CN104433023A - Novel manufacture technology of jewelry and creative coating jewelry - Google Patents
Novel manufacture technology of jewelry and creative coating jewelry Download PDFInfo
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- CN104433023A CN104433023A CN201410824965.2A CN201410824965A CN104433023A CN 104433023 A CN104433023 A CN 104433023A CN 201410824965 A CN201410824965 A CN 201410824965A CN 104433023 A CN104433023 A CN 104433023A
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- Prior art keywords
- jewelry
- metal
- idiosome
- polishing
- film
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- 238000000576 coating method Methods 0.000 title claims abstract description 27
- 239000011248 coating agent Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 238000005516 engineering process Methods 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 142
- 239000002184 metal Substances 0.000 claims abstract description 142
- 239000010977 jade Substances 0.000 claims abstract description 62
- 238000001771 vacuum deposition Methods 0.000 claims abstract description 31
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052737 gold Inorganic materials 0.000 claims abstract description 18
- 239000010931 gold Substances 0.000 claims abstract description 18
- 238000013461 design Methods 0.000 claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000007747 plating Methods 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 238000005498 polishing Methods 0.000 claims description 42
- 239000012530 fluid Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 12
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- 229920003023 plastic Polymers 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 230000008719 thickening Effects 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- -1 Polytetrafluoroethylene Polymers 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 6
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 6
- 238000007517 polishing process Methods 0.000 claims description 6
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- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
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- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- 150000003568 thioethers Chemical class 0.000 claims description 4
- 235000003392 Curcuma domestica Nutrition 0.000 claims description 3
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- 238000010521 absorption reaction Methods 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
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- 239000010408 film Substances 0.000 description 96
- 239000010437 gem Substances 0.000 description 18
- 229910001751 gemstone Inorganic materials 0.000 description 16
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- 241000579895 Chlorostilbon Species 0.000 description 2
- 244000163122 Curcuma domestica Species 0.000 description 2
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- 229910003460 diamond Inorganic materials 0.000 description 2
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- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 244000132059 Carica parviflora Species 0.000 description 1
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
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- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 1
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- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
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- Adornments (AREA)
Abstract
The invention provides a novel manufacture technology of jewelry and a creative coating jewelry; the creative coating jewelry comprises a jade main body, a plurality of metal regions are formed on the jade main body, each metal region is provided with a layer of metal film by vacuum coating mode. The novel manufacture technology of jewelry comprises the following steps: step 1, design the jewelry blank; step 2, adopting the gold immersing technology and nickel plating technology for the convex function regions in the jewelry blank and guaranteeing the reliability for the convex function regions; step 3, printing patch, bonding and fixing the printing patch at the position appointed by the printing character corresponding to the design position; and etc., according to the technical scheme, a plurality of metal regions are formed on the jewelry, each metal region is provided with a layer of metal film and the novel jewelry structure is offered; the manufacture technology is applied to manufacture the jewelry having the metal film, the volume production is realized for forming the industrialization products, and higher market application value can be achieved.
Description
Technical field
The present invention relates to jewelry and preparation method thereof, in particular, a kind of Novel jewellery manufacture craft and a kind of intention plated film jewelry.
Background technology
Natural material (mineral, rock, biology etc.) outside the metals such as gold and silver is made by general custom, there is the jewellery of certain values, handicraft or other collections and be referred to as jewelry, therefore having the saying of " gold, silver and jewelry ", the jewelry managing these article is capable to be also referred to as " jewelry is capable ".Scientifically say, " jewelry " is identical with the concept of " jewel " of broad sense.The jewel of broad sense is made a general reference those and is suitablely carried out pondering or Carving Machining is the raw material of jewellery or handicraft.
Jewelry roughly comprises natural jewels and jade and artificial gem, substantially jade can be referred to as, wherein, natural jewels and jade comprises natural gemstone, natural jade, natural organic gemstone etc., and artificial gem comprises synthetic cut stone, reproduces jewel, split jewel, synthetic gem etc.Such as, natural gemstone comprises diamond, ruby, sapphire, golden green opal, beryl, emerald, tourmaline, opal, ice color calcedony, the jade of the He family etc.; Natural jade comprises Huanglong's jade, agate, jasper, Lingbi jade, Khotan jade, Xiuyan Jade, Nanyang jade, the color calcedony of ice, emerald, Lantian jade, malachite, turquoise, Dongling jade, white marble, Zhunger Basin is beautiful, noctilucence is beautiful, chrysocolla, green lardite, lapis lazuli, golden yellow jade, ice flower jade, diamond stone etc.Natural color stone comprises agalmatolite, orpiment, stone from Qingtian county in Zhejiang Province, used to make seals, bloodstoen, five flower stone, changbaiite, end stone, wash one's face stone, preserved egg stone, Yuhuatai colorful pebble, Balin Stone, Helan jade, chrysanthemum stone, purple marble, huge solid rock, swallow stones, inhales stone, red silk stone, rocks, prosperous fossil, serpentine, upper water stone, talcum, granite, marble etc.Natural organic gemstone comprises amber, pearl, coral, ivory, jet etc.
Jewelry processing mainly comprises following several.
