CN104441852B - Layered wear-erosion resistant rubber lining plate and preparation method thereof - Google Patents

Layered wear-erosion resistant rubber lining plate and preparation method thereof Download PDF

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Publication number
CN104441852B
CN104441852B CN201410749567.9A CN201410749567A CN104441852B CN 104441852 B CN104441852 B CN 104441852B CN 201410749567 A CN201410749567 A CN 201410749567A CN 104441852 B CN104441852 B CN 104441852B
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rubber
abrasion resistance
surface abrasion
content
micropowder
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CN104441852A (en
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乔金昌
白国钦
李军鸿
文献才
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PINGDINGSHAN HUARUI JINXIANG WEAR-RESISTANT MATERIALS Co Ltd
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PINGDINGSHAN HUARUI JINXIANG WEAR-RESISTANT MATERIALS Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/02Layered products comprising a layer of natural or synthetic rubber with fibres or particles being present as additives in the layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/34Silicon-containing compounds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
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    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/10Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance

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  • Chemical & Material Sciences (AREA)
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  • Polymers & Plastics (AREA)
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Abstract

The invention relate to a layered wear-erosion resistant rubber lining plate and a preparation method thereof, belonging to rubber materials in the field of polymer materials. The rubber lining plate is formed by splicing a rubber substrate with a surface wear resistant rubber through heat curing. The rubber lining plate is prepared from a surface wear resistant rubber, a special anticorrosion rubber and additives, wherein the surface wear resistant rubber serves as a framework and comprises aramid glass fiber and polyamide fiber, the special anticorrosion rubber servers as a substrate, and the additives comprise silicon carbide micropowder or zirconium carbide micropowder, aluminium oxide micropowder, silicon oxide micropowder and elemental silicon micropowder. The rubber lining plate can be used as a lining material, has a certain strength, abrasion resistance, erosion resistance and puncture resistance and also has a certain resilience and flexibility. Compared with the conventional metal linings or inorganic nonmetallic material poured linings, the rubber lining plate provided by the invention has the characteristics of light weight and easiness for installation and replacement.

Description

Wear-resisting resistance to erosion rubber lining of a kind of Rotating fields and preparation method thereof
Technical field
The present invention relates to the elastomeric material in polymeric material field, the wear-resisting resistance to erosion of specifically a kind of Rotating fields Rubber lining and preparation method thereof.
Background technology
Rubber is a kind of resilient polymer, (natural rubber) can be obtained from the myron of some plants it is also possible to It is artificial (synthetic rubber), because elastomeric species is a lot, different types of rubber possesses different performances, such as Butadiene rubber has especially excellent tolerance to cold, wearability, elasticity and ageing-resistant performance, but tear resistance is poor, anti-slippery Performance is bad;Isoprene rubber, as natural rubber, has good elasticity and wearability, excellent thermostability and preferableization Learn stability;EP rubbers chemical stability is good, and wearability, elasticity, oil resistivity and butadiene-styrene rubber are close.
But the so-called wearability of rubber is well mainly only applied to the wearability during industrial products such as tire, but works as rubber When glue is applied to other field, its wearability will far be not by far up to the mark, such as by rubber applications in inner lining material to hold By certain when washing away with tear resistance, its wearability is just far not by far up to the mark.
Content of the invention
For solving existing elastomeric material wearability and penetration-resistant when as the inner lining material needing to bear scouring force The problem of needs can not be met, the invention provides a kind of Rotating fields wear-resisting resistance to erosion rubber lining and preparation method thereof, sacrifice Fall the partial elastic of elastomeric material to improve its wear-resisting, resistance to erosion and puncture-resistant performance so that it can be widely used in The liner of the pipelines such as some conveying powder body, corrosive liquids, industrial mortars, or the inner lining material of wear-resisting classifying cyclone.
