CN104425664B - Has the optoelectronic semiconductor component of barrier layer - Google Patents

Has the optoelectronic semiconductor component of barrier layer Download PDF

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CN104425664B
CN104425664B CN201310404407.6A CN201310404407A CN104425664B CN 104425664 B CN104425664 B CN 104425664B CN 201310404407 A CN201310404407 A CN 201310404407A CN 104425664 B CN104425664 B CN 104425664B
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layer
dopant
semiconductor layer
semiconductor
semiconductor component
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CN104425664A (en
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刘宗宪
李荣仁
李世昌
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Epistar Corp
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Epistar Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/14Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

The present invention discloses a kind of optoelectronic semiconductor component, comprising:One barrier layer;One first semiconductor layer is located on barrier layer, and the first semiconductor layer includes one first dopant and one second dopant;And one second semiconductor layer be located under barrier layer include the second dopant, wherein in the first semiconductor layer, the concentration of first dopant is more than the concentration of the second dopant, and concentration of second dopant in the second semiconductor layer is more than the concentration in the first semiconductor layer.

Description

Has the optoelectronic semiconductor component of barrier layer
Technical field
The present invention relates to a kind of structures of optoelectronic semiconductor component.
Background technology
Optoelectronic semiconductor component, such as light emitting diode (LED), under brightness is constantly promoted in recent years, application field It has expanded to the light source of all kinds of devices from traditional indicator light or decorative use or even in the near future, it is most likely that substitution Traditional fluorescent lamp becomes the light source of lighting area of new generation.
Existing light emitting diode (LED) structure is single p-n junction structure, as shown in Figure 1, its basic structure includes one On the substrate 13, a p-type semiconductor layer 12 is in n-type semiconductor layer 11 and one shines for substrate 13, a n-type semiconductor layer 11 Layer 10 is between p-type semiconductor layer 12 and n-type semiconductor layer 11.
In order to improve the luminous quantity in light emitting diode (LED) per unit area, as shown in Fig. 2, one shines with multilayer First p-n junction structure I and the second p-n junction structure I I are passed through a tunneling layer 17 by light emitting diode (LED) structure of lamination It is together in series, thus in identical unit area, the luminous quantity of per unit area will be promoted, while driving voltage can become For twice, but driving current can't increase.This high voltage, the characteristic of low current help to be applied to illuminating product.It is existing Tunneling layer 17 for high-concentration dopant n+ semiconductor layers and p+ semiconductor layers form, due to the n+ semiconductor layers of high-concentration dopant And p+ semiconductor layers are poor for the penetrance of light, so usually tunneling layer 17 must be very thin to improve the penetrance of light, still Tunneling layer 17 is too thin, and easily incorporation affects tunneling layer 17 from the dopant that other semiconductor layers are spread in manufacture craft Function.
The content of the invention
To solve the above problems, the present invention provides a kind of optoelectronic semiconductor component, comprising:One barrier layer;One the first half leads Body layer is located on barrier layer, and the first semiconductor layer includes one first dopant and one second dopant;And one second Semiconductor layer is located under barrier layer comprising the second dopant, wherein in the first semiconductor layer, the first dopant it is dense Degree is more than the concentration of the second dopant, and concentration of second dopant in the second semiconductor layer is more than in the first semiconductor layer Concentration.
Description of the drawings
Fig. 1 is existing light emitting diode (LED) structure diagram;
Fig. 2 is light emitting diode (LED) structure diagram of the existing lamination that shines with multilayer;
