CN104449222A - High-adhesion corrosion-resistant modified titanium dioxide paint - Google Patents
High-adhesion corrosion-resistant modified titanium dioxide paint Download PDFInfo
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- CN104449222A CN104449222A CN201410681885.6A CN201410681885A CN104449222A CN 104449222 A CN104449222 A CN 104449222A CN 201410681885 A CN201410681885 A CN 201410681885A CN 104449222 A CN104449222 A CN 104449222A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses high-adhesion corrosion-resistant modified titanium dioxide paint. The paint comprises the raw materials in parts by weight: 83-86 parts of epoxy resin, 15-18 parts of melamine formaldehyde resin, 9-12 parts of powdered ethylene propylene diene monomer rubber, 7-9 parts of super-fine calcium carbonate, 2-4 parts of organic montmorillonite, 2-4 parts of zeolite powder, 4-6 parts of sodium dodecyl benzene sulfonate, 3-5 parts of calcium sulfate, 8-11 parts of modified titanium dioxide, 2-5 parts of cresyl diphenyl phosphate, 4-7 parts of microencapsulated red phosphorus, 13-16 parts of nano aluminium hydroxide, 11-14 parts of melamine phosphate, 0.8-1.1 parts of manganese linoleate, 2-3 parts of rosin acid aluminium, 20-30 parts of paint, 3-4 parts of a flexibilizer, 2-3 parts of a foam killer, 1.5-2 parts of a levelling agent, and 1-2 parts of a mould inhibitor. The modified titanium dioxide paint has excellent adhesive force and decay resistance, and is easy to solidify.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to the corrosion-resistant modifying titanium dioxide coating of a kind of high attachment.
Background technology
Paint, after building surface, has function attractive in appearance, and coating, in the middle of application, proposes very high requirement to the corrosion-resistant of coating and sticking power.Under atrocious weather, along with rainwater is continual, coating top layer is scrubbed, if paint adhesion is poor, coating can produce fade, problems of crack, erosion resistance is poor, along with rainwash, corrosion is not stopped to coating, causes the performance of coating to change.Affect the normal function of coating.Need now to find and a kind of there is corrosion-resistant and coating that is high adhesive force.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes the corrosion-resistant modifying titanium dioxide coating of a kind of high attachment, has excellent sticking power and corrosion resistance nature, be easy to solidification.
The corrosion-resistant modifying titanium dioxide coating of one height attachment that the present invention proposes, its raw material comprises by weight: epoxy resin 83-86 part, terpolycyantoamino-formaldehyde resin 15-18 part, powder terpolymer EP rubber 9-12 part, calcium carbonate superfine powder 7-9 part, organo montmorillonite 2-4 part, zeolite powder 2-4 part, Sodium dodecylbenzene sulfonate 4-6 part, calcium sulfate 3-5 part, modifying titanium dioxide 8-11 part, phosphate toluene diphenyl ester 2-5 part, microcapsule red phosphorus 4-7 part, nano-aluminum hydroxide 13-16 part, melamine phosphate 11-14 part, manganous linoleate 0.8-1.1 part, sylvic acid aluminium 2-3 part, pigment 20-30 part, toughner 3-4 part, defoamer 2-3 part, advection agent 1.5-2 part, mould inhibitor 1-2 part.
Preferably, the weight ratio of epoxy resin, terpolycyantoamino-formaldehyde resin and powder terpolymer EP rubber is 84-85:16-17:10-11.
Preferably, its raw material comprises by weight: epoxy resin 84-85 part, terpolycyantoamino-formaldehyde resin 16-17 part, powder terpolymer EP rubber 10-11 part, calcium carbonate superfine powder 7.8-8.9 part, organo montmorillonite 2.7-3.4 part, zeolite powder 2.8-3.4 part, Sodium dodecylbenzene sulfonate 4.4-5.6 part, calcium sulfate 3.2-4.5 part, modifying titanium dioxide 9-10 part, phosphate toluene diphenyl ester 3-4 part, microcapsule red phosphorus 5-6 part, nano-aluminum hydroxide 14-15 part, melamine phosphate 12-13 part, manganous linoleate 0.9-1 part, sylvic acid aluminium 2.2-2.6 part, pigment 23-25 part, toughner 3.1-3.4 part, defoamer 2.5-2.7 part, advection agent 1.8-1.9 part, mould inhibitor 1.2-1.5 part.
