CN104478169A - Water purifying agent for wastewater treatment of tire production enterprises and wastewater treatment method - Google Patents

Water purifying agent for wastewater treatment of tire production enterprises and wastewater treatment method Download PDF

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Publication number
CN104478169A
CN104478169A CN201410760860.5A CN201410760860A CN104478169A CN 104478169 A CN104478169 A CN 104478169A CN 201410760860 A CN201410760860 A CN 201410760860A CN 104478169 A CN104478169 A CN 104478169A
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water
bacterium powder
stir
waste water
hour
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CN104478169B (en
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尤晓明
王显涛
李洋
迟文泉
邓世海
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Dinghu Zhaoqing Jian Xiang Environmental Protection Technology Co., Ltd.
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Shandong Yongtai Chemical Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

The invention belongs to the technical field of environment-friendly water treatment, particularly relates to a water purifying agent for wastewater treatment of tire production enterprises and further relates to a method for treating wastewater of the tire production enterprises by adopting the water purifying agent. The water purifying agent contains an inorganic water purifying agent, a microbial water purifying agent and an enzyme preparation, wherein the inorganic water purifying agent is prepared from the ingredients in parts by weight: 5-20 parts of polyaluminum chloride, 4-16 parts of polyacrylamide, 2-15 parts of ferrous sulfate and 5-16 parts of aluminum sulfate; the microbial water purifying agent is prepared from the ingredients in parts by weight: 0.5-2.0 parts of nitrobacterium powder, 0.4-1.4 parts of paracoccus denitrificans powder, 0.2-0.8 part of thiobacterium powder and 0.3-1.2 parts of aniline degrading bacteria powder; the enzyme preparation is prepared from the ingredients in parts by weight: 0.1-1.5 parts of pectinase, 0.4-1.5 parts of cellulase, 0.1-0.8 part of dehydrogenase, 0.2-0.8 part of oxidoreductase and 0.1-0.6 part of xylanase. The water purifying agent and the method have the beneficial effects that by adopting the water purifying agent for wastewater treatment, disclosed by the invention, the water purifying effect is good, the water purifying speed is high, the safety is high, and no secondary pollution is caused; materials with adsorption capacity are used as raw materials and are assisted with microbes, so as to treat the wastewater, so that the range of use is wide, the transparency of treated water is extremely high, and recycling can be achieved.

Description

Tyre production enterprise use in waste water treatment water purification agent and method of wastewater treatment
Technical field
The invention belongs to environment-protective water processing technology field, be specifically related to a kind of tyre production enterprise use in waste water treatment water purification agent, also relate to the method adopting above-mentioned water purification agent process tire production enterprise wastewater.
Background technology
Tire plant wastewater flow rate is that every acid etching processing 30kg tire produces waste water 0.0001m 3, containing sour 2.5g/L, chloride containing iron <5g/L in waste water, sulfur acid iron 5g/L etc., waste water need through neutralization precipitation process.Tire plant and technical rubber goods factory every infuse 30kg tire produces waste water 0.001m 3, goods per ton produce waste water 40-45m 3, containing soap 0.1g/L, calcium chloride 5g/L in waste water, glue juice 10-30g/L etc., generally need through coagulating sedimentation and filtration treatment.
The wastewater flow rate of each factory cooling tire and goods is: every 30kg tire produces 0.2-0.3m 3waste water, can reach 10-15m according to different production technique goods per ton 3, it is main containing talcum powder 3-8mg/L in water.In addition, brass plating piece waste water, Cleaning Wastewater, sulfuration waste water, reclaimed rubber waste water etc. are also produced.Various wastewater flow rate is little, pollutes and does not weigh, can enter Urban Underground water channel after the Local treatment of workshop.
The main raw material of tire production is rubber, and the source of rubber production waste water comprises in glue production process, solidify and diluted latex, washing grumeleuse and glue machine with water, and a large amount of whey of fresh latex and do not solidify part.As long as concentrated natural latex production line rubber-clear freezing waste discharge, its pollutent has dissolved organic matter, ammonia-state nitrogen and sulfate radical etc., caouttchouc is then the machine water of washing grumeleuse and glue, and major part is dissolved organic matter, also has the magazine such as silt, leaf.These waste water contain two kinds of main potential pollutents, organic carbon and ammonia-state nitrogen, are just directly discharged into surface water body if unprocessed, that will exhaust the dissolved oxygen in water, cause a large amount of algal grown, hydrobiont occurs thereupon and suffocates, serious threat is formed to ecotope.