The present invention by solving the technical scheme that adopted of above-mentioned technical problem is: a kind of wear-resisting resistance to erosion rubber lining of Rotating fields Plate, this rubber lining is formed by bonding hot vulcanization by rubber substrate and surface abrasion resistance rubber, and described rubber substrate and surface are resistance to Rubber milling is made by aramid fiber glass and nylon fibre composition skeleton, using extraordinary anti-corrosive rubber as base material, and surface abrasion resistance Being added with the silicon carbide micro-powder that particle diameter is 150 mesh or zirconium carbide micropowder, particle diameter in rubber is the alumina powder of 150 mesh, particle diameter The additive that ultrafine silica powder for 200 mesh and the simple substance silicon powder that particle diameter is 300 mesh mix, wherein, in rubber substrate, The content of aramid fiber glass is 8-9%, and the content of nylon fibre is 6-7%, and remaining is extraordinary anti-corrosive rubber;Surface abrasion resistance rubber In, the content of aramid fiber glass is 4-5%, and the content of nylon fibre is 6-7%, and the content of silicon carbide micro-powder or zirconium carbide micropowder is 0.3-0.5%, the content of alumina powder is 0.2-0.3%, the content of ultrafine silica powder is 0.1-0.2%, the containing of simple substance silicon powder Measure as 0.1-0.2%, remaining is extraordinary anti-corrosive rubber, and extraordinary anti-corrosive rubber is commercially available fluorubber, FFKM or 4 third Fluorubber.
In described rubber substrate and surface abrasion resistance rubber, also fill up in the skeleton being constituted with aramid fiber glass and nylon fibre There is carbon fiber, the content of carbon fiber is 0.05-0.1%.
Also containing the calcined kaolin micropowder below particle diameter 300 mesh, the content of calcined kaolin micropowder in described additive For 0.1-0.2%.
In described rubber substrate and surface abrasion resistance rubber, also fill up in the skeleton being constituted with aramid fiber glass and nylon fibre There is glass fibre, the content of glass fibre is 0.05-0.1%.
The preparation method of the wear-resisting resistance to erosion rubber lining of above-mentioned Rotating fields, comprises the following steps:
1) pull into diameter after aramid fiber glass and nylon fibre being melted respectively and be less than 0.1mm filament, then according to above-mentioned Ratio weigh composition rubber substrate and each component of surface abrasion resistance rubber, then rubber substrate and surface abrasion resistance rubber bone will be constituted The component of frame mixes into material a and material b respectively in different proportions, to be respectively used to prepare rubber substrate and surface abrasion resistance rubber The skeleton of glue;
2) will be used in step 1) preparing the material a and material b feeding of rubber substrate and surface abrasion resistance rubber skeleton respectively Once kneaded in two banburies, melting temperature be 150-170 degree Celsius, pressure be 25-30mpa, rotor speed is 60rpm, kneads 30s-60s, and before mixing, first adds additional in the material b for preparing surface abrasion resistance rubber skeleton Silicon carbide micro-powder in agent or zirconium carbide micropowder and alumina powder, are re-fed into mixing in banbury after stirring;
3) material a is added thereto to extraordinary anti-corrosive rubber after once kneading, and is kneaded again, melting temperature is 150-170 degree Celsius, pressure be 40-42mpa, rotor speed is 60rpm, kneads 30s-60s, natural cooling obtains rubber-based Bottom, standby;
4) will be used for preparing remaining additive of surface abrasion resistance rubber and extraordinary anti-corrosive rubber mixing, melting temperature is 160-170 degree Celsius, pressure be 35-45mpa, rotor speed be 90rpm, knead 30-60s, standby;
5) by extraordinary anti-corrosive rubber and step 2 after kneading in step 4)) middle knead after material b mix after mix again Refining, melting temperature is 165-170 degree Celsius, pressure is 40-42mpa, and rotor speed is 90rpm, kneads 2-3min, and mixing terminates Natural cooling obtains surface abrasion resistance rubber afterwards;
6) rubber substrate being obtained in step 3) is passed through hot vulcanization process with prepared surface abrasion resistance rubber in step 5) Glue and form and obtain product.