Preferably, the preparation method of modifying titanium dioxide comprises: added in dehydrated alcohol by nano titanium oxide and stir, and then suction filtration obtains the first filter cake, the first filter cake is carried out vacuum-drying and obtains pretreated material A; Capryl(yl)chloride and saleratus are added in chloroform and stir, then continue to stir after adding pretreated material A, then suction filtration obtains the second filter cake, after being washed with water by the second filter cake, carries out vacuum-drying and obtains modifying titanium dioxide.
Preferably, the preparation method of modifying titanium dioxide comprises: add in 10-13 part dehydrated alcohol by molfraction by 1.8-2.1 part nano titanium oxide, after stirring 1.6-1.9h with the stirring velocity of 840-870rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 69-72 DEG C; By weight 20-23 part capryl(yl)chloride and 25-28 part saleratus are added in chloroform and stir, 5.2-5.5h is stirred after adding 3-6 part pretreated material A again, stirring velocity is 1700-1850rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 61-64 DEG C.
Preferably, the preparation method of modifying titanium dioxide comprises: add in 11-12 part dehydrated alcohol by molfraction by 1.9-2 part nano titanium oxide, after stirring 1.7-1.8h with the stirring velocity of 850-860rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 70-71 DEG C; By weight 21-22 part capryl(yl)chloride and 26-27 part saleratus are added in chloroform and stir, 5.3-5.4h is stirred after adding 4-5 part pretreated material A again, stirring velocity is 1750-1800rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 62-63 DEG C.
The present invention adopts epoxy resin, terpolycyantoamino-formaldehyde resin and powder terpolymer EP rubber blending and modifying as major ingredient, the present invention is made to have excellent sticking power, weather-proof and resistance toheat, and anti-erosion, wear resisting property are good, also improve heat-resisting, light fastness, condition of cure is low, and curing speed is fast, add Sodium dodecylbenzene sulfonate again, polarity of the present invention is increased, in water-soluble or ethanol, the use range of carrier of the present invention can be expanded, calcium carbonate superfine powder, organo montmorillonite, zeolite powder, calcium sulfate and modifying titanium dioxide add in major ingredient, assisting by phosphate toluene diphenyl ester, can be dispersed in uniformly between major ingredient molecule, significantly improve of the present invention high temperature resistant, corrosion resistant performance and anti-thixotroping ability, wherein modifying titanium dioxide first and blended pre-treatment of dehydrated alcohol by nano titanium oxide, make nano titanium oxide surface attachment hydroxyl, add capryl(yl)chloride again, make it to form modifying titanium dioxide with the hydroxy combining being attached to nano titanium oxide surface, add in major ingredient, greatly improve dispersiveness of the present invention and wettability, manganous linoleate and sylvic acid aluminium coordinate, and improve curing speed of the present invention further, phosphate toluene diphenyl ester, microcapsule red phosphorus, nano-aluminum hydroxide and melamine phosphate coordinate formation flame-retardant system, wherein melamine phosphate, microcapsule red phosphorus and phosphate toluene diphenyl ester are as phosphorus flame retardant, melamine phosphate can be used as nitrogenated flame retardant again, significantly improve oxygen index of the present invention, improve flame retardant properties of the present invention, nano-aluminum hydroxide at high temperature dewaters formation aluminum oxide, not only suppress the generation of smog, and product alumina can also strengthen resistance toheat of the present invention and corrosion resistance nature further.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The corrosion-resistant modifying titanium dioxide coating of one height attachment that the present invention proposes, its raw material comprises by weight: epoxy resin 83 parts, terpolycyantoamino-formaldehyde resin 18 parts, powder terpolymer EP rubber 9 parts, calcium carbonate superfine powder 7 parts, organo montmorillonite 4 parts, zeolite powder 2 parts, Sodium dodecylbenzene sulfonate 6 parts, 3 parts, calcium sulfate, modifying titanium dioxide 11 parts, phosphate toluene diphenyl ester 2 parts, microcapsule red phosphorus 4 parts, nano-aluminum hydroxide 16 parts, melamine phosphate 11 parts, manganous linoleate 1.1 parts, 2 parts, sylvic acid aluminium, pigment 30 parts, toughner 3 parts, defoamer 3 parts, advection agent 1.5 parts, mould inhibitor 2 parts.
