CN104418314A - Formula and preparation process of aluminium phosphide - Google Patents
Formula and preparation process of aluminium phosphide Download PDFInfo
- Publication number
- CN104418314A CN104418314A CN201310391834.5A CN201310391834A CN104418314A CN 104418314 A CN104418314 A CN 104418314A CN 201310391834 A CN201310391834 A CN 201310391834A CN 104418314 A CN104418314 A CN 104418314A
- Authority
- CN
- China
- Prior art keywords
- aluminium
- aluminium phosphide
- formula
- preparation process
- red phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005952 Aluminium phosphide Substances 0.000 title claims abstract description 18
- PPNXXZIBFHTHDM-UHFFFAOYSA-N aluminium phosphide Chemical compound P#[Al] PPNXXZIBFHTHDM-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000009472 formulation Methods 0.000 title abstract description 3
- 238000002360 preparation method Methods 0.000 title abstract 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 12
- 239000004411 aluminium Substances 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 6
- 239000000460 chlorine Substances 0.000 claims abstract description 6
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000002917 insecticide Substances 0.000 abstract description 4
- 238000003958 fumigation Methods 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 231100000518 lethal Toxicity 0.000 description 3
- 230000001665 lethal effect Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 102000004316 Oxidoreductases Human genes 0.000 description 2
- 108090000854 Oxidoreductases Proteins 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000002438 mitochondrial effect Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000035806 respiratory chain Effects 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a formula and preparation process of aluminium phosphide. Aluminium phosphide is characterized by comprising the following raw components: about 200-500kg/t of red phosphorus, about 1300-1400kg/t of aluminium powder and 600-800kg/t of chlorine. The preparation process of aluminium phosphide is characterized by subjecting red phosphorus and the aluminium powder to reaction and preparing aluminium phosphide after a chlorination process. A broad-spectrum, efficient and multifunctional fumigation insecticide is prepared by adopting the formula and the preparation process.
Description
Technical field
The invention belongs to technical field of pesticide manufacture, be specifically related to a kind of formula and manufacturing process of aluminium phosphide.
Background technology
Aluminium phosphide, normally as a kind of broad spectrum fumigating insecticide, is mainly used in the storage pest of smoked kill goods, the various pests in space, the grain storage pest of grain, the grain storage pest of seed, the outdoor rodent etc. in cave.The phosphine gas of high poison can be produced after aluminium phosphide water suction immediately, enter in body by the respiratory system of insect animals such as (or) mouse, act on respiratory chain and the Terminal oxidase of cell mitochondrial, suppress its eupnea and lethal.
summary of the invention
The present invention proposes a kind of formula and manufacturing process of aluminium phosphide, and the present invention substantially increases sterilizing ability, respond well.Technical scheme is: its feature feed composition is: the about 200-500kg/t of red phosphorus, the about 1300-1400kg/t of aluminium powder, chlorine 600-800kg/t form.Its manufacturing process is that red phosphorus and aluminium powder react, obtained aluminium phosphide after chlorination flow process.What produced by the present invention is a kind of wide spectrum, efficient, multi-functional fumigating insecticide.
This agricultural chemicals i.e. tool outer protection and therapeutic action but also have interior suction sterilizing function.
Aluminium phosphide is a kind of broad spectrum fumigating insecticide, can with some other combined use of pesticides, with expanding prevention scope, the lasting period is long.The phosphine gas of high poison can be produced after aluminium phosphide water suction immediately, enter in body by the respiratory system of insect animals such as (or) mouse, act on respiratory chain and the Terminal oxidase of cell mitochondrial, suppress its eupnea and lethal.In anaerobic situation, phosphuret-(t)ed hydrogen is not easily sucked by insect, does not show toxicity, and in aerobic situation, phosphuret-(t)ed hydrogen can be inhaled into and make insect lethal.Insect can produce paralysis or protective stupefaction in the phosphuret-(t)ed hydrogen of high density, breathes and reduces.Formulation products can be fumigated raw grain, finished product of grain, oil plant and potato and do.If during stifling seed, its moisture requires difference because of Different Crop.
the present invention has following beneficial effect:
The present invention substantially increases sterilizing ability, and characteristic is also fine, and economic benefit and social benefit improve greatly.
Embodiment:
Embodiment 1:
Its feed composition of the present invention is: red phosphorus 100kg/t, aluminium powder 1000kg/t chlorine 600kg/t form, and its manufacturing process is that red phosphorus and aluminium powder react, through chlorination flow process, and the obtained aluminium phosphide of reaction after alkalization flow process.
Embodiment 2:
Feed composition is: red phosphorus 300kg/t, aluminium powder 1500kg/t, and chlorine 800kg/t forms, and its manufacturing process is that red phosphorus and aluminium powder react, through the obtained aluminium phosphide of chlorination flow process reaction.
Embodiment 3:
Feed composition is: red phosphorus 200kg/t, aluminium powder 1600kg/t, chlorine 700kg/t form, and its manufacturing process is that red phosphorus and aluminium powder react, through the obtained aluminium phosphide of chlorination flow process reaction
.
Claims (1)
1. the formula of aluminium phosphide and manufacturing process, its feature feed composition is: the about 200-500kg/t of red phosphorus, the about 1300-1400kg/t of aluminium powder, chlorine 600-800kg/t form, and its manufacturing process is that red phosphorus and aluminium powder react, obtained aluminium phosphide after chlorination flow process.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310391834.5A CN104418314A (en) | 2013-09-02 | 2013-09-02 | Formula and preparation process of aluminium phosphide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310391834.5A CN104418314A (en) | 2013-09-02 | 2013-09-02 | Formula and preparation process of aluminium phosphide |
Publications (1)
Publication Number | Publication Date |
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CN104418314A true CN104418314A (en) | 2015-03-18 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310391834.5A Pending CN104418314A (en) | 2013-09-02 | 2013-09-02 | Formula and preparation process of aluminium phosphide |
Country Status (1)
Country | Link |
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CN (1) | CN104418314A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107646835A (en) * | 2017-08-22 | 2018-02-02 | 广西壮族自治区烟草公司百色市公司 | A kind of sustained release preparation for preventing and treating tobacco storage insect and preparation method thereof |
-
2013
- 2013-09-02 CN CN201310391834.5A patent/CN104418314A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107646835A (en) * | 2017-08-22 | 2018-02-02 | 广西壮族自治区烟草公司百色市公司 | A kind of sustained release preparation for preventing and treating tobacco storage insect and preparation method thereof |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150318 |