CN104441880A - Blue-ray preventing and antistatic protecting film - Google Patents
Blue-ray preventing and antistatic protecting film Download PDFInfo
- Publication number
- CN104441880A CN104441880A CN201410681543.4A CN201410681543A CN104441880A CN 104441880 A CN104441880 A CN 104441880A CN 201410681543 A CN201410681543 A CN 201410681543A CN 104441880 A CN104441880 A CN 104441880A
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- China
- Prior art keywords
- blue light
- membrane layer
- antistatic
- blue
- separation membrane
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- 241001025261 Neoraja caerulea Species 0.000 title abstract 12
- 239000003292 glue Substances 0.000 claims abstract description 44
- 239000000853 adhesive Substances 0.000 claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 claims abstract description 22
- 210000002469 basement membrane Anatomy 0.000 claims description 58
- 210000004379 membrane Anatomy 0.000 claims description 54
- 239000012528 membrane Substances 0.000 claims description 54
- 238000000926 separation method Methods 0.000 claims description 54
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 36
- 230000001681 protective effect Effects 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 25
- 239000012752 auxiliary agent Substances 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- -1 Ethoxylated alkyl acid amide Chemical class 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 14
- 239000004642 Polyimide Substances 0.000 claims description 10
- 229920001721 polyimide Polymers 0.000 claims description 10
- 150000004032 porphyrins Chemical class 0.000 claims description 10
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 claims description 9
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 9
- 238000007046 ethoxylation reaction Methods 0.000 claims description 9
- 150000004767 nitrides Chemical class 0.000 claims description 9
- 229920001197 polyacetylene Polymers 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000741 silica gel Substances 0.000 claims description 7
- 229910002027 silica gel Inorganic materials 0.000 claims description 7
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 6
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 6
- 229920002799 BoPET Polymers 0.000 claims description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Chemical class 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002318 adhesion promoter Substances 0.000 claims description 6
- 239000001913 cellulose Chemical class 0.000 claims description 6
- 229920002678 cellulose Chemical class 0.000 claims description 6
- 239000006184 cosolvent Substances 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 229920001223 polyethylene glycol Chemical class 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- CSUFEOXMCRPQBB-UHFFFAOYSA-N 1,1,2,2-tetrafluoropropan-1-ol Chemical compound CC(F)(F)C(O)(F)F CSUFEOXMCRPQBB-UHFFFAOYSA-N 0.000 claims description 5
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cis-cyclohexene Natural products C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical class CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229960004050 aminobenzoic acid Drugs 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 229940090181 propyl acetate Drugs 0.000 claims description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 claims description 2
- 230000006378 damage Effects 0.000 abstract description 8
- 229910052754 neon Inorganic materials 0.000 abstract description 5
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000428 dust Substances 0.000 abstract description 3
- 230000005611 electricity Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 230000003068 static effect Effects 0.000 abstract 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 6
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- 210000001525 retina Anatomy 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 210000000695 crystalline len Anatomy 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 210000003583 retinal pigment epithelium Anatomy 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a blue-ray preventing and antistatic protecting film. The protecting film comprises a first separating film layer, a first blue-ray preventing film layer, a first basilar film layer, an antistatic film layer, a second basilar film layer, a second blue-ray preventing film layer and a second separating film layer in sequence from top to bottom, wherein the first separating film layer and the upper surface of the first blue-ray preventing film layer are connected through an adhesive; the second blue-ray preventing film layer and the second separating film layer are connected through the adhesive; the first blue-ray preventing film layer and the second blue-ray preventing film layer are both made of blue-ray preventing glue; the antistatic film layer is made of antistatic glue liquid. Obstruction of blue-ray is realized by absorbing and converting the blue-ray emitted by luminescent sources of a panel display device, an LED neon light, a fluorescent lamp, and the like; damage of the blue-ray to eyes is relieved greatly; human eyes are protected; meanwhile, the protecting film effectively prevents static electricity, and avoids influence and damage, such as dust adsorption, breakdown of coating, and electric shock of human body, caused by discharge of static electricity to production.