The preparation method of modifying titanium dioxide comprises: add in 11 parts of dehydrated alcohols by molfraction by 2 parts of nano titanium oxides, after stirring 1.7h with the stirring velocity of 860rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 71 DEG C; By weight 21 parts of capryl(yl)chlorides and 27 parts of saleratus are added in chloroform and stir, 5.4h is stirred after adding 4 parts of pretreated material A again, stirring velocity is 1750rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 63 DEG C.
Embodiment 2
The corrosion-resistant modifying titanium dioxide coating of one height attachment that the present invention proposes, its raw material comprises by weight: epoxy resin 85 parts, terpolycyantoamino-formaldehyde resin 16 parts, powder terpolymer EP rubber 11 parts, calcium carbonate superfine powder 7.8 parts, organo montmorillonite 3.4 parts, zeolite powder 2.8 parts, Sodium dodecylbenzene sulfonate 5.6 parts, 3.2 parts, calcium sulfate, modifying titanium dioxide 10 parts, phosphate toluene diphenyl ester 3 parts, microcapsule red phosphorus 6 parts, nano-aluminum hydroxide 14 parts, melamine phosphate 13 parts, manganous linoleate 0.9 part, 2.6 parts, sylvic acid aluminium, pigment 23 parts, toughner 3.4 parts, defoamer 2.5 parts, advection agent 1.9 parts, mould inhibitor 1.2 parts.
The preparation method of modifying titanium dioxide comprises: add in 12 parts of dehydrated alcohols by molfraction by 1.9 parts of nano titanium oxides, after stirring 1.8h with the stirring velocity of 850rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 70 DEG C; By weight 22 parts of capryl(yl)chlorides and 26 parts of saleratus are added in chloroform and stir, 5.3h is stirred after adding 5 parts of pretreated material A again, stirring velocity is 1800rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 62 DEG C.
Embodiment 3
The corrosion-resistant modifying titanium dioxide coating of one height attachment that the present invention proposes, its raw material comprises by weight: epoxy resin 84 parts, terpolycyantoamino-formaldehyde resin 17 parts, powder terpolymer EP rubber 10 parts, calcium carbonate superfine powder 8.9 parts, organo montmorillonite 2.7 parts, zeolite powder 3.4 parts, Sodium dodecylbenzene sulfonate 4.4 parts, 4.5 parts, calcium sulfate, modifying titanium dioxide 9 parts, phosphate toluene diphenyl ester 4 parts, microcapsule red phosphorus 5 parts, nano-aluminum hydroxide 15 parts, melamine phosphate 12 parts, manganous linoleate 1 part, 2.2 parts, sylvic acid aluminium, pigment 25 parts, toughner 3.1 parts, defoamer 2.7 parts, advection agent 1.8 parts, mould inhibitor 1.5 parts.
The preparation method of modifying titanium dioxide comprises: add in 13 parts of dehydrated alcohols by molfraction by 1.8 parts of nano titanium oxides, after stirring 1.9h with the stirring velocity of 840rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 69 DEG C; By weight 23 parts of capryl(yl)chlorides and 25 parts of saleratus are added in chloroform and stir, 5.2h is stirred after adding 6 parts of pretreated material A again, stirring velocity is 1850rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 61 DEG C.