Rubber production be in petrochemical industry with one of water draining rich and influential family.Its draining water quality is complicated, and variation is comparatively large, more difficult.The main products of ordinary rubber is cis-1,4-polybutadiene rubber and styrene-butadiene rubber(SBR).Main factory effluent is along fourth waste water and butylbenzene waste water.Its wastewater treatment process is: butylbenzene waste water mixes in the duct after air supporting with along fourth waste water, after precipitation oil removal, enters wastewater treatment biochemical treatment, discharge after rapid filter filters.
Report about tyre production enterprise wastewater treatment is rarely seen, and the waste water produced in tire production is very serious for the pollution of environment, because the waste water that must produce for tyre production enterprise processes, designs a kind of water purification agent or process for purifying water.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of tyre production enterprise use in waste water treatment water purification agent.
The present invention is realized by following technical scheme:
Tyre production enterprise use in waste water treatment water purification agent, this water purification agent comprises inorganic water purification agent and microbial water-purifying agent, zymin, and its parts by weight are as follows respectively:
Inorganic water purification agent is: polymerize aluminum chloride 5-20, Polyscrylamide 4-16, ferrous sulfate 2-15, Tai-Ace S 150 5-16;
Microbial water-purifying agent is: nitrobacteria bacterium powder 0.5-2.0, Paracoccus denitrificans bacterium powder 0.4-1.4, thiobacterium bacterium powder 0.2-0.8, microphenomenon of degradation of aniline bacterium powder 0.3-1.2;
Zymin is polygalacturonase 0.1-1.5, cellulase 0.4-1.5, desaturase 0.1-0.8, oxydo-reductase 0.2-0.8, zytase 0.1-0.6.
Preferably, inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12.
Preferably, microbial water-purifying agent is: nitrobacteria bacterium powder 1.2, Paracoccus denitrificans bacterium powder 0.9, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.9.
Preferably, zymin is polygalacturonase 0.8, cellulase 0.9, desaturase 0.6, oxydo-reductase 0.5, zytase 0.3.
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 10-20 rev/min, stir 0.2-1 hour, leave standstill 2-5 hour; Inorganic water purification agent is: polymerize aluminum chloride 5-20, Polyscrylamide 4-16, ferrous sulfate 2-15, Tai-Ace S 150 5-16;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 10-20 rev/min in the clear water of upper strata, stirs 0.2-1 hour, leaves standstill 2-6 hour; Microbial water-purifying agent is: nitrobacteria bacterium powder 0.5-2.0, Paracoccus denitrificans bacterium powder 0.4-1.4, thiobacterium bacterium powder 0.2-0.8, microphenomenon of degradation of aniline bacterium powder 0.3-1.2;
Zymin is added again in above-mentioned steps, stir with the rotating speed of 10-20 rev/min, stir 0.2-1 hour, leave standstill 3-8 hour, zymin is polygalacturonase 0.1-1.5, cellulase 0.4-1.5, desaturase 0.1-0.8, oxydo-reductase 0.2-0.8, zytase 0.1-0.6.
Preferably, tyre production enterprise method of wastewater treatment comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 15 revs/min, stir 0.6 hour in the clear water of upper strata, leaves standstill 4 hours; Microbial water-purifying agent is nitrobacteria bacterium powder 1.2, Paracoccus denitrificans bacterium powder 0.9, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.9;
In above-mentioned steps, add zymin again, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours, zymin is: polygalacturonase 0.8, cellulase 0.9, desaturase 0.6, oxydo-reductase 0.5, zytase 0.3.
Inorganic water purification agent, microbial water-purifying agent, enzyme are acted on water body by the present invention respectively, better purifying water body.Inorganic water purification agent has the effect of the chlorine removed in suspended substance, oil removing, decolouring, removing heavy metals and water; Microorganism can remove the organic pollutant in water body further; Enzyme acts on water body, acts on mutually with the material being difficult to decompose in water body, reaches the object removing pollutent in water body thoroughly.