Description
Technical field
The present invention relates to a kind of diaphragm, particularly a kind of blue light that prevents for display screens such as mobile phone screen, digital camera, computer monitors injures anti-blue light film of eyes and preparation method thereof.
Background technology
Blue light is different from ultraviolet, and it does not exist only in sunshine, is also present in a large number in computer monitor (no matter LED or CCFL), digital electronic goods display screen, mobile phone, TV, even automobile lamp, neon light.Shortwave blue light has very high energies, can penetrate crystalline lens and to go directly retina.Blue light illumination retina can produce free radical, and these free radicals can cause retinal pigment epithelium to become feeble and die, and epithelial decline can cause photaesthesia cell lack nutrient thus cause vision impairment, and these damages are irreversible.
Correlative study shows, the blue light of different wave length is different for the occurrence situation of human eye, and the occurrence situation of blue light to eyes between 435 nanometer to 440 nanometers is maximum, this effect along with wavelength increase or successively decrease and reduce gradually.Although in LED light source, the peak value of spectral energy seems and is in blue wave band, in fact endangers maximum 435nm wave band lower than traditional C CFL display, so the blue light harm of LED is less than traditional C CFL display.In life, the light source that can send blue light has a lot, except super bath, the light sources of all having powerful connections such as flat-panel monitor, LED neon light, fluorescent lamp, cathode tube backlit display, iPad, large-screen mobile phone, containing abnormal high energy shortwave blue light in the light source excited by powerful electron stream, capital affects the retina of child, should avoid long-term direct-view.In addition, conventional diaphragm does not all possess anti-static function, easily absorbs dust, or be difficult to accurately locate on mobile phone screen because producing Electrostatic Absorption in attaching use procedure, affects the electronic product using function after pad pasting and reduces.
Therefore the invention provides a kind of anti-blue light Antistatic protective film, it mainly by being converted into the visible ray of its all band to the absorption of blue light, realizing the obstruct to blue light, greatly alleviating the injury of blue light to eyes, protection human eye.
Summary of the invention
The present invention is directed to present situation; provide a kind of anti-blue light Antistatic protective film, it mainly by absorbing and the blue light that comes out of the illuminating source such as transformation plate display, LED neon light, fluorescent lamp, realizes the obstruct to blue light; greatly alleviate the injury of blue light to eyes, protection human eye.A kind of anti-blue light Antistatic protective film that this case provides also has an object to be exactly antistatic, maintains good light transmittance simultaneously.
For achieving the above object, the present invention is achieved through the following technical solutions:
A kind of anti-blue light Antistatic protective film, comprises from top to bottom successively:
First separation membrane layer, the first anti-blue light rete, the first basement membrane layer, antistatic layer, the second basement membrane layer, the second anti-blue light rete and the second separation membrane layer, wherein,
Described first separation membrane layer is connected by adhesive with the upper surface of described first anti-blue light rete;
Described first anti-blue light rete, it is arranged between described first separation membrane layer and described first basement membrane layer, is made up of anti-blue light glue;
Described antistatic layer, it is arranged between described first basement membrane layer and the second basement membrane layer, is made up of antistatic glue;
Described second anti-blue light rete, it is arranged between described second basement membrane layer and the second separation membrane layer, is made up of same anti-blue light glue;
Described second anti-blue light rete is connected by adhesive with described second separation membrane layer;
The composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 15%-21%
O-phenylenediamine: 5%-12%
Azo metal dye: 30%-40%
Acetylacetone,2,4-pentanedione: 13%-28%
Porphyrins: 13%-25%
Acrylate: 10%-20%
Auxiliary agent: 0.3%-0.6%;
The composition of raw materials of described antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 12%-20%;
Ethoxylation oleyl amine: 23%-26%;
Ethoxylated alkyl acid amide: 15%-24%;
Polyimides: 18.5%-26%;
Monostearin: 10%-16%;
Polyacetylene: 13%-18%;
Auxiliary agent: 0.3%-0.6%.
