CN104458518B - Method for monitoring and qualitatively and quantitatively analyzing sediments in small-caliber sewer line - Google Patents
Method for monitoring and qualitatively and quantitatively analyzing sediments in small-caliber sewer line Download PDFInfo
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Abstract
一种小管径污水管道内沉积物的监测和定性定量分析方法,该方法的原理为:在没有微生物作用下,其沉积物主要来源于水中的SS,基于该原理,首先选择一条距离较短的小管径管道,定期从连接管道的检查井一取样,并根据水流到达检查井二的时间同时对检查井二进行取样,计算两个检查井之间的SS沉降速率以判断沉积物的沉积状况,然后,对样品常规指标进行测量,通过对不同指标的变化对比发现显著降解,从而确定沉积物所含有的物质成分。接着,测量水样中的粒径分布,根据粒径变分布变化情况判断小管径管道沉积物的粒径组成,最后根据公式得到检查井一与检查井二之间的沉积物累积量,本发明适用于管径在300mm以下的无分流和汇流管段沉积物的研究。
A method for monitoring and qualitative and quantitative analysis of sediments in small-diameter sewage pipes. The principle of the method is: without the action of microorganisms, the sediments mainly come from SS in the water. Based on this principle, first select a short distance For small-diameter pipelines, samples are regularly taken from inspection well 1 connected to the pipeline, and inspection well 2 is sampled at the same time according to the time when the water flow reaches inspection well 2, and the SS settlement rate between the two inspection wells is calculated to determine the deposition of sediments Then, measure the routine indicators of the sample, and find significant degradation by comparing the changes of different indicators, so as to determine the material composition contained in the sediment. Next, measure the particle size distribution in the water sample, judge the particle size composition of the sediment in the small-diameter pipeline according to the change of the particle size distribution, and finally obtain the sediment accumulation between the inspection well 1 and the inspection well 2 according to the formula. The invention is suitable for the research of the sediments in the non-split and confluence pipes with pipe diameters below 300mm.
Description
技术领域technical field
本发明属于污水处理技术领域,特别涉及一种对小管径污水管道内沉积物的监测和定性定量分析方法。The invention belongs to the technical field of sewage treatment, in particular to a method for monitoring and qualitatively and quantitatively analyzing sediments in small-diameter sewage pipes.
背景技术Background technique
城市排水管道是城市排水系统的重要组成部分,在污水输送过程中由于随污水或雨水进入管道的颗粒物类型的多样性以及管道流量变化的随机性,城市排水管道几乎都存在不同程度的污染物沉积现象。然而上述沉积物不仅会导致管道输水能力下降,而且随着流量的不均匀变化,沉积物被冲刷释放,造成管道污染物负荷增加,严重威胁受纳水体的水环境。因而研究沉积物的性状和沉积量具有十分重要的意义。Urban drainage pipes are an important part of urban drainage systems. During sewage transportation, due to the diversity of particulate matter types entering the pipes with sewage or rainwater and the randomness of pipe flow changes, almost all urban drainage pipes have varying degrees of pollutant deposition. Phenomenon. However, the above-mentioned sediments will not only reduce the water delivery capacity of the pipeline, but also will be washed and released with the uneven flow rate, which will increase the pollutant load of the pipeline and seriously threaten the water environment of the receiving water body. Therefore, it is of great significance to study the properties and deposition amount of sediments.
但是城市污水管网的类型多,管径、坡度等水利条件各不相同,且随着水力条件的变化沉积物也会相应的增加或者减少。因而针对管道沉积物的监测方法研究寥寥,仅局限于大管径管段的沉积特性分析与定性定量监测。However, there are many types of urban sewage pipe networks, and the water conservancy conditions such as pipe diameter and slope are different, and the sediment will increase or decrease correspondingly with the change of hydraulic conditions. Therefore, there are few studies on monitoring methods for pipeline sediments, which are limited to the analysis of sediment characteristics and qualitative and quantitative monitoring of large-diameter pipe sections.