Beneficial effect: the present invention passes through by rubber liner with two kinds of different rubber adhesions together, and top layer employing Special abrasive rubber, this abrasive rubber is constituted skeleton with aramid fiber glass and nylon fibre, is then made with extraordinary anti-corrosive rubber Kneaded with it for base material, mixing process is aided with silicon carbide micro-powder or zirconium carbide micropowder, alumina powder, silicon oxide again Micropowder and simple substance silicon powder uniform wearability strong material filling, thus high degree improve final production product intensity, Wearability, abrasion resistance and paracentesis resistance so as to when application is for inner lining material, not only have certain intensity, wearability, resistance to concurrently Erosion and paracentesis resistance, and had certain resilience and pliability concurrently, with conventional metal inner lining or inorganic non-gold The liner that genus material pours is compared, and has the characteristics that lightweight and is easily installed, changes.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated, the corrosion-resistant rubber of special type used in each embodiment Glue is commercially available fluorubber, FFKM or 4 third fluorubber.
Embodiment 1
A kind of wear-resisting resistance to erosion rubber lining of Rotating fields, this rubber lining passes through heat by rubber substrate and surface abrasion resistance rubber Bonding by Vulcanization forms, and described rubber substrate and surface abrasion resistance rubber constitute skeleton by aramid fiber glass and nylon fibre, with special type Anti-corrosive rubber is made as base material, and be added with surface abrasion resistance rubber particle diameter be the silicon carbide micro-powder of 150 mesh, particle diameter be The alumina powder of 150 mesh, particle diameter are the ultrafine silica powder of 200 mesh and simple substance silicon powder that particle diameter is 300 mesh mixes Additive, wherein, in rubber substrate, the content of aramid fiber glass is 8%, and the content of nylon fibre is 6%, and remaining is extraordinary corrosion-resistant Rubber;In surface abrasion resistance rubber, the content of aramid fiber glass is 4%, and the content of nylon fibre is 6%, and the content of silicon carbide micro-powder is 0.3%, the content of alumina powder is 0.2%, the content of ultrafine silica powder is 0.1%, and the content of simple substance silicon powder is 0.1%, its Remaining for extraordinary anti-corrosive rubber.
The preparation method of this Rotating fields wear-resisting resistance to erosion rubber lining, comprises the following steps:
1) pull into diameter after aramid fiber glass and nylon fibre being melted respectively and be less than 0.1mm filament, then according to above-mentioned Ratio weigh composition rubber substrate and each component of surface abrasion resistance rubber, then rubber substrate and surface abrasion resistance rubber bone will be constituted The component of frame mixes into material a and material b respectively in different proportions, to be respectively used to prepare rubber substrate and surface abrasion resistance rubber The skeleton of glue;
2) will be used in step 1) preparing the material a and material b feeding of rubber substrate and surface abrasion resistance rubber skeleton respectively Once kneaded in two banburies, melting temperature be 150 degrees Celsius, pressure be 25mpa, rotor speed be 60rpm, mix Refining 60s, and before mixing, in the material b for preparing surface abrasion resistance rubber skeleton, first add the carborundum in additive Micropowder and alumina powder, are re-fed into mixing in banbury after stirring;
3) material a is added thereto to extraordinary anti-corrosive rubber after once kneading, and is kneaded again, melting temperature is 150 degrees Celsius, pressure be 40mpa, rotor speed be 60rpm, knead 60s, natural cooling obtains rubber substrate, standby;
4) will be used for preparing remaining additive of surface abrasion resistance rubber and extraordinary anti-corrosive rubber mixing, melting temperature is 160 degrees Celsius, pressure be 35mpa, rotor speed be 90rpm, knead 60s, standby;
5) by extraordinary anti-corrosive rubber and step 2 after kneading in step 4)) middle knead after material b mix after mix again Refining, melting temperature is 165 degrees Celsius, pressure is 40mpa, and rotor speed is 90rpm, kneads 3min, and mixing is naturally cold after terminating But obtain surface abrasion resistance rubber;
6) rubber substrate being obtained in step 3) is passed through hot vulcanization process with prepared surface abrasion resistance rubber in step 5) Glue and form and obtain product.
It is the basic embodiment of the present embodiment above, can be further optimized on the basis of above or improve:
As in described rubber substrate and surface abrasion resistance rubber, in the skeleton being constituted with aramid fiber glass and nylon fibre also It is filled with carbon fiber, the content of carbon fiber is 0.05%;
And for example, also contain calcined kaolin micropowder in described additive, the content of calcined kaolin micropowder is 0.1%;
For another example, in described rubber substrate and surface abrasion resistance rubber, in the skeleton being constituted with aramid fiber glass and nylon fibre It is also filled with glass fibre, the content of glass fibre is 0.05%.