Fig. 3 is the structure diagram according to first embodiment of the invention;
Fig. 4 A~Fig. 4 B are aluminium (Al) content ratio figure according to first embodiment of the invention;
Fig. 5 A~Fig. 5 B are band gap (Ec-Ev) schematic diagram according to first embodiment of the invention;
Fig. 6 is the structure diagram according to another embodiment of the present invention.
Symbol description
1 first is semiconductor laminated
10 first luminescent layers
11 first n-type semiconductor layers
12 first p-type semiconductor layers
13 substrates
2 second is semiconductor laminated
21 second p-type semiconductor layers
22 second n-type semiconductor layers
23 second luminescent layers
3 tunneling laminations
31 first electrical tunneling layers
32 second electrical tunneling layers
4 barrier layers
51 first electrodes
52 second electrodes
53 surfaces
54 surfaces
Specific embodiment
First embodiment
Fig. 3 is the structure diagram according to first embodiment of the invention.Disclosed optoelectronic semiconductor component according to the present invention For a pair of p-n junction structure, it is located at comprising one first semiconductor laminated 1 and one second semiconductor laminated 2 on a substrate 13, wherein First semiconductor laminated 1 is located on second semiconductor laminated 2, and a tunneling lamination 3 is located at first semiconductor laminated 1 and the second half leads Between body lamination 2, for a barrier layer 4 between tunneling lamination 3 and second semiconductor laminated 2, a first electrode 51 is arranged on 53 and one second electrode 52 of surface of semiconductor lamination 1 is arranged on the surface 54 of substrate 13, first electrode 51 and second Electrode 52 passes through first semiconductor laminated 1 and second semiconductor laminated 2 for steering current.
Substrate 13 be electrically-conductive backing plate, material include silicon (Si), GaAs (GaAs), carborundum (SiC), zinc oxide (ZnO), Gallium nitride (GaN), one kind of aluminium nitride (AlN) or metal material or its combination.
First semiconductor laminated 1, second semiconductor laminated 2, tunneling lamination 3 and barrier layer 4 can be grown up by extensional mode On the substrate 13 or by aligning sticking method, bonded in a manner of heating, pressurizeing with substrate 13.
First semiconductor laminated 1, which includes at least one first n-type semiconductor layer 11, has the first conductive type state, and one first shines 10 and one first p-type semiconductor layer 12 of layer has the second conductive type state;Second semiconductor laminated 2 includes at least one second n-type Semiconductor layer 22 has the first conductive type state, and one second luminescent layer 23 and one second p-type semiconductor layer 21 have the second conduction Kenel;First semiconductor laminated 1 and second semiconductor laminated 2 sequentially epitaxial growth on substrate 13.First n-type semiconductor layer 11st, the first p-type semiconductor layer 12, the second n-type semiconductor layer 22 and the second p-type semiconductor layer 21 can be two single layer structures or two A multilayered structure (multilayered structure refers to two layers or more than two layers).First n-type semiconductor layer 11 and the first p-type semiconductor layer 12 have Different conductivity, electrically, polarity or according to the element of doping to provide electronics or hole;Second n-type semiconductor layer 22 and Two p-type semiconductor layers 21 also have different conductivities, electrically, polarity or according to the element of doping to provide electronics or hole. First luminescent layer 10 is formed between the first n-type semiconductor layer 11 and the first p-type semiconductor layer 12, and the second luminescent layer 23 is formed in Between second n-type semiconductor layer 22 and the second p-type semiconductor layer 21, the first luminescent layer 10 and the second luminescent layer 23 are to turn electric energy Change luminous energy into.Pass through wherein one or more layers the physics and chemistry of change first semiconductor laminated 1 and second semiconductor laminated 2 Composition, adjusts the optical wavelength sent.Common material is AlGaInP (aluminum gallium indium Phosphide, AlGaInP) serial, aluminum indium gallium nitride (aluminum gallium indium nitride, AlGaInN) system Row, zinc oxide are serial (zinc oxide, ZnO).First luminescent layer 10 and the second luminescent layer 23 can be single heterojunction structure (single