Embodiment 4
The corrosion-resistant modifying titanium dioxide coating of one height attachment that the present invention proposes, its raw material comprises by weight: epoxy resin 86 parts, terpolycyantoamino-formaldehyde resin 15 parts, powder terpolymer EP rubber 12 parts, calcium carbonate superfine powder 7 parts, organo montmorillonite 4 parts, zeolite powder 2 parts, Sodium dodecylbenzene sulfonate 6 parts, 3 parts, calcium sulfate, modifying titanium dioxide 11 parts, phosphate toluene diphenyl ester 2 parts, microcapsule red phosphorus 7 parts, nano-aluminum hydroxide 13 parts, melamine phosphate 14 parts, manganous linoleate 0.8 part, 3 parts, sylvic acid aluminium, pigment 20 parts, toughner 4 parts, defoamer 2 parts, advection agent 2 parts, mould inhibitor 1 part.
The preparation method of modifying titanium dioxide comprises: add in 10 parts of dehydrated alcohols by molfraction by 2.1 parts of nano titanium oxides, after stirring 1.6h with the stirring velocity of 870rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 72 DEG C; By weight 20 parts of capryl(yl)chlorides and 28 parts of saleratus are added in chloroform and stir, 5.5h is stirred after adding 3 parts of pretreated material A again, stirring velocity is 1700rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 64 DEG C.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (6)
1. the corrosion-resistant modifying titanium dioxide coating of high attachment, it is characterized in that, its raw material comprises by weight: epoxy resin 83-86 part, terpolycyantoamino-formaldehyde resin 15-18 part, powder terpolymer EP rubber 9-12 part, calcium carbonate superfine powder 7-9 part, organo montmorillonite 2-4 part, zeolite powder 2-4 part, Sodium dodecylbenzene sulfonate 4-6 part, calcium sulfate 3-5 part, modifying titanium dioxide 8-11 part, phosphate toluene diphenyl ester 2-5 part, microcapsule red phosphorus 4-7 part, nano-aluminum hydroxide 13-16 part, melamine phosphate 11-14 part, manganous linoleate 0.8-1.1 part, sylvic acid aluminium 2-3 part, pigment 20-30 part, toughner 3-4 part, defoamer 2-3 part, advection agent 1.5-2 part, mould inhibitor 1-2 part.
2. the corrosion-resistant modifying titanium dioxide coating of high attachment according to claim 1, it is characterized in that, the weight ratio of epoxy resin, terpolycyantoamino-formaldehyde resin and powder terpolymer EP rubber is 84-85:16-17:10-11.
3. the corrosion-resistant modifying titanium dioxide coating of high attachment according to claim 1 or 2, it is characterized in that, its raw material comprises by weight: epoxy resin 84-85 part, terpolycyantoamino-formaldehyde resin 16-17 part, powder terpolymer EP rubber 10-11 part, calcium carbonate superfine powder 7.8-8.9 part, organo montmorillonite 2.7-3.4 part, zeolite powder 2.8-3.4 part, Sodium dodecylbenzene sulfonate 4.4-5.6 part, calcium sulfate 3.2-4.5 part, modifying titanium dioxide 9-10 part, phosphate toluene diphenyl ester 3-4 part, microcapsule red phosphorus 5-6 part, nano-aluminum hydroxide 14-15 part, melamine phosphate 12-13 part, manganous linoleate 0.9-1 part, sylvic acid aluminium 2.2-2.6 part, pigment 23-25 part, toughner 3.1-3.4 part, defoamer 2.5-2.7 part, advection agent 1.8-1.9 part, mould inhibitor 1.2-1.5 part.