Embodiment 2
A kind of wear-resisting resistance to erosion rubber lining of Rotating fields, this rubber lining passes through heat by rubber substrate and surface abrasion resistance rubber Bonding by Vulcanization forms, and described rubber substrate and surface abrasion resistance rubber constitute skeleton by aramid fiber glass and nylon fibre, with special type Anti-corrosive rubber is made as base material, and be added with surface abrasion resistance rubber particle diameter be the zirconium carbide micropowder of 150 mesh, particle diameter be The alumina powder of 150 mesh, particle diameter are the ultrafine silica powder of 200 mesh and simple substance silicon powder that particle diameter is 300 mesh mixes Additive, wherein, in rubber substrate, the content of aramid fiber glass is 9%, and the content of nylon fibre is 7%, and remaining is extraordinary corrosion-resistant Rubber;In surface abrasion resistance rubber, the content of aramid fiber glass is 5%, and the content of nylon fibre is 7%, and the content of zirconium carbide micropowder is 0.5%, the content of alumina powder is 0.3%, the content of ultrafine silica powder is 0.2%, and the content of simple substance silicon powder is 0.2%, its Remaining for extraordinary anti-corrosive rubber.
The preparation method of this Rotating fields wear-resisting resistance to erosion rubber lining, comprises the following steps:
1) pull into diameter after aramid fiber glass and nylon fibre being melted respectively and be less than 0.1mm filament, then according to above-mentioned Ratio weigh composition rubber substrate and each component of surface abrasion resistance rubber, then rubber substrate and surface abrasion resistance rubber bone will be constituted The component of frame mixes into material a and material b respectively in different proportions, to be respectively used to prepare rubber substrate and surface abrasion resistance rubber The skeleton of glue;
2) will be used in step 1) preparing the material a and material b feeding of rubber substrate and surface abrasion resistance rubber skeleton respectively Once kneaded in two banburies, melting temperature be 170 degrees Celsius, pressure be 30mpa, rotor speed be 60rpm, mix Refining 30s, and before mixing, in the material b for preparing surface abrasion resistance rubber skeleton, first add the zirconium carbide in additive Micropowder and alumina powder, are re-fed into mixing in banbury after stirring;
3) material a is added thereto to extraordinary anti-corrosive rubber after once kneading, and is kneaded again, melting temperature is 170 degrees Celsius, pressure be 42mpa, rotor speed be 60rpm, knead 30s, natural cooling obtains rubber substrate, standby;
4) will be used for preparing remaining additive of surface abrasion resistance rubber and extraordinary anti-corrosive rubber mixing, melting temperature is 170 degrees Celsius, pressure be 45mpa, rotor speed be 90rpm, knead 30s, standby;
5) by extraordinary anti-corrosive rubber and step 2 after kneading in step 4)) middle knead after material b mix after mix again Refining, melting temperature is 170 degrees Celsius, pressure is 42mpa, and rotor speed is 90rpm, kneads 2min, and mixing is naturally cold after terminating But obtain surface abrasion resistance rubber;
6) rubber substrate being obtained in step 3) is passed through hot vulcanization process with prepared surface abrasion resistance rubber in step 5) Glue and form and obtain product.
It is the basic embodiment of the present embodiment above, can be further optimized on the basis of above or improve:
As in described rubber substrate and surface abrasion resistance rubber, in the skeleton being constituted with aramid fiber glass and nylon fibre also It is filled with carbon fiber, the content of carbon fiber is 0.1%;
And for example, also contain calcined kaolin micropowder in described additive, the content of calcined kaolin micropowder is 0.2%;
For another example, in described rubber substrate and surface abrasion resistance rubber, in the skeleton being constituted with aramid fiber glass and nylon fibre It is also filled with glass fibre, the content of glass fibre is 0.1%.
