CN104446345B - The preparation method of kaolin whipping agent - Google Patents
The preparation method of kaolin whipping agent Download PDFInfo
- Publication number
- CN104446345B CN104446345B CN201410615773.0A CN201410615773A CN104446345B CN 104446345 B CN104446345 B CN 104446345B CN 201410615773 A CN201410615773 A CN 201410615773A CN 104446345 B CN104446345 B CN 104446345B
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- CN
- China
- Prior art keywords
- parts
- kaolin
- ore slurry
- whipping agent
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005995 Aluminium silicate Substances 0.000 title claims abstract description 49
- 235000012211 aluminium silicate Nutrition 0.000 title claims abstract description 49
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000002002 slurry Substances 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical class [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 5
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 5
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 235000010755 mineral Nutrition 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 4
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 abstract description 2
- 239000011268 mixed slurry Substances 0.000 abstract description 2
- 238000009413 insulation Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention discloses a kind of preparation method of kaolin whipping agent, belongs to whipping agent preparing technical field.The present invention is by being first adjusted to certain pH value by the mixed slurry of kaolin ore slurry and vat powder, kaolinic performance is effectively improved, and then to prepare burden according to certain formula and ratio and other stir, ball milling, thus obtain that there is multi-functional kaolin whipping agent.
Description
Technical field
The present invention relates to whipping agent preparing technical field, particularly relate to a kind of preparation method of kaolin whipping agent.
Background technology
Whipping agent is exactly the material making object material pore-forming, and it can be divided into chemical foaming agent and pneumatogen and tensio-active agent three major types.Chemical foaming agent is that those can discharge the gas such as carbonic acid gas and nitrogen after thermal degradation, and forms the compound of pore in polymkeric substance composition; Pneumatogen is exactly the change that foam pore is the physical aspect by a certain material, is namely formed by the dissolving of the expansion of pressurized gas, the volatilization of liquid or solid; Whipping agent all has higher surfactivity, effectively can reduce the surface tension of liquid, and surrounds air in the electric double layer arrangement of liquid film surface, forms bubble, then forms foam by single isolated bubbles.
Wherein, although whipping agent kind is many, Application comparison is wide, and its function is comparatively single, particularly kaolin whipping agent.
Summary of the invention
The invention provides a kind of preparation method of kaolin whipping agent, this preparation method can solve the problem of existing kaolin whipping agent function singleness.
In order to solve the problems of the technologies described above, the technical solution adopted in the present invention is:
It adopts following preparation process:
A. kaolin mineral aggregate is isolated clay, foreign material, then add 8 times of water and make slurry, obtain kaolin ore slurry;
B. kaolin ore slurry first slurry step A obtained and vat powder kaolin ore slurry in mass ratio: vat powder=1:0.002 mixes, and then adds conditioning agent, regulates its pH value to 6, obtains kaolin ore slurry fine fodder;
C. kaolin ore slurry fine fodder step B obtained washs, then spray-dried one-tenth microballoon;
D. by weight, the microballoon obtained by 40 parts ~ 45 parts step C, 5 parts ~ 6 parts activated attapulgites, 8 parts ~ 10 parts sodium bicarbonates, 1 part ~ 2 parts sodium polyacrylates, 0.5 part ~ 0.8 part ammonium polyphosphate, 1 part ~ 5 parts hydrogen peroxide, 0.01 part ~ 0.10 part polyether modified silicon oil and 20 parts ~ 30 parts water input in stirrers, stir, then through being milled to particle fineness≤0.05 millimeter.
In technique scheme, technical scheme is more specifically: described conditioning agent is the one in oxalic acid, phosphoric acid.
Owing to adopting technique scheme, the beneficial effect that the present invention obtains is:
The present invention is by being first adjusted to certain pH value by the mixed slurry of kaolin ore slurry and vat powder, kaolinic performance is effectively improved, and then to prepare burden according to certain formula and ratio and other stir, ball milling, thus obtain that there is multi-functional kaolin whipping agent.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, and protection scope of the present invention is not only confined to following examples.
Embodiment 1
The preparation method of this kaolin whipping agent is as follows:
A. kaolin mineral aggregate is isolated clay, foreign material, then add 8 times of water and make slurry, obtain kaolin ore slurry;
B. kaolin ore slurry first slurry step A obtained and vat powder kaolin ore slurry in mass ratio: vat powder=1:0.002 mixes, and then adds oxalic acid, regulates its pH value to 6, obtains kaolin ore slurry fine fodder;
C. kaolin ore slurry fine fodder step B obtained washs, then spray-dried one-tenth microballoon;
D. by weight, the microballoon obtained by 40 parts of step C, 6 parts of activated attapulgites, 10 parts of sodium bicarbonates, 1 part of sodium polyacrylate, 0.8 part of ammonium polyphosphate, 1 part of hydrogen peroxide, 0.10 part of polyether modified silicon oil and 20 parts of water input in stirrers, stir, then through being milled to particle fineness≤0.05 millimeter.
Compared with similar products, the kaolin whipping agent that the present embodiment obtains not only has the function of insulation, heat insulation, sound insulation, the function purified air in addition.