Cutting: mainly according to the difference of jade (or being called jewel) and form, massive material is divided into specific size and dimension, may blanking machine be used;
Pre-shape: woollen finishing is called preliminary moulding, may finishing machine be used;
Grinding: mainly in order to grinding goes out the moulding of jewel.Different with grinding tool according to grinding method, equipment for grinding can be divided into Wheel grinder, disc mill, band grinding machine, tumbling mill etc.;
Polishing: for by jewel polishing.Polishing can be carried out in some cases by the grinding tool of replacing equipment for grinding, abrasive material, but, also there is special polishing machine;
Boring: some jewellery, as suspension member, pearl etc. need punching, this just needs to use puncher.
Certainly, according to circumstances different, the processing process of jewel also has cleaning, bonding even other processing procedures, only in this way, finally could create exquisite jewelry and come.
But, jewelry overlay film is then studied seldom.
Chinese patent 201280013894.7 discloses the formation method of noble metal diaphragm and noble metal diaphragm; it forms a kind of diaphragm; and the excellent adhesion between noble metal matrix; the process had in daily life need not pay special attention to the durability that just can be worn on continually with it; firmly and fine and close; further, can by this excellent corrosion resistance and the diaphragm that above-mentioned effect can continue for a long time be conveniently formed on the surface of noble metal matrix.Noble metal diaphragm involved by this invention is the quartz glass film as following manner is formed; namely; the surface of noble metal matrix applies the glass film formation composition using polysilazane as main component; in the atmosphere that there is steam; the noble metal matrix being coated with described glass film formation composition is placed at lower than the temperature of fusing point, forms the quartz glass film that thickness is 0.2 μm ~ 1.0 μm thus.
But this invention does not relate to jewelry overlay film.
Chinese patent 200810065146.9 discloses jewellery surface protective film and preparation method thereof, jewellery surface protective film wherein, is made up of the raw material of following parts by weight: aminopropyl triethoxysilane 0.5 ~ 3, Al
2o
31 ~ 5, SiO
215 ~ 25, isopropyl alcohol 20 ~ 30, water 35 ~ 42.The preparation method of jewellery surface protective film, comprises the following steps: (1) is at SiO
2first add after 10-15 part (parts by weight) isopropyl alcohol stirs in micro mist, then add Al
2o
3micro mist and aminopropyl triethoxysilane, finally add remaining isopropyl alcohol and water mixing and stirring, namely become the coating fluid of jewellery surface protective film; (2) clean jewelry surface; (3) by the coating liquid of jewelry diaphragm at jewelry surface; (4) dry, on jewelry, namely form the hard diaphragm of one deck.Diaphragm hardness of the present invention is high, protected effect good, be not easily damaged, and its preparation method technique is simple, cost is low.
In addition, vacuum coating technology is full-fledged, specifically, it is begun to show the thirties in 20th century, four the fifties start to occur commercial Application, industrialization large-scale production starts from the eighties in 20th century, obtains and apply widely in the industry such as electronics, aerospace, packaging, decoration, gold stamping printing.Vacuum coating refers under vacuum conditions, certain metal or metallic compound is deposited to material surface (normally nonmetallic materials) with the form of gas phase, belongs to physical gas-phase deposition.Because coating is often metallic film, therefore also claims vacuum metallization processes.The vacuum coating of broad sense is also included in the nonmetal functional film such as metal or non-metal material surface vacuum evaporation polymer.In all plated materials, the most common with plastics, secondly, be paper plated film.Relative to materials such as metal, pottery, timber, plastics have the advantages such as source is sufficient, performance is easy to regulation and control, easy to process, therefore miscellaneous plastics or other macromolecular materials are as engineering decorative structural material, are widely used in the industrial circles such as automobile, household electrical appliances, daily packaging, Handicraft decorative.But mostly there is the defects such as case hardness is not high, outward appearance is magnificent not, wearability is low in plastic material, as at the very thin metallic film of frosting evaporation one deck, the metal appearance of plastics Cheng Liang can be given, suitable source metal also can increase Surface Wear Resistance of Materials energy greatly, has greatly widened the ornamental of plastics and range of application.
The function of vacuum coating is many-sided, and it is very abundant that this also determines its application scenario.On the whole, the major function of vacuum coating comprises gives plating piece apparent height metallic luster and mirror effect, thin-film material makes rete have outstanding barrier property, provides excellent electromagnetic shielding and conductive effect.
But, jewelry lacks the structure arranging metal film.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of jewelry of new vacuum coating.
