CN104449033A - Environment-friendly heat-resistant printing ink and preparation method thereof - Google Patents
Environment-friendly heat-resistant printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN104449033A CN104449033A CN201410558308.8A CN201410558308A CN104449033A CN 104449033 A CN104449033 A CN 104449033A CN 201410558308 A CN201410558308 A CN 201410558308A CN 104449033 A CN104449033 A CN 104449033A
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- environment
- friendly type
- ink
- fumed silica
- solvent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses environment-friendly heat-resistant printing ink and a preparation method thereof. The environment-friendly heat-resistant printing ink comprises the following components in parts by weight: 28-32 parts of methyl methacrylate, 24-26 parts of polyurethane, 14-16 parts of nano-fumed silica, 7-9 parts of a chelating agent, 4-6 parts of a slipping agent and 14-16 parts of a solvent. The environment-friendly heat-resistant printing ink disclosed by invention has the effects of resisting high temperature, protecting base layer printing ink, and preventing adhesion between printed materials and adhesion between coatings; the grade of the printed materials can be improved; and meanwhile, the environment-friendly heat-resistant printing ink has the characteristics of being non-toxic, safe, environment-friendly, sanitary and the like.
Description
Technical field
The present invention relates to a kind of environment-friendly type thermostable ink and preparation method thereof, belong to paint field.
Background technology
Environment-friendly type thermostable ink is methyl methacrylate; urethane; the material such as nano fumed silica and auxiliary agent forms; and there is the aqueous gluing body of certain degree of mobilization; through being uniformly mixed; printed matter heatproof can be made more than 180 DEG C after printing drying on the substrate, playing the effect of protection basic unit ink, anti, is a kind of novel functional printing environment-friendly material.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly type thermostable ink and preparation method thereof; The brush product of high temperature resistant ink of the present invention are used to have high temperature resistant; Protection basic unit ink, prevents between printed matter and is coated with the inter-adhesive effect of interlayer; There is the features such as nontoxic, safety, environmental protection, health simultaneously.
The present invention adopts following technical scheme:
Environment-friendly type thermostable ink, the weight part of its constitutive material is: methyl methacrylate 28-32, urethane 24-26, nano fumed silica 14-16, sequestrant 7-9, smooth agent 4-6 and solvent 14-16.
Environment-friendly type thermostable ink, the weight part of its constitutive material is: methyl methacrylate 30, urethane 25, nano fumed silica 15, sequestrant 8, smooth agent 5 and solvent 15.
Described solvent is ethanol or ethyl ester; Described sequestrant is one or more in polyacrylic acid, toxilic acid, amino trimethylammonium phosphonic acids, ethylene diamine tetra methylene phosphonic acid, Amino Trimethylene Phosphonic Acid; Described smooth agent is methyl-silicone oil, dimethyl silicone oil, polyacrylic acid ester cpds, modified polyacrylate, polydimethylsiloxane, the one of polysiloxane-polyether copolymer or mixture.
The preparation method of environment-friendly type thermostable ink, comprises the following steps:
(1) take each raw material by the weight part of constitutive material, first solvent is dropped into dispersion cylinder, start and stir, rotating speed 300 revs/min;
(2) methyl methacrylate and urethane are added in dispersion cylinder successively, stir 30 minutes;
(3) after step (2) is fully uniformly mixed, add nano fumed silica, after nano fumed silica is wetting, rotating speed is promoted to 1500 revs/min, stirs 50 minutes;
(4) add smooth agent more in step (3), stir and can obtain after 10 minutes;
(5) dispersing speed is adjusted to 100 revs/min, slowly adds sequestrant, stir 120 minutes.
Beneficial effect of the present invention:
The brush product of high temperature resistant ink of the present invention are used to have high temperature resistant; Protection basic unit ink, prevents between printed matter and is coated with the inter-adhesive effect of interlayer; There is the features such as nontoxic, safety, environmental protection, health simultaneously.
The technical problem that the present invention solves:
(1) when disperseing nano fumed silica, utilizing high-shear to make it get back to primary granule as far as possible, improving ink transparency.
(2) the strict sequestrant that controls adds dispersing speed, avoids high speed dispersion to destroy chelant stability.
(3) when controlling to disperse, ink temperature is not higher than 45 DEG C, prevents ink from producing crosslinking reaction.
Embodiment
Embodiment 1: environment-friendly type thermostable ink, the weight part (kg) of its constitutive material is: methyl methacrylate 30, urethane 25, nano fumed silica 15, sequestrant 8, smooth agent 5 and solvent 15.
Described solvent is ethanol or ethyl ester; Described sequestrant is one or more in polyacrylic acid, toxilic acid, amino trimethylammonium phosphonic acids, ethylene diamine tetra methylene phosphonic acid, Amino Trimethylene Phosphonic Acid; Described smooth agent is methyl-silicone oil, dimethyl silicone oil, polyacrylic acid ester cpds, modified polyacrylate, polydimethylsiloxane, the one of polysiloxane-polyether copolymer or mixture.