Embodiment 2
The preparation method of this kaolin whipping agent is as follows:
A. kaolin mineral aggregate is isolated clay, foreign material, then add 8 times of water and make slurry, obtain kaolin ore slurry;
B. kaolin ore slurry first slurry step A obtained and vat powder kaolin ore slurry in mass ratio: vat powder=1:0.002 mixes, and then adds phosphoric acid, regulates its pH value to 6, obtains kaolin ore slurry fine fodder;
C. kaolin ore slurry fine fodder step B obtained washs, then spray-dried one-tenth microballoon;
D. by weight, the microballoon obtained by 45 parts of step C, 5 parts of activated attapulgites, 8 parts of sodium bicarbonates, 2 parts of sodium polyacrylates, 0.5 part of ammonium polyphosphate, 5 parts of hydrogen peroxide, 0.01 part of polyether modified silicon oil and 30 parts of water input in stirrers, stir, then through being milled to particle fineness≤0.05 millimeter.
Compared with similar products, the kaolin whipping agent that the present embodiment obtains not only has the function of insulation, heat insulation, sound insulation, the function purified air in addition.
Embodiment 3
The preparation method of this kaolin whipping agent is as follows:
A. kaolin mineral aggregate is isolated clay, foreign material, then add 8 times of water and make slurry, obtain kaolin ore slurry;
B. kaolin ore slurry first slurry step A obtained and vat powder kaolin ore slurry in mass ratio: vat powder=1:0.002 mixes, and then adds oxalic acid, regulates its pH value to 6, obtains kaolin ore slurry fine fodder;
C. kaolin ore slurry fine fodder step B obtained washs, then spray-dried one-tenth microballoon;
D. by weight, the microballoon obtained by 42 parts of step C, 5 parts of activated attapulgites, 9 parts of sodium bicarbonates, 1.5 parts of sodium polyacrylates, 0.7 part of ammonium polyphosphate, 3 parts of hydrogen peroxide, 0.05 part of polyether modified silicon oil and 25 parts of water input in stirrers, stir, then through being milled to particle fineness≤0.05 millimeter.
Compared with similar products, the kaolin whipping agent that the present embodiment obtains not only has the function of insulation, heat insulation, sound insulation, the function purified air in addition.
Claims (2)
1. a preparation method for kaolin whipping agent, is characterized in that comprising the following steps:
A. kaolin mineral aggregate is isolated clay, foreign material, then add 8 times of water and make slurry, obtain kaolin ore slurry;
B. kaolin ore slurry step A obtained and vat powder kaolin ore slurry in mass ratio: vat powder=1:0.002 mixes, and then adds conditioning agent, regulates its pH value to 6, obtains kaolin ore slurry fine fodder;
C. kaolin ore slurry fine fodder step B obtained washs, then spray-dried one-tenth microballoon;
D. by weight, the microballoon obtained by 40 parts ~ 45 parts step C, 5 parts ~ 6 parts activated attapulgites, 8 parts ~ 10 parts sodium bicarbonates, 1 part ~ 2 parts sodium polyacrylates, 0.5 part ~ 0.8 part ammonium polyphosphate, 1 part ~ 5 parts hydrogen peroxide, 0.01 part ~ 0.10 part polyether modified silicon oil and 20 parts ~ 30 parts water input in stirrers, stir, then through being milled to particle fineness≤0.05 millimeter.
2. the preparation method of kaolin whipping agent according to claim 1, is characterized in that:
Described conditioning agent is the one in oxalic acid, phosphoric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410615773.0A CN104446345B (en) | 2014-11-05 | 2014-11-05 | The preparation method of kaolin whipping agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410615773.0A CN104446345B (en) | 2014-11-05 | 2014-11-05 | The preparation method of kaolin whipping agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104446345A CN104446345A (en) | 2015-03-25 |
| CN104446345B true CN104446345B (en) | 2016-03-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410615773.0A Expired - Fee Related CN104446345B (en) | 2014-11-05 | 2014-11-05 | The preparation method of kaolin whipping agent |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3060339B1 (en) | 2016-12-20 | 2020-01-17 | L'oreal | HAIR LIGHTENING COMPOSITION COMPRISING HYDROGEN PEROXIDE, PEROXYGEN SALT, CARBONATE, AND AT LEAST ONE POLYPHOSPHORUS DERIVATIVE |
| CN107629700A (en) * | 2017-10-30 | 2018-01-26 | 惠州市华昱美实业有限公司 | A kind of degradable formula coating and its preparation technology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117003A (en) * | 2007-08-24 | 2008-02-06 | 中国地质大学（武汉） | Production technology of paper coating kaoline |
| CN102976348A (en) * | 2012-12-17 | 2013-03-20 | 茂名市茂群高岭土有限公司 | Preparation method of kaolin having high colloid index |
| CN103265200A (en) * | 2013-05-27 | 2013-08-28 | 许盛英 | Kaolin flame-retardant foaming agent |
-
2014
- 2014-11-05 CN CN201410615773.0A patent/CN104446345B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117003A (en) * | 2007-08-24 | 2008-02-06 | 中国地质大学（武汉） | Production technology of paper coating kaoline |
| CN102976348A (en) * | 2012-12-17 | 2013-03-20 | 茂名市茂群高岭土有限公司 | Preparation method of kaolin having high colloid index |
| CN103265200A (en) * | 2013-05-27 | 2013-08-28 | 许盛英 | Kaolin flame-retardant foaming agent |
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| Publication number | Publication date |
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| CN104446345A (en) | 2015-03-25 |
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Address after: 547000 the Guangxi Zhuang Autonomous Region Hechi District of Jinchengjiang City Jinfu Road No. 16 Patentee after: Wu Junrong Address before: 545005 the Guangxi Zhuang Autonomous Region Liuzhou Liunan District City Station Road No. 94 District 18 Building 2 unit 401 Patentee before: Wu Junrong |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160330 |
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| CF01 | Termination of patent right due to non-payment of annual fee |