Technical scheme of the present invention is as follows: a kind of Novel jewellery manufacture craft, comprises the steps,
The first, jewelry idiosome design procedure, first divides distribution and the jewelry idiosome thickness region of jewelry idiosome, then the jewelry idiosome figure completing section region, each portion makes and the serial connection in section region, each portion;
The second, jewelry idiosome protrusions partial function district adopts turmeric technique and nickel plating technology, guarantees lug boss subregion functional areas reliability;
Three, printed paster, is adhesively fixed all printed pasters according to the position specified by the corresponding print character in design design position;
Four, printed paster nation is fixed, printed paster by certain arrangement mode, carry out die bond with bonding machine and die bond welding is carried out to stamp, carrying out baking after die bond completes makes jewelry idiosome be combined with printed paster completely, adopt gold ball bonding or aluminum steel electric arc bond technology, carry out bonding wire to the chip be completely fixed, wherein baking temperature is 150 DEG C-430 DEG C, baking time is 2H-10H;
Five, laser polishing, utilizes millisecond pulse laser and the process of ps pulsed laser and ns pulsed laser Multiple-Scan to increase material and manufactures metal parts surface, realize increasing the polishing that material manufactures metal parts surface; In Multiple laser scans polishing process, metalwork is manufactured to increasing material and carries out isothermal holding, increasing material can be made to manufacture metalwork surface stress and be evenly distributed;
Six, fluid polishing, carries out fluid polishing the jewelry idiosome after laser polishing, adds abrasive particle or non-newtonian fluid polishing fluid prepared by micro mist in the non-newtonian fluid with shear thickening effect; Wherein, non-newtonian fluid accounts for 91% ~ 98% of polishing fluid quality, and abrasive particle or micro mist account for 2% ~ 9% of polishing fluid quality, and the particle size range of abrasive particle or micro mist is: 0.008-22 μm; In polishing process, doing relative motion between workpiece and described polishing fluid, can there is shear thickening phenomenon by shear action in described polishing fluid and absorption surface part, and the viscosity of the polishing fluid of contact area increases;
Seven, ultrasonic wave immerses cleaning, the jewelry idiosome after fluid polishing is carried out ultrasonic wave and immerses cleaning: adopt aqueous cleaning agent, temperature is 77-99 DEG C; 2) pressure-air dropping liquid: pressure is 0.2 ~ 0.5Mpa; Spray rinsing: adopt rinsing liquid, temperature is 76 ~ 95 DEG C, and pressure is 0.2 ~ 0.3Mpa, adopts stainless steel Fan Spray Nozzle;
Eight, the air-dry cutter blowing of hot blast is dried: electrical heating, and temperature is 90 ~ 100 DEG C, the configuration finned air electric heating tube of stainless steel and overtemperature sensor, adopts high-pressure vortex air pump, by the pure air after filtration through heating, drying;
Nine, electron microscopic detects, and the jewelry idiosome after air-dry is carried out electron microscopic detection, and testing product meets product requirement and enters next link, finds substandard product, then can not enter next flow process if detect;
Ten, vacuum coating, carries out vacuum coating the jewelry idiosome through detecting;
Adopt vacuum type coating machine, the vacuum arranging vacuum type coating machine is 5 × 10
-1pa ~ 10 × 10
-7pa
Select plated film mixture to be target, by the electron gun bombardment plated film mixture of vacuum type coating machine, the electric current of the electron gun of vacuum type coating machine is 2 ~ 28A; Vacuum coating is carried out to the jewelry idiosome in vacuum type coating machine, at the anti-reflection film that the plated surface last layer of jewelry idiosome is transparent; In coating process, film thickness gauge measurement is used to be deposited on the thickness of the anti-reflection film of jewelry surface; Shut down after the thickness of anti-reflection film reaches setting value, control is deposited on the thickness of the anti-reflection film of jewelry surface and formation has corresponding refract light effect anti-reflection film on the surface of jewelry; Anti-reflection film thickness is thickness is 80-255nm.
Wherein, plated film mixture, is prepared from by the raw material of following parts by weight:
Dense titanium dioxide: 5--8 part;
PC plastic material: 22-33 part;
Flexibilizer 0.5-0.8 part;
Color powder 1--5 part;
Antioxidant 0.3-0.55 part;
Fire retardant 1-2 part;
Silica 1 0-30 part;
Magnesium fluoride 10-25 part;
Merlon 12-18 part;
PETG 8-12 part;
Polytetrafluoroethylene (PTFE) 7-9 part;
Silicon carbide fibre 1-5 part;
Titanium dioxide 1-5 part;
Two (3,5-tert-butyl-hydroxy phenyl) thioether 5-6 part;
Polytrimethylene ether 2 ~ 7%;
Anti-impact agent 1.2-3.8 part;
EVA1-4 part;
Organic solvent 0.5-4.5 part;
Compatilizer 0.3-1.8 part;
Antistatic additive 0.3-1.8 part.
A jewelry for intention plated film, it comprises jade body, and described jade body arranges some metal areas, metal area described in each adopts vacuum coating mode arrange layer of metal film.
Preferably, metal area described at least two is interconnected setting.
Preferably, the shape of described metal area is triangle, arc, fan-shaped or its combination.
Preferably, at least there is the metal area of a circle.
Preferably, described in each, the marginal position of metal area arranges a limiting section.
Preferably, described limiting section projection is arranged.
Preferably, described limiting section is recessed is arranged.
Preferably, each described metal area and described jade body have a preset height difference.
Preferably, each described metal area projection is arranged.
Preferably, each described metal area is recessed is arranged.
Preferably, described jade body arranges some connection bits.
Preferably, described metal area arranges some pits.