Preferably, described anti-blue light Antistatic protective film, the composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 16%
O-phenylenediamine: 8%
Azo metal dye: 32%
Acetylacetone,2,4-pentanedione: 18%
Porphyrins: 12%
Acrylate: 11%
Auxiliary agent: 0.5%.
Preferably, described anti-blue light Antistatic protective film, described azo metal dye, its structure is (A-N=N-B)
2m, wherein A is phenyl ring, and B is cyclohexene, and M is metal.
Preferably, described anti-blue light Antistatic protective film, the composition of raw materials of described antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 15%;
Ethoxylation oleyl amine: 23%;
Ethoxylated alkyl acid amide: 16%;
Polyimides: 19.6%;
Monostearin: 11%;
Polyacetylene: 14%;
Auxiliary agent: 0.5%.
Preferably, described anti-blue light Antistatic protective film, described auxiliary agent comprises:
Cosolvent: select one or more mixtures in toluene, p-aminobenzoic acid, cyclohexane, acetamide, propyl acetate;
Dispersant: select one or more mixtures in vinyl bis-stearamides, methyl anyl alcohol, polyethylene glycol, cellulose derivative;
Adhesion promoter: glycerin ether oxygen propyl trimethoxy silicane.
Preferably, described anti-blue light Antistatic protective film, described first separation membrane layer and described second separation membrane layer all select polypropylene material.
Preferably; described anti-blue light Antistatic protective film; the thickness of described first basement membrane layer is 30-36um; the thickness of described second basement membrane layer is 26-30um; the thickness of described antistatic layer is 15-22um; the thickness of described first anti-blue light rete is 8-15um, and the thickness of described second anti-blue light rete is 15-23um, and the thickness of described first separation membrane layer and described second separation membrane layer is 13-20um.
Preferably, described anti-blue light Antistatic protective film, described first basement membrane layer and described second basement membrane layer all select PET film.
Preferably, described anti-blue light Antistatic protective film, described adhesive adopts organic silica gel.
A kind of anti-blue light Antistatic protective film provided by the invention, its beneficial effect comprises: 1) anti-blue light: by absorbing and the blue light that comes out of the illuminating source such as transformation plate display, LED neon light, fluorescent lamp, realize the obstruct to blue light, greatly alleviate the injury of blue light to eyes, protection human eye; 2) antistatic: the generation effectively preventing electrostatic, avoiding the electric discharge of electrostatic on producing the impact and destruction that cause, such as adsorbing dust, coating punctures, human body is shocked by electricity.
Accompanying drawing explanation
Fig. 1 is a kind of anti-blue light Antistatic protective film schematic diagram described in one embodiment of the invention.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, can implement according to this with reference to description word to make those skilled in the art.
A kind of anti-blue light Antistatic protective film, as shown in Figure 1, comprises from top to bottom successively:
First separation membrane layer 1, first anti-blue light rete 3, first basement membrane layer 4, antistatic layer 5, second basement membrane layer 6, second anti-blue light rete 7 and the second separation membrane layer 9, wherein, the first separation membrane layer 1 is connected by adhesive 2 with the upper surface of the first anti-blue light rete 3; First anti-blue light rete 3, it is arranged between the first separation membrane layer 1 and the first basement membrane layer 4, is made up of anti-blue light glue; Antistatic layer 5, it is arranged between the first basement membrane layer 4 and the second basement membrane layer 6, is made up of antistatic glue; Second anti-blue light rete 7, it is arranged between the second basement membrane layer 6 and the second separation membrane layer 9, is made up of same anti-blue light glue; Second anti-blue light rete 7 is connected by adhesive 8 with the second separation membrane layer 9;
The composition of raw materials of described anti-blue light glue is made up of the material of following mass percent: styrene: 15%-21%; O-phenylenediamine: 5%-12%; Azo metal dye: 30%-40%; Acetylacetone,2,4-pentanedione: 13%-28%; Porphyrins: 13%-25%; Acrylate: 10%-20%; Auxiliary agent: 0.3%-0.6%.