目前对于大管径的污水管段的沉积物监测分析,也只是使用管道机器人深入管道进行取样,并通过安装于机器人上的声纳探头在与之相连接的监控器上生成管道内部沉积物与管道的实时图像。而小管径管道直径较小,且流速水深均不大,这不仅直接导致机器人无法顺利进入管道进行取样而且使得声纳探头无法完全浸没于水平面以下。从而无法取出小管径管道沉积物进行性状分析,也无法得到沉积物的沉积状况。At present, for the sediment monitoring and analysis of the large-diameter sewage pipe section, only the pipeline robot is used to go deep into the pipeline to take samples, and the sonar probe installed on the robot generates the sediment inside the pipeline and the pipeline on the monitor connected to it. real-time images. The small-diameter pipeline has a small diameter, and the flow rate and water depth are not large, which not only directly leads to the inability of the robot to smoothly enter the pipeline for sampling, but also prevents the sonar probe from being completely submerged below the water level. Therefore, it is impossible to take out the deposits of small-diameter pipelines for property analysis, and it is also impossible to obtain the deposition status of the deposits.
因此本专利对于监测小管径沉积物的含量,探究污水管网沉积物性状,都具有十分重要的意义。Therefore, this patent is of great significance for monitoring the content of small-diameter sediments and exploring the properties of sewage pipe network sediments.
发明内容Contents of the invention
为了克服上述现有技术的缺点,本发明提供一种对小管径污水管道内沉积物的监测和定性定量分析方法,完善了对城市污水管网沉积物的监测与分析研究,达到完善城市污水管网沉积物监测分析的目的。In order to overcome the shortcomings of the above-mentioned prior art, the present invention provides a method for monitoring and qualitative and quantitative analysis of sediments in small-diameter sewage pipes, which improves the monitoring and analysis of sediments in urban sewage pipe networks, and achieves the goal of perfecting urban sewage. The purpose of pipe network sediment monitoring and analysis.
为了实现上述目的,本发明采用的技术方案是:In order to achieve the above object, the technical scheme adopted in the present invention is:
选择短距离、无汇流和分流的管道3,从连接管道3的检查井一1定期取样,同时使用流量计测得该处水流的流量与流速,根据间距和流速得到水流到达位于检查井一1下游的检查井二2的时间,并于该时间在检查井二2取样。然后根据公式计算SS在其间的沉降速率,其中D为沉降速率,单位mg/L·s;SS1是检查井一1处SS测定值,单位mg/L;SS2是检查井二2处SS测定值,单位mg/L;S是检查井一1与检查井二2之间的间距,单位m;v是水流在检查井一1与检查井二2之间的流速,单位m/s;根据所述沉降速率得到沉积物状况,同时测定水流的常规指标与粒径分布,从而对管道内沉积物进行定性分析与判断,并根据公式M沉积=(SS1-SS2)·Q·Δt得到检查井一1与检查井二2之间的沉积物累积量M沉积,其中Q为管道中的平均流量,Δt为从检查井一1和检查井二2取样的间隔时间。Select a short-distance, non-converging and diverging pipeline 3, and take regular samples from the inspection well 1 connected to the pipeline 3. At the same time, use a flowmeter to measure the flow and velocity of the water flow there, and get the water flow to the inspection well 1 according to the spacing and flow velocity. The time of inspection well 2 2 downstream, and sampling in inspection well 2 2 at this time. Then according to the formula Calculate the sedimentation rate of SS during the period, where D is the sedimentation rate, unit mg/L s; SS 1 is the measured value of SS at 1 place in inspection well 1, unit mg/L; SS 2 is the measured value of SS at 2 places in inspection well 2, The unit is mg/L; S is the distance between the inspection well 1 and the inspection well 2, the unit is m; v is the flow velocity of the water flow between the inspection well 1 and the inspection well 2, the unit is m/s; according to the The sedimentation rate is obtained by the sedimentation rate, and the conventional indicators and particle size distribution of the water flow are measured at the same time, so as to conduct qualitative analysis and judgment on the sediments in the pipeline, and the inspection well is obtained according to the formula M deposition = (SS 1 -SS 2 )·Q·Δt The sediment accumulation amount M between inspection well 1 and inspection well 2 2, where Q is the average flow rate in the pipeline, and Δt is the interval time of sampling from inspection well 1 and inspection well 2.