Adopt such scheme, the present invention adopts on jewelry, arranges some metal areas, metal area has layer of metal film, provide new jewelry structure, be applicable in production technology, the jewelry with metal film can be manufactured, and can manufacture be produced in batches, form industrialization product, there is very high market using value.The present invention selects silica and is target, is banged by the electron gun of vacuum type coating machine
Hit silica and magnesium fluoride mixture, at the antireflecting silicon dioxide film that the plated surface last layer of jewelry is transparent, present invention process is simple, low to equipment and process conditional request, easy to implement, cost is lower, makes jewelry have the visual effect of similar crystal and optical glass, make jewelry have higher ornamental value, under the prerequisite that cost is little, increase substantially value-added content of product.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of embodiments of the invention 1;
Fig. 2 is the schematic diagram of embodiments of the invention 2;
Fig. 3 is the schematic diagram of embodiments of the invention 3;
Fig. 4 is the schematic diagram of embodiments of the invention 4;
Fig. 5 is the schematic diagram of embodiments of the invention 5;
Fig. 6 is the schematic diagram of embodiments of the invention 6.
Detailed description of the invention
For the ease of understanding the present invention, below in conjunction with the drawings and specific embodiments, the present invention will be described in more detail.Give preferred embodiment of the present invention in this description and accompanying drawing thereof, but the present invention can realize in many different forms, is not limited to the embodiment described by this description.On the contrary, provide the object of these embodiments be make the understanding of disclosure of the present invention more comprehensively thorough.
It should be noted that, when a certain element is fixed on another element, comprise and this element is directly fixed on this another element, or this element is fixed on this another element by least one other element placed in the middle.When an element connects another element, comprise and this element is directly connected to this another element, or this element is connected to this another element by least one other element placed in the middle.
The invention solves technical problem jewelry being arranged metal film, provide the jewelry of vacuum coating, be suitable for industrialized mass production, this is that prior art never provides.One embodiment of the present of invention are, a kind of jewelry of intention plated film, and it comprises jade body, and described jade body arranges some metal areas, metal area described in each adopt vacuum coating mode arrange layer of metal film.As shown in Figure 1, a kind of jewelry of intention plated film, it comprises heart-shaped jade body 100, described jade body is arranged two heart-shaped metal areas 200; Preferably, as shown in Figure 1, the shape congruence of each metal area 200 is arranged; And for example, each metal area is symmetrical arranged.And for example, as shown in Figure 2, a kind of jewelry of intention plated film, it comprises heart-shaped jade body, described jade body is arranged the metal area of two stars; And for example, as shown in Figure 3, a kind of jewelry of intention plated film, it comprises heart-shaped jade body, described jade body is arranged side by side two heart-shaped metal areas, and a meniscate metal area; And for example, as shown in Figure 4, a kind of jewelry of intention plated film, it comprises heart-shaped jade body, described jade body is arranged side by side the metal area of two stars, and a meniscate metal area; And for example, as shown in Figure 5, a kind of jewelry of intention plated film, it comprises circular jade body, described jade body is arranged the metal area of star, meniscate metal area and criss-cross metal area.Various embodiments of the present invention do not make special restriction to described jade body, only need it to have jade material and can use as jewelry, and jade wherein can be equal to and is interpreted as jewel.
Wherein, described metal area has layer of metal film.Preferably, at least one described metal area adopt vacuum coating mode to arrange layer of metal film; Such as, described metal film covers the metal area at its place at least partly; Preferably, described metal film partly or completely covers the metal area at its place.And for example, metal area described in each adopt vacuum coating mode layer of metal film is set.Such as, adopt magnetic control multi-arc ion plating film mode to be coated with metal film on the metal area of jade body, comprise the metal film etc. such as titanium nitride and titanium, nickel, chromium, copper, gold, described metal film comprises alloy film etc., thus increase Beauty of Product perception, improve product specification, be suitable for batch production; And for example, same ornaments contain two kinds and above color coated surface treatment technology, and then through surface after polishing, polishing, then through treatment before plating and plating, forming electrodeposited coating, jewelry is more seemed, and light is incomparable, so beautiful that it excites men.
Preferably, described metal film is gold film.Gold film has popular characteristic, and quality compactness is high, and wearability is strong, difficult drop-off.Such as, the thickness of described gold film is 10-100 nanometer.And for example, preferably, the average thickness of described gold film is 15-20 nanometer; Such as, the thickness of described gold film is 18 nanometers.Like this, saved gold on the one hand, reduced product cost; On the other hand gold film is elegant in appearance, is greatly favored by consumers, and can bring the result of use of metal reflective and refraction for product.
For saving the consumption of gold further, preferably, in described jade body, only one side arranges each described metal area; Such as, face of only viewing and admiring arranges each described metal area.Such as, described jade body is flat pattern, and it has two sides, and wherein, only side described in arranges each described metal area.
Preferably, at least part of described metal area forms a preset shape; Such as, preset shape is triangle, fan-shaped, arc or its combination, and like this, can derive various different shape or pattern in theory, applying flexible is extensive; And for example, preset shape is pattern in specific red-letter day, comprises Santa Claus, teacher, lantern or pyramid-shaped dumpling etc.Such as, as shown in Figure 6, five leg-of-mutton metal areas form a similar pentalpha, thus form the metal film district of a similar pentalpha.