Wherein, why anti-blue light rete plays the effect of anti-blue light, is that its structure is (A-N=N-B) because wherein azo metal dye
2m, wherein, nitrogen nitrogen double bond be phenyl ring, while be cyclohexene, research finds, such azo dyes can absorbing wavelength at the blue light of 380-450nm.Porphyrins has larger conjugated system and abundant pi-electron due to it, and electron donation is stronger, has stronger absorbability in blue region, and has good heat endurance.When they and other inhale blue light material be dissolved in together with time, inhale blue light capacity multiplication, Absorbable rod blue wavelength range is 378-472nm.When each material in filling a prescription is within the scope of above-mentioned mass percent, all there is the anti-blue light effect of different-effect.And when the composition of raw materials of described anti-blue light rete is made up of the material of following mass percent: styrene: 16%; O-phenylenediamine: 8%; Azo metal dye: 32%; Acetylacetone,2,4-pentanedione: 18%; Porphyrins: 12%; Acrylate: 11%; Auxiliary agent: when 0.5%, best results, reaches 99% to the obstruct of blue light.
Further, the composition of raw materials of antistatic glue is made up of the material of following mass percent: polysulfur nitride class: 12%-20%; Ethoxylation oleyl amine: 23%-26%; Ethoxylated alkyl acid amide: 15%-24%; Polyimides: 18.5%-26%; Monostearin: 10%-16%; Polyacetylene: 13%-18%; Auxiliary agent: 0.3%-0.6%.
Wherein, and the antistatic effect of antistatic layer 5 is determined by the proportioning of each component in the composition of raw materials of antistatic glue, in the formula of antistatic glue, the mass fraction of polyimides lower than 18.5% time, antistatic effect is very faint, and higher than 26% time, be difficult to has dissolved, and antistatic effect decline.Therefore proportioning must be carried out in strict accordance with this formula.Through repeatedly comparing, when the proportioning of antistatic glue is: polysulfur nitride class: 15%, ethoxylation oleyl amine: 23%, ethoxylated alkyl acid amide: 16%, polyimides: 19.6%, monostearin: 11%, polyacetylene: 14%, auxiliary agent: when 0.5%, antistatic effect reaches optimum state.
Wherein, cosolvent: select one or more mixtures in tetrafluoropropanol, toluene, p-aminobenzoic acid, cyclohexane, acetamide, propyl acetate; Dispersant: select one or more mixtures in vinyl bis-stearamides, methyl anyl alcohol, polyethylene glycol, cellulose derivative; Adhesion promoter: glycerin ether oxygen propyl trimethoxy silicane.
Further, a kind of anti-blue light Antistatic protective film, the first basement membrane layer 4 and the second basement membrane layer 6 all select PET film.
Further, a kind of anti-blue light Antistatic protective film, the first separation membrane layer 1 and the second separation membrane layer 9 all select polypropylene material.
Further, a kind of anti-blue light Antistatic protective film, adhesive 2 and 8 adopts organic silica gel.The organic silica gel adopted, has low adhesion, fast, high temperature resistant, the easy shearing stamp of high adsorption, Automatic-exhausting pickle and tear off and do not stay the characteristics such as cull.