Embodiment 3
A kind of wear-resisting resistance to erosion rubber lining of Rotating fields, this rubber lining passes through heat by rubber substrate and surface abrasion resistance rubber Bonding by Vulcanization forms, and described rubber substrate and surface abrasion resistance rubber constitute skeleton by aramid fiber glass and nylon fibre, with special type Anti-corrosive rubber is made as base material, and be added with surface abrasion resistance rubber particle diameter be the silicon carbide micro-powder of 150 mesh, particle diameter be The alumina powder of 150 mesh, particle diameter are the ultrafine silica powder of 200 mesh and simple substance silicon powder that particle diameter is 300 mesh mixes Additive, wherein, in rubber substrate, the content of aramid fiber glass is 8.5%, and the content of nylon fibre is 6.5%, and remaining is extraordinary resistance to Corrosion rubber;In surface abrasion resistance rubber, the content of aramid fiber glass is 4.5%, and the content of nylon fibre is 6.5%, silicon carbide micro-powder Content be 0.4%, the content of alumina powder is 0.25%, the content of ultrafine silica powder be 0.15%, the content of simple substance silicon powder For 0.15%, remaining is extraordinary anti-corrosive rubber.
The preparation method of this Rotating fields wear-resisting resistance to erosion rubber lining, comprises the following steps:
1) pull into diameter after aramid fiber glass and nylon fibre being melted respectively and be less than 0.1mm filament, then according to above-mentioned Ratio weigh composition rubber substrate and each component of surface abrasion resistance rubber, then rubber substrate and surface abrasion resistance rubber bone will be constituted The component of frame mixes into material a and material b respectively in different proportions, to be respectively used to prepare rubber substrate and surface abrasion resistance rubber The skeleton of glue;
2) will be used in step 1) preparing the material a and material b feeding of rubber substrate and surface abrasion resistance rubber skeleton respectively Once kneaded in two banburies, melting temperature be 160 degrees Celsius, pressure be 28mpa, rotor speed be 60rpm, mix Refining 45s, and before mixing, in the material b for preparing surface abrasion resistance rubber skeleton, first add the carborundum in additive Micropowder and alumina powder, are re-fed into mixing in banbury after stirring;
3) material a is added thereto to extraordinary anti-corrosive rubber after once kneading, and is kneaded again, melting temperature is 160 degrees Celsius, pressure be 41mpa, rotor speed be 60rpm, knead 45s, natural cooling obtains rubber substrate, standby;
4) will be used for preparing remaining additive of surface abrasion resistance rubber and extraordinary anti-corrosive rubber mixing, melting temperature is 165 degrees Celsius, pressure be 40mpa, rotor speed be 90rpm, knead 45s, standby;
5) by extraordinary anti-corrosive rubber and step 2 after kneading in step 4)) middle knead after material b mix after mix again Refining, melting temperature is 1680 degrees Celsius, pressure is 41mpa, and rotor speed is 90rpm, kneads 2.5min, and mixing is natural after terminating Cooling obtains surface abrasion resistance rubber;
6) rubber substrate being obtained in step 3) is passed through hot vulcanization process with prepared surface abrasion resistance rubber in step 5) Glue and form and obtain product.
It is the basic embodiment of the present embodiment above, can be further optimized on the basis of above or improve:
As in described rubber substrate and surface abrasion resistance rubber, in the skeleton being constituted with aramid fiber glass and nylon fibre also It is filled with carbon fiber, the content of carbon fiber is 0.075%;
And for example, also contain calcined kaolin micropowder in described additive, the content of calcined kaolin micropowder is 0.15%;
For another example, in described rubber substrate and surface abrasion resistance rubber, in the skeleton being constituted with aramid fiber glass and nylon fibre It is also filled with glass fibre, the content of glass fibre is 0.075%.
Performance comparison is tested
The final products taking various embodiments of the present invention are compiled respectively and are made 1,2, No. 3 samples, choose the commercially available corrosion-resistant rubber of special type Glue (FFKM) is No. 4 samples, respectively 1 to No. 4 sample is made liner and is applied in mining hydrocyclone, in identical Its service life is measured, experimental result is under current and water quality situation:
1st, 2, No. 3 liner that sample is made its surfaces after using 67 days start appearance by the defect of current scour;
The liner that No. 4 samples are made its surface after using 43 days starts to occur by the defect of current scour;
It follows that for the wear-resisting resistance to erosion rubber of the present invention is compared to existing wear resistant corrosion resistant rubber, possessing more Good wear-resisting, resistant to corrosion, resistance to erosion and puncture resistance.