Preferably, described jade body arranges cover layer, it covers described jade body surface; Wherein, described cover layer covers described jade body surface at least partly; Such as, described cover layer all covers described jade body surface; And for example, described cover layer part covers described jade body surface.Preferably, the corresponding each described metal area of described cover layer arranges some portions of leaving a blank, and for exposing each described metal area respectively, such structural design is easy to the work flow in later stage; Such as, described in the portion of leaving a blank be room, or machine cut after room etc.Like this, when carrying out vacuum coating, metal area covering metal film, cover layer is covering metal film also, takes off the jewelry that cover layer can realize having metal film afterwards.For enhancing productivity, be easy to take off cover layer, preferably, described cover layer electrostatic adheres to described jade body surface, like this, after carrying out vacuum coating operation, is easy to take off described cover layer.Preferably, described cover layer has paper structure, like this, after carrying out vacuum coating operation, is easy to reclaim unnecessary gold, has fabulous practical function.Such as, the cover layer taken off after burning vacuum coating operation, namely recyclable unnecessary gold, easy to use, is applicable to large-scale production.
Preferably, described jade body arranges some connection bits, and described connection bit is fixedly connected with a movable part, described movable part is arranged some metal subregions, wherein, metal subregion described in each adopts vacuum coating mode arrange layer of metal film.Preferably, described movable part also arranges some bonding pads, metal subregion described in each, by least one described bonding pad, is connected to other metal subregion.Preferably, described movable part is a jade split, or a jade stone.Preferably, described jade stone and described jade body have different material.Preferably, each described metal subregion is arranged in series, and metal subregion described in each connects metal subregion described in by bonding pad described in, such as, be designed to the shapes such as the Big Dipper.And for example, on described movable part, in the position be connected with described connection bit, around arranging a thickening metal subregion, preferably, the metal film on this thickening metal subregion, its thickness is greater than the thickness of the metal film on other metal subregions; Such as, both Thickness Ratios are 1.5 to 2:1; Like this, the durability of the position strengthening connection is to a certain extent conducive to; And for example, this thickening metal subregion is endless belt shape, is similar to a lax cloth ring; Preferably, the narrowest width of this thickening metal subregion is 2 millimeters.Like this, the physical strength strengthening the position connected is conducive to, metal film difficult drop-off.Preferably, at least one described movable part is fixedly attached in corresponding described connection bit by chain portion, like this, can realize overall longer jewelry product; And for example, movable part described in is only set.
Preferably, described metal area arranges some pits, like this, be conducive to the overall adhesiveness strengthening metal film, there is higher working strength.Such as, each pit is uniformly distributed; And for example, described pit is hemispherical, and preferably, its radius is 3 to 8 nanometers; A good example is, annular arranges each described pit, and described pit is hemispherical, and its radius is 4 to 6 nanometers.Preferably, described in each, pit side also arranges three lug bosses, and three lug bosses are arranged as a triangle; Preferably, described pit is arranged at described barycenter oftriangle or geometric center.Preferably, described triangle is equilateral triangle.Preferably, described lug boss is hemispherical; Such as, the shape of described lug boss is identical with described pit with size.Like this, be conducive to the bulk strength strengthening metal film, effectively increase the service life.
And for example, a kind of jewelry of intention plated film, it comprises jade body, and described jade body arranges some metal areas, metal area described in each adopts vacuum coating mode arrange layer of metal film.Preferably, metal area described at least two is interconnected setting.Such as, arrange five endless metal districts of Olympic Five Ring shape, each endless metal district is at least interconnected with other two endless metals district and arranges.Preferably, the shape of described metal area is triangle, arc, fan-shaped or its combination, like this, can form various pattern or shape.Preferably, at least there is the metal area of a circle, like this, certain reflecting effect can be had.Preferably, at least one described metal area has segment structure, is a spherosome and is divided into two parts by a plane, part remaining after an excision part; Like this, after layer of metal film is set, the reflecting effect of optically focused can be obtained; This be the known all jewelry of applicant all not disclosed in; Use in conjunction with the embodiment with LED chip, effect is dazzle the eyes dazzling especially, attracts the attention of millions of people.
Preferably, described in each, the marginal position of metal area arranges a limiting section; Such as, limiting section is one closed around structure, and such as, described limiting section be annular or moulding shape etc.Preferably, described limiting section projection is arranged, such as described limiting section projection 20 to 40 nanometer; Or described limiting section is recessed to be arranged, recessed 40 to 80 nanometers of such as described limiting section.Like this, production is easy to realize, and the effect of vacuum coating can be guaranteed to a certain extent.Preferably, described limiting section combines and respectively comprises described tectal related embodiment, jointly uses, after carrying out vacuum coating operation, is easy to take off described cover layer, very easy to use, and stereoeffect is good.
Preferably, each described metal area and described jade body have a preset height difference, and such as, preset height difference is 1 millimeter, or preset height difference is 20 nanometers, 30 nanometers, 50 nanometers or 100 nanometers etc.Like this, each described metal area and described jade body have difference in height, and after arranging layer of metal film, each described metal area is concordant with described jade body; Such as, or preferably, each described metal area projection is arranged, metal area projection 20 to 40 nanometer described in each; Preferably, the height that each described metal area projection is arranged is equal with the thickness of the described metal film on it; The extremely strong jewelry product of third dimension can be made like this.Or each described metal area is recessed to be arranged, recessed 40 to 80 nanometers of such as metal area described in each.Preferably, each described metal area is recessed into the degree of depth of setting, equal with the thickness of the described metal film on it.