Heterostructure, SH), double-heterostructure (double heterostructure, DH), bilateral double heterojunction (double-side double heterostructure, DDH), multi layer quantum well (multi-quantum well, MWQ). Specifically, the first luminescent layer 10 and the second luminescent layer 23 can be semiconductor neutral, that p-type or n-type are electrical.Electric current is imposed to pass through When first semiconductor laminated 1 and second semiconductor laminated 2, the first luminescent layer 10 and the second luminescent layer 23 can shine, wherein first The light that luminescent layer is sent has first wave length, and the light that the second luminescent layer is sent has second wave length, first wave length and second Wavelength difference is less than 20nm.When the material of the first luminescent layer 10 and the second luminescent layer 23 based on AlGaInP (AlGaInP) During material, the light of red, orange, yellow light amber colour system can be sent, wherein first wave length and second wave length between 600nm~620nm it Between;When the material based on aluminum indium gallium nitride (AlGaInN), blue or green light can be sent.In the present embodiment, the first semiconductor The material of lamination 1 and second semiconductor laminated 2 for AlGaInP (aluminum gallium indium phosphide, AlGaInP) series, the first p-type semiconductor layer 12 and the second p-type semiconductor layer 21 magnesium-doped (Mg) or zinc (Zn) element, wherein Magnesium (Mg) or zinc (Zn) element are more than 10 in the concentration of the first p-type semiconductor layer 12 and the second p-type semiconductor layer 2117cm-3(/ cm3), it is preferred that between 3*1017~5*1017cm-3Between;First n-type semiconductor layer 11 and the second n-type semiconductor layer 22 are mixed Miscellaneous silicon (Si) element, wherein silicon (Si) element the concentration of the first n-type semiconductor layer 11 and the second n-type semiconductor layer 22 between 1017~1018cm-3Between, it is preferred that between 4*1017~6*1017cm-3Between.
There is a tunneling lamination 3 between first semiconductor laminated 1 and second semiconductor laminated 2.Tunneling lamination 3 can make electric current It is passed through by tunneling effect (tunneling effect), electric current is made to flow through the first semiconductor laminated 1 and second semiconductor simultaneously Lamination 2, material include more than one element and are selected from gallium (Ga), aluminium (Al), indium (In), phosphorus (P), arsenic (As), nitrogen (N), zinc (Zn), the group that cadmium (Cd) is formed with selenium (Se).Tunneling lamination 3 is electrically worn comprising one first electrical tunneling layer 31 and 1 second Tunnel layer 32, wherein, the first electrical tunneling layer 31 is close to the polarity and the 2nd p of the second semiconductor laminated 2, first electrical tunneling layer 31 Type semiconductor layer 21 is identical, and in the present embodiment, the first electrical 31 and second p-type semiconductor layer 21 of tunneling layer is all p-type semiconductor, First electrical tunneling layer 31 be comprising aluminium (Al), gallium (Ga), arsenic (As) compound, and with the first dopant and second doping Object, wherein the first dopant is carbon (C), the concentration of the first dopant is between 1019~1021cm-3, it is preferred that between 1019~5* 1020cm-3, the second dopant is magnesium (Mg) or zinc (Zn), and the concentration of the second dopant is less than 1018cm-3, it is preferred that it is less than 1017cm-3, the concentration of the first dopant is 10 times of the second concentration of dopant, it is preferred that more than 100 times or more.First electrically The first dopant in tunneling layer 31, such as carbon (C) are a deliberately dopants, and the first electrical tunneling layer 31 is made to form a tool There is the p-type semiconductor of high-concentration dopant;The second dopant in first electrical tunneling layer 31, such as magnesium (Mg) or zinc (Zn) are One non-deliberately dopant, spreads during extension from the second p-type semiconductor layer 21.Second electrical tunneling layer 32 is close First semiconductor laminated 1, the polarity of the second electrical tunneling layer 32 is identical with the first n-type semiconductor layer 11, in the present embodiment, second Electrical 32 and first n-type semiconductor layer 11 of tunneling layer is all n-type semiconductor, and the second electrical tunneling layer 32 is to include indium (In), gallium (Ga), the compound of phosphorus (P), and tellurium (Te) is adulterated, wherein the concentration of tellurium (Te) is between 1019~1021cm-3, it is preferred that between 1019~2*1020cm-3