Beneficial effect of the present invention is, adopt use in waste water treatment water purification agent of the present invention, there is purifying water effect good, water purification speed is fast, security is high, does not produce secondary pollution, is raw material with the material with adsorptive power, be aided with microorganism to process waste water, use range is wide, and the water clarity after process is high, recoverable.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
Tyre production enterprise method of wastewater treatment comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 15 revs/min, stir 0.6 hour in the clear water of upper strata, leaves standstill 4 hours; Microbial water-purifying agent is nitrobacteria bacterium powder 1.2, Paracoccus denitrificans bacterium powder 0.9, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.9;
In above-mentioned steps, add zymin again, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours, zymin is: polygalacturonase 0.8, cellulase 0.9, desaturase 0.6, oxydo-reductase 0.5, zytase 0.3.
Comparative example 1
Tyre production enterprise method of wastewater treatment comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, in above-mentioned steps, add zymin, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 3-8 hour, zymin is: polygalacturonase 0.8, cellulase 0.9, desaturase 0.6, oxydo-reductase 0.5, zytase 0.3.
Comparative example 2
Tyre production enterprise method of wastewater treatment comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 15 revs/min, stir 0.6 hour in the clear water of upper strata, leaves standstill 4 hours; Microbial water-purifying agent is nitrobacteria bacterium powder 1.2, Paracoccus denitrificans bacterium powder 0.9, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.9.
The index of the water body before and after process is as follows:
As can be seen from above embodiment and comparative example, bacterium powder and zymin act synergistically on waste water water body, do not add bacterium powder in comparative example 1, do not add zymin in comparative example 2, and both effects of process will inferior to embodiment 1.
Embodiment 1 is compared with the data of each index before treatment, and in embodiment 1, each index obviously declines, and water body obtains good purification.
Embodiment 2
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 10 revs/min, stir 0.2 hour, leave standstill 2 hours; Inorganic water purification agent is: polymerize aluminum chloride 5, Polyscrylamide 4, ferrous sulfate 2, Tai-Ace S 150 5;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 10 revs/min, stir 0.2 hour in the clear water of upper strata, leaves standstill 2 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 0.5, Paracoccus denitrificans bacterium powder 0.4, thiobacterium bacterium powder 0.2, microphenomenon of degradation of aniline bacterium powder 0.3;
In above-mentioned steps, add zymin again, stir with the rotating speed of 10 revs/min, stir 0.2 hour, leave standstill 3 hours, zymin is polygalacturonase 0.1, cellulase 0.4, desaturase 0.1, oxydo-reductase 0.2, zytase 0.1-0.6.
Embodiment 3
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 20 revs/min, stir 1 hour, leave standstill 5 hours; Inorganic water purification agent is: polymerize aluminum chloride 20, Polyscrylamide 16, ferrous sulfate 15, Tai-Ace S 150 16;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 20 revs/min, stir 1 hour in the clear water of upper strata, leaves standstill 6 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 2.0, Paracoccus denitrificans bacterium powder 1.4, thiobacterium bacterium powder 0.8, microphenomenon of degradation of aniline bacterium powder 1.2;
In above-mentioned steps, add zymin again, stir with the rotating speed of 20 revs/min, stir 1 hour, leave standstill 8 hours, zymin is polygalacturonase 1.5, cellulase 1.5, desaturase 0.8, oxydo-reductase 0.8, zytase 0.6.
Embodiment 4
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 16 revs/min, stir 0.6 hour, leave standstill 3 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 18 revs/min, stir 0.8 hour in the clear water of upper strata, leaves standstill 4 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 1.5, Paracoccus denitrificans bacterium powder 1.2, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 1.0;
In above-mentioned steps, add zymin again, stir with the rotating speed of 15 revs/min, stir 0.6 hour, leave standstill 5 hours, zymin is polygalacturonase 0.9, cellulase 1.2, desaturase 0.6, oxydo-reductase 0.6, zytase 0.4.
