoroughly isolate ultraviolet ray, avoid light fatigue, can reach the effect of uvioresistant UV400, have the fully anti-ultraviolet function, and, further improved the transparency and the sharpness of material because β-1# decomposes the interpolation of transparent agent.
Compared with prior art; prescription provided by the present invention can reach the effect of 100% uvioresistant UV400; particularly creatively adopted β-1# to decompose the intermiscibility that transparent agent improves additive and base-material; thereby improved the usage quantity of additive widely; the optical protective material that obtains can prevent effectively that harmful light from causing that human body produces malignant melanoma; avoid the caused human-body fatigue of harmful light, furniture variable color and embrittlement; especially child, student and Ms there is preferably protective effect in advance; can protect tender and lovely skin, delaying senility.Whole anti-UV antifatigue provided by the present invention and anti-malignant melanoma optical protective material are made optical protection layer, electron membrane, building film, automobile adhesive film, aircraft rupture disk or the like, and rete is clear, can thoroughly isolate ultraviolet ray.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Base-material among the following embodiment can be chosen all material that can make optical protective material in the prior art wantonly, for example acrylic polymer, PET, PVC, PVB, PC, PVP, PS, PU or glass;
White dyes is selected from the white dyes of classes such as dibenzoxazine class of the prior art, diphenylethyllene benzene class and distyryl biphenyl class.For example: 2, two (the 5-tertiary butyl-2-benzoxazolyl) thiophene or 2,2 of 5-'-(4,4 '-diphenylethyllene) dibenzoxazine;
Described UV light absorber be selected from 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-the diamyl phenyl) benzotriazole, 2-(2 '-hydroxyl-5 '-the Te octyl phenyl) benzotriazole, 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-the 5-chlorinated benzotriazole, 2-(2H-benzotriazole-2-yl)-6-(dodecyl)-4-methylphenol, Octabenzone, 2-hydroxyl-4-methoxy benzophenone, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole or ether aldehyde;
Colour-changing agent is selected from photosensitive colour-changing agent of the prior art and/or temperature sensing color changing agent.For example can select sensitization discoloration MC powder, sensitization discoloration PS powder, sensitization discoloration OP powder, sensitization discoloration aqueous emulsion etc. for use.
Toner can be selected red agent, blue light agent or the like various toners of the prior art for use.
It is that company limited of permanent Shi Li group (Hong Kong) produces that used β-1# decomposes transparent agent.
Embodiment 1:
Composition consumption (wt%)
White dyes 0.800
UV light absorber 0.500
β-1# decomposes transparent agent 0.008
The base-material surplus
The each component sum is 100wt%.
Above-mentioned materials is made into optical protection layer, and its manufacture craft process is:
Above-mentioned each component is mixed, and melt pelletization adopts rolling process then, extrudes the blown film method, to become thickness be the film of 50 μ m for extruding hydrostomia method or solvent salivation method.
Test the ultraviolet resistance of this film:
Renminbi is lain on the horizontal table top, face up, be radiated on the Renminbi with UV-lamp, the distance between UV-lamp and the bank note a tangible watermark can occur under " people " word about 5cm.At this moment, put into above-mentioned film between Renminbi and UV-lamp, watermark moment disappears fully, and this explanation ultraviolet ray fails to penetrate film, all is blocked in this film outside, has really reached uvioresistant UV400.Adopt this film can be prepared into the protective film of various articles for use; for example adhering film to glass, eyeglass pad pasting, electron membrane, building film, automobile adhesive film, aircraft rupture disk etc.; can prevent effectively that harmful light from causing that human body produces malignant melanoma; avoid the caused human-body fatigue of harmful light, furniture variable color and embrittlement; especially child, student and Ms there is preferably protective effect in advance; can protect tender and lovely skin, delaying senility.
Embodiment 2
Component content (wt%)
UV light absorber 0.400
White dyes 0.600
Toner 0.015
The base-material surplus
Embodiment 3
Component content (wt%)
White dyes 3.000
Colour-changing agent 15.000
β-1# decomposes transparent agent 0.050
The base-material surplus
Embodiment 4
Component content (wt%)
White dyes 10.000
UV light absorber 10.000
Colour-changing agent 3.200
β-1# decomposes transparent agent 0.090
Blue light agent 0.005
The base-material surplus
Embodiment 5
Component content (wt%)
UV light absorber 0.200
White dyes 2.000
Colour-changing agent 1.000
β-1# decomposes transparent agent 0.020
The base-material surplus
Embodiment 6
Component content (wt%)
UV light absorber 6.000
White dyes 5.000
Colour-changing agent 8.000
β-1# decomposes transparent agent 0.055
Coffee toner 1.500
The base-material surplus
Adopt prior art that the material of embodiment 2 to embodiment 6 is made the film that sheet material, sheet material or thickness do not wait respectively, adopt the method identical to test each end properties with embodiment 1.These materials all have the fully anti-ultraviolet function, and sharpness is good.
The content that does not relate in the foregoing description is same as the prior art.