Barrier layer 4 between the second p-type semiconductor layer 21 and the first electrical tunneling layer 31 is to include aluminium (Al), gallium (Ga), the compound Al of indium (In) and phosphorus (P)xGa1-xThe scope of InP, wherein x can be between 0.05~0.95, it is preferred that between 0.2~0.7, x are passed from barrier layer 4 close to the part of the second p-type semiconductor layer 21 to the part close to the first electrical tunneling layer 31 Subtract, the mode successively decreased includes linear decrease or stepped successively decreases.Therefore, aluminium (Al) concentration profile as shown in fig. 4 a and fig. 4b, In barrier layer 4, aluminium (Al) is about 35% in the moiety content ratio close to the second p-type semiconductor layer 21, with linear decrease (figure 4A) or the stepped mode for successively decreasing (Fig. 4 B), until its content ratio of part close to the first electrical tunneling layer 31 is about 10%. Due to the first epitaxial growth of barrier layer 4 on second semiconductor laminated 2 after, tunneling lamination 3 continues epitaxial growth on barrier layer 4, In epitaxial growth process, barrier layer 4 can reduce the element adulterated in second semiconductor laminated 2, such as magnesium (Mg) or zinc (Zn), It diffuses in the first electrical tunneling layer 31.If barrier layer free 4 is formed in the second p-type semiconductor layer 21 and the first electrical tunneling layer 31 Between, in the epitaxial process of the first electrical tunneling layer 31, the second dopant of the second p-type semiconductor layer 21, such as magnesium (Mg) Or zinc (Zn), it will diffuse in large quantities in the first electrical tunneling layer 31, make the second dopant of the first electrical tunneling layer 31 Concentration improves, when the concentration of the second dopant is more than 1018cm-3More than, the resistance for causing the first electrical tunneling layer 31 is promoted, So that operating voltage (the V of optoelectronic semiconductor componentf) improve, efficiency is caused to decline.
Due in barrier layer 4, the concentration of aluminium (Al) is about in the moiety content ratio close to the second p-type semiconductor layer 21 35%, linear decrease or it is stepped successively decrease until close to the first electrical tunneling layer 31 part when, content ratio is about 10%, such as Shown in Fig. 5 A and Fig. 5 B so that band gap (Ec-Ev) declines (Fig. 5 A) or rank from the partial linear of the second p-type semiconductor layer 21 Scalariform successively decreases (Fig. 5 B) to the first electrical tunneling layer 31, and the linear or stepped of this band gap (Ec-Ev) gradually changes, can keep away Exempt from electronics to be blocked in transmission process, to reduce operating voltage (Vf)。
Second embodiment
Second embodiment is that barrier layer 4 is comprising aluminium (Al), gallium (Ga), indium (In) or phosphorus with first embodiment difference (P) compound, such as AlxGa1-xThe scope of InP, wherein x can be between 0.05~0.95, it is preferred that between 0.2~0.7, And antimony dopant (Sb), wherein the concentration of antimony (Sb) is between 1017~1018cm-3Between.During extension, since barrier layer 4 is mixed Miscellaneous antimony (Sb), can inhibit the element adulterated in second semiconductor laminated 2, such as magnesium (Mg) or zinc (Zn), diffuse to first It in electrical tunneling layer 31, avoids in the first electrical tunneling layer 31, the concentration of the second dopant is more than 1018cm-3, it is preferred that Avoid exceeding 1017cm-3
Fig. 6 is the structure diagram according to another embodiment of the present invention.One bulb lamp 600 includes a lampshade 602, a lens 604th, a light emitting module 610, a lamp holder 612, a cooling fin 614, a connecting portion 616 and an electrical connecting element.Light emitting module 610 comprising the optoelectronic semiconductor component 608 described in a supporting part 606 and multiple previous embodiments on supporting part 606.
Each embodiment cited by the present invention is only to illustrate the present invention, is not used to limit the scope of the present invention.It is any People's any modification apparent easy to know made for the present invention or change all do not depart from spirit and scope of the invention.