Comparative example 3
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 16 revs/min, stir 0.6 hour, leave standstill 3 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 18 revs/min, stir 0.8 hour in the clear water of upper strata, leaves standstill 4 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 1.7, Paracoccus denitrificans bacterium powder 1.0, microphenomenon of degradation of aniline bacterium powder 1.0;
In above-mentioned steps, add zymin again, stir with the rotating speed of 15 revs/min, stir 0.6 hour, leave standstill 5 hours, zymin is polygalacturonase 0.9, cellulase 1.2, desaturase 0.6, oxydo-reductase 0.6, zytase 0.4.
Comparative example 4
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 16 revs/min, stir 0.6 hour, leave standstill 3 hours; Inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 18 revs/min, stir 0.8 hour in the clear water of upper strata, leaves standstill 4 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 1.5, Paracoccus denitrificans bacterium powder 0.8, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.8;
In above-mentioned steps, add zymin again, stir with the rotating speed of 15 revs/min, stir 0.6 hour, leave standstill 5 hours, zymin is polygalacturonase 1.2, desaturase 0.8, oxydo-reductase 0.8, zytase 0.6.
As can be seen from above contrast, change microbiobacterial agent or zymin, also can produce certain impact for purifying water effect.

Claims (8)

1. tyre production enterprise use in waste water treatment water purification agent, is characterized in that, described water purification agent comprises inorganic water purification agent and microbial water-purifying agent, zymin, and its parts by weight are as follows respectively:
Described inorganic water purification agent is: polymerize aluminum chloride 5-20, Polyscrylamide 4-16, ferrous sulfate 2-15, Tai-Ace S 150 5-16;
Described microbial water-purifying agent is: nitrobacteria bacterium powder 0.5-2.0, Paracoccus denitrificans bacterium powder 0.4-1.4, thiobacterium bacterium powder 0.2-0.8, microphenomenon of degradation of aniline bacterium powder 0.3-1.2;
Described zymin is: polygalacturonase 0.1-1.5, cellulase 0.4-1.5, desaturase 0.1-0.8, oxydo-reductase 0.2-0.8, zytase 0.1-0.6.
2. tyre production enterprise use in waste water treatment water purification agent as claimed in claim 1, it is characterized in that, described inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12.
3. tyre production enterprise use in waste water treatment water purification agent as claimed in claim 1, it is characterized in that, described microbial water-purifying agent is: nitrobacteria bacterium powder 1.2, Paracoccus denitrificans bacterium powder 0.9, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.9.
4. tyre production enterprise use in waste water treatment water purification agent as claimed in claim 1, it is characterized in that, described zymin is: polygalacturonase 0.8, cellulase 0.9, desaturase 0.6, oxydo-reductase 0.5, zytase 0.3.
5. adopt the method for tyre production enterprise use in waste water treatment water purification agent process waste water as claimed in claim 1, it is characterized in that, described method comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 10-20 rev/min, stir 0.2-1 hour, leave standstill 2-5 hour; Described inorganic water purification agent is: polymerize aluminum chloride 5-20, Polyscrylamide 4-16, ferrous sulfate 2-15, Tai-Ace S 150 5-16;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 10-20 rev/min in the clear water of upper strata, stirs 0.2-1 hour, leaves standstill 2-6 hour; Described microbial water-purifying agent is: nitrobacteria bacterium powder 0.5-2.0, Paracoccus denitrificans bacterium powder 0.4-1.4, thiobacterium bacterium powder 0.2-0.8, microphenomenon of degradation of aniline bacterium powder 0.3-1.2;
Zymin is added again in above-mentioned steps, stir with the rotating speed of 10-20 rev/min, stir 0.2-1 hour, leave standstill 3-8 hour, described zymin is polygalacturonase 0.1-1.5, cellulase 0.4-1.5, desaturase 0.1-0.8, oxydo-reductase 0.2-0.8, zytase 0.1-0.6.