Preferably, on at least one described metal area, solar cell film is set, i.e. film solar cell, described jade body also arranges a mounting groove, described mounting groove arranges a control system, minicell and some installations and divides groove, install described in each on point groove and arrange a LED chip, solar cell film connects described minicell by described control system, for being its charging, described minicell connects each LED chip respectively by described control system, for being its power supply.Such as, described jade body is flat pattern, and it has two sides, and wherein, side described in arranges each described metal area, and same described side arranges described mounting groove.Preferably, described set-up of control system touch sensible switch, for being communicated with or cutting off the power supply circuits of each LED chip.Like this, by day or brightness is enough time, solar cell film is minicell charging, under night or dark surrounds, user, by touching described touch sensible switch, makes the luminous or flicker of each LED chip or closes, to make jewelry Integral luminous or flicker or closedown, Consumer's Experience makes jewelry more brilliant dazzling, stretch out one's hand market welcome.It should be noted that, solar cell film, minicell, control system, touch sensible switch, each LED chip and connection thereof, be prior art, such as LED chip is luminous or glimmer or close, belong to the control technology of existing LED flashlight, the concrete time limit of these prior aries does not belong to the present invention's scope required for protection, the inventive point of each related embodiment of the present invention is these to glisten, charging, the technology such as touch control, be applied to jewelry art, especially there is the jewelry of metal film, the luminescence of LED shines upon on jade body and/or metal film, there is refraction and reflection, under certain structure, there is repeatedly refraction and reflection, jewelry is glittered blaze, this is that existing jewelry is never accomplished.Another example, installs a point groove described in each of described mounting groove, is communicated to metal area place described in respectively, and described installation divides the light emission direction of the described LED chip in groove facing to described metal area, and namely the illumination of LED is to described metal area; Preferably, described installation divides groove and described metal area noncontact to arrange.Like this, achieve the micro lighting of jewelry, make jewelry also can be high-visible in dark surrounds; Further, effectively make use of reflective, the refraction action of metal film, the light of LED is fully utilized, there is fabulous market value.
Further, embodiments of the invention also comprise, each technical characteristic of the various embodiments described above, the jewelry of the vacuum coating be mutually combined to form.
A kind of Novel jewellery manufacture craft, comprises the steps,
The first, jewelry idiosome design procedure, first divides distribution and the jewelry idiosome thickness region of jewelry idiosome, then the jewelry idiosome figure completing section region, each portion makes and the serial connection in section region, each portion;
The second, jewelry idiosome protrusions partial function district adopts turmeric technique and nickel plating technology, guarantees lug boss subregion functional areas reliability;
Three, printed paster, is adhesively fixed all printed pasters according to the position specified by the corresponding print character in design design position;
Four, printed paster nation is fixed, printed paster by certain arrangement mode, carry out die bond with bonding machine and die bond welding is carried out to stamp, carrying out baking after die bond completes makes jewelry idiosome be combined with printed paster completely, adopt gold ball bonding or aluminum steel electric arc bond technology, carry out bonding wire to the chip be completely fixed, wherein baking temperature is 150 DEG C-430 DEG C, baking time is 2H-10H;
Five, laser polishing, utilizes millisecond pulse laser and the process of ps pulsed laser and ns pulsed laser Multiple-Scan to increase material and manufactures metal parts surface, realize increasing the polishing that material manufactures metal parts surface; In Multiple laser scans polishing process, metalwork is manufactured to increasing material and carries out isothermal holding, increasing material can be made to manufacture metalwork surface stress and be evenly distributed;
Six, fluid polishing, carries out fluid polishing the jewelry idiosome after laser polishing, adds abrasive particle or non-newtonian fluid polishing fluid prepared by micro mist in the non-newtonian fluid with shear thickening effect; Wherein, non-newtonian fluid accounts for 91% ~ 98% of polishing fluid quality, and abrasive particle or micro mist account for 2% ~ 9% of polishing fluid quality, and the particle size range of abrasive particle or micro mist is: 0.008-22 μm; In polishing process, doing relative motion between workpiece and described polishing fluid, can there is shear thickening phenomenon by shear action in described polishing fluid and absorption surface part, and the viscosity of the polishing fluid of contact area increases;
Seven, ultrasonic wave immerses cleaning, the jewelry idiosome after fluid polishing is carried out ultrasonic wave and immerses cleaning: adopt aqueous cleaning agent, temperature is 77-99 DEG C; 2) pressure-air dropping liquid: pressure is 0.2 ~ 0.5Mpa; Spray rinsing: adopt rinsing liquid, temperature is 76 ~ 95 DEG C, and pressure is 0.2 ~ 0.3Mpa, adopts stainless steel Fan Spray Nozzle;
Eight, the air-dry cutter blowing of hot blast is dried: electrical heating, and temperature is 90 ~ 100 DEG C, the configuration finned air electric heating tube of stainless steel and overtemperature sensor, adopts high-pressure vortex air pump, by the pure air after filtration through heating, drying;
Nine, electron microscopic detects, and the jewelry idiosome after air-dry is carried out electron microscopic detection, and testing product meets product requirement and enters next link, finds substandard product, then can not enter next flow process if detect;
Ten, vacuum coating, carries out vacuum coating the jewelry idiosome through detecting;
Adopt vacuum type coating machine, the vacuum arranging vacuum type coating machine is 5 × 10
-1pa ~ 10 × 10
-7pa
Select plated film mixture to be target, by the electron gun bombardment plated film mixture of vacuum type coating machine, the electric current of the electron gun of vacuum type coating machine is 2 ~ 28A; Vacuum coating is carried out to the jewelry idiosome in vacuum type coating machine, at the anti-reflection film that the plated surface last layer of jewelry idiosome is transparent; In coating process, film thickness gauge measurement is used to be deposited on the thickness of the anti-reflection film of jewelry surface; Shut down after the thickness of anti-reflection film reaches setting value, control is deposited on the thickness of the anti-reflection film of jewelry surface and formation has corresponding refract light effect anti-reflection film on the surface of jewelry; Anti-reflection film thickness is thickness is 80-255nm.