其次,测定检查井一1和检查井二2样品中的水质常规指标。常规指标包括总磷(TP)、总氮(TN)、氨氮(NH4 +-N)、硝氮(NO3-N)、化学需氧量(COD),上述指标既可以通过哈希试剂进行测定,也可以通过国标方法测量。通过对不同指标的变化对比发现显著降解(平均降解30%左右)的具体指标,从而得到其间沉积物的主要组分成分。Secondly, measure the routine indicators of water quality in the samples of inspection well 1 and inspection well 2. Routine indicators include total phosphorus (TP), total nitrogen (TN), ammonia nitrogen (NH 4 + -N), nitrate nitrogen (NO 3 -N), and chemical oxygen demand (COD). Determination can also be measured by the national standard method. By comparing the changes of different indicators, it is found that the specific indicators that are significantly degraded (average degradation is about 30%), so as to obtain the main components of the sediments.
然后,采用粒径分析仪器或者筛分法测量粒径变化,基于粒径变化状况分析出不同时间段内在不同流速流量下沉积物粒径组成。Then, particle size analysis instrument or sieving method is used to measure the particle size change, and based on the particle size change status, the particle size composition of sediments under different flow rates and flow rates in different time periods is analyzed.
本发明中,基于对检查井一1和检查井二2定期测量的SS、流速v和流量Q,绘制成横轴为时间的曲线,并采用最小二乘法对检查井一1和检查井二2的SS、流速v和流量Q进行公式拟合。所述管道3的管径在300mm以下且无分流和汇流作用。In the present invention, based on the SS, flow velocity v and flow Q measured regularly to the inspection well one 1 and the inspection well two 2, the horizontal axis is drawn as a curve of time, and the least square method is used to analyze the inspection well one 1 and the inspection well two 2 The SS, flow velocity v and flow Q are used for formula fitting. The pipe 3 has a pipe diameter below 300mm and has no diversion and confluence functions.
与现有技术相比,本发明适用于管径在300mm以下的管段沉积物的研究,通过对所取水样的常规指标、SS差值及粒径分布等一系列指标的监测计算,得到所研究管段内沉积物的性状及沉积特性的总体情况,对污染物在其中的转化有更深入的认识。本方法避免了原有方法对小管径沉积物研究的不利影响,完善了对沉积物研究的范围,通过间接方式对小管径沉积物的性状进行科学的探究。Compared with the prior art, the present invention is suitable for the research on the sediments in the pipe section with a pipe diameter below 300mm. By monitoring and calculating a series of indexes such as the conventional indexes, SS difference and particle size distribution of the water samples taken, the obtained Study the properties of the sediments in the pipe section and the overall situation of the sedimentary characteristics, so as to have a deeper understanding of the transformation of pollutants in it. This method avoids the adverse effect of the original method on the study of small-diameter sediments, improves the scope of sediment research, and scientifically explores the properties of small-diameter sediments through indirect methods.
附图说明Description of drawings
图1是采用海洋沉积物温德华粒级分类标准研究管道中水质SS变化的示意图。Figure 1 is a schematic diagram of the study of SS changes in water quality in pipelines using the Wendehua classification standard for marine sediments.
图2是本发明采样原理图。Fig. 2 is a schematic diagram of the sampling principle of the present invention.
图3是本发明实施例1的中值粒径分布图。Fig. 3 is a diagram of the median particle size distribution of Example 1 of the present invention.