Further, a kind of preparation method of anti-blue light Antistatic protective film:
Step 1, the composition of raw materials of antistatic glue is placed in super mixer mixing 10 to 20 minutes, rotating speed is 150-4500 rev/min, obtains antistatic glue;
Step 2, sided corona treatment is carried out to the first basement membrane layer 4 and the second basement membrane layer 6 after, antistatic layer 5 is coated between the first basement membrane layer 4 and the second basement membrane layer 6, and with UV light source thermalization 30s, makes antistatic layer 5;
Step 3, the composition of raw materials of anti-blue light glue is placed in super mixer mixing 3 to 10 minutes, rotating speed is 150-4500 rev/min, obtains anti-blue light glue;
Step 4, anti-blue light glue is coated in the another side of the first basement membrane layer 4 and the second basement membrane layer 6, and with UV light source thermalization 20s, makes the first anti-blue light rete 3 and the second anti-blue light rete 7;
Step 5, all apply the adhesive 8 of 3-6um at the another side of the first anti-blue light rete 3 and the second anti-blue light rete 7, adhesive fits with the first separation membrane layer 1 and the second separation membrane layer 9 respectively, makes anti-blue light Antistatic protective film.
Detailed description of the invention 1:
A kind of anti-blue light Antistatic protective film, comprises from top to bottom successively:
First separation membrane layer 1, first anti-blue light rete 3, first basement membrane layer 4, antistatic layer 5, second basement membrane layer 6, second anti-blue light rete 7 and the second separation membrane layer 9, wherein, the first separation membrane layer 1 is connected by adhesive 2 with the upper surface of the first anti-blue light rete 3; First anti-blue light rete 3, it is arranged between the first separation membrane layer 1 and the first basement membrane layer 4, is made up of anti-blue light glue; Antistatic layer 5, it is arranged between the first basement membrane layer 4 and the second basement membrane layer 6, is made up of antistatic glue; Second anti-blue light rete 7, it is arranged between the second basement membrane layer 6 and the second separation membrane layer 9, is made up of same anti-blue light glue; Second anti-blue light rete 7 is connected by adhesive 8 with the second separation membrane layer 9;
The composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 15%
O-phenylenediamine: 5%
Azo metal dye: 30%
Acetylacetone,2,4-pentanedione: 13%
Porphyrins: 13%
Acrylate: 10%
Auxiliary agent: 0.3%.
The composition of raw materials of antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 12%;
Ethoxylation oleyl amine: 23%;
Ethoxylated alkyl acid amide: 15%;
Polyimides: 18.5%;
Monostearin: 10%;
Polyacetylene: 13%;
Auxiliary agent: 0.3%.
Wherein, cosolvent: the mixture selecting tetrafluoropropanol, toluene and cyclohexane; Dispersant: the mixture selecting polyethylene glycol and cellulose derivative; Adhesion promoter: glycerin ether oxygen propyl trimethoxy silicane.
First basement membrane layer 4 and the second basement membrane layer 6 all preferably use PET film, and the first separation membrane layer 1 and the second separation membrane layer 9 all preferably use polypropylene material, and adhesive 2 and 8 adopts organic silica gel.
Detailed description of the invention 2:
A kind of anti-blue light Antistatic protective film, comprises from top to bottom successively:
First separation membrane layer 1, first anti-blue light rete 3, first basement membrane layer 4, antistatic layer 5, second basement membrane layer 6, second anti-blue light rete 7 and the second separation membrane layer 9, wherein, the first separation membrane layer 1 is connected by adhesive 2 with the upper surface of the first anti-blue light rete 3; First anti-blue light rete 3, it is arranged between the first separation membrane layer 1 and the first basement membrane layer 4, is made up of anti-blue light glue; Antistatic layer 5, it is arranged between the first basement membrane layer 4 and the second basement membrane layer 6, is made up of antistatic glue; Second anti-blue light rete 7, it is arranged between the second basement membrane layer 6 and the second separation membrane layer 9, is made up of same anti-blue light glue; Second anti-blue light rete 7 is connected by adhesive 8 with the second separation membrane layer 9;
The composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 21%
O-phenylenediamine: 12%
Azo metal dye: 40%
Acetylacetone,2,4-pentanedione: 28%
Porphyrins: 25%
Acrylate: 20%
Auxiliary agent: 0.6%.