6. adopt the method for tyre production enterprise use in waste water treatment water purification agent process waste water as claimed in claim 1, it is characterized in that, described method comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours; Described inorganic water purification agent is: polymerize aluminum chloride 16, Polyscrylamide 12, ferrous sulfate 10, Tai-Ace S 150 12;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 15 revs/min, stir 0.6 hour in the clear water of upper strata, leaves standstill 4 hours; Described microbial water-purifying agent is nitrobacteria bacterium powder 1.2, Paracoccus denitrificans bacterium powder 0.9, thiobacterium bacterium powder 0.6, microphenomenon of degradation of aniline bacterium powder 0.9;
In above-mentioned steps, add zymin again, stir with the rotating speed of 15 revs/min, stir 0.5 hour, leave standstill 4 hours, described zymin is: polygalacturonase 0.8, cellulase 0.9, desaturase 0.6, oxydo-reductase 0.5, zytase 0.3.
7. adopt the method for tyre production enterprise use in waste water treatment water purification agent process waste water as claimed in claim 1, it is characterized in that, described method comprises following step:
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 10 revs/min, stir 0.2 hour, leave standstill 2 hours; Inorganic water purification agent is: polymerize aluminum chloride 5, Polyscrylamide 4, ferrous sulfate 2, Tai-Ace S 150 5;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 10 revs/min, stir 0.2 hour in the clear water of upper strata, leaves standstill 2 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 0.5, Paracoccus denitrificans bacterium powder 0.4, thiobacterium bacterium powder 0.2, microphenomenon of degradation of aniline bacterium powder 0.3;
In above-mentioned steps, add zymin again, stir with the rotating speed of 10 revs/min, stir 0.2 hour, leave standstill 3 hours, zymin is polygalacturonase 0.1, cellulase 0.4, desaturase 0.1, oxydo-reductase 0.2, zytase 0.1.
8. adopt the method for tyre production enterprise use in waste water treatment water purification agent process waste water as claimed in claim 1, it is characterized in that, described method comprises following step:
Tyre production enterprise method of wastewater treatment, comprises following step:
In waste water, first add inorganic water purification agent, stir with the rotating speed of 20 revs/min, stir 1 hour, leave standstill 5 hours; Inorganic water purification agent is: polymerize aluminum chloride 20, Polyscrylamide 16, ferrous sulfate 15, Tai-Ace S 150 16;
Release above-mentioned waste water upper strata clear water, the pollutent of removing bottom, adds microbial water-purifying agent, stirs with the rotating speed of 20 revs/min, stir 1 hour in the clear water of upper strata, leaves standstill 6 hours; Microbial water-purifying agent is: nitrobacteria bacterium powder 2.0, Paracoccus denitrificans bacterium powder 1.4, thiobacterium bacterium powder 0.8, microphenomenon of degradation of aniline bacterium powder 1.2;
In above-mentioned steps, add zymin again, stir with the rotating speed of 20 revs/min, stir 1 hour, leave standstill 8 hours, zymin is polygalacturonase 1.5, cellulase 1.5, desaturase 0.8, oxydo-reductase 0.8, zytase 0.6.
CN201410760860.5A 2014-12-13 2014-12-13 Tyre production enterprise use in waste water treatment water purification agent and method of wastewater treatment Expired - Fee Related CN104478169B (en)

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CN105198021A (en) * 2015-10-19 2015-12-30 晋城职业技术学院 Chemical wastewater treatment agent and preparation method thereof
CN105271621A (en) * 2015-11-19 2016-01-27 济南昊泽环保科技有限公司 Fruit can production waste water treatment agent and waste water treatment method
CN105461161A (en) * 2015-11-19 2016-04-06 济南昊泽环保科技有限公司 Pickles production wastewater treatment agent and wastewater treatment method
CN105481172A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Purifier for butadiene rubber production and wastewater treatment method
CN105481066A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Water purifier and wastewater treatment method used in butadiene styrene rubber production
CN105481067A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Water purifying agent used in chlorinated polyethylene rubber production and wastewater treatment method