图4是本发明实施例的五个常规指标浓度图,图4a为TN浓度,图4b为NH4 +-N浓度,图4c为NO3-N浓度,图4d为COD浓度,图4e为TP浓度。Figure 4 is the concentration diagram of five conventional indicators in the embodiment of the present invention, Figure 4a is the concentration of TN, Figure 4b is the concentration of NH 4 + -N, Figure 4c is the concentration of NO 3 -N, Figure 4d is the concentration of COD, and Figure 4e is the concentration of TP concentration.
图5是本发明实施例2的中值粒径分布图。Fig. 5 is a graph showing the median particle size distribution of Example 2 of the present invention.
具体实施方式detailed description
下面结合附图和实施例详细说明本发明的实施方式。The implementation of the present invention will be described in detail below in conjunction with the drawings and examples.
本发明原理为:在不考虑微生物作用的条件下,管网中SS的变化量为管道中沉积物的变化量,如公式(1)所示。The principle of the invention is: under the condition of not considering the action of microorganisms, the variation of SS in the pipe network is the variation of sediment in the pipeline, as shown in the formula (1).
M沉积=(SS1-SS2)·Q·Δt (1)M deposition = (SS 1 -SS 2 )·Q·Δt (1)
基于上述原理本发明采用海洋沉积物温德华粒级分类标准研究了管道中水质SS变化(如图1所示),得出D<4μm的颗粒物最容易冲刷,D>63μm颗粒物开始沉积。且粒径越大沉积越好,粒径D>125μm颗粒物最容易沉积。而其他研究表明,管道内沉积物为重力沉降,流速越大,沉降效果越差冲刷效果越好。Based on the above principles, the present invention uses the Wendehua classification standard for marine sediments to study the SS changes in water quality in pipelines (as shown in Figure 1), and finds that particles with D<4 μm are the easiest to wash away, and particles with D>63 μm begin to deposit. And the larger the particle size, the better the deposition, and the particle size D>125μm is the easiest to deposit. Other studies have shown that the sediment in the pipeline is settled by gravity, and the greater the flow rate, the worse the settlement effect and the better the scouring effect.
根据上述原理和沉积物特性,本发明适用于:According to above-mentioned principle and sediment characteristic, the present invention is applicable to:
1)没有汇流和分流管道;1) There is no confluence and diversion pipeline;
2)流动时间短且管段较小的管道。2) Pipelines with short flow times and small pipe sections.
因而,如图2所示,本方法在实施过程中首先选择适合上述条件的管道。并选择符合条件的检查井一1和检查井二2。在此基础上定期对检查井一1和检查井二2进行采样和流量流速监测,其采样规则为:检查井二2采样必须在检查井一1采样后进行并间隔水流到达检查井二2的时间。采样完毕后,根据检查井一1和检查井二2的SS,计算各个时间段内沉积物沉积速率,该结果反映沉积物的沉积状态。其公式为:Therefore, as shown in Fig. 2, in the implementation process of this method, a pipeline suitable for the above conditions is firstly selected. And select the qualified inspection well 1 and inspection well 2 2. On this basis, the inspection well 1 and the inspection well 2 2 are regularly sampled and the flow rate is monitored. The sampling rules are: the sampling of the inspection well 2 2 must be carried out after the sampling of the inspection well 1 1 and the water flow reaches the inspection well 2 2 at intervals. time. After sampling, according to the SS of inspection well 1 and inspection well 2, the sediment deposition rate in each time period is calculated, and the results reflect the sediment deposition state. Its formula is:
式中:D——沉降速率(mg/L·s)In the formula: D——sedimentation rate (mg/L s)
SS1——检查井一1处SS测定值(mg/L)SS 1 ——measured value of SS in inspection well 1 (mg/L)
SS2——检查井二2处SS测定值(mg/L)SS 2 ——measured value of SS at 2 places in inspection well 2 (mg/L)
l——检查井间距(m)l——Inspection Well Spacing (m)
v——即时流速(m/s)v——Instant velocity (m/s)
然后,基于上述所采集样品,对管道3中检查井一1和检查井二2进行常规水质指标的监测。常规指标包括总磷(TP)、总氮(TN)、氨氮(NH4 +-N)、硝氮(NO3-N)、化学需氧量(COD),上述指标既可以通过哈希试剂进行测定,也可以通过国标方法测量。通过对不同指标的变化对比发现显著降解(平均降解30%左右)的具体指标,从而得到其间沉积物的主要组分成分。Then, based on the samples collected above, routine monitoring of water quality indicators is performed on the inspection well 1 and the inspection well 2 2 in the pipeline 3 . Routine indicators include total phosphorus (TP), total nitrogen (TN), ammonia nitrogen (NH 4 + -N), nitrate nitrogen (NO 3 -N), and chemical oxygen demand (COD). Determination can also be measured by the national standard method. By comparing the changes of different indicators, it is found that the specific indicators that are significantly degraded (average degradation is about 30%), so as to obtain the main components of the sediments.