The composition of raw materials of antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 20%;
Ethoxylation oleyl amine: 26%;
Ethoxylated alkyl acid amide: 24%;
Polyimides: 26%;
Monostearin: 16%;
Polyacetylene: 18%;
Auxiliary agent: 0.6%.
Wherein, cosolvent: the mixture selecting tetrafluoropropanol, toluene and cyclohexane; Dispersant: the mixture selecting polyethylene glycol and cellulose derivative; Adhesion promoter: glycerin ether oxygen propyl trimethoxy silicane.
First basement membrane layer 4 and the second basement membrane layer 6 all preferably use PET film, and the first separation membrane layer 1 and the second separation membrane layer 9 all preferably use polypropylene material, and adhesive 2 and 8 adopts organic silica gel.
Detailed description of the invention 3:
A kind of anti-blue light Antistatic protective film, comprises from top to bottom successively:
First separation membrane layer 1, first anti-blue light rete 3, first basement membrane layer 4, antistatic layer 5, second basement membrane layer 6, second anti-blue light rete 7 and the second separation membrane layer 9, wherein, the first separation membrane layer 1 is connected by adhesive 2 with the upper surface of the first anti-blue light rete 3; First anti-blue light rete 3, it is arranged between the first separation membrane layer 1 and the first basement membrane layer 4, is made up of anti-blue light glue; Antistatic layer 5, it is arranged between the first basement membrane layer 4 and the second basement membrane layer 6, is made up of antistatic glue; Second anti-blue light rete 7, it is arranged between the second basement membrane layer 6 and the second separation membrane layer 9, is made up of same anti-blue light glue; Second anti-blue light rete 7 is connected by adhesive 8 with the second separation membrane layer 9;
The composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 16%; O-phenylenediamine: 8%; Azo metal dye: 32%; Acetylacetone,2,4-pentanedione: 18%; Porphyrins: 12%; Acrylate: 11%; Auxiliary agent: 0.5%
The composition of raw materials of antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 15%, ethoxylation oleyl amine: 23%, ethoxylated alkyl acid amide: 16%, polyimides: 19.6%, monostearin: 11%, polyacetylene: 14%, auxiliary agent: 0.5%.
Wherein, cosolvent: the mixture selecting tetrafluoropropanol, toluene and cyclohexane; Dispersant: the mixture selecting polyethylene glycol and cellulose derivative; Adhesion promoter: glycerin ether oxygen propyl trimethoxy silicane.
First basement membrane layer 4 and the second basement membrane layer 6 all preferably use PET film, and the first separation membrane layer 1 and the second separation membrane layer 9 all preferably use polypropylene material, and adhesive 2 and 8 adopts organic silica gel.
Although embodiment of the present invention are open as above, but it is not restricted to listed in description and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the legend described.
Claims (9)
1. an anti-blue light Antistatic protective film, is characterized in that, comprises successively from top to bottom:
First separation membrane layer, the first anti-blue light rete, the first basement membrane layer, antistatic layer, the second basement membrane layer, the second anti-blue light rete and the second separation membrane layer, wherein,
Described first separation membrane layer is connected by adhesive with the upper surface of described first anti-blue light rete;
Described first anti-blue light rete, it is arranged between described first separation membrane layer and described first basement membrane layer, is made up of anti-blue light glue;
Described antistatic layer, it is arranged between described first basement membrane layer and the second basement membrane layer, is made up of antistatic glue;
Described second anti-blue light rete, it is arranged between described second basement membrane layer and the second separation membrane layer, is made up of same anti-blue light glue;
Described second anti-blue light rete is connected by adhesive with described second separation membrane layer;
The composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 15%-21%
O-phenylenediamine: 5%-12%
Azo metal dye: 30%-40%
Acetylacetone,2,4-pentanedione: 13%-28%
Porphyrins: 13%-25%
Acrylate: 10%-20%
Auxiliary agent: 0.3%-0.6%;
The composition of raw materials of described antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 12%-20%;
Ethoxylation oleyl amine: 23%-26%;
Ethoxylated alkyl acid amide: 15%-24%;
Polyimides: 18.5%-26%;
Monostearin: 10%-16%;
Polyacetylene: 13%-18%;
Auxiliary agent: 0.3%-0.6%.