Claims (22)

1. a kind of optoelectronic semiconductor component, comprising:
Barrier layer;
First semiconductor layer, on the barrier layer, which includes the first dopant and the second dopant Matter;
Second semiconductor layer includes second dopant under the barrier layer;
First luminous lamination, comprising the first luminescent layer, on first semiconductor layer;
Second shines lamination, comprising the second luminescent layer, under the barrier layer, and this second shine lamination include this second half Conductor layer, second semiconductor layer are located between second luminescent layer and the barrier layer;And
Tunneling lamination, positioned at this first shine between lamination and the barrier layer, and the tunneling lamination include first semiconductor layer,
Wherein in first semiconductor layer, the concentration of first dopant is more than the concentration of second dopant, and this Concentration of two dopants in second semiconductor layer is more than the concentration in first semiconductor layer,
Wherein this first shines lamination also comprising the first p-type semiconductor layer, on first luminescent layer and the first n-type half Conductor layer, under first luminescent layer;This second shines lamination also comprising the second n-type semiconductor, second shines positioned at this Under layer, wherein second semiconductor layer is a p-type semiconductor;The tunneling lamination also comprising the 3rd semiconductor layer, positioned at this Between semi-conductor layer and the first luminous lamination.
2. optoelectronic semiconductor component as described in claim 1, wherein first dopant are dense in the first semiconductor layer Degree is more than 10 times of the concentration of second semiconductor layer in the first semiconductor layer or more.
3. optoelectronic semiconductor component as claimed in claim 2, wherein first dopant include carbon (C).
4. optoelectronic semiconductor component as described in claim 1, wherein second dopant are dense in the first semiconductor layer Degree is less than 1018cm-3
5. optoelectronic semiconductor component as claimed in claim 4, wherein second dopant include magnesium (Mg) or zinc (Zn).
6. optoelectronic semiconductor component as described in claim 1, the wherein barrier layer include AlGaInP (AlxGa1-xInP), And x scopes are 0.2≤x≤0.7.
7. optoelectronic semiconductor component as claimed in claim 6, wherein x are from the barrier layer close to the part of second semiconductor layer Successively decrease to the part close to first semiconductor layer.
8. the decreasing fashion of optoelectronic semiconductor component as claimed in claim 7, wherein x is linear decrease.
9. the decreasing fashion of optoelectronic semiconductor component as claimed in claim 7, wherein x successively decreases to be stepped.
10. optoelectronic semiconductor component as described in claim 1, the wherein barrier layer include antimony (Sb), and the concentration of antimony (Sb) Between 1017~1018cm-3Between.
11. optoelectronic semiconductor component as described in claim 1, wherein the 3rd semiconductor layer include the 3rd dopant, with this Second dopant is different.
12. optoelectronic semiconductor component as claimed in claim 11, wherein the 3rd dopant include tellurium (Te), and the 3rd The concentration of dopant is more than 1019cm-3
13. optoelectronic semiconductor component as described in claim 1, also comprising substrate, led positioned at the first semiconductor layer or the second half Body layer side.
14. optoelectronic semiconductor component as described in claim 1, the light that wherein first luminescent layer is sent has first wave Long, the light which is sent has second wave length, which is less than 20nm with the second wave length difference.
15. optoelectronic semiconductor component as claimed in claim 14, the wherein first wave length and the second wave length between 600nm~ Between 620nm.
16. optoelectronic semiconductor component as described in claim 1, the wherein concentration of first dopant are second dopant 10 times or more.
17. optoelectronic semiconductor component as described in claim 1, the wherein barrier layer include group iii elements, the group iii elements Ratio of components is decremented to close to the part of second semiconductor layer close to the part of first semiconductor layer from the barrier layer.
18. optoelectronic semiconductor component as described in claim 1, wherein first dopant are same lead with second dopant Electrical dopant.
19. the energy rank of optoelectronic semiconductor component as described in claim 1, the wherein barrier layer is from close to second semiconductor layer Part successively decrease to close to the part of first semiconductor layer.
20. the energy rank of optoelectronic semiconductor component as claimed in claim 19, the wherein barrier layer is close to second semiconductor layer Be partially interposed between 2.3eV~2.5eV, be partially interposed in close to first semiconductor layer between 1.9eV~2.1eV.
21. first dopant in optoelectronic semiconductor component as described in claim 1, wherein first semiconductor layer is One deliberately dopant, second dopant are a non-deliberately dopant.
22. second dopant in optoelectronic semiconductor component as claimed in claim 21, wherein second semiconductor layer For a deliberately dopant.
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Citations (1)

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US5740192A (en) * 1994-12-19 1998-04-14 Kabushiki Kaisha Toshiba Semiconductor laser

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JPH0955522A (en) * 1995-08-10 1997-02-25 Japan Energy Corp Tunnel diode
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US5740192A (en) * 1994-12-19 1998-04-14 Kabushiki Kaisha Toshiba Semiconductor laser

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