接下来,采用粒径分析仪器或者筛分法测量粒径变化,基于粒径变化状况分析出不同时间段内在不同流速流量下沉积物粒径组成。Next, use a particle size analysis instrument or a sieving method to measure the particle size change, and analyze the particle size composition of the sediment under different flow rates and flow rates in different time periods based on the particle size change status.
最后,测定小管径管道中沉积物的含量。本方法中,基于原理得出的沉积物沉积量公式为:Finally, determine the sediment content in small diameter pipes. In this method, the formula for the amount of sediment deposited based on the principle is:
t0为初试时间、t为终止时间,Q(t)为流量拟合函数、SS1(t)为检查井一1点的SS拟合函数、SS2(t)为检查井二2点的SS拟合函数、V(t)为流速拟合函数。t 0 is the initial test time, t is the end time, Q(t) is the flow fitting function, SS 1 (t) is the SS fitting function of inspection well 1 point 1, SS 2 (t) is the SS fitting function of inspection well 2 point 2 SS fitting function, V(t) is the velocity fitting function.
其具体求解方法如下:The specific solution method is as follows:
1)对检查井一1、检查井二2的SS、流速v和流量Q进行定期测量,绘制成横轴为时间的曲线。1) Regularly measure the SS, flow velocity v and flow Q of inspection well 1 and inspection well 2, and draw a curve with the horizontal axis as time.
2)采用最小二乘法对检查井一1、检查井二2的SS、流速v和流量Q曲线进行公式拟合,并保证期拟合后的R2符合相关规定要求。2) Use the least squares method to fit the SS, flow velocity v and flow Q curves of inspection well 1 and inspection well 2 2, and ensure that the R 2 after the period fitting meets the requirements of relevant regulations.
3)将拟合方程带入到相应的方程中求解。复杂公式可以采用计算机积分(随机寻点法、矩形求解法、定义法等),积分结果为管道沉积物沉积量。3) Bring the fitting equation into the corresponding equation to solve. Complicated formulas can be integrated by computer (random point finding method, rectangle solution method, definition method, etc.), and the integral result is the amount of pipeline sediment deposition.
需要指出的是,公式(3)有如下2个特例,在该特例下可以直接简化计算过程:It should be pointed out that formula (3) has the following two special cases, under which the calculation process can be directly simplified:
1.流速、流量稳定状态下沉积物的沉积速率1. The deposition rate of the sediment under the steady state of flow velocity and flow
在该状态下,流速保持稳定,此时沉积物的沉积量可以表示为:In this state, the flow rate remains stable, and the amount of sediment deposited at this time can be expressed as:
当距离非常短时,在一定的误差范围内可以忽略不计,此时公式(4)可以进一步简化为:When the distance is very short, within a certain error range can be ignored, at this time formula (4) can be further simplified as:
公式(5)表明在流量恒定,距离较短的管道,沉积量为曲线SS1和曲线SS2围成的面积与流量Q的乘积。Formula (5) shows that in a pipeline with a constant flow rate and a short distance, the deposition amount is the product of the area enclosed by the curve SS 1 and the curve SS 2 and the flow rate Q.
