CN104445344B - A kind of synthetic method of nano yttrium oxide powder - Google Patents
A kind of synthetic method of nano yttrium oxide powder Download PDFInfo
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- CN104445344B CN104445344B CN201410760030.2A CN201410760030A CN104445344B CN 104445344 B CN104445344 B CN 104445344B CN 201410760030 A CN201410760030 A CN 201410760030A CN 104445344 B CN104445344 B CN 104445344B
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- oxide powder
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- yttrium oxide
- nano yttrium
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Crystallography & Structural Chemistry (AREA)
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- General Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The present invention discloses the synthetic method of a kind of nano yttrium oxide powder, comprises the steps: that (1) first adds erythrol in acetic acid yttrium solution；(2) adding sodium hydroxide solution again in the solution of step (1), regulation pH value of solution, to 11 13, then reacts 20 30 hours at 170 200 DEG C；(3) step (2) reacting liquid filtering, filtering residue is scrubbed, dry, obtain nano yttrium oxide powder after calcining.Compared with the conventional method, the nano yttrium oxide powder using the inventive method gained is homogeneous spherical of pattern, and size tunable system is at 40 50nm.
Description
Technical field
The present invention relates to the synthetic method of a kind of nano yttrium oxide powder.
Background technology
Yittrium oxide (Y2O3) it is a kind of important rare earth compound, there is thermostability, corrosion resistance, high-k and a series of excellent optical property of uniqueness, be widely used in the fields such as advanced ceramic, photoelectric device, catalyst.
In recent years, preparation to nano yttrium oxide powder both at home and abroad expands and studies widely, and main preparation methods includes sol-gel process, vapour deposition process, microemulsion method and hydro-thermal method, and hydro-thermal method has the advantage that technique is simple, equipment cost is low, but the powder body generated easily is reunited, separate difficulty.
Summary of the invention
The technical problem to be solved in the present invention is to overcome existing defect, it is provided that the synthetic method of a kind of nano yttrium oxide powder.
In order to solve above-mentioned technical problem, the invention provides following technical scheme:
The synthetic method of a kind of nano yttrium oxide powder, comprises the steps:
(1) in acetic acid yttrium solution, erythrol is first added；
(2) adding sodium hydroxide solution again in the solution of step (1), regulation pH value of solution, to 11-13, then reacts 20-30 hour at 170-200 DEG C；
(3) reacting liquid filtering of step (2), filtering residue is scrubbed, dry, obtain nano yttrium oxide powder after calcining.
Further, the consumption of erythrol is the 1-5% of acetic acid yttrium quality.
Acetic acid yttrium solution concentration is preferably 0.05-0.5mol/L.
Detailed description of the invention
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is merely to illustrate and explains the present invention, is not intended to limit the present invention.
Embodiment
1
The synthetic method of a kind of nano yttrium oxide powder, comprises the steps:
(1) first adding erythrol in the acetic acid yttrium solution that solution is 0.2mol/L, erythrol is pressed 1% addition of acetic acid yttrium quality, is stirred；
(2) adding saturated sodium hydroxide solution again in the solution of step (1), regulation pH value of solution, to 11, then reacts 24 hours at 180 DEG C；
(3), after reaction, reacting liquid filtering, filtering residue washes with water 6 times, is vacuum dried 4 hours, then calcines 1 hour at 600 DEG C, obtains nano yttrium oxide powder.
Embodiment
2
The synthetic method of a kind of nano yttrium oxide powder, comprises the steps:
(1) first adding erythrol in the acetic acid yttrium solution that solution is 0.1mol/L, erythrol is pressed 5% addition of acetic acid yttrium quality, is stirred；
(2) adding saturated sodium hydroxide solution again in the solution of step (1), regulation pH value of solution, to 13, then reacts 24 hours at 200 DEG C；
(3), after reaction, reacting liquid filtering, filtering residue washes with water 6 times, is vacuum dried 4 hours, then calcines 1 hour at 600 DEG C, obtains nano yttrium oxide powder.
Embodiment
3
The synthetic method of a kind of nano yttrium oxide powder, comprises the steps:
(1) first adding erythrol in the acetic acid yttrium solution that solution is 0.05mol/L, erythrol is pressed 2% addition of acetic acid yttrium quality, is stirred；
(2) adding saturated sodium hydroxide solution again in the solution of step (1), regulation pH value of solution, to 12, then reacts 24 hours at 180 DEG C；
(3), after reaction, reacting liquid filtering, filtering residue washes with water 6 times, is vacuum dried 4 hours, then calcines 1 hour at 620 DEG C, obtains nano yttrium oxide powder.
The inventive method is easily isolated, and the nano yttrium oxide powder of gained is homogeneous spherical of pattern, and size tunable system is at 40-50nm.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention, although the present invention being described in detail with reference to previous embodiment, for a person skilled in the art, technical scheme described in foregoing embodiments still can be modified by it, or wherein portion of techniques feature is carried out equivalent.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (1)
1. a synthetic method for ball shaped nano yttrium oxide powder, comprises the steps:
(1) first adding erythrol in acetic acid yttrium solution, the consumption of described erythrol is the 1-5% of acetic acid yttrium quality；
(2) adding sodium hydroxide solution again in the solution of step (1), regulation pH value of solution, to 11-13, then reacts 20-30 hour at 170-200 DEG C；
(3) reacting liquid filtering of step (2), filtering residue is scrubbed, dry, obtain ball shaped nano yttrium oxide powder after calcining.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410760030.2A CN104445344B (en) | 2014-12-13 | 2014-12-13 | A kind of synthetic method of nano yttrium oxide powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410760030.2A CN104445344B (en) | 2014-12-13 | 2014-12-13 | A kind of synthetic method of nano yttrium oxide powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104445344A CN104445344A (en) | 2015-03-25 |
| CN104445344B true CN104445344B (en) | 2016-09-28 |
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| CN201410760030.2A Expired - Fee Related CN104445344B (en) | 2014-12-13 | 2014-12-13 | A kind of synthetic method of nano yttrium oxide powder |
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| CN113772712A (en) * | 2020-07-29 | 2021-12-10 | 英迪那米(徐州)半导体科技有限公司 | Synthesis method of nano yttrium oxide powder |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1400168A (en) * | 2002-08-15 | 2003-03-05 | 山东大学 | Preparation method of barium titanate powder body |
| CN102531023A (en) * | 2010-12-16 | 2012-07-04 | 中国科学院福建物质结构研究所 | Method for preparing nanometer flaky yttrium oxide powder |
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- 2014-12-13 CN CN201410760030.2A patent/CN104445344B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1400168A (en) * | 2002-08-15 | 2003-03-05 | 山东大学 | Preparation method of barium titanate powder body |
| CN102531023A (en) * | 2010-12-16 | 2012-07-04 | 中国科学院福建物质结构研究所 | Method for preparing nanometer flaky yttrium oxide powder |
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| CN104445344A (en) | 2015-03-25 |
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