CN105481100A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Water purifying agent used in polysulfide rubber production and wastewater treatment method
CN105502683A (en) * 2015-12-16 2016-04-20 山东永泰集团有限公司 Water purifying agent used in isoprene rubber production and wastewater treatment method
CN105502681A (en) * 2015-12-16 2016-04-20 山东永泰集团有限公司 Water purifying agent used in neoprene production and wastewater treatment method
CN105502682A (en) * 2015-12-16 2016-04-20 山东永泰集团有限公司 Water purifier adopted in nitrile rubber production and wastewater treatment method
CN105540868A (en) * 2015-12-16 2016-05-04 山东永泰集团有限公司 Water cleaning agent for chlorine ether rubber production and waste water treatment method
CN105541002A (en) * 2015-12-16 2016-05-04 山东永泰集团有限公司 Water cleaning agent for chlorosulfonated polyethylene rubber production and waste water treatment method
CN105967449A (en) * 2016-06-24 2016-09-28 山东永泰集团有限公司 Water purifier for production of rubber accelerator DZ and wastewater treatment method
CN105967450A (en) * 2016-06-24 2016-09-28 山东永泰集团有限公司 Water purifier for production of rubber accelerator NOBS and wastewater treatment method
CN106430698A (en) * 2016-08-03 2017-02-22 张海棠 Special water purifying agent for chloroprene rubber production and wastewater treatment method
CN106830370A (en) * 2017-03-28 2017-06-13 安徽中煦环保新材料科技有限公司 A kind of toxic wastewater inorganic agent and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101538089A (en) * 2009-04-16 2009-09-23 上海兴胜生物科技有限公司 Biological water purification agent powder and preparation thereof
CN102963986A (en) * 2012-12-04 2013-03-13 沧州旺发生物技术研究所有限公司 Biological sediment modifier for fishpond
CN103739051A (en) * 2014-01-29 2014-04-23 江声 Rapid flocculant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101538089A (en) * 2009-04-16 2009-09-23 上海兴胜生物科技有限公司 Biological water purification agent powder and preparation thereof
CN102963986A (en) * 2012-12-04 2013-03-13 沧州旺发生物技术研究所有限公司 Biological sediment modifier for fishpond
CN103739051A (en) * 2014-01-29 2014-04-23 江声 Rapid flocculant

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105198021A (en) * 2015-10-19 2015-12-30 晋城职业技术学院 Chemical wastewater treatment agent and preparation method thereof
CN105271621A (en) * 2015-11-19 2016-01-27 济南昊泽环保科技有限公司 Fruit can production waste water treatment agent and waste water treatment method
CN105461161A (en) * 2015-11-19 2016-04-06 济南昊泽环保科技有限公司 Pickles production wastewater treatment agent and wastewater treatment method
CN105481172A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Purifier for butadiene rubber production and wastewater treatment method
CN105481066A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Water purifier and wastewater treatment method used in butadiene styrene rubber production
CN105481067A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Water purifying agent used in chlorinated polyethylene rubber production and wastewater treatment method
CN105481100A (en) * 2015-12-16 2016-04-13 山东永泰集团有限公司 Water purifying agent used in polysulfide rubber production and wastewater treatment method
CN105502683A (en) * 2015-12-16 2016-04-20 山东永泰集团有限公司 Water purifying agent used in isoprene rubber production and wastewater treatment method
CN105502681A (en) * 2015-12-16 2016-04-20 山东永泰集团有限公司 Water purifying agent used in neoprene production and wastewater treatment method
CN105502682A (en) * 2015-12-16 2016-04-20 山东永泰集团有限公司 Water purifier adopted in nitrile rubber production and wastewater treatment method
CN105540868A (en) * 2015-12-16 2016-05-04 山东永泰集团有限公司 Water cleaning agent for chlorine ether rubber production and waste water treatment method
CN105541002A (en) * 2015-12-16 2016-05-04 山东永泰集团有限公司 Water cleaning agent for chlorosulfonated polyethylene rubber production and waste water treatment method
CN105967449A (en) * 2016-06-24 2016-09-28 山东永泰集团有限公司 Water purifier for production of rubber accelerator DZ and wastewater treatment method
CN105967450A (en) * 2016-06-24 2016-09-28 山东永泰集团有限公司 Water purifier for production of rubber accelerator NOBS and wastewater treatment method
CN106430698A (en) * 2016-08-03 2017-02-22 张海棠 Special water purifying agent for chloroprene rubber production and wastewater treatment method
CN106830370A (en) * 2017-03-28 2017-06-13 安徽中煦环保新材料科技有限公司 A kind of toxic wastewater inorganic agent and preparation method thereof

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