2. anti-blue light Antistatic protective film according to claim 1, is characterized in that, the composition of raw materials of described anti-blue light glue is made up of the material of following mass percent:
Styrene: 16%
O-phenylenediamine: 8%
Azo metal dye: 32%
Acetylacetone,2,4-pentanedione: 18%
Porphyrins: 12%
Acrylate: 11%
Auxiliary agent: 0.5%.
3. anti-blue light Antistatic protective film according to claim 1, is characterized in that, described azo metal dye, and its structure is (A-N=N-B)
2m, wherein A is phenyl ring, and B is cyclohexene, and M is metal.
4. anti-blue light Antistatic protective film according to claim 1, is characterized in that, the composition of raw materials of described antistatic glue is made up of the material of following mass percent:
Polysulfur nitride class: 15%;
Ethoxylation oleyl amine: 23%;
Ethoxylated alkyl acid amide: 16%;
Polyimides: 19.6%;
Monostearin: 11%;
Polyacetylene: 14%;
Auxiliary agent: 0.5%.
5. anti-blue light Antistatic protective film according to claim 1, is characterized in that, described auxiliary agent comprises:
Cosolvent: select one or more mixtures in tetrafluoropropanol, toluene, p-aminobenzoic acid, cyclohexane, acetamide, propyl acetate;
Dispersant: select one or more mixtures in vinyl bis-stearamides, methyl anyl alcohol, polyethylene glycol, cellulose derivative;
Adhesion promoter: glycerin ether oxygen propyl trimethoxy silicane.
6. anti-blue light Antistatic protective film according to claim 1, is characterized in that, described first separation membrane layer and described second separation membrane layer all select polypropylene material.
7. anti-blue light Antistatic protective film according to claim 1; it is characterized in that; the thickness of described first basement membrane layer is 30-36um; the thickness of described second basement membrane layer is 26-30um; the thickness of described antistatic layer is 15-22um; the thickness of described first anti-blue light rete is 8-15um, and the thickness of described second anti-blue light rete is 15-23um, and the thickness of described first separation membrane layer and described second separation membrane layer is 13-20um.
8. anti-blue light Antistatic protective film according to claim 1, is characterized in that, described first basement membrane layer and described second basement membrane layer all select PET film.
9. anti-blue light Antistatic protective film according to claim 1, is characterized in that, described adhesive adopts organic silica gel.
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| CN201410681543.4A CN104441880B (en) | 2014-11-24 | 2014-11-24 | A kind of anti-blue light Antistatic protective film |
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| CN201410681543.4A CN104441880B (en) | 2014-11-24 | 2014-11-24 | A kind of anti-blue light Antistatic protective film |
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| CN109553792A (en) * | 2017-09-25 | 2019-04-02 | 安徽屹珹新材料科技有限公司 | A kind of anti-blue light film of double optics coating and preparation method thereof |
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Address after: 223900 Sihong Province Economic Development Zone, West Ocean Road, No. 6, No. Patentee after: JIANGSU SIDIKE NEW MATERIALS SIENCE & TECHNOLOGY Co.,Ltd. Address before: 215400 Taicang Economic Development Zone, Jiangsu, Qingdao West Road, No. 11, No. Patentee before: SUZHOU SIDIKE NEW MATERIALS SIENCE & TECHNOLOGY Co.,Ltd. |
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