2.无汇流小管径支杆管道短时间内的沉积状况2. The short-term deposition status of non-confluent small-diameter strut pipes
支杆小管径主要位于排水管道的起始端,水质、水量和流速的变化情况主要取决于区域土地用途、生产工艺、生活习惯以及降雨等因素。故在误差允许范围内,可以将SS、流量Q和流速v视为分段函数,因而公式(3)可以简化为:The small diameter of the pole is mainly located at the beginning of the drainage pipe, and the change of water quality, water volume and flow rate mainly depends on factors such as regional land use, production technology, living habits and rainfall. Therefore, within the allowable range of error, SS, flow Q and flow velocity v can be regarded as piecewise functions, so formula (3) can be simplified as:
式中n为监测时间段数,Qi为第i段内管道中平均流量,SS1,i(ti)为第i段内检查井一1点的SS拟合函数,SS2,i(ti)为第i段内检查井二2点的SS拟合函数,l为检查井一1和检查井二2之间距离,Vi为第i时间段内平均流速,ti为第i时间段所持续的时间。In the formula, n is the number of monitoring time periods, Q i is the average flow rate in the pipeline in the i-th section, SS 1, i (t i ) is the SS fitting function of one point in the inspection well in the i-th section, and SS 2, i (t i ) is the SS fitting function of the inspection well 2 and 2 points in the i-th section, l is the distance between the inspection well 1 and the inspection well 2 2, V i is the average flow velocity in the i-th time period, and t i is the i-th time duration of the segment.
本发明所涉及到的监测方法与实验仪器都易实现,例如如下实施例。The monitoring methods and experimental instruments involved in the present invention are easy to implement, such as the following examples.
实施例1:Example 1:
1.实地选取西安市东郊一路段符合条件的110m长管段,管径为300mm,其间无汇流。研究时间段为8:00-16:00的沉积物沉积状况;1. Select a qualified 110m long pipe section in the Dongjiao 1st Road section of Xi'an City on the spot, with a pipe diameter of 300mm and no confluence in between. The sediment deposition status of the research time period is 8:00-16:00;
2.对所取水样进行总磷(TP)、总氮(TN)、氨氮(NH4 +-N)、硝氮(NO3-N)、化学需氧量(COD)等常规指标的监测计算。常规指标利用哈希试剂进行测定;SS差值的测定利用烘干称重的方法进行测定,利用以下公式计算SS在其间的沉降速率:2. Monitor routine indicators such as total phosphorus (TP), total nitrogen (TN), ammonia nitrogen (NH 4 + -N), nitrate nitrogen (NO 3 -N), and chemical oxygen demand (COD) on the water samples taken calculate. Routine indicators are measured by Hach reagent; SS difference is measured by drying and weighing method, and the sedimentation rate of SS is calculated by the following formula:
D——沉降速率(mg/L·s)D——Sedimentation rate (mg/L s)
SS1——检查井一1处SS测定值(mg/L)SS 1 ——measured value of SS in inspection well 1 (mg/L)
SS2——检查井二2处SS测定值(mg/L)SS 2 ——measured value of SS at 2 places in inspection well 2 (mg/L)
l——检查井间距(m)l——Inspection Well Spacing (m)
v——即时流速(m/s)v——Instant velocity (m/s)
3.粒径分布可利用专业的粒度分析仪进行测定,用中值粒径D50表示之间的关系,如图3所示,可以发现,不同时间两取样点的悬浮物粒径都有所下降,中值粒径普遍降低,初始时D50降低量达到23.1%,但随着流量流速的增加效果逐渐减弱。3. The particle size distribution can be measured by a professional particle size analyzer, and the relationship between the median particle size D50 is represented, as shown in Figure 3. It can be found that the particle sizes of the suspended matter at the two sampling points at different times are all different. Decrease, the median particle size generally decreases, and the D 50 reduction reaches 23.1% at the beginning, but the effect gradually weakens with the increase of flow rate.