Claims (9)

1. a whole anti-UV antifatigue reaches anti-malignant melanoma optical protective material, it is characterized in that comprising:
Additive 0.010-30.000wt%
The base-material surplus
The each component sum is 100wt%; Wherein, described additive is selected from white dyes and/or UV light absorber.
2. whole anti-UV antifatigue according to claim 1 and anti-malignant melanoma optical protective material, it is characterized in that also comprising: the β of 0.001-0.150wt%-1# decomposes transparent agent.
3. whole anti-UV antifatigue according to claim 2 and anti-malignant melanoma optical protective material is characterized in that described additive also comprises colour-changing agent, and the consumption of described colour-changing agent is 0.010-20.000wt%.
4. whole anti-UV antifatigue according to claim 3 and anti-malignant melanoma optical protective material, the consumption that it is characterized in that described colour-changing agent is 0.100-10.000wt%.
5. whole anti-UV antifatigue according to claim 4 and anti-malignant melanoma optical protective material, the consumption that it is characterized in that described colour-changing agent is 0.200-4.000wt%.
6. whole anti-UV antifatigue according to claim 1 and anti-malignant melanoma optical protective material is characterized in that also comprising toner, and the addition of described toner is 0.001-2.000wt%.
7. whole anti-UV antifatigue according to claim 6 and anti-malignant melanoma optical protective material, the addition that it is characterized in that described toner is 0.005-1.500wt%.
8. according to described whole anti-UV antifatigue of the arbitrary claim of claim 1 to 7 and anti-malignant melanoma optical protective material, the amount that it is characterized in that described additive is 0.100-15.000wt%.
9. whole anti-UV antifatigue according to claim 8 and anti-malignant melanoma optical protective material, the consumption that it is characterized in that described additive is 0.200-8.000wt%.
CN2010101697151A 2010-03-22 2010-03-22 Fully anti-ultraviolet, anti-fatigue, and anti-malignant melanoma optical protective material Active CN101831126B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103287013A (en) * 2013-06-19 2013-09-11 江西科为薄膜新型材料有限公司 High thermal insulation ultraviolet-proof solar film
CN103467936A (en) * 2013-09-12 2013-12-25 苏州金海薄膜科技发展有限公司 PET (polyethylene terephthalate) film capable of absorbing and converting ultraviolet light and shortwave blue light and preparation method thereof
CN105295279A (en) * 2015-10-22 2016-02-03 袁敏华 Optical protecting material preventing ultraviolet light and blue light

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CN104130553A (en) * 2014-08-01 2014-11-05 苏州袭麟光电科技产业有限公司 Anti-ultraviolet solar film and preparation method thereof

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CN1422301A (en) * 2000-04-10 2003-06-04 博里利斯技术有限公司 Polymer-based composition and use thereof in packaging
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103287013A (en) * 2013-06-19 2013-09-11 江西科为薄膜新型材料有限公司 High thermal insulation ultraviolet-proof solar film
CN103467936A (en) * 2013-09-12 2013-12-25 苏州金海薄膜科技发展有限公司 PET (polyethylene terephthalate) film capable of absorbing and converting ultraviolet light and shortwave blue light and preparation method thereof
CN103467936B (en) * 2013-09-12 2016-01-20 苏州金海薄膜科技发展有限公司 A kind of Absorbable rod also transforms PET film of UV-light and shortwave blue light and preparation method thereof
CN105295279A (en) * 2015-10-22 2016-02-03 袁敏华 Optical protecting material preventing ultraviolet light and blue light
WO2017067091A1 (en) * 2015-10-22 2017-04-27 袁敏华 Optical protective material anti ultraviolet light and blue light
CN107418114A (en) * 2015-10-22 2017-12-01 袁敏华 The optical protective material of antiultraviolet and blue light

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Effective date of registration: 20170417

Address after: 315040 hi tech Zone, Zhejiang Province, R & D Park C14

Patentee after: ZHEJIANG PURPLE LIGHT TECHNOLOGY CO., LTD.

Address before: 315000 Ningbo hi tech Zone Development Zone, Zhejiang Province, the 14 Zhejiang purple Technology Co., Ltd.

Patentee before: Yuan Minhua

TR01 Transfer of patent right