Claims (4)

1. the wear-resisting resistance to erosion rubber lining of a kind of Rotating fields, this rubber lining passes through hot sulfur by rubber substrate and surface abrasion resistance rubber Change bonding form it is characterised in that: described rubber substrate and surface abrasion resistance rubber constitute bone by aramid fiber glass and nylon fibre Frame, made as base material using extraordinary anti-corrosive rubber, and in surface abrasion resistance rubber, be added with the silicon carbide micro-powder that particle diameter is 150 mesh Or zirconium carbide micropowder, particle diameter be the alumina powder of 150 mesh, particle diameter be the ultrafine silica powder of 200 mesh and list that particle diameter is 300 mesh The additive that matter silicon powder mixes, wherein, in rubber substrate, the content of aramid fiber glass is 8-9%, the content of nylon fibre For 6-7%, remaining is extraordinary anti-corrosive rubber;In surface abrasion resistance rubber, the content of aramid fiber glass is 4-5%, the containing of nylon fibre Measure as 6-7%, the content of silicon carbide micro-powder or zirconium carbide micropowder is 0.3-0.5%, the content of alumina powder is 0.2-0.3%, oxygen The content of SiClx micropowder is 0.1-0.2%, and the content of simple substance silicon powder is 0.1-0.2%, and remaining is extraordinary anti-corrosive rubber, extraordinary Anti-corrosive rubber is commercially available fluorubber.
2. a kind of wear-resisting resistance to erosion rubber lining of Rotating fields according to claim 1 it is characterised in that: described rubber substrate In surface abrasion resistance rubber, the skeleton being constituted with aramid fiber glass and nylon fibre is also filled with carbon fiber, the containing of carbon fiber Measure as 0.05-0.1%.
3. a kind of wear-resisting resistance to erosion rubber lining of Rotating fields according to claim 1 it is characterised in that: in described additive Also contain calcined kaolin micropowder, the content of calcined kaolin micropowder is 0.1-0.2%.
4. the wear-resisting resistance to erosion rubber lining of Rotating fields according to claim 1 preparation method it is characterised in that include with Lower step:
1) pull into diameter after aramid fiber glass and nylon fibre being melted respectively and be less than 0.1mm filament, then according to claim 1 Described ratio weighs composition rubber substrate and each component of surface abrasion resistance rubber, then will constitute rubber substrate and surface abrasion resistance rubber The component of glue skeleton mixes into material a and material b respectively in different proportions, resistance to be respectively used to preparation rubber substrate and surface The skeleton of rubber milling;
2) will be used in step 1) preparing the material a and material b feeding two of rubber substrate and surface abrasion resistance rubber skeleton respectively Once kneaded in banbury, melting temperature be 150-170 degree Celsius, pressure be 25-30mpa, rotor speed is 60rpm, kneads 30s-60s, and before mixing, first adds additional in the material b for preparing surface abrasion resistance rubber skeleton Silicon carbide micro-powder in agent or zirconium carbide micropowder and alumina powder, are re-fed into mixing in banbury after stirring;
3) material a is added thereto to extraordinary anti-corrosive rubber after once kneading, and is kneaded again, melting temperature is 150- 170 degrees Celsius, pressure be 40-42mpa, rotor speed be 60rpm, knead 30s-60s, natural cooling obtains rubber substrate, standby With;
4) will be used for preparing remaining additive of surface abrasion resistance rubber and extraordinary anti-corrosive rubber mixing, melting temperature is 160- 170 degrees Celsius, pressure be 35-45mpa, rotor speed be 90rpm, knead 30-60s, standby;
5) by extraordinary anti-corrosive rubber and step 2 after kneading in step 4)) middle knead after material b mix after knead again, Melting temperature is 165-170 degree Celsius, pressure is 40-42mpa, and rotor speed is 90rpm, kneads 2-3min, after mixing terminates Natural cooling obtains surface abrasion resistance rubber;
6) by the surface abrasion resistance rubber being obtained in the rubber substrate being obtained in step 3) and step 5) pass through hot vulcanization process glue and Form and obtain product.
CN201410749567.9A 2014-12-10 2014-12-10 Layered wear-erosion resistant rubber lining plate and preparation method thereof Expired - Fee Related CN104441852B (en)

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