4.由于该管道水样水质、水量和流速大致随时间跳跃式变化,跳跃时间为2h左右,在某一时段内变化不显著,属于特例2。故从8:00至16:00每隔2小时进行一组的取样;4. Since the water quality, water volume, and flow rate of the water sample in the pipeline roughly change with time, the jump time is about 2 hours, and the change is not significant within a certain period of time, which belongs to special case 2. Therefore, a group of samples is taken every 2 hours from 8:00 to 16:00;
5.将ΔSS函数、Q函数和V函数按照时间分段,如表1所示,并将该函数按照相应区段放入公式(6)中,结果列于表1:5. Divide the ΔSS function, Q function and V function into sections according to time, as shown in Table 1, and put the functions into formula (6) according to the corresponding sections, and the results are listed in Table 1:
表1 分段函数及计算结果Table 1 Piecewise functions and calculation results
6.由表1和图2、图4的数据分析可知,小管径内悬浮物沉降速率与管道内流量流速呈反相关,其间大粒径悬浮物优先于小粒径悬浮物在管道内沉降,而沉积效果会随着流量流速的增加减弱。除TN以外,其他指标浓度降低程度很小,但在12:00浓度较大时的NH4 +、NO3有明显降解,分别为33.4%和58.6%,主要是由于悬浮物沉降引起;其他时间可能由于其的降解主要依赖于生物分解或者物理化学等的其他过程,所以效果并不明显;TN的浓度有明显减小,平均降解率为0.034mg/L·s,达到34.6%,证明沉积物N含量较高。由此也能看出浓度较高时悬浮物沉降效果更明显。而其从6点到16点的沉积为量34814.42mg。6. From the data analysis in Table 1 and Figure 2 and Figure 4, it can be seen that the sedimentation rate of suspended solids in small pipe diameters is inversely correlated with the flow rate in the pipeline, and the large-sized suspended solids settle in the pipeline preferentially over the small-sized suspended solids , and the deposition effect will decrease with the increase of flow velocity. Except for TN, the concentration of other indicators decreased very little, but at 12:00 when the concentration was high, NH 4 + and NO 3 were significantly degraded, which were 33.4% and 58.6% respectively, which was mainly caused by the sedimentation of suspended solids; at other times It may be that its degradation mainly depends on other processes such as biological decomposition or physical chemistry, so the effect is not obvious; the concentration of TN is significantly reduced, and the average degradation rate is 0.034mg/L·s, reaching 34.6%, which proves that the sediment N content is higher. It can also be seen that the sedimentation effect of suspended solids is more obvious when the concentration is higher. And its deposition from 6 o'clock to 16 o'clock is 34814.42 mg.
实施例2:Example 2:
1.西安市一路段符合条件的80m长管道,管径300mm,期间没有汇流,定期调研水质水量和沉积物。研究时间为0:00~10:00,结果列于表2;1. The qualified 80m-long pipeline in the first section of Xi'an City, with a pipe diameter of 300mm, has no confluence during the period, and regularly investigates the water quality, quantity and sediment. The research time is from 0:00 to 10:00, and the results are listed in Table 2;
2.对所取水样进行总磷(TP)、总氮(TN)、氨氮(NH4 +-N)、硝氮(NO3-N)、化学需氧量(COD)等常规指标的监测计算,并列于表3。常规指标利用哈希试剂进行测定;SS差值的测定利用烘干称重的方法进行测定,利用以下公式计算SS在其间的沉降速率:2. Monitor routine indicators such as total phosphorus (TP), total nitrogen (TN), ammonia nitrogen (NH 4 + -N), nitrate nitrogen (NO 3 -N), and chemical oxygen demand (COD) on the water samples taken calculated and listed in Table 3. Routine indicators are measured by Hach reagent; SS difference is measured by drying and weighing method, and the sedimentation rate of SS is calculated by the following formula:
D——沉降速率(mg/L·s)D——Sedimentation rate (mg/L s)
SS1——检查井一1处SS测定值(mg/L)SS 1 ——measured value of SS in inspection well 1 (mg/L)
SS2——检查井二2处SS测定值(mg/L)SS 2 ——measured value of SS at 2 places in inspection well 2 (mg/L)
l——检查井间距(m)l——Inspection Well Spacing (m)
v——即时流速(m/s)v——Instant velocity (m/s)
3.粒径分布可利用专业的粒度分析仪进行测定,用中值粒径D50表示之间的关系,如图5所示,可以发现,不同时间两取样点的悬浮物粒径都有所下降,中值粒径普遍降低,凌晨12点中D50降低量达到最低为23%,但随着流量流速的增加效果逐渐减弱。3. The particle size distribution can be measured by a professional particle size analyzer, and the relationship between the median particle size D50 is represented, as shown in Figure 5. It can be found that the particle sizes of the suspended matter at the two sampling points at different times are all different. Decrease, the median particle size generally decreased, and the D 50 decrease reached a minimum of 23% at 12 o'clock in the morning, but the effect gradually weakened with the increase of flow rate.