Wherein, plated film mixture, is prepared from by the raw material of following parts by weight:
Dense titanium dioxide: 5--8 part;
PC plastic material: 22-33 part;
Flexibilizer 0.5-0.8 part;
Color powder 1--5 part;
Antioxidant 0.3-0.55 part;
Fire retardant 1-2 part;
Silica 1 0-30 part;
Magnesium fluoride 10-25 part;
Merlon 12-18 part;
PETG 8-12 part;
Polytetrafluoroethylene (PTFE) 7-9 part;
Silicon carbide fibre 1-5 part;
Titanium dioxide 1-5 part;
Two (3,5-tert-butyl-hydroxy phenyl) thioether 5-6 part;
Polytrimethylene ether 2 ~ 7%;
Anti-impact agent 1.2-3.8 part;
EVA1-4 part;
Organic solvent 0.5-4.5 part;
Compatilizer 0.3-1.8 part;
Antistatic additive 0.3-1.8 part.
Above-mentioned plated film mixture optimized proportion is: dense titanium dioxide: 6--7 part;
PC plastic material: 23-28 part;
Flexibilizer 0.5-0.6 part;
Color powder 2--4 part;
Antioxidant 0.4-0.48 part;
Fire retardant 1.5-1.8 part;
Silica 1 8-26 part;
Magnesium fluoride 16-22 part;
Merlon 15-17 part;
PETG 10-11 part;
Polytetrafluoroethylene (PTFE) 8-8.5 part;
Silicon carbide fibre 2-4 part;
Titanium dioxide 3-4 part;
Two (3,5-tert-butyl-hydroxy phenyl) thioether 5.5-5.8 part;
Polytrimethylene ether 4.5 ~ 6%;
Anti-impact agent 1.8-3.6 part;
EVA2-3 part;
Organic solvent 0.9-2.9 part;
Compatilizer 1.5-1.8 part;
Antistatic additive 1.6-1.8 part.
Above-mentioned composition fully stirs, and at 100-150 degree temperature, abundant mixed dissolution becomes plated film fluid-mixing shape.
Adopt such scheme, the present invention adopts on jewelry, arranges some metal areas, metal area has layer of metal film, provide new jewelry structure, be applicable in production technology, the jewelry with metal film can be manufactured, and can manufacture be produced in batches, form industrialization product, there is very high market using value.The present invention selects silica and is target, is banged by the electron gun of vacuum type coating machine
Hit silica and magnesium fluoride mixture, at the antireflecting silicon dioxide film that the plated surface last layer of jewelry is transparent, present invention process is simple, low to equipment and process conditional request, easy to implement, cost is lower, makes jewelry have the visual effect of similar crystal and optical glass, make jewelry have higher ornamental value, under the prerequisite that cost is little, increase substantially value-added content of product.
It should be noted that, above-mentioned each technical characteristic continues combination mutually, is formed not in above-named various embodiment, is all considered as the scope that description of the present invention is recorded; Further, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.