4. the corrosion-resistant modifying titanium dioxide coating of high attachment according to any one of claim 1-3, it is characterized in that, the preparation method of modifying titanium dioxide comprises: added in dehydrated alcohol by nano titanium oxide and stir, then suction filtration obtains the first filter cake, the first filter cake is carried out vacuum-drying and obtains pretreated material A; Capryl(yl)chloride and saleratus are added in chloroform and stir, then continue to stir after adding pretreated material A, then suction filtration obtains the second filter cake, after being washed with water by the second filter cake, carries out vacuum-drying and obtains modifying titanium dioxide.
5. the corrosion-resistant modifying titanium dioxide coating of high attachment according to any one of claim 1-4, it is characterized in that, the preparation method of modifying titanium dioxide comprises: add in 10-13 part dehydrated alcohol by molfraction by 1.8-2.1 part nano titanium oxide, after stirring 1.6-1.9h with the stirring velocity of 840-870rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 69-72 DEG C; By weight 20-23 part capryl(yl)chloride and 25-28 part saleratus are added in chloroform and stir, 5.2-5.5h is stirred after adding 3-6 part pretreated material A again, stirring velocity is 1700-1850rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 61-64 DEG C.
6. the corrosion-resistant modifying titanium dioxide coating of high attachment according to any one of claim 1-5, it is characterized in that, the preparation method of modifying titanium dioxide comprises: add in 11-12 part dehydrated alcohol by molfraction by 1.9-2 part nano titanium oxide, after stirring 1.7-1.8h with the stirring velocity of 850-860rpm, suction filtration obtains the first filter cake, first filter cake is carried out vacuum-drying and obtains pretreated material A, vacuum drying temperature is 70-71 DEG C; By weight 21-22 part capryl(yl)chloride and 26-27 part saleratus are added in chloroform and stir, 5.3-5.4h is stirred after adding 4-5 part pretreated material A again, stirring velocity is 1750-1800rpm, then suction filtration obtains the second filter cake, after second filter cake is washed with water, carry out vacuum-drying and obtain modifying titanium dioxide, vacuum drying temperature is 62-63 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410681885.6A CN104449222A (en) | 2014-11-24 | 2014-11-24 | High-adhesion corrosion-resistant modified titanium dioxide paint |
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| CN201410681885.6A CN104449222A (en) | 2014-11-24 | 2014-11-24 | High-adhesion corrosion-resistant modified titanium dioxide paint |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304962A (en) * | 1999-12-08 | 2001-07-25 | 菊水化学工业株式会社 | Foaming type fireproof coating and steel product coated with said fireproof coating and forming method of foaming type fireproof coating layer |
| WO2006005716A2 (en) * | 2004-07-13 | 2006-01-19 | Huntsman Advanced Materials (Switzerland) Gmbh | Fire retardant composition |
| CN102153937A (en) * | 2011-05-13 | 2011-08-17 | 惠东美新塑木型材制品有限公司 | Surface fireproof coating of wood plastic composite material and preparation method of surface fireproof coating |
| CN102876088A (en) * | 2012-10-24 | 2013-01-16 | 杭州水处理技术研究开发中心有限公司 | Preparation method of novel organic acryl-chlorinated titanium dioxide nanoparticles |
-
2014
- 2014-11-24 CN CN201410681885.6A patent/CN104449222A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304962A (en) * | 1999-12-08 | 2001-07-25 | 菊水化学工业株式会社 | Foaming type fireproof coating and steel product coated with said fireproof coating and forming method of foaming type fireproof coating layer |
| WO2006005716A2 (en) * | 2004-07-13 | 2006-01-19 | Huntsman Advanced Materials (Switzerland) Gmbh | Fire retardant composition |
| CN102153937A (en) * | 2011-05-13 | 2011-08-17 | 惠东美新塑木型材制品有限公司 | Surface fireproof coating of wood plastic composite material and preparation method of surface fireproof coating |
| CN102876088A (en) * | 2012-10-24 | 2013-01-16 | 杭州水处理技术研究开发中心有限公司 | Preparation method of novel organic acryl-chlorinated titanium dioxide nanoparticles |
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Application publication date: 20150325 |