4.取样研究发现,该管道中流量、流速和SS属于连续流动变化较为显著,故需要拟合出拟合曲模拟曲线。每2个小时取一组样,其指标如表2所示,各曲线的拟合方程为:4. The sampling research found that the flow rate, flow rate and SS in the pipeline belong to continuous flow and the changes are relatively significant, so it is necessary to fit a fitting curve simulation curve. A group of samples is taken every 2 hours, and its indicators are shown in Table 2. The fitting equation of each curve is:
SS1(t)=0.1706t5-4.3542t4+37.901t3-124.21t2+101.92t+130SS 1 (t)=0.1706t 5 -4.3542t 4 +37.901t 3 -124.21t 2 +101.92t+130
R2=1.000R 2 =1.000
SS2(t)=0.1549t5-3.8177t4+31.922t3-99.229t2+68.333t+120SS 2 (t)=0.1549t 5 -3.8177t 4 +31.922t 3 -99.229t 2 +68.333t+120
R2=1.000R 2 =1.000
Q(t)=0.1707t4+2.9172t3-12.258t2+3.9303t+48.622Q(t)=0.1707t 4 +2.9172t 3 -12.258t 2 +3.9303t+48.622
R2=1.000R 2 =1.000
V(t)=-0.006t4+0.011t3-0.0502t2+0.0325t+0.248V(t)=-0.006t 4 +0.011t 3 -0.0502t 2 +0.0325t+0.248
R2=0.998R 2 =0.998
5.将上述拟合公式带入公式(3),并采用随机寻点算法对公式(3)进行0:00~10:00的积分运算。结合表2、表3和图5分析,小管径内悬浮物沉降速率与管道内流量流速呈反相关,其间大粒径悬浮物优先于小粒径悬浮物在管道内沉降,而沉积效果会随着流量流速的增加减弱。除COD以外,其他指标浓度降低程度很小,证明沉积物COD含量较高。由此也能看出浓度较高时悬浮物沉降效果更明显。而SS分析得出其从6点到16点的沉积量为33769.35mg。5. Bring the above fitting formula into formula (3), and use the random point-seeking algorithm to carry out the integral operation of formula (3) from 0:00 to 10:00. Combined with the analysis of Table 2, Table 3 and Figure 5, the sedimentation rate of suspended solids in small pipe diameters is inversely correlated with the flow rate in the pipeline, during which suspended solids with large particle diameters settle in the pipeline preferentially over suspended solids with small particle diameters, and the deposition effect will decrease. Decreases with increasing flow velocity. Except for COD, the concentration of other indicators decreased very little, which proved that the content of COD in the sediment was high. It can also be seen that the sedimentation effect of suspended solids is more obvious when the concentration is higher. The SS analysis shows that the deposition amount from 6 o'clock to 16 o'clock is 33769.35 mg.
表2 监测数据Table 2 Monitoring data
表3 水质参数(mg/L)Table 3 Water quality parameters (mg/L)
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