Claims (10)
1. a Novel jewellery manufacture craft, is characterized in that, comprises the steps,
The first, jewelry idiosome design procedure, first divides distribution and the jewelry idiosome thickness region of jewelry idiosome, then the jewelry idiosome figure completing section region, each portion makes and the serial connection in section region, each portion;
The second, jewelry idiosome protrusions partial function district adopts turmeric technique and nickel plating technology, guarantees lug boss subregion functional areas reliability;
Three, printed paster, is adhesively fixed all printed pasters according to the position specified by the corresponding print character in design design position;
Four, printed paster nation is fixed, printed paster by certain arrangement mode, carry out die bond with bonding machine and die bond welding is carried out to stamp, carrying out baking after die bond completes makes jewelry idiosome be combined with printed paster completely, adopt gold ball bonding or aluminum steel electric arc bond technology, carry out bonding wire to the chip be completely fixed, wherein baking temperature is 150 DEG C-430 DEG C, baking time is 2H-10H;
Five, laser polishing, utilizes millisecond pulse laser and the process of ps pulsed laser and ns pulsed laser Multiple-Scan to increase material and manufactures metal parts surface, realize increasing the polishing that material manufactures metal parts surface; In Multiple laser scans polishing process, metalwork is manufactured to increasing material and carries out isothermal holding, increasing material can be made to manufacture metalwork surface stress and be evenly distributed;
Six, fluid polishing, carries out fluid polishing the jewelry idiosome after laser polishing, adds abrasive particle or non-newtonian fluid polishing fluid prepared by micro mist in the non-newtonian fluid with shear thickening effect; Wherein, non-newtonian fluid accounts for 91% ~ 98% of polishing fluid quality, and abrasive particle or micro mist account for 2% ~ 9% of polishing fluid quality, and the particle size range of abrasive particle or micro mist is: 0.008-22 μm; In polishing process, doing relative motion between workpiece and described polishing fluid, can there is shear thickening phenomenon by shear action in described polishing fluid and absorption surface part, and the viscosity of the polishing fluid of contact area increases;
Seven, ultrasonic wave immerses cleaning, the jewelry idiosome after fluid polishing is carried out ultrasonic wave and immerses cleaning: adopt aqueous cleaning agent, temperature is 77-99 DEG C; 2) pressure-air dropping liquid: pressure is 0.2 ~ 0.5Mpa; Spray rinsing: adopt rinsing liquid, temperature is 76 ~ 95 DEG C, and pressure is 0.2 ~ 0.3Mpa, adopts stainless steel Fan Spray Nozzle;
Eight, the air-dry cutter blowing of hot blast is dried: electrical heating, and temperature is 90 ~ 100 DEG C, the configuration finned air electric heating tube of stainless steel and overtemperature sensor, adopts high-pressure vortex air pump, by the pure air after filtration through heating, drying;
Nine, electron microscopic detects, and the jewelry idiosome after air-dry is carried out electron microscopic detection, and testing product meets product requirement and enters next link, finds substandard product, then can not enter next flow process if detect;
Ten, vacuum coating, carries out vacuum coating the jewelry idiosome through detecting;
Adopt vacuum type coating machine, the vacuum arranging vacuum type coating machine is 5 × 10
-1pa ~ 10 × 10
-7pa
Select plated film mixture to be target, by the electron gun bombardment plated film mixture of vacuum type coating machine, the electric current of the electron gun of vacuum type coating machine is 2 ~ 28A; Vacuum coating is carried out to the jewelry idiosome in vacuum type coating machine, at the anti-reflection film that the plated surface last layer of jewelry idiosome is transparent; In coating process, film thickness gauge measurement is used to be deposited on the thickness of the anti-reflection film of jewelry surface; Shut down after the thickness of anti-reflection film reaches setting value, control is deposited on the thickness of the anti-reflection film of jewelry surface and formation has corresponding refract light effect anti-reflection film on the surface of jewelry; Anti-reflection film thickness is thickness is 80-255nm.
2. a kind of Novel jewellery manufacture craft according to claim 1, is characterized in that,
Plated film mixture, is prepared from by the raw material of following parts by weight:
Dense titanium dioxide: 5--8 part;
PC plastic material: 22-33 part;
Flexibilizer 0.5-0.8 part;
Color powder 1--5 part;
Antioxidant 0.3-0.55 part;
Fire retardant 1-2 part;
Silica 1 0-30 part;
Magnesium fluoride 10-25 part;
Merlon 12-18 part;
PETG 8-12 part;
Polytetrafluoroethylene (PTFE) 7-9 part;
Silicon carbide fibre 1-5 part;
Titanium dioxide 1-5 part;
Two (3,5-tert-butyl-hydroxy phenyl) thioether 5-6 part;
Polytrimethylene ether 2 ~ 7%;
Anti-impact agent 1.2-3.8 part;
EVA1-4 part;
Organic solvent 0.5-4.5 part;
Compatilizer 0.3-1.8 part;
Antistatic additive 0.3-1.8 part.
3. an intention plated film jewelry, is characterized in that, comprises jade body, and described jade body arranges some metal areas, metal area described in each adopts vacuum coating mode arrange layer of metal film.
4. jewelry according to claim 3, is characterized in that, metal area described at least two is interconnected setting.
5. jewelry according to claim 4, is characterized in that, the shape of described metal area is triangle, arc, fan-shaped or its combination.
6. jewelry according to claim 5, is characterized in that at least having the metal area of a circle.
7. jewelry according to claim 6, it is characterized in that, described in each, the marginal position of metal area arranges a limiting section.
8. jewelry according to claim 7, is characterized in that, described limiting section projection is arranged.
9. jewelry according to claim 7, is characterized in that, described limiting section is recessed to be arranged.
10. according to the arbitrary described jewelry of claim 3 to 9, it is characterized in that, each described metal area and described jade body have a preset height difference.
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| CN111660211A (en) * | 2019-12-31 | 2020-09-15 | 河南联合精密材料股份有限公司 | Polycrystalline diamond-like abrasive and preparation method thereof |
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