The preparation method of environment-friendly type thermostable ink, comprises the following steps:
(1) take each raw material by the weight part of constitutive material, first solvent is dropped into dispersion cylinder, start and stir, rotating speed 300 revs/min
(2) methyl methacrylate and urethane are added in dispersion cylinder successively, stir 30 minutes;
(3) after step (2) is fully uniformly mixed, add nano fumed silica, after nano fumed silica is wetting, rotating speed is promoted to 1500 revs/min, stirs 50 minutes;
(4) add smooth agent more in step (3), stir and can obtain after 10 minutes;
(5) dispersing speed is adjusted to 100 revs/min, slowly adds sequestrant, stir 120 minutes.
The performance data of environment-friendly type thermostable ink of the present invention:
Physical index:
Viscosity: 40 "; Scrape sample viscosity: 19 " (zhan2# cup inspection viscosity); Solid content: 50%.
Sanitary index:
Arsenic: 0.52ppm, lead: 0.35ppm, mercury: 0 ppm, chromium: 0.84ppm and nickel: 0.45ppm.
Claims (6)
1. an environment-friendly type thermostable ink, is characterized in that the weight part of its constitutive material is: methyl methacrylate 28-32, urethane 24-26, nano fumed silica 14-16, sequestrant 7-9, smooth agent 4-6 and solvent 14-16.
2. environment-friendly type thermostable ink according to claim 1, is characterized in that the weight part of its constitutive material is: methyl methacrylate 30, urethane 25, nano fumed silica 15, sequestrant 8, smooth agent 5 and solvent 15.
3. environment-friendly type thermostable ink according to claim 1, is characterized in that: described solvent is ethanol or ethyl ester.
4. a preparation method for environment-friendly type thermostable ink as claimed in claim 1, is characterized in that comprising the following steps:
(1) take each raw material by the weight part of constitutive material, first solvent is dropped into dispersion cylinder, start and stir, rotating speed 300 revs/min;
(2) methyl methacrylate and urethane are added in dispersion cylinder successively, stir 30 minutes;
(3) after step (2) is fully uniformly mixed, add nano fumed silica, after nano fumed silica is wetting, rotating speed is promoted to 1500 revs/min, stirs 50 minutes;
(4) add smooth agent more in step (3), stir and can obtain after 10 minutes;
(5) dispersing speed is adjusted to 100 revs/min, slowly adds sequestrant, stir 120 minutes.
5. environment-friendly type thermostable ink according to claim 1, is characterized in that: described sequestrant is one or more in polyacrylic acid, toxilic acid, amino trimethylammonium phosphonic acids, ethylene diamine tetra methylene phosphonic acid, Amino Trimethylene Phosphonic Acid.
6. environment-friendly type thermostable ink according to claim 1, is characterized in that: described smooth agent is methyl-silicone oil, dimethyl silicone oil, polyacrylic acid ester cpds, modified polyacrylate, polydimethylsiloxane, the one of polysiloxane-polyether copolymer or mixture.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410558308.8A CN104449033A (en) | 2014-10-21 | 2014-10-21 | Environment-friendly heat-resistant printing ink and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410558308.8A CN104449033A (en) | 2014-10-21 | 2014-10-21 | Environment-friendly heat-resistant printing ink and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN104449033A true CN104449033A (en) | 2015-03-25 |
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CN201410558308.8A Pending CN104449033A (en) | 2014-10-21 | 2014-10-21 | Environment-friendly heat-resistant printing ink and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107954592A (en) * | 2018-01-09 | 2018-04-24 | 江西联创电子有限公司 | A kind of processing method of 3D bend glasses |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2359556B (en) * | 1999-11-19 | 2003-08-20 | Sericol Ltd | An ink for decoration of substrates such as polycarbonate |
CN102079900A (en) * | 2010-12-13 | 2011-06-01 | 东莞市锐达涂料有限公司 | Polyetherdiol(PD) type alcohol soluble printing composite oil ink |
CN102746734A (en) * | 2012-07-02 | 2012-10-24 | 大连军乐印刷包装有限公司 | Printing ink-jet |
CN103992690A (en) * | 2014-04-24 | 2014-08-20 | 苏州中亚油墨有限公司 | Novel environmentally-friendly high-speed gravure printing compound ink |
-
2014
- 2014-10-21 CN CN201410558308.8A patent/CN104449033A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2359556B (en) * | 1999-11-19 | 2003-08-20 | Sericol Ltd | An ink for decoration of substrates such as polycarbonate |
CN102079900A (en) * | 2010-12-13 | 2011-06-01 | 东莞市锐达涂料有限公司 | Polyetherdiol(PD) type alcohol soluble printing composite oil ink |
CN102746734A (en) * | 2012-07-02 | 2012-10-24 | 大连军乐印刷包装有限公司 | Printing ink-jet |
CN103992690A (en) * | 2014-04-24 | 2014-08-20 | 苏州中亚油墨有限公司 | Novel environmentally-friendly high-speed gravure printing compound ink |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107954592A (en) * | 2018-01-09 | 2018-04-24 | 江西联创电子有限公司 | A kind of processing method of 3D bend glasses |
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RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150325 |